Claims
- 1. A polymerizable compound represented by the following formula (1):
- 2. A compound according to claim 1, wherein each R1 is independently at least one member selected from the organic residues represented by the following structural formulae (6) to (12):
- 3. A compound according to claim 1 or 2, wherein R2 is an organic residue derived from a compound selected from the group consisting of ethylene glycol, propylene glycol, 1,3-propanediol, 1,4-butanediol, 1,6-hexanediol, neopentyl glycol, glycerin, trimethylolethane, trimethylolpropane, 1,4-cyclohexanediol, 1,4-cyclohexanedimethanol, bisphenol A, bisphenol A propylene oxide adduct, bisphenol A ethylene oxide adduct, brominated bisphenol A, hydrogenated bisphenol A, bisphenol F, phenol novolak resin, cresol novolak resin, 1,2-cyclohexanedicarboxylic acid, 1,3-cyclohexanedicarboxylic acid, 1,4-cyclohexanedicarboxylic acid, 3-cyclohexene-1,2-dicarboxylic acid, phthalic acid, isophthalic acid and terephthalic acid.
- 4. A compound according to any one of claims 1 to 3, wherein each R1 is independently at least one member selected from the organic residues represented by the following structural formulae (6) to (12), and R2 is an organic residue derived from a compound selected from the group consisting of ethylene glycol, propylene glycol, 1,3-propanediol, 1,4-butanediol, 1,6-hexanediol, neopentyl glycol, glycerin, trimethylolethane, trimethylolpropane, 1,4-cyclohexanediol, 1,4-cyclohexanedimethanol, bisphenol A, bisphenol A propylene oxide adduct, bisphenol A ethylene oxide adduct, brominated bisphenol A, hydrogenated bisphenol A, bisphenol F, phenol novolak resin, cresol novolak resin, 1,2-cyclohexane-dicarboxylic acid, 1,3-cyclohexanedicarboxylic acid, 1,4-cyclohexanedicarboxylic acid, 3-cyclohexene-1,2-dicarboxylic acid, phthalic acid, isophthalic acid and terephthalic acid:
- 5. A process for producing a polymerizable compound as set forth in any one of claims 1 to 4, comprising:
a step of performing an addition reaction between at least one compound selected from the compounds represented by the following formula (4) and at least one compound selected from the compounds represented by the following formula (5) in the presence of a catalyst to obtain a polymerizable compound: 22wherein R4 represents an organic residue derived from an alcohol compound, a phenol compound or a carboxylic acid compound, and q represents an integer of 1 or more; 23wherein R5 represents at least one member selected from an alkylene group, a branched alkylene group, a cycloalkylene group and an arylene group, and n represents an integer of 0 to 20.
- 6. A process for producing a polymerizable compound as set forth in any one of claims 1 to 4, comprising:
a step of performing an addition reaction between at least one compound selected from the compounds represented by the following formula (4), at least one compound selected from the compounds represented by the following formula (5) and at least one compound selected from the compounds represented by the following formula (13) in the presence of a catalyst to obtain a polymerizable compound: 24wherein R4 represents an organic residue derived from an alcohol compound, a phenol compound or a carboxylic acid compound, and q represents an integer of 1 or more; 25wherein R5 represents at least one member selected from an alkylene group, a branched alkylene group, a cycloalkylene group and an arylene group, and n represents an integer of 0 to 20; 26wherein R6 represents H or CH3.
- 7. A process according to claim 5 or 6, wherein R4 is at least one organic residue derived from ethylene glycol, propylene glycol, 1,3-propanediol, 1,4-butanediol, 1,6-hexanediol, neopentyl glycol, glycerin, trimethylolethane, trimethylolpropane, 1,4-cyclohexanediol, 1,4-cyclohexanedimethanol, bisphenol A, bisphenol A propylene oxide adduct, bisphenol A ethylene oxide adduct, brominated bisphenol A, hydrogenated bisphenol A, bisphenol F, phenol novolak resin, cresol novolak resin, 1,2-cyclohexanedicarboxylic acid, 1,3-cyclohexanedicarboxylic acid, 1,4-cyclohexanedicarboxylic acid, 3-cyclohexene-1,2-dicarboxylic acid, phthalic acid, isophthalic acid and terephthalic acid.
- 8. A process according to any one of claims 5 to 7, wherein each R5 is independently at least one member selected from the organic residues represented by the following structural formulae (6) to (12):
- 9. A process according to any one of claims 5 to 8, wherein the catalyst is at least one member selected from the group consisting of metal halides, pyridine compounds, pyridinium salts, tertiary amines, quaternary ammonium salts, phosphine compounds and phosphonium salts.
- 10. A process according to claim 9, wherein the catalyst is at least one member selected from the group consisting of tin chloride, pyridine, isoquinoline, quinoline, 2,4,6-tris(dimethylaminomethyl)-phenol, triethylamine, triphenylphosphine, benzyltrimethylammonium salts, benzyltriethylammonium salts, ethyltriphenylphosphonium salts, tetraphenylphosphonium salts and benzyltriphenylphosphonium salts.
- 11. A process according to any one of claims 5 to 8, wherein the catalyst is a catalyst having a radical polymerization-functional group.
- 12. A process according to claim 11, wherein the catalyst is at least one member selected from the group consisting of 2-vinylpyridine, 3-vinylpyridine, 4-vinylpyridine, N,N-dimethylaminoethyl methacrylate, N,N-dimethylaminoethyl acrylate, N-(3-N′,N′-dimethylaminopropyl)-acrylamide, N-(3-N′,N′-dimethylaminopropyl)-methacrylamide, trimethylmethacryloyloxyethylammonium salts, trimethylacryloyloxyethylammonium salts, trimethylacryloylaminopropylammonium salts, trimethylmethacryloylaminopropylammonium salts and dimethyldiallylammonium salts.
- 13. A polymerizable composition comprising at least one polymerizable compound as set forth in any one of claims 1 to 4 as an essential component.
- 14. A composition according to claim 13, which contains from 0.1 to 10 parts by mass of at least one radical polymerization initiator per 100 parts by mass of all curable components in the polymerizable composition.
- 15. A cured product obtained by curing a polymerizable composition as set forth in claim 13 or 14.
- 16. A process for producing a cured product comprising curing a polymerizable composition as set forth in claim 13 or 14.
- 17. A process according to claim 16, wherein the polymerization composition is heat cured or cured by an active energy.
CROSS-REFERENCE TO RELATED APPLICATION
[0001] This application is an application filed under 35 U.S.C. § 111(a) claiming benefit pursuant to 35 U.S.C. § 119(e)(1) of the filing date of the Provisional Application 60/308,862 filed Aug. 1, 2001, pursuant to 35 U.S.C. § 111(b).
PCT Information
Filing Document |
Filing Date |
Country |
Kind |
PCT/JP02/07569 |
7/25/2002 |
WO |
|