Claims
- 1. A method for the manufacture of a graft copolymer composition which comprises polymerizing under continued agitation a styrene in the presence of 20 to 85 percent by weight based on the final composition of a polyphenylene ether represented by the general formula: ##STR2## wherein R and R.sup.1 each denote a hydrogen atom or an alkyl group having one to four carbon atoms and n the degree of polymerization, 3 to 40 percent by weight of an ethylene copolymer comprising ethylene and 1.0 to 40 mol percent of at least one unsaturated compound represented by the general formula of CH.sub.2 .dbd.CHOCOR.sub.1 or CH.sub.2 .dbd.CR.sub.2 COOR.sub.3 wherein, R.sub.1 denotes an alkyl group having one to four carbon atoms and R.sub.2 and R.sub.3 each denote a hydrogen atom or an alkyl group having one to four carbon atoms and a radical polymerization initiator, at a temperature in the range of from 120.degree. to 290.degree. C.
- 2. A method as in claim 1 wherein the polyphenylene ether is poly(2,6-dimethylphenylene-1,4-ether) and the temperature for polymerizing the styrene is from 180.degree. to 250.degree. C.
- 3. A method as in claim 2 wherein the styrene is styrene alone or a mixture of styrene with acrylonitrile.
- 4. A method as in claim 3 wherein the ethylene copolymer is an ethylene-methyl methacrylate copolymer or ethylene-vinyl acetate copolymer.
- 5. A method as in claim 4 wherein 4 to 200 parts by weight of the ethylene copolymer, 10 to 200 parts by weight of the styrene and 0.3 to 15 parts by weight of a radical initiator are used per 100 parts by weight of the polyphenylene ether.
- 6. A method as in claim 5 wherein the styrene is in the range from 15 to 180 parts by weight.
- 7. A method as in claim 6 wherein the radical initiator is in the range from 0.5 to 12 parts by weight.
- 8. A method as in claim 1 wherein the styrene is styrene alone or a mixture of styrene with acrylonitrile.
- 9. A method as in claim 1 wherein the ethylene copolymer is an ethylene-methyl methacrylate copolymer or ethylene-vinyl acetate copolymer.
- 10. A method as in claim 1 wherein 4 to 200 parts by weight of the ethylene copolymer, 10 to 200 parts by weight of the styrene and 0.3 to 15 parts by weight of a radical initiator are used per 100 parts by weight of the polyphenylene ether.
- 11. A method as in claim 10 wherein the styrene is in the range from 15 to 180 parts by weight.
- 12. A method as in claim 10 wherein the radical initiator is in the range from 0.5 to 12 parts by weight.
- 13. A method as in claim 1 wherein polymerization is carried out in the presence of 1 to 10 percent by weight of a rubbery substance.
- 14. A method as in claim 13 wherein a styrene type compound polymer and/or a high impact styrene copolymer is further added.
- 15. A method as in claim 1 wherein a styrene type compound polymer and/or a high impact styrene copolymer is further added.
- 16. A method as in claim 13 wherein the polyphenylene ether is poly(2,6-dimethylphenylene-1,4-ether) and the temperature for polymerizing the styrene is from 150.degree. to 230.degree. C.
- 17. A method as in claim 16 wherein the styrene is styrene alone or a mixture of styrene with acrylonitrile.
- 18. A method as in claim 17 wherein the ethylene copolymer is an ethylene-methyl methacrylate copolymer or an ethylene-vinyl acetate copolymer.
- 19. A method as in claim 18 wherein the rubbery substance is selected from the group consisting of polybutadiene, styrene-butadiene random copolymer, styrenebutadiene block copolymer and ethylene-propylene-non-conjugated diene copolymer rubber.
- 20. A method as in claim 14 wherein the styrene polymer and/or the high impact styrene copolymer is at least one selected from the group consisting of polystyrene, rubber reinforced polystyrene, styrene-acrylonitrile copolymer, styrene-acrylonitrile-butadiene copolymer.
- 21. A method as in claim 20 wherein 5 to 120 parts by weight of the ethylene copolymer, 2 to 30 parts by weight of the rubbery substance, 10 to 50 parts by weight of the -styrene polymer and/or high impact styrene copolymer, 0.3 to 15 parts by weight of the radical polymerization initiator and 10 to 200 parts by weight of the styrene are used per 100 parts by weight of the polyphenylene ether.
- 22. A method as in claim 21 wherein the styrene is in the range from 15 to 180 parts by weight.
- 23. A method as in claim 22 wherein the radical initiator is in the range from 0.5 to 12 parts by weight.
- 24. A method as in claim 13 wherein the styrene is styrene alone or a mixture of styrene with acrylonitrile.
- 25. A method as in claim 13 wherein the ethylene copolymer is an ethylene-methyl methacrylate copolymer or an ethylene-vinyl acetate copolymer.
- 26. A method as in claim 13 wherein the rubbery substance is selected from the group consisting of polybutadiene, styrene-butadiene random copolymer, styrenebutadiene block copolymer and ethylene-propylene-non-conjugated diene copolymer rubber.
- 27. A method as in claim 15 wherein the styrene polymer and/or the high impact styrene copolymer is at least one selected from the group consisting of polystyrene, rubber reinforced polystyrene, styrene-acrylonitrile copolymer, styrene-acrylonitrile-butadiene copolymer.
- 28. A method as in claim 13 wherein 4 to 120 parts by weight of the ethylene copolymer, 2 to 30 parts by weight of the rubbery substance, 10 to 50 parts by weight of the styrene polymer and/or the high impact styrene copolymer, 0.3 to 15 parts by weight of the radical polymerization initiator and 10 to 200 parts by weight of the styrene are used per 100 parts by weight of the polyphenylene ether.
- 29. A method as in claim 28 wherein the styrene is in the range from 15 to 180 parts by weight.
- 30. A method as in claim 28 wherein the radical initiator is in the range from 0.5 to 12 parts by weight.
- 31. A method as in claim 13, wherein polymerization is carried out by extrusion of a mixture of the polyphenylene ether, the radical initiator, the styrene, ethylene copolymer and the rubbery substance.
- 32. A method as in claim 14, wherein polymerization is carried out by extrusion of a mixture of the polyphenylene ether, the radical initiator, the styrene, ethylene copolymer, the rubbery substance, and the styrene polymer and/or the high impact styrene copolymer.
- 33. A method as in claim 1, wherein polymerization is carried out by extrusion of a mixture of the polyphenylene ether, the radical initiator, the styrene and the ethylene copolymer.
Priority Claims (2)
Number |
Date |
Country |
Kind |
51-12846 |
Feb 1976 |
JPX |
|
51-156567 |
Dec 1976 |
JPX |
|
Parent Case Info
This is a division of application Ser. No. 766,514 filed Feb. 7, 1977, now U.S. Pat. No. 4,132,684.
US Referenced Citations (3)
Number |
Name |
Date |
Kind |
3700750 |
Yamanouchi et al. |
Oct 1972 |
|
3929930 |
Izawa et al. |
Dec 1975 |
|
3983090 |
Abolins et al. |
Sep 1976 |
|
Foreign Referenced Citations (1)
Number |
Date |
Country |
2126434 |
Dec 1971 |
DEX |
Divisions (1)
|
Number |
Date |
Country |
Parent |
766514 |
Feb 1977 |
|