Claims
- 1. A propoxylated allyl alcohol polymer derivative which comprises the reaction product of:
- (a) a copolymer which comprises recurring units of:
- (1) allyl alcohol; and
- (2) a propoxylated allyl alcohol of the formula
- CH.sub.2 .dbd.CH--CH.sub.2 --(A).sub.n --OH
- in which A is an oxypropylene group, and n, which is the average number of oxypropylene groups in the propoxylated allyl alcohol, has a value within the range of about 1 to about 5;
- wherein the copolymer has an average hydroxyl functionality within the range of about 2 to about 10, and a number average molecular weight within the range of about 300 to about 5000; and
- (b) a member selected from the group consisting of:
- (1) an anhydride or a di- or polycarboxylic acid, to produce a thermoset polyester;
- (2) a polyisocyanate or an isocyanate-terminated prepolymer, to produce a polyurethane;
- (3) an anhydride- or carboxylic acid-containing polymer, to produce a thermoset resin;
- (4) a melamine resin, to produce a melamine-based polymer;
- (5) an unsaturated fatty acid, to produce an alkyd;
- (6) an unsaturated fatty acid, a low molecular weight polyol, and a polyisocyanate to produce a polyurethane-modified alkyd;
- (7) ammonia or a primary or secondary amine, to produce a polyamine;
- (8) acrylic acid or an acrylic acid derivative, to produce an acrylate.
- 2. A polymer blend which comprises:
- (a) a copolymer which comprises recurring units of:
- (1) allyl alcohol; and
- (2) a propoxylated allyl alcohol of the formula
- CH.sub.2 .dbd.CH--CH.sub.2 --(A).sub.n --OH
- in which A is an oxypropylene group, and n, which is the average number of oxypropylene groups in the propoxylated allyl alcohol, has a value within the range of about 1 to about 5;
- wherein the copolymer has an average hydroxyl functionality within the range of about 2 to about 10, and a number average molecular weight within the range of about 300 to about 5000; and
- (b) one or more polymers selected from the group consisting of polyether polyols, phenolic resins, and epoxy resins.
- 3. A propoxylated allyl alcohol polymer derivative which comprises the reaction product of:
- (a) the polymer blend of claim 2; and
- (b) a member selected from the group consisting of:
- (1) an anhydride or a di- or polycarboxylic acid, to produce a thermoset polyester;
- (2) a polyisocyanate or an isocyanate-terminated prepolymer, to produce a polyurethane;
- (3) an anhydride- or carboxylic acid-containing polymer, to produce a thermoset resin:
- (4) a melamine resin, to produce a melamine-based polymer;
- (5) an unsaturated fatty acid, to produce an alkyd;
- (6) an unsaturated fatty acid, a low molecular weight polyol, and a polyisocyanate to produce a polyurethane-modified alkyd;
- (7) ammonia or a primary or secondary amine, to produce a polyamine;
- (8) acrylic acid or an acrylic acid derivative, to produce an acrylate.
- 4. A propoxylated allyl alcohol polymer derivative which comprises the reaction product of:
- (a) a polymer which consists essentially of recurring units of a propoxylated allyl alcohol of the formula:
- CH.sub.2 .dbd.CH--CH.sub.2 --(A).sub.n --OH
- in which A is an oxypropylene group, and n, which is the average number of oxypropylene groups in the propoxylated allyl alcohol, has a value within the range of about 1 to about 5;
- wherein the homopolymer has an average hydroxyl functionality within the range of about 2 to about 10, and a number average molecular weight within the range of about 300 to about 5000; and
- (b) a member selected from the group consisting of:
- (1) an anhydride or a di- or polycarboxylic acid, to produce a thermoset polyester;
- (2) a polyisocyanate or an isocyanate-terminated prepolymer, to produce a polyurethane;
- (3) an anhydride- or carboxylic acid-containing polymer, to produce a thermoset resin;
- (4) a melamine resin, to produce a melamine-based polymer;
- (5) an unsaturated fatty acid, to produce an alkyd;
- (6) an unsaturated fatty acid, a low molecular weight polyol, and a polyisocyanate to produce a polyurethane-modified alkyd;
- (7) ammonia or a primary or secondary amine, to produce a polyamine;
- (8) acrylic acid or an acrylic acid derivative, to produce an acrylate.
- 5. A polymer blend which comprises:
- (a) a polymer which consists essentially of recurring units of a propoxylated allyl alcohol of the formula
- CH.sub.2 .dbd.CH--CH.sub.2 --(A).sub.n --OH
- in which A is an oxypropylene group, and n, which is the average number of oxypropylene groups in the propoxylated allyl alcohol, has a value within the range of about 1 to about 5;
- wherein the polymer has an average hydroxyl functionality within the range of about 2 to about 10, and a number average molecular weight within the range of about 300 to about 5000; and
- (b) one or more polymers selected from the group consisting of polyether polyols, phenolic resins, and epoxy resins.
- 6. A propoxylated allyl alcohol polymer derivative which comprises the reaction product of:
- (a) the polymer blend of claim 5; and
- (b) a member selected from the group consisting of:
- (1) an anhydride or a di- or polycarboxylic acid, to produce a thermoset polyester;
- (2) a polyisocyanate or an isocyanate-terminated prepolymer, to produce a polyurethane;
- (3) an anhydride- or carboxylic acid-containing polymer, to produce a thermoset resin;
- (4) a melamine resin, to produce a melamine-based polymer;
- (5) an unsaturated fatty acid, to produce an alkyd;
- (6) an unsaturated fatty acid, a low molecular weight polyol, and a polyisocyanate to produce a polyurethane-modified alkyd;
- (7) ammonia or a primary or secondary amine, to produce a polyamine;
- (8) acrylic acid or an acrylic acid derivative, to produce an acrylate.
Parent Case Info
This is a division of application Ser. No. 08/234,745 filed Apr. 28, 1994, now U.S. Pat. No. 5,451,652.
US Referenced Citations (14)
Foreign Referenced Citations (3)
Number |
Date |
Country |
45-28786 |
Sep 1970 |
JPX |
185514 |
Aug 1986 |
JPX |
1240227 |
Jul 1971 |
GBX |
Non-Patent Literature Citations (2)
Entry |
"Solubility Parameters . . . " H. Ahmad; Journal of Oil and Colour Chemists Assoc. 63(7) pp. 263-270; Jul. 1980. |
Swern et al., J. Am. Chem. Soc., 71 (1949) 1152. |
Divisions (1)
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Number |
Date |
Country |
Parent |
234745 |
Apr 1994 |
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