Claims
- 1. A new water-insoluble polymeric composition having polythiaformal linkages therein, of the formula:
- R.sub.1 --O--A--O--CH.sub.2 --.sub.n S--R.sub.2, wherein
- R.sub.1 is selected from the group consisting of hydrogen and the group R.sub.3 --O--CH.sub.2 --; R.sub.2 and R.sub.3 are independently selected from the group consisting of hydrogen and the monovalent residue of monothiols, said residue of monothiols being present in the statistical average polymer chain at least to about 50 mole percent of the terminal groups; A is the divalent residue of thiadiols having at least 4 carbon atoms; and n is an integer from 2 to 40, said monothiols selected from the group consisting of primary alkyls and aralkyls and mixtures thereof, and said thiadiols selected from the group consisting of primary thiaalkylenes, oxa-thiaalkylenes and mixtures thereof.
- 2. The composition of claim 1 in which the divalent residues of thiadiols are primary thiaalkylenes having from 4 to 20 carbon atoms.
- 3. The composition of claim 1 in which the monovalent residues of the monothiols are primary alkyls having from 4 to 20 carbon atoms.
- 4. The composition of claim 1 in which the divalent residues of the thiadiols are primary thiaalkylenes having from 4 to 20 carbon atoms and the monovalent residues of the monothiols are primary alkyls having from 4 to 20 carbon atoms.
- 5. The composition of claim 1 in which the monovalent residues of the monothiols are primary aralkyls having from 7 to 20 carbon atoms.
- 6. The composition of claim 1 in which the divalent residues of thiadiol are oxa-thiaalkylenes having from 4 to 20 carbon atoms.
- 7. The composition of claim 1 which is the liquid phase reaction product of a primary thiadiol, formaldehyde and a monothiol.
- 8. The composition of claim 1 in which the thiadiol is thiodiglycol.
- 9. The composition of claim 1 in which the monothiol is dodecyl mercaptan.
- 10. The composition of claim 1 in which the monothiol is tridecylmercaptan.
CROSS REFERENCE TO RELATED APPLICATIONS
This application is a continuation-in-part of application Ser. No. 300,685 entitled "Novel Plasticizer Compositions and Method for Their Preparation," filed Oct. 25, 1972, now abandoned.
US Referenced Citations (8)
Non-Patent Literature Citations (2)
Entry |
Lienhard et al.; J. Am. Chem. Soc. 88 pp. 3982-3995 (1966). |
Walker; "Formaldehyde" (1963) pp. 279-280. |
Continuation in Parts (1)
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Number |
Date |
Country |
Parent |
300685 |
Oct 1972 |
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