Patent Grant
6838508
1. Field of the Invention
The present invention relates to a polymer nanocomposite, and in particular to a polyolefin-based nanocomposite prepared by melt kneading.
2. Description of the Related Art
Nanocomposites include dispersion phase having dimensions in the size ranging from 1 nm to 100 nm. The distribution of the nano-sized inorganic dispersion phase makes the nanocomposites exhibit molecular structure characteristics, such as reduced size of the inorganic particles in the dispersion, high aspect ratio of the inorganic particles, layered reinforced structure and enforced ionic bonding between inorganic phase and organic phase. The nanocomposites possessing the above characteristics accordingly can be fabricated into products that requires light-weight, high strength, high rigidity, high heat resistance, superior flame retardance, low moisture absorbability, and low permeability.
Commercially available polymer/clay dispersed nanocomposites are mainly based on Nylon 6. For example, UBE Industries Ltd. Japan has successfully produced Nylon 6-based nanocomposites, which can be fabricated into automobile parts, and high non-permeable packing films. Unitika Co., Ltd., has developed a Nylon 6-based nanocomposite which can be fabricated into automobile parts or be used as compounding materials of engineering plastics.
Nanocomposites based on other polymers are now attracting great attention from some plastics companies in the world. For example, nylon 6/clay nanodispersion formed by blend kneading developed by Allied-Signal Inc., U.S.A.; mamoacrylic paint and nanorubber developed by Kabushiki Kaisha Toyota Chuo Kenkyusho, Japan; nanonylon 66 engineering plastics by Showa Denko Kabushiki Kaisha, Japan; and nanoPET composites by Nanoco company, U.S.A are all under investigation for commercialization.
Polyolefin-based nanocomposites are now becoming more important, because a large amount of this kind of composites is used in various industries. For example, polypropylene-based nanocomposites have been largely used in automobile-related industries to replace conventional polypropylene composites.
However, since polyolefins, such as polypropylene, are non-polar functional polymers, the compatibility between the organic polyolefin and the inorganic dispersion phase, usually clay material, is inferior. To overcome the compatibility problem, one approach is to tropically functionalize the polyolefins by using a catalyst to produce polar functional groups, followed by melt kneading the modified polyolefin with organic clay material. One disadvantage of this approach is the use of a catalyst for the modification of the polyolefin. Another approach is to introduce a small amount of polymer into the organic layered clay material to swell the layered clay material. The swollen clay material is then blended with compatilizer, followed by blending with polyolefin in a batch reactor to obtain nanocomposite material. This approach involves a number of processing steps, and thus the economic effect is not high. There is another proposal which solves the compatibility problem by organization or organomodification treatment. For example, a layered-structure clay material may be modified with organic moieties attached thereto through ionic bonding, where the clay material is dispersed in an aqueous solution of an organic onium salt so as to cause the ion-exchange to take place. By doing so, the compatibility of the layered-structure clay material, the compatilizer and the polyolefin is improved. However, only the surface of the particles of the layered-structure clay material is modified and the dispersion of the particles of the clay materials is improved, the interlayer spacing (d-spacing) of the layered clay material is not improved and the compatibility problem is not completely solved.
It is therefore an object of the invention to provide a polyolefin-based nanocomposite that exhibits superior compatibility.
It is another object of the invention to provide a melt kneading process for the preparation of a polyolefin-based nanocomposite material.
It is further an object of the invention to provide a method of modifying a layered clay material.
The above objects of the invention are attained by modifying the layered-structure clay material by intercalating a modifier, a quaternary ammonium containing at least one terminal reactive group and —Si—O—Si linkage into the interlayers of the layered-structure clay material by means of ion-exchange. By using the modification method mentioned above, the inorganic layered-structure clay materials become hydrophobic and reactive-group carrying. Thus, when the modified layered clay material is then blended with a polyolefin compatilizer containing polar reactive groups, followed by melt kneading with the polyolefin, a polyolefin-based nanoocmposite material with superior compatibility is obtained.
The layered clay materials which may be suitably used according to the invention are layer-structured silicate minerals having a cation exchange capacity(CEC) of 50-200 meq/100 g. Examples of these silicate minerals include but are not limited to smectite clay, vermiculite, halloysite, sericite, and mica. Among them, smectite clay is preferred. Smectite clay includes montmorillonite, saponite, beidellite, nontronite, hectorite and stevensite etc.
According to the invention, the modifier, quaternary ammonium containing at least one terminal reactive group and —Si—O—Si linkage is prepared by subjecting a quaternary ammonium having an alkoxysilyl group and a coupling agent to a sol-gel reaction. The ammonium salts having alkoxysilyl group, which are suitably used according to the invention, have the general formula as indicated below:
wherein R1 is a alkyl having at least 15 carbon atoms; R2, R3 can be same of different and are an alkyl having 1-12 carbon atoms;
R4 and R5 can be same or different and are methoxy or ethoxy; Y is a terminal group having a substitutent selected from the group consisting of carboxy, hydroxy, amino, vinyl, sulfo and epoxy. The coupling agent used in the invention is an alkoxysilane having reactive terminal groups. The reactive terminal groups include carboxy, hydroxy, amino, vinyl sulfo and epoxy.
The modification of the layered clay materials is conducted by immersing the layered clay materials into an aqueous solution containing the modifier obtained by the above-mentioned process for about 2-3 hours to cause the ion-exchange to take place. After the ion-exchange process is completed, the immersed layered clay material is then washed with hot water, and dried to remove residual ammonium ions. The modified layered clay materials so obtained have a d-spacing of at least 30° A.
The organomodified layered clay materials are then blended with polar reactive group-containing compatilizers to obtain a homogeneous blend with the layered clay materials are further exfoliated and intercalated. The compatilizers suitably used in this invention are polyolefin compatibilizers, such as anhydride-modified oligomers or hydroxy-containing polyolefin oligomers. Among them, polypropylene-maleic anhdydride copolymer is preferred. The blending is usually carried out by first dissolving polyolefin compatibilizers in an organic solvent, such as toluene and xylene in which the polyolefin compatibilizer is soluble and the organomodified clay material is evenly dispersed, at an elevated temperature, such as 90° C. After a solution of the polyolefin compatibilizer is formed, the solution is then blended with the organomodified clay material at an elevated temperature, such as at 110° C., and dried to obtain a homogeneous blend. The weight ratio of the organomodified clay material and the polyolefin compatibilizer is 1/1-1/3.
According to the process of preparing a polyolefin-based nanocomposite of the invention, the homogeneous blend so obtained is then subject to a melt kneading process with a polyolefin or a matrix polymer containing polyolefin. Examples of the polyolefin or matrix polymer containing polyolefin that may be used for this purpose include polyethylene, polypropylene, poly(1-butene), poly(1-hesene), polyisopropylene, poly(3-methyl-1-hexene), poly(4-methyl-1-hexene), copoly(ethylene/propylene), copoly(ethylene/1-butene), copoly(propylene/4-methyl-1-pentene), copoly(propylene/1-butene), copoly(ethylene/propylene/1-butene), and copoly(decene/1-methyl-1-pentene) and the like. Among them, polypropylene is preferred.
According to the invention, as an alternative, the blending step of the organomodified clay material and the polyolefin compatilizer can be omitted. That is, the three ingredients, the matric polymer containing polyolefin, the polyolefin compatilizer and the organomodified clay material can be directly subject to a melt kneading process to obtain the polyolefin-based nanocomposite material of the invention. In the melt kneading process, the reactive functional groups of the organomodified clay material and the compatilizer are reacted.
The weight ratio of the matrix polymer containing polyolefin, the polyolef in compatilizer and the organomodified layered clay material is in the range of 40-99.8%: 0.1-30%: 0.1-30%, preferably in the range of 70-99.8%: 0.1-10%: 0.1-20%.
The melt kneading is usually conducted in a closed system by using a melt-kneading device, such as a Banbury mixer with a rotator, a single screw or twin-screw extruder or a kneader at a temperature that is 20-30° C. higher than the melting point of the polyolefin or polymer matrix containing the polyolefin. Usually, the melt kneading is carried out at a temperature of at least 180° C.
In the kneading process, various additives, which are conventionally used in a polyolefin, such as inorganic or organic fillers, anti-oxidants, UV absorbents, light stabilizers, anti-static agents, plasticizers, flame-retardants, lubricants and the like may be added at such a level that such an additive does not interfere with the advantages of the invention.
The polyolefin/clay nanocomposite materials so obtained usually have a d-spacing greater than 30° A. or preferably greater than 40° A. Also, the layered clay materials within the composites are exfoliated and derivatized to an extent that is intercalated and fully exfoliated. In this manner, by adjusting the weight ratio of the clay material and the compatibilizer, a nanocomposite with superior physical and mechanical characteristics can be obtained. As can be seen from the hereinafter-stated examples, the obtained nanocomposite material has a heat deformation temperature (H.D.T) of 138° C. which is 18° C. higher than the H.D.T. of a composite which is formed by a conventional method. The nanocomposite materials prepared by the method of the invention also exhibit a flexural modulus (F.M.), which is 1.17 times of that of a composite material prepared by a conventional method.
The reactive terminal groups of the layered organomodified clay materials are reacted directly with the compatilizer in the subsequent melt kneading process to form chemical bonds in the interlayers of the layered clay materials, and thus the compatibility of the polyolefin and the clay materials is further improved. Moreover, the process of the invention for the preparation of polyolefin-based nanocomposite materials involves no polymerization or catalyzed reaction, and thus is more suitable for use in industry.
Without any intent to limit the scope of the invention, the present invention will be hereinafter explained in more detail with reference to the following examples and accompanying drawings in which:
50 grams of white montmorillonite (Clay 1,CEC=78 meq/100 g, d-spacing=15° A., Taiwan PeiKon Ceramics Co., Ltd) was dissolved in 4000 ml of deionized water and agitated at room temperature for 4 hours to allow swell to give an aqueous solution of clay. 38.25 grams of octodecyldimethyl(3-trimethoxysilylpropyl)ammonium chloride (C18-N—Si) was then dissolved in 200 ml of deionized water to obtain a clear canary solution. 10.9 grams of coupling agent, 3-glycidoxypropyl-trimethoxysilane (S510, epoxy 1) was dissolved in a mixed solution of 10 grams of water and 15 ml of ethanol to form a clear solution. The S510 solution and the C18-N—Si solution were then mixed, and the temperature was raised to 80° C. and agitated for 20 minutes to form a solution of a quaternary ammonium containing multiple terminal epoxy reactive groups. Thereafter, the mixed solution of S510/C-18-N—Si was added to the clay solution and the temperature was raised to about 75° C. and agitated for 2 hours to cause the modification reaction. A white precipitate of modified layered clay material was obtained after the modification reaction was complete. The white precipitate was then washed with hot water three times and filtrated and dried at room temperature for one day. The residual water of the dried precipitate was then extracted in a vacuum oven at a temperature of 100° C., resulting in the clay material (Clay 1-epoxy 1). The interlayer spacing (d-spacing) of the Clay 1-epoxy 1 was 31° A. when measured by X-ray diffraction. The content of the inorganic substance of the Clay 1-epoxy 1 measured by TGA at 850° C. is 67.68%.
The same procedures were then repeated except that the amount of the coupling agent were 1.2 times (epoxy 2) or 2 times (epoxy 3) of the amount of epoxy 1. The interlayer spacing of the obtained modified clays are summarized in Table 1 as indicated below.
As can be seen from the above Table 1, when coupling agent, epoxy 3 is used, the modified clay material has a d-spacing of 42° A., which is 16-27° A. greater than the unmodified clay 1 and the clay 1/C18-N—Si which is modified using no coupling agent.
The modified clay, clay 1-epoxy 1, obtained in preparative example 1 was poured into toluene, and agitated at 90° C. for 4 hours to completely swell the clay material. A polypropylene compatilizer solution was then prepared by dissolving Orevac-CA100, (Elf Atochem Co., Ltd. maleic anhydride-polypropylene copolymer, Mw=30000-50000) in toluene at a temperature of 110° C. for 20 minutes. The polypropylene comtatilizer solution was then blended with the swelled clay material at various weight ratios, i.e., 1/1, 1/2 and 1/3, and agitated at 110° C. for 1.5 hours to obtain a homogenous blend. The homogeneous blend was then evacuated and filtrated to remove the organic solution and dried in vacuum at 120° C. to prepare blends with different weight ratios of organomodified clay/polypropylene compatilizer.
The blends prepared in the above preparative example were then dry mixed with polypropylene(Fu-Chu Company, Taiwan, MFR=13) and extruded using a twin-screw extruder (L/D=15, MP-2015). The kneading was conducted at a barrel temperature of 210° C., and at a screw rotational frequency of 25 rpm. The pelletized extrudate was molded into test samples and tested for mechanical properties and dispersibility. The results are set forth or shown in Table 2 below and the drawings.
As can be seen from the XRD analysis data indicated above and the TEM image of FIG. 1A and
Moreover, it is indicative from Table 2 that the mechanical properties of the test samples prepared from examples 1-4 are superior to those of the test sample prepared from comparative example 1, that is, polypropylene. In particular, the heat distortation temperature (H.D.T) of the test samples prepared from examples 1-4 are all 10° C. higher than those of the test sample prepared from comparative example 1. Among them, the H.D.T. of the test sample prepared from example 4 is 16° C. higher than that of the test sample prepared form comparative example 1. Also, as indicated in Table 2, the flexural modulus (F.M.) of all the test samples prepared from examples 1-4 are 14% higher than those of the test sample prepared from comparative example 1. Moreover, the 4-6% ash amount indicated in the last column of Table 2 reveals that adding only a small amount of organomodified clays makes a significant improvement on the mechanical properties of the PP/clay nanocomposites.
10 grams of purified and Na+ ion-exchanged layered clay (hereinafter Na+-clay) was blended with 190 grams of polypropylene (Fu-Chi Company, Taiwan, MFR=13). A small amount of antioxidants was added during the blending process. The blend was then subject to melt kneading by using a twinscrew extruder (L/D=15, MP-2015) to obtained pelletized extrudate. The pelletized extrudate was then molded into comparative test samples. The comparative test samples were then inspected by by means of X-ray diffractometry and tested for flexural modulus, heat distortion temperature and ash amount, and the results are summarized in Table 3 below.
It is seen from the test results of Table 3 that without modifying the clay material by the process of the invention, the flexural modulus and the heat distortion temperature are lower, indicating that the present invention can provide a means for improving the mechanical properties of a polypropylene/clay nanocomposite.
| Number | Date | Country | Kind |
|---|---|---|---|
| 90131748 A | Dec 2001 | TW | national |
| Number | Name | Date | Kind |
|---|---|---|---|
| 6407155 | Qian et al. | Jun 2002 | B1 |
| 6462122 | Qian et al. | Oct 2002 | B1 |
| 6583209 | Mehta et al. | Jun 2003 | B2 |
| 6632868 | Qian et al. | Oct 2003 | B2 |
| Number | Date | Country | |
|---|---|---|---|
| 20030153659 A1 | Aug 2003 | US |
