Poly(oxyalkylene) modified phthalocyanine colorants

This invention concerns new colorant compositions, their manufacture and their uses and particularly concerns such compositions for the tinting or deeper coloring of natural and synthetic polymeric or resinous materials or substrates, especially polyurethanes and other thermosetting resins and polyolefins, wherein the chemical structures of the colorants are readily tailored to meet, in exceptional manner, the physical and chemical requirements of the specific industrial application.
Some of the desired physical and chemical characteristics of such colorants in addition to having at least substantial tinctorial power, include one or more of excellent clarity and light fastness, high heat stability, crystal structure and shade immutability, availability as liquids or at least good resin compatibility at processing temperatures for easy blending with the substrate, easy clean-up from processing, homogeneity of dispersal in the substrate, non-nucleating propensity of the colorant, and resistance to migration, settling, streaking, plating, subliming, blooming and the like of the colorant from the substrate.
Other desirable colorant properties and also other problems often encountered with the use of pigment material are discussed in U.S. Pat. No. 4,284,729 the disclosure of which is incorporated herein by reference. In that patent which is principally concerned with coloring thermosetting or cross-linkable resins, it is disclosed that conventional organic dyes can be modified with poly(oxyalkylene) constitutents which carry reactive groups for entering the colorant into the polymer chain, e.g., by condensation. This technique is indicated as providing a mechanism whereby highly efficient (high tinctorial power) conventional organic dyes can readily be incorporated, chemically, into the resin molecule such that the dyes become essentially nonmigratory. Similarly, in U.S. Pat. No. 4,640,690 the disclosure of which is incorporated herein by reference, it is taught to color thermoplastic resins with compounds which contain conventional types of organic dyes such as azo, anthraquinone, triarylmethane and methine, linked directly to poly(oxyalkylene) moiety through a nitrogen, oxygen or sulfur atom or a carboxyl group.
It is noted that in these patents the methods for associating the poly(oxyalkylene) moieties with the chromophore are specific to the reactants. For example, in the preparation of azo containing colorants, an aromatic amine is reacted with an alkylene oxide under basic conditions. Similarly, where the poly(oxyalkylene) is attached directly to an anthraquinone nucleus the method comprises reacting a hydroxyl substituted anthraquinone with an amino group on a poly(oxyalkylene). Neither of these nor similar methods are useful in the present invention.
It has been found, moreover, that the use of such conventional organic dye moieties in thermosetting substrates limits the utility of the product in, e.g., high temperature applications for which the substrate material may actually have been designed. This results from the inherent instability of the conventional organic dye moiety at the higher use or processing temperatures of the product substrate.
Also noted here are the copper phthalocyanine (CuPc) compounds of U.S. Pat. No. 5,634,555 which are solids in contrast to the great majority of the compounds of the present invention. The liquid colorants are quite easily blended uniformly with a variety of thermoplastic or thermosetting resins. In contrast, the solid prior art CuPc compositions would need to be converted into fine particles and then blended in conventional equipment which necessarliy is time consuming and operator intensive, and incurs homogeneity problems, substantial power requirements, and great difficulty in handling and equipment clean-up.
Objects, therefore, of the present invention are to provide colorants, the physical and chemical properties of which are readily modifiable to adapt them for blending or incorporation into various polymeric substrates, especially in thermosetting resin materials, wherein the colorants exhibit one or more of the aforementioned characteristics of substantial tinctorial power, light fastness excellent clarity, high heat stability(crystal structure and shade immutability), availability as liquids for easy blending with the substrate; to give essentially complete homogeneity of colorant, easy clean-up from processing, non-nucleating propensity, and resistance to migration, settling, streaking, plating, subliming, blooming and the like of the colorant from the substrate; to provide compositions comprising polymeric substrates, especially polyurethane foams, tinted or deeper colored with the present colorants; and to provide a highly efficient and non-complex process for the manufacture of the present colorants.
These and other objects hereinafter becoming evident have been attained in accordance with the present invention in which the colorant has the formula A--[SO.sub.2 --N(R.sub.2)--Y].sub.1-4 wherein:
A is a nonionic metallophthalocyanine chromophore which can be substituted or unsubstituted;
R.sub.2 is selected from hydrogen or unsubsituted or substituted alkyl, cycloalkyl, aryl or Y;
Y is a poly(oxyalkylene) moiety comprised of at least about 50 mole percent, preferably at least 70 mole percent, of monomeric units or mixture thereof of the formula (--RO--) wherein each R is substituted or unsubstituted straight or branched alkylene of 1-4 carbons or mixtures thereof; and wherein each aliphatic hydrocarbon portion or moiety of the groups, moieties or substituents recited above contains from 1-20 carbons.
In certain preferred embodiments:
(a) A is a nonionic metallophthalocyanine chromophore which can be substituted with 1-8 substitutents selected from halogen, alkyl, alkoxy, alkylthio, or aryloxyl; Y is a poly(oxyalkylene) moiety comprised of at least three monomeric units or mixture thereof of the formula (--RO--) wherein, each R is straight or branched alkylene of 1-4 carbons or mixtures thereof, up to about 20 mole percent of said monomeric units may be connected by one or more linking groups selected from alkyleneoxy, aryleneoxy, alkylenedioxy, alkylenetrioxy, --N(R.sub.3)--, or --N(R.sub.2)CON(R.sub.2)--, wherein each R.sub.3 is selected from R.sub.2 or --SO.sub.2 --A, and wherein Y can be terminated by hydrogen, or by or contain as branch substitutents, 1--3 groups or moieties selected from alkyl, cycloalkyl, acyl, or aryl; wherein any of the above recited hydrocarbon groups, moieties or substitutents may themselves be substituted, for example, with up to four substitutents selected from alkyl, halogen, mercapto, alkylthio, arylthio, aryl, cycloalkyl, alkoxycarbonyl, hydroxy, alkoxy, alkylenedioxy, --N(R.sub.2)CO(R.sub.2)(R.sub.2), --N(R.sub.2)(R.sub.2), --N(R.sub.2)SO.sub.2 --A, --N(R.sub.2)acryl, acyloxy or the like substituents which are known in the art; and wherein each aliphatic hydrocarbon portion or moiety of the groups, moieties or substitutents recited above contains from 1-12, preferably 1-4 carbons.
(b) Y has an average molecular weight of from about 200 to about 1500;
(c) the chromophore A nucleus is unsubstituted;
(d) Y is terminated with hydrogen or a group selected from alkyl, aryl, acyl, alkoxyalkyl, mono- or dihydroxyalkyl, acryloxyalkyl, or a group of the formula: ##STR1## wherein each of R.sub.4, R.sub.5, and R.sub.6 is selected from hydrogen, alkyl, or aryl;
(e) the total mole percentage of all --(RO)-- unit linking groups relative to all said --(RO)-- units in Y is from zero to about 20 percent;
(f) R.sub.2 is hydrogen or Y:
(g) R is --CH.sub.2 CH.sub.2 --, --CH(CH.sub.3)CH.sub.2 --, --CH(C.sub.2 H.sub.5)CH.sub.2 -- or mixtures thereof;
(h) the chromophore is an unsubstituted phthalocyanine of Cu, Ni or Al;
(i) the polymeric or resinous material composition contains from about 0.001 to about 10.0 weight percent of one or a mixture of any of the colorants as defined above;
(j) the material is thermoplastic:
(k) the material is polyurethane; and
(l) the process for preparing the colorant comprises reacting at a temperature of e.g., from about 0.degree. C. to about 100.degree. C., a metallophthalocyanine of the formula A--(SO.sub.2 X).sub.1-4 with at least a stoichiometric quantity of an amine of the formula HN(R.sub.2)Y wherein X is selected from Cl, F, Br, I, or alkoxy, and A, R.sub.2, and Y are as defined above. Preferred reaction media include water, alcohols or ethers containing acid acceptors such as alkali metal carbonates, hydroxide or tertiary amines. Other more specific and preferred process embodiments will hereinafter become evident. With reference to the above general formula for the colorant, the phthalocyanine chromophore can be provided with one to four --SO.sub.2 X groups, each of which can be reacted with a reactive amine group HN(R.sub.2)-- which can be on the same or different ones of the poly(oxyalkylene) moieties Y. In this regard it is noted that where the Y moiety is large, steric hinderance is less likely to interfere with the reaction of multiple NH(R.sub.2)-groups spaced thereon with multiple SO.sub.2 X groups on the same phthalocyanine chromophore.
Thermoplastic resins which may be used according to the present invention include a wide range of resins and synthetic resin compositions which are known in the art as being essentially thermoplastic in nature. The term "thermoplastic" is used herein in its conventional sense to mean a resin "having the property of softening or fusing when heated and of hardening again when cooled " (see Webster's Seventh Collegiate Dictionary, G & C Merriam Co., 1965). Thermoplastic resins are to be clearly distinguished both in terms of their essential physical and chemical characteristics from thermosetting resins. The term "thermosetting" used herein is also used in its conventional sense to means a resin having the property of becoming permanently rigid when heated or cured.
Examples of thermoplastic resin systems which may be employed include a wide range of polyolefin polymers, e.g., polyethylene, linear low density polyethylene, polyproplene, polybutylene, and copolymers made from ethylene, propylene and/or butylene. Other thermoplastic polymers which may be employed according to the present invention include polyvinyl chloride, polyvinylidene chloride, cellulosic resins such as cellulose acetate, cellulose acetate butyrate and cellulose acetate propionate, acrylic resins such as polymethyl methacrylate, styrene acrylonitrile, polystyrene, polycarbonate and acrylonitrile butadiene styrene (therein ABS), polyamides such as nylon 6 and nylon 66 and polyesters such as polyethylene terephthalate, especially glycol modified polyethylene terephthalate and polybutylene terephthalate.
As mentioned above, the colorants may be employed in the thermoplastic resins in a minor amount sufficient to provide the desired degree of coloration in the resin. The actual amount used will, in addition to the desired depth of shade, depend upon the tinctorial strength of the chromophore used and the overall molecular weight of the colorant, e.g., chromophore plus poly(oxyalkylene) chain length. Typically the amount of colorant employed may be from about 0.001 percent to about 10 percent, preferably from about 0.001 percent to about 3 percent, and most preferably from about 0.1 to about 1.0 percent by weight based upon the overall weight of the resin composition.
Other conventional additives may also be present in the resin compositions of the present invention. For instance, such additives may include plasticizers, antioxidants, light, UV, and heat stabilizers, lubricants, flame retardants, nucleating agents and other additives which will be readily identified by those skilled in the art. In general, the colorants have been observed to have little or no adverse interactions with these conventional additives.
Because the colorants if used properly ordinarily do not detract from the clarity of the resin, it has been found that additives which improve the clarity of such resins may be particularly desirable for use in combination with colorants as described herein to provide resin products that are both colored and which also have excellent clarity. One particular class of additives which have been found to be useful in this regard are the benzylidene sorbitols including substituted benzylidene sorbitols such as those described in U.S. Pat. No. 4,016,118 to Hamada, et al. (E.C. Chemical); U.S. Pat. No. 4,371,645 to Mahaffey (Milliken Research Corporation); and Japanese Pat. No. SHO [1977] 53-117044 to Kobsyashi, et al. (New Japan Chemical); all of these patents being hereby incorporated herein by reference. The particular shade of the colorant will depend primarily upon the particular chromophore group selected. A large variety of colors and shades may be obtained by blending two or more colorants. Blending the colorants of the present invention can be readily accomplished as the colorants are polymeric materials which may have substantially identical solubility characteristics, which are dictated by the nature of the polymeric chain. Therefore, the colorants are in general soluble in one another, and are also in general completely compatible with each other.
According to the process of the invention, the colorant may be incorporated into the thermoplastic resin using conventional techniques such as those employed to incorporate other additives in such resins. For instance, the colorant may he incorporated into the resin by simply adding it to the resin while the resin is in a plasticized or molten state, typically prior to formation of the polymer into its final shape, e.g., by molding, extrusion, blow-molding and the like. For instance when the thermoplastic resin to be colored is a polyolefin resin the process may be carried out by adding a colorant comprised of a poly(oxyalkylene) substituted chromophore group directly to the molten polymer, by tumbling it onto a pre-extruded pelletized resin, or by mixing it into the resin powder prior to extrusion. The polymer may then be molded or extruded in the usual manner, i.e., in the same way as for polyolefin resins which are not colored. Details about these procedures may be found in the relevant literature.
Alternatively, a concentrate of the colorant in an appropriate resin or vehicle may first be prepared. Such concentrate may contain an appropriately high percentage of colorant. The concentrates may be in the form of liquids, solids, e.g., powders, pellets, etc., as may be desired. These concentrates may then incorporated into the thermoplastic resin as is well understood in the art.
The colorants used in the process and in the composition of the present invention are polymeric colorants which may according to one embodiment be in the liquid phase. Thus, if in the liquid phase, they may be added to the thermoplastic polymer melt in solvent-free form rather than in the form of solutions or dispersions in a suitable solvent or dispersing medium. Obviously, liquids may have certain processing advantages over solids, and moreover liquids may, if desired, be added directly to the molten polymer and therefore contain no extraneous solvent or dispersing gents. This process may, therefore, provide unusual and advantageous properties in the final thermoplastic resin product. Alternatively, however, the colorants may be premixed with minor amounts of or solvent or dispersing agent which is compatible with the resin, thus providing certain processing advantages.
According to the process of the invention, the liquid colorant may be incorporated into the thermosetting resins by simply adding it to the reaction mixture or to one of the components of the reaction mixture before or during the polyaddition reaction. For instance, when the thermosetting resin to be colored is a polyurethane resin the process may be carried out by adding the coloring agent in the form of a liquid to the polyol or even in some instances to the polyisocyanate component of the reaction mixture either before or during polyurethane formation. The subsequent reaction may be carried out in the usual manner, i.e., in the same way as for polyurethane resins which are not colored. Details about this procedure may be found in the relevant literature.
The present coloring agents of one embodiment of the present invention are polymeric, liquid, reactive coloring agents. Thus, they may be added to the reaction mixture or to one of the components thereof in solvent-free form rather than in the form of solutions or dispersions in suitable solvent or dispersing medium. Obviously liquids have significant processing advantages over solids, and moreover liquids of the present invention may, if desired, be added directly to the reaction mixture and therefore contain no extraneous nonreactive solvent or dispersing agent. This process may, therefore, provide unusual and advantageous properties int he final thermoset resin product. Alternatively, however, the coloring agent may be premixed with minor amounts of one or more of the precursors of the polymeric product, thus providing certain processing advantages.
The thermosetting resins to which the process of the present invention may be applied may be made by the reaction of a nucleophile with an electrophile. Examples of such resins include alkyds, allylics, the amines, e.g., melamine and urea, epoxies, phenolics, polyesters, silicones and urethanes. The thermosetting resin colored according to the present invention can be used in a variety of different end uses. e.g., as moldings, sealants, elastomers, films, fibers, lacquers, coating and foamed materials. It has been found in particular that the present colorants may quite advantageously be employed for the production of forms, such as polyurethane foams which may be soft, semi-rigid or rigid foams, or the so-called polyurethane integral skin and microcellular foams. Such foams are useful for producing shaped products by injection molding, extrusion or calendaring and may be obtained by adding the liquid coloring agent to the polyol or diol component of the reaction mixture, or to one of the other components, although addition to the polyol component is preferred. The polyols may be polyesters which contain hydroxyl groups, in particular reaction products of dihydric alcohols and dibasic carboxylic acids, or polyethers which contain hydroxyl groups, in particular products of the addition of ethylene oxide, propylene oxide, styrene oxide or epichlorohydrin to water, alcohols or amines, preferably dialcohols. The colorant may also be admixed with chain extending diols, e.g., ethylene glycol, diethylene glycol and butane diol. In general, it is desirable not to use more than about 20 percent by weight of colorant based on the weight of polyol. In most cases very strong colorations are produced with a small proportion of the colorant, for example, from about 0.1 to about 2 percent, preferably 0.5 to 1 percent by weight colorant based on the weight of polyol.
Because the present colorants are, in themselves, polymeric compounds, they may he soluble, for instance, in most polyols which would be used in polyurethane manufacture, in most epoxy formulations, in polyester formulations and themselves in admixtures. This property may be particularly valuable in that this solubility may permit rapid mixing and homogeneous distribution throughout the resin, thus eliminating shading differences and streaks when properly mixed, the colorant may have no tendency to settle as would be the base with pigment dispersions, and it is possible to prepare a blend of two or more colorants which provides a wide range of color availability.
The present liquid reactive coloring agents may also be of considerable value in reaction injection molding (RIM) applications. The RIM process is a method of producing molded polyurethanes and other polymers wherein the two reactive streams are mixed while being poured into a mold. Upon reaction, the polymer is "blown" by chemicals to produce a foam structure. This process may be hindered by the presence of solid particles, such as conventional pigments. The present invention may not cause this hinderance because there are not particles in the system and the colorant becomes part of the polymer through reaction with one of the components.
Commercially available and preferred amines from which the present preferred colorants are prepared are the JEFFAMINE series described in Texaco Chemical Company, New Product Development brochures as the M, D, ED, DU, BUD, T, MNPA: and EDR series: the disclosures of which are incorporated herein by reference and copies of which are transmitted herewith.
The preferred amines finding special utility in the present invention are as follows:
R.sub.9 --O(C.sub.2 H.sub.4 O).sub.a [CH.sub.2 CH(CH.sub.3)O].sub.b CH.sub.2 CH(CH.sub.3)NH.sub.2
R.sub.9 --O(C.sub.2 H.sub.4 O).sub.a [CH.sub.2 CH(C.sub.2 H.sub.5)O].sub.b CH.sub.2 CH(CH.sub.3)NH.sub.2
R.sub.9 --O(C.sub.2 H.sub.4 O).sub.a [CH.sub.2 CH(C.sub.2 H.sub.5)O].sub.b CH.sub.2 CH(C.sub.2 H.sub.5)NH.sub.2
R.sub.9 --O(C.sub.2 H.sub.4 O).sub.a [CH.sub.2 CH(CH.sub.3)O].sub.b CH.sub.2 CH(C.sub.2 H.sub.5)NH.sub.2
R.sub.9 --O[CH.sub.2 CH(CH.sub.3)O].sub.a CH.sub.2 CH(CH.sub.3)NH.sub.2
R.sub.9 --O[CH.sub.2 CH(C.sub.2 H.sub.5)O].sub.a CH.sub.2 CH(C.sub.2 H.sub.5)NH.sub.2
R.sub.9 --O[CH.sub.2 CH(C.sub.2 H.sub.5)O].sub.a CH.sub.2 CH(CH.sub.3)NH.sub.2
R.sub.9 --O[CH.sub.2 CH(CH.sub.3)O].sub.a CH.sub.2 CH(C.sub.2 H.sub.5)NH.sub.2
wherein a=1-19; b=2-31; and R.sub.9 is selected from CH.sub.3, C.sub.2 H.sub.5, n-C.sub.3 H.sub.7 n-C.sub.4 H.sub.9, n-C.sub.5 H.sub.11, or n-C.sub.6 H.sub.13. ##STR2## wherein a=1-19; b=2-31; and JR.sub.10 is selected from CH.sub.3, C.sub.2 H.sub.5, C.sub.4 H.sub.9, C.sub.9 H.sub.19, OCH.sub.3, OC.sub.2 H.sub.5, or OC.sub.4 H.sub.9. ##STR3## wherein a=1-19; b=2-31; and R.sub.11 is selected from hydrogen, CH.sub.3, or C.sub.2 H.sub.5. ##STR4## wherein a=1-19; b=2-31. ##STR5## wherein a=1-19; b=2-31; and R.sub.11 is recited above.
H.sub.2 NCH(CH.sub.3)CH.sub.2 [OCH(CH.sub.3)CH.sub.2 ].sub.a (OCH.sub.2 CH.sub.2).sub.b [OCH.sub.2 CH(CH.sub.3)].sub.c NH.sub.2
H.sub.2 NCH(CH.sub.3)CH.sub.2 [OCH(C.sub.2 H.sub.5)CH.sub.2 ].sub.a (OCH.sub.2 CH.sub.2).sub.b [OCH.sub.2 CH(CH.sub.3)].sub.c NH.sub.2
H.sub.2 NCH(CH.sub.3)CH.sub.2 [OCH(C.sub.2 H.sub.5)CH.sub.2 ].sub.8 (OCH.sub.2 CH.sub.2).sub.b [OCH.sub.2 CH(C.sub.2 H.sub.5)].sub.c NH.sub.2
H.sub.2 NCH(C.sub.2 H.sub.5)CH.sub.2 [OCH(C.sub.2 H.sub.5)CH.sub.2 ].sub.a (OCH.sub.2 CH.sub.2).sub.b [OCH.sub.2 CH(C.sub.2 H.sub.5)].sub.c NH.sub.2
H.sub.2 NCH(C.sub.2 H.sub.5)CH.sub.2 [OCH(CH.sub.3)CH.sub.2 ].sub.a (OCH.sub.2 CH.sub.2).sub.b [OCH.sub.2 CH (C.sub.2 H.sub.5)].sub.c NH.sub.2
H.sub.2 NCH(CH.sub.3)CH.sub.2 [OCH(CH.sub.3)CH.sub.2 ].sub.a NH.sub.2
H.sub.2 NCH(C.sub.2 H.sub.5)CH.sub.2 [OCH(C.sub.2 H.sub.5)CH.sub.2 ].sub.a NH.sub.2
wherein b=4-132; and a+c=2-5.
H.sub.2 N(CH.sub.3)CHCH.sub.2 [OCH.sub.2 CH(CH.sub.3)].sub.a HN(CO)NH[CH(CH.sub.3)CH.sub.2 O].sub.b CH.sub.2 CH(CH.sub.3)NH.sub.2
H.sub.2 N(C.sub.2 H.sub.5)CHCH.sub.2 [OCH.sub.2 CH(C.sub.2 H.sub.5)].sub.a HN(CO)NH[CH(C.sub.2 H.sub.5)CH.sub.2 O].sub.b CH.sub.2 CH(C.sub.2 H.sub.5)NH.sub.2
H.sub.2 N(CH.sub.3)CHCH.sub.2 [OCH.sub.2 CH(C.sub.2 H.sub.5)].sub.a HN(CO)NH[CH(C.sub.2 H.sub.5)CH.sub.2 O].sub.b CH.sub.2 CH(CH.sub.3)NH.sub.2
H.sub.2 N(C.sub.2 H.sub.5)CHCH.sub.2 [OCH.sub.2 CH(CH.sub.3)].sub.a HN(CO)NH[CH(CH.sub.3)CH.sub.2 O].sub.b CH.sub.2 CH(C.sub.2 H.sub.5)NH.sub.2
wherein a=2-68 and b=2-68.
HOCH(CH.sub.3)CH.sub.2 NHCH(CH.sub.3)CH.sub.2 [OCH.sub.2 CH(CH.sub.3)].sub.a NHCH.sub.2 CH(CH.sub.3)OH
wherein a is 2.6. ##STR6## wherein a+b+c=1-80; and x+y+z=5-85; and R.sub.11 is recited above.
The following examples illustrate preparation of the present colorants, parts and percentages, unless otherwise stated being by weight. The abbreviation EO, PO, and BO refer to --CH.sub.2 CH.sub.2 O--, CH.sub.2 CH(CH.sub.3)O-- and --CH.sub.2 CH(C.sub.2 H.sub.5)O--, respectively.

EXAMPLE 1 ##STR7##
A mixture was prepared by adding 189.6 grams (0.26 moles) of a primary amine with an amine equivalent weight of 1.35 meq/g) to 31.4 grams of sodium carbonate(0.30 moles) in 250 grams of water. The mixture was stirred mechanically and cooled to 10.degree.-15.degree. C., and 259 grams (0.105 moles) of a 33% active aqueous wet cake of freshly prepared copper phthalocyaninesulfonyl chloride derivative(containing an average of about 2 chlorosulfonyl groups per molecule) were added to the mixture over one and a half hours. After the addition was complete, the mixture was warmed to 50.degree. C. for an additional two hours to insure complete reaction. Afterwards, the mixture was cooled and the product was extracted into methylene chloride. The methylene chloride solution was separated from the salt water solution, washed several times with water to neutral pH, and dried over anhydrous magnesium sulfate. The dried methylene chloride solution was filtered and stripped under reduced pressure at 90.degree. C. to give a blue liquid with an absorbance at 667 nm.
EXAMPLE 2 ##STR8##
A mixture was prepared by adding 91.0 grams (0.19 moles) of a primary amine with an amine equivalent weight of 2.10 meq/g) to 24.0 grams (0.23 moles) sodium carbonate in 400 ml of THF. The mixture was cooled to 10.degree.-15.degree. C. and 100 grams (0.061 moles) of a 50% active aqueous wet cake of freshly prepared copper phthalocyanine-sulfonyl chloride derivative (containing an average of about 2 chlorosulfonyl groups per molecule) were added to the mixture over one and a half hours. After the addition was complete, the mixture was warmed to 50.degree. C. for an additional two hours to insure complete reaction. The aqueous THF solution was allowed to evaporate in a fume hood, 300 ml of methylene chloride was added followed by 300 ml of water. The methylene chloride solution was separated from the salt water solution, further washed several times with water to neutral pH, and dried over anhydrous magnesium sulfate. The dried solution was filtered and stripped under reduced pressure at 90 .degree. C. to a blue liquid with an absorbance at 667 nm.
EXAMPLE 3 ##STR9##
A mixture was prepared by adding 81.7 grams (0.14 moles) of a primary amine with an amine equivalent weight of 1.68 meq/g to 24.0 grams (0.23 moles) sodium carbonate in 400 ml of THF. The mixture was cooled to 10.degree.-15.degree. C. and 113 grams (0.046 moles) of a 50% active aqueous wet cake of freshly prepared copper phthalocyanine-sulfonyl chloride derivative (containing an average of about 2 chlorosulfonyl groups per molecule) were added to the mixture over one and a half hours. After the addition was complete, the mixture was warmed to 50.degree. C. for an additional two hours to insure complete reaction. The aqueous THF solution was allowed to evaporate in a fume hood, 300 ml of methylene chloride was added followed by 300 ml of water. The methylene chloride solution was separated from the salt water solution, further washed several times with water to neutral pH, and dried over anhydrous magnesium sulfate. The dried solution was filtered and stripped under reduced pressure at 90 .degree. C. to a blue liquid with an absorbance at 667 nm.
EXAMPLE 4 ##STR10##
A mixture was prepared by adding 71.4 grams (0.10 moles) of a primary amine with an amine equivalent weight of 1.35 meq/g to 21.6 grams (0.20 moles) sodium carbonate in 500 ml of water. The mixture was cooled to 10.degree.-15.degree. C. and 0.026 moles of an aqueous wet cake of freshly prepared copper phthalocyaninesulfonyl chloride derivative (containing an average of about 4 chlorosulfonyl groups per molecule) was added to the mixture over one-half hour. After the addition was complete, the mixture was warmed to 50.degree. C for an additional two hours to insure complete reaction. Afterwards, the mixture was cooled and the product was extracted into methylene chloride. The methylene chloride solution was separated from the salt water solution, washed several times with water to neutral pH, and dried over anhydrous magnesium sulfate. The dried methylene chloride solution was filtered and stripped under reduced pressure at 90.degree. C. to give a blue liquid with an absorbance at 667 nm.
EXAMPLE 5 ##STR11##
A mixture was prepared by adding 244.8 grams (0.41 moles) of Jeffamine M-600 primary amine with an amine equivalent weight of 1.66 meq/g to 173.0 grams (1.63 moles) sodium carbonate in 1000 ml of water. The mixture was cooled to 10.degree.-15.degree. C. and 0.10 moles of an aqueous wet cake of freshly prepared nickel phthalocyaninesulfonyl chloride derivative (containing an average of about 4 chlorosulfonyl groups per molecule) was added to the mixture about one hour. When the addition was complete, the mixture was warmed to 50.degree. C. to for an additional two hours to insure complete reaction. Afterwards, the mixture was cooled and the product was extracted into methylene chloride. The methylene chloride solution was separated from the salt water solution, washed several times with water to neutral pH, and dried over anhydrous magnesium sulfate. The dried methylene chloride solution was filtered and stripped under reduced pressure at 90.degree. C. to give a blue liquid with an absorbance at 660 nm.
EXAMPLE 6 ##STR12##
A mixture was prepared by adding 71.4 grams (0.10 moles) of a primary amine with an amine equivalent weight of 1.35 meq/g to 21.6 grams (0.20 moles) sodium carbonate in 500 ml of water. The mixture was cooled to 10.degree.-15.degree. C. and 0.025 moles of an aqueous wet cake of freshly prepared nickel phthalocyaninesulfonyl chloride derivative (containing an average of about 4 chlorosulfonyl groups per molecule) was added to the mixture over about one hour. When the addition was complete, the mixture was warmed to 50.degree. C. to for an additional two hours to insure complete reaction. Afterwards, the mixture was cooled and the product was extracted into methylene chloride. The methylene chloride solution was separated from the salt water solution, washed several times with water to neutral pH, and dried over anhydrous magnesium sulfate. The dried methylene chloride solution was filtered and stripped under reduced pressure at 90.degree. C. to give a blue liquid with an absorbance at 662 nm.
EXAMPLE 7 ##STR13##
A mixture was prepared by adding 44.1 grams (0.062 moles) of a primary amine with an amine equivalent weight of 1.35 meq/g to 11.9 grams (0.11 moles) sodium carbonate in 250 ml of water. The mixture was cooled to 10.degree.-15.degree. C. and 0.014 moles an aqueous wet cake of freshly prepared cobalt phthalocyaninesulfonyl chloride derivative (containing an average of about 4 chlorosulfonyl groups per molecule) was added to the mixture over one and a half hours. When the addition was complete, the mixture was warmed to 50.degree. C. to for an additional two hours to insure complete reaction. Afterwards, the mixture was cooled and the product was extracted into methylene chloride. The methylene chloride solution was separated from the salt water solution, washed several times with water to neutral pH, and dried over anhydrous magnesium sulfate. The dried methylene chloride solution was filtered and stripped under reduced pressure at 90.degree. C. to give a blue liquid with an absorbance at 661 nm.
EXAMPLE 8 ##STR14##
A mixture was prepared by adding 45.9 grams (0.10 moles) of a primary amine with an amine equivalent weight of 2.06 meq/g to 10.6 grams (0.10 moles) sodium carbonate in 400 ml of THF. The mixture was cooled to 10.degree.-15.degree. C. and 77.8 grams (0.0315 moles) of a 33% active aqueous wet cake of freshly prepared copper phthalocyaninesulfonyl chloride derivative (containing an average of about 2 chlorosulfonyl groups per molecule) was added to the mixture over one and a half hours. When the addition was complete, the mixture was warmed to 50.degree. C. to for an additional two hours to insure complete reaction. The aqueous THF solution was allowed to evaporate in a fume hood, 300 ml of methylene chloride was added followed by 300 ml of water. The methylene chloride solution was separated from the salt water solution, further washed several times with water to neutral pH, and dried over anhydrous magnesium sulfate. The dried solution was filtered and stripped under reduced pressure at 90.degree. C. to a blue liquid with an absorbance at 667 nm.
EXAMPLE 9 ##STR15##
A mixture was prepared by adding 70.3 grams (0.19 moles) of a primary amine with an amine equivalent weight of 2.7 meq/g to 24.0 grams (0.23 moles) sodium carbonate in 400 ml of THF. The mixture was cooled to 10.degree.-15.degree. C. and 100 grams (0.061 moles) of a 50% active aqueous wet cake of freshly prepared copper phthalocyaninesulfonyl chloride derivative (containing an average of about 2 chlorosulfonyl groups per molecule) was added to the mixture over one and a half hours. After the addition was complete, the mixture was warmed to 50.degree. C. to for an additional two hours to insure complete reaction. The aqueous THF solution was allowed to evaporate in a fume hood, 300 ml of methylene chloride was added followed by 300 ml of water. The methylene chloride solution was separated from the salt water solution, further washed several times with water to neutral pH, and dried over anhydrous magnesium sulfate. The dried solution was filtered and stripped under reduced pressure at 90.degree. C. to a blue liquid with an absorbance at 667 nm.
EXAMPLE 10 ##STR16##
Fifty grams (0.0302 moles) of the acetal prepared in example nine were added along with 100 ml of water to a three necked 250 ml flask equipped with overhead stirrer, heating mantle, and Dean Stark trap. The mixture was heated to 80.degree. C. and 2 grams of 70% sulfuric acid were added. This reaction mixture was maintained at 80.degree. C. until no more acetone could be detected overhead in the trap. The mixture was then cooled and the product was extracted into methylene chloride. The methylene chloride solution was separated, washed several times with water to neutral pH, and dried over anhydrous magnesium sulfate. The dried methylene chloride solution was filtered and stripped under reduced pressure at 90.degree. C. to give a blue product containing a hydroxyl band in the IR spectrum and an absorbance at 667 nm.
EXAMPLE 11 ##STR17##
A mixture was prepared by adding 130.4 grams (0.352 moles) of a primary amine with an amine equivalent weight of 2.7 meq/g to 52.1 grams (0.081 moles) potassium carbonate in 500 ml of water. The mixture was cooled to 10.degree.-15.degree. C. and 0.88 moles of an aqueous wet cake of freshly prepared nickel phthalocyaninesulfonyl chloride derivative (containing an average of about 4 chlorosulfonyl groups per molecule) was added to the mixture over one-half hour. When the addition was complete, the mixture was warmed to 50.degree. C. to for an additional two hours to insure complete reaction. Afterwards, the mixture was cooled and the product was extracted into methylene chloride. The methylene chloride solution was separated from the salt water solution, washed several times with water to neutral pH, and dried over anhydrous magnesium sulfate. The dried methylene chloride solution was filtered and stripped under reduced pressure at 90.degree. C. to give a blue liquid with an absorbance at 662 nm.
EXAMPLE 12 ##STR18##
Fifty grams (0.22 moles) of the acetal prepared in example 11 were added along with 100 ml of water to a three necked 250 ml flask equipped with overhead stirrer, heating mantle, and Dean Stark trap. The mixture was heated to 80.degree. C. and 2 grams of 70% sulfuric acid was added. This reaction mixture was maintained at 80.degree. C. until no more acetone could be detected overhead in the trap. The mixture was then cooled and the product was extracted into methylene chloride. The methylene chloride solution was separated, washed several times with water to neutral pH, and dried over anhydrous magnesium sulfate. The dried methylene chloride solution was filtered and stripped under reduced pressure at 90.degree. C. to give a blue product containing a hydroxyl band in the IR spectrum and an absorbance at 661 nm.
EXAMPLE 13
This example demonstrates the improved heat stability of a polymeric copper phthalocyanine over copper phthalocyanine pigment. The polymeric colorant of example 1 and Copper phthalocyanine blue pigment(Sun Chemical Company, 99% pure) were evaluated in the following formulations:
______________________________________INGREDIENT Formulation A Formulation B______________________________________4MF Polypropylene resin 5000 g 5000 g(Exxon 9142G)Irganox 1010 (Ciba-Geigy) 5 g 5 gIrgaphos 168 (Ciba-Geigy) 2.5 g 2.5 gCalcium stearate 5 g 5 gPolymeric colorant 12.5 g --(example 1)Copper phthalocyanine -- 5 gpigment______________________________________ *For comparison purposes, the colorant concentrations shown were used to obtain about the same depth of shade in each formation.
The additives were mixed mechanically, melt compounded at 440.degree. F. through a one inch extruder, and chopped into pellets. Injection molded step plaques(2.times.3.increment.) were prepared from each formulation. The resins were then re-extruded two more times at 575.degree. F., and plaques were molded after each extrusion. Color changes (delta E) between the control plaques (440.degree. F. extrusion) and the plaques after re-extrusion were measured on a Hunter Colorimeter. The results shown in the table below indicate that the pigment showed significant change in shade during high temperature extrusion, while the polymeric colorant of example one was virtually unchanged.
______________________________________ DELTAFORMULATION EXTRUSION CONDITIONS E*______________________________________A 1 .times. 440.degree. F. --A 1 .times. 440.degree. F., 1 .times. 575.degree. F. 1.0A 1 .times. 440.degree. F., 2 .times. 575.degree. F. 1.2B 1 .times. 440.degree. F. --B 1 .times. 440.degree. F., 1 .times. 575.degree. F. 6.3B 1 .times. 440.degree. F., 2 .times. 575.degree. F. 13.7______________________________________ *CIELAB Coordinates
EXAMPLE 14
This example demonstrates the ease with which the polymeric colorants are purged from compounding equipment such as extruders. After completion of the heat stability experiments for each formulation of example 13, the extruder was purged with one poundshots of uncolored resin until the extrudate showed an insignificant amount of residual color. For formulation A (containing the polymeric colorant of example one), 3-4 pounds of purge resin were required to obtain a virtually colorless extrudate. In Contrast, for formulation B (Copper phthalocyanine pigment), blue color was still observed in the extrudate even after purging the extruder with twenty-five one pound shots of purge resin.
EXAMPLE 15
This example demonstrates the non-nucleation properties of polymeric phthalocyanine colorants of the present invention verses phthalocyanine pigment in a polyolefin resin. Formulation A(polymeric colorant of example 1) and formulation B(phthalocyanine pigment) from example 13 were analyzed by Differential Scanning Calorimetry(Perkin-Elmer Series 7 Thermal analysis System) to determine crystallization temperature. The base resin(uncolored) was also tested. The results shown in the table below indicate that the polymeric colorant has no effect on crystallization properties, while in contrast, the phthalocyanine pigment has a significant effect.
______________________________________ CRYSTALLIZATION TEMPERATURE (.degree.C.)*FORMULATION T1 T2 PEAK______________________________________Base Resin (No Colorant) 105 87 94A (Polymeric Colorant Example #1) 105 87 95B (Pigment) 119 104 112______________________________________ *Cooling Rate = 10.degree. C./min
EXAMPLE I6
This example demonstrates the non-migration properties of the phthalocyanines of this invention. Two plaques from formulation A (surface area=25 in.sup.2 13 grams polymer, 0.0325 grams of colorant) were extracted with 500 ml of 95% ethanol at 120.degree. F. for ten days. The colorant is soluble in this solvent. The extract was analyzed using a 1 cm path length cell on a Beckman DU-7 spectrophotometer (detection limit approximately 8.times.10.sup.-6 grams of colorant per liter). The colorant was not detected in the extract, indicating that less than 0.012% of the colorant had migrated or been extracted from the polymer.
EXAMPLE 17
This example illustrates the use of polymeric phthalocyanine colorants in polyurethane. A polyurethane foam was prepared using the colorant of example 12 in the formulation shown below:
______________________________________Niax 16-56 Polyol (Union Carbide Corp.) 100 gWater 4.8 mlDabco 33 LV (Air Products) 0.31 mlT-9 Catalyst (M & T Chemical Co.) 0.2 mlL-520 Silicone (Union Carbide Corp.) 1.5 mlMethylene Chloride 5.4 mlToluene Diisocyanate 55 mlColorant 1 g______________________________________
This foam was cured for one hour at 160.degree. F. to give an even, bright, aqua blue shade. The polymeric colorant was not extractable with methanol, indicating that the colorant had copolymerized into the polyurethane structure.
The following tables represent prophetic examples to further illustrate specific colorants separated out from Y column for purposes of clarity, and wherever A is used in the tables, it designates the metallophthalocyanine specified in that example.
TABLE 1__________________________________________________________________________ ##STR19##Exam. M (R.sub.1) N(R.sub.2) n W Y__________________________________________________________________________ 1 Cu H NH 1 n-Bu 2BO/3EO 2 Cu H NH 2 Me 2BO/3EO 3 Cu H NH 2 Me 2BO/4EO 4 Ni H N(C.sub.2 H.sub.5) 2 Me 2BO/1EO 5 Ni H NH 2 Me 2PO/19EO 6 Al H N(C.sub.6 H.sub.5) 2 Me 2PO/14EO 7 Al H NH 2 Me 2PO/7EO 8 Cu H N(C.sub.6 H.sub.11) 2 Me 2PO/31EO 9 Cu H NH 2 Me 31PO/3EO10 Al H NH 2 n-C.sub.6 H.sub.13 2BO/6EO11 Cu H NH 2 n-C.sub.6 H.sub.13 3BO/6EO12 Cu H N(CH.sub.2 C.sub.6 H.sub.5) 2 n-C.sub.6 H.sub.13 2PO/8EO13 Cu H NH 2 n-C.sub.6 H.sub.13 5PO/3EO14 Mn H NH 2 n-C.sub.6 H.sub.13 3PO/6EO15 Cu H NH 2 n-C.sub.6 H.sub.13 3PO/4EO16 Cu H NH 2 n-C.sub.6 H.sub.13 4PO/5EO17 Fe H NH 2 n-C.sub.6 H.sub.13 4PO/5EO18 Cu H NH 2 n-C.sub.6 H.sub.13 6PO/6EO19 Cu H NH 2 n-C.sub.10 H.sub.21 2PO20 Cu H NH 2 Me 9PO/1EO21 Cu H N(CH.sub.3) 2 Me 7EO22 Cu H N(CH.sub.3) 2 Me 12EO23 Cr H N(CH.sub.3) 2 Me 16EO24 Cu H NH 2 C.sub.6 H.sub.5 2PO/4EO25 Cu H NH 2 C.sub.6 H.sub.5 2PO/10EO26 Cu H NH 2 p(n-Bu)C.sub.6 H.sub.4 2PO/4EO27 Cr H NH 2 p(n-Bu)C.sub.6 H.sub.4 2PO/11EO28 Cu H NH 2 p(n-Bu)C.sub.6 H.sub.4 2PO/10EO29 Cu H NH 4 Me 3BO/3EO30 Cu H NH 4 n-C.sub.6 H.sub.13 3BO/6EO31 Cu H NH 4 n-C.sub.6 H.sub.13 3PO/4EO32 Cu H NH 4 Me 2PO/19EO33 Cu H NH 4 Me 2PO/10EO34 Cu H NH 4 Me 2PO/7EO35 Cu H NH 4 n-Bu 2BO/3EO36 Cu H NH 4 n-Bu 2BO/4EO37 Cu H NH 4 C.sub.6 H.sub.5 2PO/4EO38 Cu H NH 4 C.sub.6 H.sub.5 2PO/11EO39 Cu H NH(CH.sub.3) 4 Me 7EO40 Cu H NH 3 Me 2BO/4EO41 Cu H NH 3 n-C.sub.6 H.sub.13 2BO/6EO42 Cu H NH 3 n-C.sub.6 H.sub.13 5PO/3EO43 Cu tetra-O-t-C.sub.4 H.sub.9 NH 3 n-Bu 2BO/4EO44 Cu tetra-O-n-C.sub.4 H.sub.9 NH 3 Me 2PO/4EO45 Cu Cl NH 2 n-Bu 2BO/4EO46 Cu di-Cl NH 2 n-Bu 2BO/4EO47 Cu tri-Cl NH 2 Me 2PO/7EO48 Cu tetra-Cl NH 2 n-C.sub.6 H.sub.13 6BO/6EO49 Cu Br NH 2 n-Bu 2BO/3EO50 Cu di-Br NH 2 Me 2PO/10EO51 Cu tetra-Br NH 2 n-C.sub.6 H.sub.13 3PO/4EO52 Cu Me NH 2 C.sub.6 H.sub.5 2PO/4EO53 Cu di-Me NH 2 Me 2PO/7EO54 Cu tetra-C.sub.6 H.sub.5 NH 2 Me 2PO/10EO55 Cu tetra-C.sub.6 H.sub.5 NH 4 n-Bu 2BO/3EO56 Cu tetra-C.sub.6 H.sub.5 NH 3 n-C.sub.6 H.sub.13 6PO/6EO57 Cu OMe NH 2 n-Bu 2BO/3EO58 Cu di-OMe NH 4 Me 2BO/3EO59 Cu tetra-OMe NH 4 Me 2BO/4EO60 Cu OC.sub.6 H.sub.5 NH 2 n-C.sub.6 H.sub.13 2BO/6EO61 Cu di-(OC.sub.6 H.sub.5) NH 2 n-C.sub.6 H.sub.13 5PO/3EO62 Cu tetra-(OC.sub.6 H.sub.5) NH 2 n-Bu 2BO/4EO63 Cu di-(SC.sub.6 H.sub.5) NH 2 Me 2PO/14EO64 Cu tetra-(SC.sub.6 H.sub.5) NH 2 Me 2PO/14EO65 Cu I NH 2 C.sub.6 H.sub.5 2PO/4EO66 Cu di-I NH 2 n-Bu 2BO/3EO67 Cu tetra-I NH 4 n-Bu 2BO/4EO68 Cu NH.sub.2 NH 4 Me 2BO/1EO69 Cu di-NH.sub.2 NH 2 Me 2PO/10EO70 Cu tetra-NH.sub.2 NH 4 n-Bu 2PO/3EO71 Cu NHCOMe NH 4 n-C.sub.6 H.sub.13 3PO/4EO72 Cu di-NHCOMe NH 4 C.sub.6 H.sub.5 2PO/4EO73 Cu tetra-NHCOMe NH 4 n-C.sub.6 H.sub.13 3PO/4EO74 Cu H N(CH.sub.3) 2 Me 2BO/4EO75 Cu H N(C.sub.2 H.sub.5) 2 Me 3BO/4EO76 Cu H N(CH.sub.2 C.sub.6 H.sub.5) 2 n-C.sub.6 H.sub.13 2PO/7EO77 Cu H N(iso-C.sub.3 H.sub.7) 2 n-Bu 2PO/7EO78 Cu H N[(5EO)-C.sub.6 H.sub.13 ] 2 Me 2BO/4EO79 Cu H N[(1EO/4PO)-Me] 2 nC.sub.6 H.sub.13 2BO/6EO80 Cu H N[(3PO)-C.sub.6 H.sub.13 ] 2 n-C.sub.6 H.sub.13 2PO/8EO81 Cu H N(CH.sub.2 C.sub.6 H.sub.13) 2 n-Bu 2BO/6EO82 Cu H N(iso-C.sub.4 H.sub.9) 2 Me 2PO/7EO83 Cu H N(C.sub.6 H.sub.11) 2 n-Bu 2PO/7EO84 Cu H N(C.sub.6 H.sub.5) 2 n-Bu 2PO/4EO85 Cu H NH 2 H 10EO86 Cu H NH 2 H 3EO/5PO87 Cu H NH 2 H .sup. 3O/10PO88 Ni H NH 2 n-Bu 2BO/4EO89 Ni H NH 3 n-Bu 2PO/3EO90 Ni H NH 4 Me 2BO/3EO91 Ni Cl NH 2 n-C.sub.6 H.sub.13 6PO/6EO92 Ni di-Cl NH 2 Me 2PO/7EO93 Ni Br NH 2 C.sub.6 H.sub.5 2PO/4EO94 Ni Me NH 4 Me 2BO/3EO95 Ni di-OMe NH 2 Me 2PO/7EO96 Ni di-(OC.sub.6 H.sub.5) NH 2 Me 2PO/7EO97 Ni tetra-(OC.sub.6 H.sub.5) NH 4 n-Bu 2BO/4EO98 Ni tetra-(SC.sub.6 H.sub.5) NH 4 n-Bu 2BO/3EO99 Co H NH 2 Me 2PO/14EO100 Co H NH 4 n-Bu 2BO/3EO101 Co di-OMe NH 2 Me 2PO/7EO102 Co di-(OC.sub.6 H.sub.5) NH 2 Me 2PO/7EO103 Co tetra-(OC.sub.6 H.sub.5) NH 4 n-Bu 2BO/4EO104 Co tetra-(SC.sub.6 H.sub.5) NH 4 n-Bu 3BO/4EO__________________________________________________________________________
TABLE 2__________________________________________________________________________ ##STR20##Example M (R.sub.1) N(R.sub.2) n W Y__________________________________________________________________________ 1 Cu H NH 1 CH.sub.2 CH(CH.sub.3)NH.sub.2 5PO 2 Al tetra-CH.sub.3 NH 2 CH.sub.2 CH(CH.sub.3)N(CH.sub.3).sub.2 5PO/3EO 3 Ni tetra-Cl NH 3 CH.sub.2 CH(CH.sub.3)SO.sub.2 NH-A 5PO-(CH.sub.2).sub.6O-5PO 4 Ni di-OCOCH.sub.3 NH 3 CH.sub.2 CH(CH.sub.3)NHC.sub.6 H.sub.5 2BO-C.sub.6 H.sub.4O-3PO 5 Cu tetra-CH.sub.3 NH 4 CH.sub.2 CH(CH.sub.3)NHC.sub.6 H.sub.4 -p-Me 5PO-O(CH.sub.2).sub.6O-5PO 6 Fe di-OC.sub.2 H.sub.5 NH 4 C.sub.2 H.sub.4OC.sub.6 H.sub.4 -p-NH.sub.2 (3PO)-NH-(14EO) 7 Cr di-NHSO.sub.2 CH.sub.3 NH 4 C.sub.2 H.sub.4OC.sub.2 H.sub.4 N(Me).sub.2 (5PO)-N(CH.sub.3)-(10PO) 8 Mn tetra-N(Me).sub.2 NH 2 CH.sub.2 CH(OH)CH.sub.3 (5PO)-N(C.sub.6 H.sub.11)-10PO 9 Cu NHCOCH.sub.3 NH 2 C.sub.2 H.sub.4 OCH.sub.3 (10PO)-N(C.sub.6 H.sub.5)-(10EO)10 Cu di-OCOCH.sub.3 NH 2 CH.sub.2 OCOCH.sub.3 (3PO)-N[(10PO)Et]-(10PO)11 Cu H NH 2 C.sub.2 H.sub.4 C.sub.6 H.sub.5 (3PO)-N(SO.sub.2 A)-10EO)12 Al H NH 1 C.sub.2 H.sub.4 OC.sub.6 H.sub.5 (2PO)-NHCONH-(3EO)13 Al H NH 1 C.sub.2 H.sub.4 NHCONH.sub.2 3PO/6EO14 Al tetra-C.sub.2 H.sub.5 NH 1 C.sub.2 H.sub.4NHCON(CH.sub.3).sub.2 9PO/1EO15 Fe tetra-Br NH 1 C.sub.2 H.sub.4 N(CH.sub.3).sub.2 20EO16 Fe tetra-C.sub.6 H.sub.5 NH 1 H 10EO17 Fe tetra-I NH 4 CH.sub.2 CH.sub.2 CH.sub.3 4PO18 Ni tetra-NH.sub.2 NH 4 C.sub.2 H.sub.4 C.sub.6 H.sub.11 2PO/14EO19 Ni tetra-NHCOMe NH 2 C.sub.2 H.sub.4 OCOCH.sub.3 4PO20 Cu H NH 2 C.sub.6 H.sub.5 3PO/6EO21 Cu H NH 4 CH.sub.2 CH(OH)CH.sub.2 OH 4PO22 Cu H NH 2 COC.sub.6 H.sub.5 3PO/6EO23 Cu H NH 2 COC.sub.6 H.sub.11 10EO24 Cu H NH 2 CO.sub.2 C.sub.2 H.sub.5 4PO25 Cu H NH 1 CON(CH.sub.3).sub.2 3PO/6EO26 Cu H NH 2 CONHC.sub.6 H.sub.5 5PO27 Cu H NH 2 CH.sub.2 CH.sub.2 COCH.sub.3 20EO28 Cu H NH 3 Cl 10PO/5EO29 Cu H NH 2 SH 10EO/5PO30 Cu H NH 2 SC.sub.2 H.sub.5 5EO/15PO/5EO31 Cu H NH 2 SC.sub.6 H.sub.5 15PO/5EO__________________________________________________________________________
TABLE 3__________________________________________________________________________ ##STR21##Exam. M n (R.sub.1) R.sub.2 R.sub.3 R.sub.4 R.sub.5 R.sub.6 Y__________________________________________________________________________ 1 Cu 2 H OH H H H H 3PO/1EO 2 Cu 2 H OH H H H H 3PO 3 Cu 2 H OH H H H H 4PO 4 Ni 2 H OH H H H H 8PO/8EO 5 Ni 2 H OH H H H H 5PO/3EO 6 Cu 2 H OH H H H H 4PO/3EO 7 Cu 2 H OH H H H H 2PO/19EO 8 Al 2 H OH H H H H 2PO/14EO 9 Al 2 H OH H H H H 2PO/7EO10 Cu 2 H OH H H H H 4PO/2EO11 Cu 2 H OH H H H H 8PO/2EO12 Mn 2 H OH H H H H 2BO/3EO13 Cu 2 H OH H H H H 2BO/4EO14 Fe 2 H OH H H H H 2BO/1EO15 Cu 2 H OH H H Me H 4PO16 Fe 2 H OH H H Me H 4PO/4EO17 Cu 2 H OH H H Me H 8PO/8EO18 Cu 2 H OH H H Me H 2/4EO19 Cu 2 H OH H H Me H 2PO/7EO20 Cu 2 H OH H H Et H 31PO/3EO21 Cu 2 H OH H H Et H 3PO22 Cu 2 H OH H H Et H 4PO/2EO23 Cu 2 H OH H H Et H 3BO/6EO24 Cr 4 H OH H H H H 4PO25 Cu 4 H OH H H H H 2BO/4EO26 Cu 4 H OH H H H H 5PO/3EO27 Cu 4 H OH H H H H 3PO28 Cu 4 H OH H H Me H 3PO/1EO29 Cr 4 H OH H H Et H 3PO30 Cu 4 H OH H H Et H 3PO/6EO31 Cu 3 H OH H H H H 2BO/4EO32 Cu 3 H OH H H H H 8BO/8EO33 Cu 3 H OH H H H H 4PO/3EO34 Cu 3 H OH H H Me H 2PO/7EO35 Cu 2 Cl OH H H H H 3BO/6EO36 Cu 2 di-Cl OH H H H H 2PO/4EO37 Cu 2 tetra-Cl OH H H H H 6PO/6EO38 Cu 2 Br OH H H H H 2BO/3EO39 Cu 2 tetra-Br OH H H H H 5PO/3EO40 Cu 2 di-C.sub.6 H.sub.5 OH H H H H 8PO/8EO41 Cu 2 tetra-C.sub.6 H.sub.5 OH H H H H 8PO/2EO42 Cu 2 OMe OH H H H H 4PO43 Cu 4 di-OMe OH H H H H 4PO/2EO44 Cu 4 tetra-OMe OH H H H H 2BO/4EO45 Cu 2 OC.sub.6 H.sub.5 OH H H H H 3PO/6EO46 Cu 2 di-(OC.sub.6 H.sub.5) OH H H H H 5PO/3EO47 Cu 2 tetra-(OC.sub.6 H.sub.5) OH H H H H 8PO/2EO48 Cu 2 di-(SC.sub.6 H.sub.5) OH H H H H 2PO/7EO49 Cu 2 tetra-(SC.sub.6 H.sub.5) OH H H H H 8PO/8EO50 Cu 2 I OH H H H H 2PO/14EO51 Cu 4 di-I OH H H H H 2PO/14EO52 Cu 4 tetra-I OH H H H H 4PO53 Cu 2 NH.sub.2 OH H H H H 4PO/4EO54 Cu 4 di-NH.sub.2 OH H H H H 2BO/4EO55 Cu 4 tetra-NH.sub.2 OH H H H H 2BO/4EO56 Cu 4 NHCOMe OH H H H H 3PO/1EO57 Cu 4 di-NHCOMe OH H H H H 4PO/4EO58 Cu 4 tetra-NHCOMe OH H H H H 2BO/4EO59 Ni 2 H OH H H H H 6PO/7EO60 Ni 2 H OH H H H H 6PO/7EO61 Ni 2 H OH H H Me H 4PO62 Ni 2 H OH H H Et H 3BO63 Ni 4 H OH H H H H 3PO/3EO64 Ni 4 Cl OH H H H H 6PO/6EO65 Ni 2 di-Cl OH H H H H 2PO/10EO66 Ni 2 tetra-Cl OH H H H H 5PO/3EO67 Ni 2 Me OH H H H H 2BO/4EO68 Ni 2 di-Me OH H H H H 4PO69 Ni 2 di-OMe OH H H H H 4PO/3EO70 Ni 2 di-(OC.sub.6 H.sub.5) OH H H H H 4PO/3EO71 Ni 4 tetra-(OC.sub.6 H.sub.5) OH H H H H 2BO/3EO72 Ni 4 tetra-(SC.sub.6 H.sub.5) OH H H Me H 2BO/3EO73 Co 4 H OH H H H H 4PO74 Co 4 H OH H H Et H 3PO75 Co 4 H OH H H Et H 3PO76 Co 2 di-OMe OH H H H H 4PO/3EO77 Co 2 di-(OC.sub.6 H.sub.5) OH H H H H 8PO/2EO78 Co 4 tetra-(OC.sub.6 H.sub.5) OH H H H H 2PO/4EO79 Co 4 tetra-(SC.sub.6 H.sub.5) OH H H H H 3PO/1EO80 Cu 2 H Me Me H H Me 2PO/8EO81 Cu 2 H Me Me H H Me 5PO/3EO82 Cu 2 H Me Me H H Me 3PO/4EO83 Cu 2 H Me Me H H Me 4PO/3EO84 Cu 2 H Me Me H H Me 6PO/6EO85 Cu 2 H Me Me H H Me 3BO/6EO86 Cu 2 H Me Me H H Me 3BO/3EO87 Cu 2 H Me Me H H Me 2BO/3EO88 Cu 4 H Me Me H H Me 3PO/6EO89 Cu 4 H Me Me H H Me 4PO90 Cu 4 H Me Me H H Me 3BO91 Cu 4 H Me Me H H Me 2PO/4EO92 Cu 2 Cl Me Me H H Me 2PO/14EO93 Cu 2 di-Cl Me Me H H Me 8PO/8EO94 Cu 2 tetra-Cl Me Me H H Me 4PO/4EO95 Cu 2 Br Me Me H H Me 5PO/3EO96 Cu 2 tetra-Br Me Me H H Me 3PO/4EO97 Cu 2 di-C.sub.6 H.sub.5 Me Me H H Me 2PO/8EO98 Cu 4 tetra-C.sub.6 H.sub.5 Me Me H H Me 3BO/6EO99 Cu 2 OMe Me Me H H Me 8PO/8EO100 Cu 4 di-OMe Me Me H H Me 3BO/3EO101 Cu 4 tetra-OMe Me Me H H Me 3BO102 Cu 2 OC.sub.6 H.sub.5 Me Me H H Me 6PO/6EO103 Cu 2 di-(OC.sub.6 H.sub.5) Me Me H H Me 2PO/14EO104 Cu 2 tetra-(OC.sub.6 H.sub.5) Me Me H H Me 4PO/3EO105 Cu 2 di-(SC.sub.6 H.sub.5) Me Me H H Me 4PO/3EO106 Cu 2 tetra-(SC.sub.6 H.sub.5) Me Me H H Me 2PO/8EO107 Cu 2 I Me Me H H Me 5PO/3EO108 Cu 4 di-I Me Me H H Me 2BO/3EO109 Cu 4 tetra-I Me Me H H Me 3BO/3EO110 Cu 2 NH.sub.2 Me Me H H Me 6PO/6EO111 Cu 4 di-NH.sub.2 Me Me H H Me 3BO/1EO112 Cu 4 tetra-NH.sub.2 Me Me H H Me 2BO/4EO113 Cu 4 NHCOMe Me Me H H Me 4PO/4EO114 Cu 4 di-NHCOMe Me Me H H Me 2PO/4EO115 Cu 4 tetra-NHCOMe Me Me H H Me 2PO/4EO116 Ni 2 H Me Me H H Me 4PO/3EO117 Ni 2 H Me Me H H Me 5PO/3EO118 Ni 2 H Me Me H H Me 4PO119 Ni 2 H Me Me H H Me 8PO/8EO120 Ni 4 H Me Me H H Me 2PO/6EO121 Ni 4 Cl Me Me H H Me 3PO/4EO122 Ni 2 di-Cl Me Me H H Me 2PO/14EO123 Ni 2 tetra-Cl Me Me H H Me 4PO/3EO124 Ni 2 Me Me Me H H Me 3BO/6EO125 Ni 2 di-Me Me Me H H Me 8PO/8EO126 Ni 2 di-OMe Me Me H H Me 2PO/8EO127 Ni 2 di-(OC.sub.6 H.sub.5) Me Me H H Me 6PO/6EO128 Ni 4 tetra-(OC.sub.6 H.sub.5) Me Me H H Me 3BO129 Ni 4 tetra-(SC.sub.6 H.sub.5) Me Me H H Me 3BO/3EO130 Co 4 H Me Me H H Me 4PO131 Co 4 H Me Me H H Me 3PO132 Co 4 H Me Me H H Me 2BO/4EO133 Co 2 di-OMe Me Me H H Me 8PO/8EO134 Co 2 di-(OC.sub.6 H.sub.5) Me Me H H Me 5PO/3EO135 Co 4 tetra-(OC.sub.6 H.sub.5) Me Me H H Me 2BO/3EO136 Co 4 tetra-(SC.sub.6 H.sub.5) Me Me H H Me 2BO/4EO__________________________________________________________________________
TABLE 4__________________________________________________________________________ ##STR22##Example M n (R.sub.1) R.sub.5 R.sub.7 R.sub.8 Y__________________________________________________________________________ 1 Cu 1 H H Me Me 3PO/1EO 2 Cu 2 H H Me Me 3PO 3 Cu 2 H H Me Me 4PO 4 Ni 2 H H Me Me 8PO/8EO 5 Cu 2 H H Me Me 5PO/3EO 6 Fe 2 H H Me Me 4PO/3EO 7 Cu 2 H H Me Me 2PO/19EO 8 Cu 2 H H Me Me 2PO/14EO 9 Al 2 H H Me Me 2PO/7EO10 Cu 2 H H Me Me 4PO/2EO11 Cu 2 H H Me Me 8PO/2EO12 Mn 2 H H Me Me 2BO/3EO13 Cu 2 H H Me Me 2BO/4EO14 Cu 2 H H Me Me 2BO/1EO15 Cu 2 H Me Me Me 4PO16 Cu 2 H Me Me Me 4PO/4EO17 Cu 2 H Me Me Me 8PO/8EO18 Al 2 H Me Me Me 2PO/4EO19 Cu 2 H Me Me Me 2PO/7EO20 Cu 2 H Et Me Me 31PO/3EO21 Cu 2 H Et Me Me 3PO22 Cr 2 H Et Me Me 4PO/2EO23 Cu 2 H Et Me Me 3BO/6EO24 Cu 4 H H Me Me 4PO25 Cu 4 H H Me Me 2BO/4EO26 Cu 4 H H Me Me 5PO/3EO27 Cu 4 H H Me Me 3PO28 Cr 4 H Me Me Me 3PO/1EO29 Cu 4 H Et Me Me 3PO30 Cu 4 H Et Me Me 3PO/6EO31 Cu 3 H H Me Me 2BO/4EO32 Cu 3 H H Me Me 8BO/8EO33 Cu 3 H H Me Me 4PO/3EO34 Cu 3 H Me Me Me 2PO/7EO35 Cu 2 Cl H Me Me 3BO/6EO36 Cu 2 di-Cl H Me Me 2PO/4EO37 Cu 2 tetra-Cl H H H 6PO/6EO38 Cu 2 Br H Me Me 2BO/3EO39 Cu 2 tetra-Br H Me Me 5PO/3EO40 Cu 2 di-C.sub.6 H.sub.5 H Me Me 8PO/8EO41 Cu 2 tetra-C.sub.6 H.sub.5 H Me Me 8PO/2EO42 Cu 2 OMe H Me Me 4PO43 Cu 4 di-OMe H Me Me 2PO/2EO44 Cu 4 tetra-OMe H Me Me 2BO/4EO45 Cu 2 OC.sub.6 H.sub.5 H Me Me 3PO/6EO46 Cu 2 di-(OC.sub.6 H.sub.5) H Me Me 5PO/3EO47 Cu 2 tetra-(OC.sub.6 H.sub.5) H Me Me 8PO/2EO48 Cu 2 di-(SC.sub.6 H.sub.5) H Me Me 2PO/7EO49 Cu 2 tetra-(SC.sub.6 H.sub.5) H Me Me 8PO/8EO50 Cu 2 I H Me Me 2PO/14EO51 Cu 4 di-I H Me Me 2PO/14EO52 Cu 4 tetra-I H Me Me 4PO53 Cu 2 NH.sub.2 H Me Me 4PO/4EO54 Cu 4 di-NH.sub.2 H Me Me 2BO/4EO55 Cu 4 tetra-NH.sub.2 H Me Me 2BO/4EO56 Cu 4 NHCOMe H Me Me 3PO/1EO57 Cu 4 di-NHCOMe H Me Me 2PO/4EO58 Cu 4 tetra-NHCOMe H Me Me 2BO/4EO59 Ni 2 H H Me Me 6PO/7EO60 Ni 2 H H Me Me 6PO/7EO61 Ni 2 H H Me Me 4PO62 Ni 2 H Et Me Me 3BO63 Ni 4 H H Me Me 3PO/3EO64 Ni 4 Cl H Me Me 6PO/6EO65 Ni 2 di-Cl H Me Me 2PO/10EO66 Ni 2 tetra-Cl H Me Me 5PO/3EO67 Ni 2 Me H Me Me 2BO/4EO68 Ni 2 di-Me H Me Me 4PO69 Ni 2 di-OMe H Me Me 4PO/3EO70 Ni 2 di-(OC.sub.6 H.sub.5) H Me Me 2PO/3EO71 Ni 4 tetra-(OC.sub.6 H.sub.5) H Me Me 2BO/3EO72 Ni 4 tetra-(SC.sub.6 H.sub.5) Me Me Me 2BO/3EO73 Co 4 H H Me Me 4PO74 Co 4 H H Me Me 3PO75 Co 4 H H Me Me 3PO76 Co 2 di-OMe H Me Me 4PO/3EO77 Co 2 di-(OC.sub.6 H.sub.5) H Me Me 8PO/2EO78 Co 4 tetra-(OC.sub.6 H.sub.5) H Me Me 2PO/4EO79 Co 4 tetra-(SC.sub.6 H.sub.5) H Me Me 3PO/1EO__________________________________________________________________________
The invention has been described in detail with particular reference to preferred embodiments thereof, but it will be understood that variations and modifications will be effected within the spirit and scope of the invention.

Poly(oxyalkylene) modified phthalocyanine colorants

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