Claims
- 1. A polyurethane composition suitable for the production of optical lenses having a refractive index higher than 1.6 and a glass transition temperature higher than 100.degree. C., said polyurethane obtained by reacting a first component made of an at least difunctional polyisocyanate free of intramolecular sulfur atoms and a second component made of an acyclic saturated monomer having at least three reactive groups with respect to isocyanates per molecule, in respective amounts, to polymerize through formation of thiocarbamate and, optionally, carbamate links, wherein said reactive groups are --SH mercapto groups for at least 40% in number and are present in a proportion at least amounting to 45% by weight with respect to the molecular weight of said monomer.
- 2. A polyurethane composition according to claim 1, wherein said first component is a difunctional arylalkyl isocyanate and the composition does not comprise any sulphur-containing isocyanate.
- 3. A composition according to claim 2, wherein said first constituent is xylylene-di-isocyanate.
- 4. A composition according to claim 2 wherein said monomer is an acyclic aliphatic compound at least tri-functional which comprises at least three carbon atoms per molecule, half at least of which are provided with a reactive --SH or --OH function, half at least of these reactive functions being --SH mercapto groups.
- 5. A composition according to claim 4 wherein said monomer comprises between three and six carbon atoms, and in that among its reactive functions at least 50% in number are --SH mercapto groups, the proportion of said reactive functions being at lest 55% by weight with respect to the molecular weight of said monomer.
- 6. A composition according to claim 1 wherein said monomer is is a linear or branched aliphatic alkane chain, in which at least 3/4 of the carbon atoms are bearers of said reactive groups.
- 7. A composition according to claim 6, wherein said monomer is selected from among the following compounds: 2,3-dimercapto propanol, dithioerythritol, trithioglycerin, or tetramercaptobutane.
- 8. A composition according to claim 6, wherein said monomer is pentaerythrithiol, provided that the polyisocyanate is not xylylene-diisocyanate.
- 9. A composition according to claim 5, wherein the proportion of said reactive functions is at least 70% by weight with respect to the molecular weight of said monomer.
- 10. A composition according to claim 6, wherein all of the carbon atoms are bearers of said reactive groups.
- 11. A composition according to claim 6, wherein all of the reactive groups are mercapto groups.
- 12. A composition according to claim 10, wherein all of the reactive groups are mercapto groups.
- 13. A composition according to claim 6, wherein said monomer is dithioerythrithiol, trithioglycerin, or tetramercaptobutane.
- 14. A composition according to claim 8, wherein the isocyanate is diethylbenzene diisocyanate.
- 15. A composition according to claim 3, wherein said monomer is dithioerythritol, trithioglycerin, or tetramercaptobutane.
- 16. An optical lens having a refractive index higher than 1.6, a constringence coefficient at least on the order of 30, and a glass transition temperature higher than 100.degree. C., said optical lens comprising a polyurethane composition according to claim 1.
- 17. An optical lens according to claim 16, wherein the refractive index is higher than 1.64.
- 18. An optical lens having a refractive index higher than 1.6, a constringence coefficient at least on the order of 30, and a glass transition temperature higher than 100.degree. C., said optical lens comprising a polyurethane composition according to claim 7.
- 19. An optical lens having a refractive index higher than 1.6, a constringence coefficient at least on the order of 30, and a glass transition temperature higher than 100.degree. C., said optical lens comprising a polyurethane composition according to claim 9.
- 20. A composition according to claim 6, wherein said monomer is trithioglycerine or tetramercaptobutane.
- 21. A process for the production of a polymeric lens, said process comprising:
- mixing 2,3-dimercaptopropanol and xylylene diisocyanate in a ratio such that the sum of mercapto and hydroxy groups is substantially equal to the sum of isocyanate groups;
- adding a catalytic amount of a polymerization catalyst;
- degassing the resultant mixture and placing the degassed mixture in an optical lens mold;
- conducting polymerization in said mold according to a temperature cycle comprising about three hours to pass from ambient temperature to about 80.degree. C., then about three hours of polymerization maintained at about 80.degree. C., followed by an increase in temperature from about 80.degree. to about 130.degree. C. for a period of about two hours, and maintaining the polymerization temperature for three hours at about 130.degree. C.; and
- removing resultant lens from the mold in order to obtain a perfectly transparent lens having a refractive index of about 1.622, a constringence of about 37, a density of about 1.28 and a glass transition temperature of about 130.degree. C.
- 22. A composition according to claim 1, wherein the polyisocyanate is free of intramolecular oxygen atoms.
- 23. An optical lens having a refractive index higher than 1.6, a constringence coefficient at least on the order of 30, and a glass transition temperature higher than 100.degree. C., said optical lens comprising a polyurethane composition according to claim 14.
Priority Claims (1)
Number |
Date |
Country |
Kind |
89 09492 |
Jul 1989 |
FRX |
|
Parent Case Info
This application is a continuation of application Ser. No. 07/552,177, filed Jul. 13, 1990, now abandoned.
US Referenced Citations (5)
Number |
Name |
Date |
Kind |
3984456 |
Guthrie et al. |
Oct 1976 |
|
4689387 |
Kajimoto et al. |
Aug 1987 |
|
4775733 |
Kanemura et al. |
Oct 1988 |
|
4788083 |
Dammann et al. |
Nov 1988 |
|
4946923 |
Nagata et al. |
Aug 1990 |
|
Foreign Referenced Citations (3)
Number |
Date |
Country |
2280888 |
Apr 1989 |
AUX |
2995089 |
Aug 1989 |
AUX |
3713689 |
Apr 1990 |
AUX |
Continuations (1)
|
Number |
Date |
Country |
Parent |
552177 |
Jul 1990 |
|