Claims
- 1. A polymer containing a diketopyrrolopyrrole of the formula (I): ##STR41## wherein R.sub.1 is a group of formula (II)
- --Y--X--Z--Q (II),
- wherein
- Y is --CR.sub.3 R.sub.4, --SO.sub.2 --, --CO--, --Si(Hal).sub.2 --, --POHal--, wherein R.sub.3 and R.sub.4 are each independently of the other hydrogen or C.sub.1 -C.sub.4 alkyl, and Hal is halogen,
- X is an unsubstituted or substituted carbocylic or heterocyclic arylene group,
- Z is a single bond, uninterrupted linear or branched C.sub.1 -C.sub.30 alkylene, or linear or branched C.sub.1 -C.sub.30 alkylene, or linear or branched C.sub.2 -C.sub.30 alkylene which is interrupted once or more than once by a hetero atom, --CH.dbd.CH--, --C.tbd.C--, --N.dbd.CH--, --CH.dbd.N-- or --NH--, or is C.sub.5 -C.sub.12 cycloalkylene,
- Q is --OH, --SH, --NH.sub.2, glycidyl, 1,2-epoxyethyl, ##STR42## --CHO, --NCO, --CH.dbd.CH.sub.2, --C(CH.sub.3).dbd.CH.sub.2, --OCO--CH.dbd.CH.sub.2, --OCO--C(Me).dbd.CH.sub.2, --CH.sub.2 --CH.dbd.CH.sub.2, --CH.sub.2 --OH, --CO--CH.dbd.CH.sub.2, --CO--C(CH.sub.3).dbd.CH.sub.2, C.sub.5 -C.sub.7 cycloalkeny, ##STR43## --CONHR.sub.6, --COOR.sub.6, --COR.sub.6, wherein R.sub.6 is hydrogen or C.sub.1 -C.sub.6 alkyl, ##STR44## wherein s is an integer from 1 to 6, and R.sub.2 is C.sub.1 -C.sub.6 alkyl, ##STR45## or R.sub.1, and R.sub.7 is hydrogen or C.sub.1 -C.sub.6 alkyl, and
- A and B are each independently of the other a group of formula ##STR46## wherein R.sub.8 and R.sub.9 are each independently of the other hydrogen, halogen, C.sub.1 -C.sub.18 alkyl, C.sub.1 -C.sub.18 alkoxy, C.sub.1 -C.sub.18 alkymercapto, C.sub.1 -C.sub.18 alkylamino, C.sub.1 -C.sub.18 alkoxycarbonyl, C.sub.1 -C.sub.18 alkylaminocarbonyl, --CN, --NO.sub.2, trifluoromethyl, C.sub.5 -C.sub.6 cycloalkyl, --CH.dbd.N--(C.sub.1 -C.sub.18 alkyl), ##STR47## imidazolyl, pyrrazolyl, triazolyl, piperazinyl, pyrrolyl, oxazolyl, benzoxazolyl, benzothiazolyl, benzimidazolyl, morpholinyl, piperidinyl or pyrrolidinyl,
- G is --CH.sub.2 --, --CH(CH.sub.3)--, --C(CH.sub.3).sub.2 --, --CH.dbd.N--, --N.dbd.N--, --O--, --S--, --SO--, --SO.sub.2 --, --CONH--
- or --NR.sub.7 --,
- R.sub.10 and R.sub.11 are each independently of the other hydrogen, halogen, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.18 alkoxy or --CN, R.sub.12 and R.sub.13 are each independently of the other hydrogen, halogen or C.sub.1 -.sub.6 alkyl,
- which polymer is obtained by polyreacting at least one diketopyrrolopyrrole of the formula (I) or a mixture consisting of
- (A) from 0.5 to 20% by weight, based on the sum of the components (A) and (B), of a mixture consisting of
- (a) from 100 to 1% by weight, based on the sum of the components (a) and (b), of a diketopyrrolopyrrole of the formula (I),
- (b) from 0 to 99% by weight,
- based on the sum of the components (a) and (b), of the diketopyrrolopyrrole of formula (V), ##STR48## wherein A and B are as defined for formula (I), R.sub.15 is a radical containing a polyreactive group, and
- R.sub.16 is C.sub.1 -C.sub.6 alkyl, ##STR49## or R.sub.15, and (B) from 99.5 to 80% by weight, based on the sum of the components (A) and (B), of a monomer which is copolymerisable with the diketopyrrolopyrroles of the formulae (I) and (V),
- the sums of (A) and (B) and of (a) and (b) each making up 100% by weight.
- 2. A process for the preparation of the polymer according to claim 1, which comprises polyreacting at least one diketopyrrolopyrrole of the formula (I) or a mixture consisting of
- (A) from 0.5 to 20% by weight, based on the sum of the components (A) and (B), of a mixture consisting of
- (a) from 100 to 1% by weight, based on the sum of the components (a) and (b), of a diketopyrrolopyrrole of the formula (I),
- (b) from 0 to 99% by weight, based on the sum of the components (a) and (b), of the diketopyrrolopyrrole of formula (V), and
- (B) from 99.5 to 80% by weight, based on the sum of the components (A) and (B), of a monomer which is copolymerisable with the diketopyrrolopyrroles of the formulae (I) and (V),
- the sums of (A) and (B) and of (a) and (b) each making up 100% by weight.
- 3. A method for colouring high molecular weight organic materials, for formulations of decorative cosmetics, for the preparation of inks, paint systems, fluorescent brighteners, photocell aggregates and coloured photoresists said method comprising admixing the polymer according to claim 1 with the high molecular organic materials.
Parent Case Info
This is a divisional of U.S. patent application Ser. No. 09/119,434 filed Jul. 20, 1998 now U.S. Pat. No. 5,919,944.
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Divisions (1)
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Number |
Date |
Country |
Parent |
119434 |
Jul 1998 |
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