The present invention relates generally to apparatuses and systems for producing electrochemically activated solutions (e.g., electrolyzed water). More particularly, the present invention relates to simultaneously producing alkaline electrolyzed water and acidic electrolyzed water.
Systems and methods are known that electrolyze water containing alkali salts to produce acidic electrolyzed water and alkaline electrolyzed water. Acidic electrolyzed water, which typically has a pH between about 3.0 and about 6.5, generally comprises a disinfectant that is increasingly used in a variety of sanitizing applications including in the medical, agricultural and food processing industries and in other institutional environments. The alkaline (i.e., basic) electrolyzed water also has a disinfecting as well as a detergent and denaturing effect and is useful in cleaning oil and grease stains. Sodium chloride is commonly used as the alkali salt that is dissolved in the water because it produces acids and bases that are environmentally friendly, potent and low in cost.
The known systems and methods for electrolyzing water can be complex, even difficult, to operate. Some known systems and methods require large-scale pre-treatment of water prior to entering the known systems. For example, some electrolytic processes require exceedingly pure water in order to consistently produce electrolyzed water product(s). Examples of large-scale pre-treatment include, but are not limited to, distillation, deionization, membrane treatment, and the like.
A need for smaller quantity production of electrolyzed water products exists in many applications. For example, households and smaller commercial establishments such as restaurants, service stations and grocery stores have a need for acidic electrolyzed water and alkaline electrolyzed water cleaning products, but at significantly lower quantities than are typically produced by commercially available water electrolyzing systems. Such commercially available water electrolyzing systems generally produce volumes of electrolyzed water products that are appropriate for much larger establishments, such as industrial facilities, hospitals, hotels and other institutional settings. The use of these large volume producing water electrolyzing systems in smaller settings is uneconomical.
Some commercially available water electrolyzing systems can also be overly complicated and expensive to maintain, which can be a problem if the system is to be operated only occasionally such as when a particular demand arises for electrolyzed water products. Additionally, known systems and methods for electrolyzing water are generally more efficient if operated continuously, or at least semi-continuously, which does not lend itself to portability. Portable systems tend to be relatively small and generally require water being input into the system to be substantially free of calcium and magnesium. All systems for electrolyzing water, but particularly systems that are relatively small in size, are generally prone to fouling caused by hard water. Water hardness varies significantly in different regions of the country, as well as locally within a geographical area. The water hardness can significantly impede the reliable electrolytic processing of water electrolyzing systems.
In view of the foregoing, it is an object of the present invention to provide an electrolyzing system having a compact design that allows for portability of the system.
A further object of the present invention is to provide an electrolyzing system of the foregoing type that provides for simple, cost effective control of operation of the system.
Another object of the present invention is provide an electrolyzing system as characterized above that is able to operate efficiently and in an on-demand manner to produce a single batch of electrolyzed water.
A further object of the present invention is to provide an electrolyzing system of the foregoing type that is capable of being operated without any fixed plumbing.
These objects are not intended to limit the scope of the present invention. Moreover, other objects and advantages of the invention will become apparent upon reading the following detailed description and upon reference to the drawings.
While embodiments encompassing the general inventive concepts may take various forms, there is shown in the drawings and will hereinafter be described various illustrative and preferred embodiments with the understanding that the present disclosure is to be considered an exemplification and is not intended to be limited to the specific embodiments.
Referring to
The terms “aqueous solution” and aqueous chemical solution are used herein to describe a water-containing liquid that is produced by a cartridge, cell, system or method disclosed herein (e.g., acidic electrolyzed water and alkaline electrolyzed water), or will become so (e.g., fresh water, any intermediate substance entering, contained in, or leaving space 100). Though brine is an aqueous solution in the general sense of the term, brine is not an “aqueous solution” or an “aqueous chemical solution” as referenced in this application.
The portable electrolyzing system 10 may include a housing 12 within which the various components associated with the system 10 may be arranged. As discussed further below, the housing 112 may be relatively compact in size. A compact configuration can not only save on space, which can be a significant issue in smaller establishments in which the electrolyzing system 10 may be used such as restaurants and homes, but also allow the electrolyzing system 10 to be portable. In this case, the housing 12 includes a base 14, an upstanding exterior wall 16 and a cover 18. The interior of the housing 12 is configured to define a brine bath or compartment 20 and a separate fresh water compartment 22. As shown for example in
At least one electrolytic cartridge 30 having a positively charged electrode 31 (i.e., an anode) and at least one electrolytic cartridge 30 having a negatively charged electrode 31 (i.e., a cathode) may be arranged in the brine compartment 20 as shown in
The cartridges 30 are configured to electrolyze the brine in the brine compartment 20 and thereby draw in positively and negatively charged ions into the respective cartridges 30. To this end, each cartridge 30 may include an ion permeable membrane 32 (visible in
As shown in
The electrode 31 contained in each cartridge 30 is generally constructed of a conductive substance, which generally is a metal. In certain embodiments the anode, i.e., the positively charged electrode 31, is constructed of a substance that is compatible with aqueous acidic solutions (e.g., acidic electrolyzed water). In a preferred embodiment, the anode is constructed of titanium coated with a mixed metal oxide coating, e.g., a coating of oxides of certain metals. In certain embodiments, the mixed metal oxide coating comprises oxides of tantalum, ruthenium, and iridium. In certain embodiments of the cathode, i.e., the negatively charged electrode 31 is constructed of a conductive substance that is compatible with aqueous alkaline solutions. In a preferred embodiment, the cathode is constructed of titanium or an alloy thereof. The electrode 31 may have, e.g., a solid plate or dimpled construction, or otherwise constructed to provide current as necessary to perform the electrolytic reactions described herein.
To allow for the flow of ions towards the electrode plate 31, the membranes 32 are ion permeable. In particular, cartridges 30 having negatively charged electrodes 31 are equipped with positive ion exchange membranes 32, i.e., cation selective membranes. In certain embodiments, cation selective membranes allow alkali ions to pass through. In a preferred embodiment, the cation selective membrane(s) allow sodium ions to pass through. In a preferred embodiment, the cation selective membrane(s) is/are constructed of a sulfonated tetrafluoroethylene based fluoropolymer-copolymer. Cartridges 30 having positively charged electrodes 31 are equipped with negative ion exchange membranes 32, i.e., anion selective membranes. In certain embodiments, anion selective membranes allow, among others, halide ions to pass through. In a preferred embodiment, the anion selective membrane(s) allow, among others, chloride and/or chlorate ions to pass through. In a preferred embodiment, the anion selective membrane(s) are constructed of a polytetrafluoroethylene cloth having a sulfonated tetrafluoroethylene coating. According to a preferred embodiment, membranes 18 have a rigid yet porous structure.
Additional information regarding the structure and operation of embodiments of the cartridges, electrodes and membranes can be found in U.S. Pat. Nos. 8,753,489 and 9,103,043 and pending U.S. Provisional Application Nos. 62/174,791 and 62/111,980 the disclosures of which are incorporated herein by reference.
As shown in
Each cartridge 30 can be considered to be self-contained in that it merely needs to be immersed in the brine compartment 20, appropriately charged, and connected to the fresh water supply in the fresh water compartment 22 and chemical outlets, as long as at least two cartridges 30 are present, with one of the cartridges having a positively charged electrode and the other cartridge having a negatively charged electrode. However, multiple cartridges 30 of each may be included in a particular system, and an equal number of each may not be present. While the illustrated embodiment has the fresh water inlet 36 at a lower end of each cartridge 30 (relative to the cartridge as supported in the brine compartment) and the aqueous chemical solution outlet 38 at an upper end of each cartridge 30, the cartridges 30 could be configured such that water is introduced and aqueous chemical solution is drawn off from the same end of the cartridges.
To allow for the transfer of fresh water from fresh water compartment 22 to the inlet 36 of each cartridge 30, the inlet 36 of each cartridge is connected to a fresh water supply line 40 (a portion of which can be seen in
In the illustrated embodiment, the platform 52 of the dispensing station 48 is configured with two dispensing positions 54 that in this case are arranged side-by-side beneath the manifold 46 as shown in
In the illustrated embodiment, the manifold 46 is configured to deliver alkaline electrolyzed water to one of the dispensing positions 54 and acidic electrolyzed water to the other dispensing position 54. It will be appreciated that the dispensing station 48 may have a configuration different than that shown in the drawings. For example, one of the dispensing positions 54 may be relatively larger than the other (i.e., capable of receiving a relatively larger volume container. Additionally, the dispensing positions 54 may be oriented differently with respect to each other, such as spaced further apart or separated by a divider wall. According to an alternative embodiment, the dispensing system 44 may be configured to direct some or all of the aqueous chemical solution produced by the cartridges 30 to a discharge hose that may be used to fill a larger container such as a bucket that is not positioned in the dispensing station 48. The dispensing system 44 may be configured to direct one or both of acidic electrolyzed water and alkaline electrolyzed water to the discharge hose.
For driving movement of the fresh water in the fresh water compartment 22 to the respective inlets 36 of the cartridges 30, the electrolyzing system 10 includes a pump 56. More specifically, the pump 56 (shown schematically in
For supplying electric power to the pump 56 as well as the electrodes 31 contained in the cartridges 30, the portable electrolyzing system 10 includes an electrical power supply 58. In the illustrated embodiment, the power supply 58 is electrically connected to each of the electrodes 31 via lines 60 as shown in
For controlling the operation of the pump 56 and the electrodes 31 in the cartridges 30 in the brine compartment 20, the connection of the power supply 58 to the electrodes 31 in the cartridges 30 and pump 56 may be directed by a control system including a control circuit 68. In particular, the control system may be configured to provide automatic control of power to the pump 56 and the electrodes 31 based on flow of fresh water to the electrode 31 in this case through the freshwater supply line 40. As shown in
The closing and opening of the relay 70 is controlled by a relay control circuit 77 that includes a manual on/off switch 78 and a flow switch 80 as shown in
The on/off switch 78 is configured to be manually operated such that an operational cycle of the electrolyzing system 10 may be begun by an operator actuating the switch to the closed position. As noted above, the closing of the switch 78 actuates the relay 70 and allows power to be delivered to the electrodes 31 and the pump 56. The pump 56 then starts-up and begins moving fluid from the fresh water compartment 22 to the cartridges 30. This initial flow of fluid to the cartridges 30 that results from actuation of the on/off switch 78 is sufficient to actuate the flow control switch 80 and close it. Thus, the on/off switch 78 need only close for a short period of time when actuated by an operator to start operation of the electrolyzing system 10. Once the pump 56 has been started, the on/off switch 78 may reopen and current through the relay control circuit 77 is then controlled by the flow control switch 80. When the fresh water compartment 22 is emptied of fresh water, flow of fresh water to the cartridges 30 will cease and the flow control switch 80 will deactivate. This will open the relay control circuit 77 halting the flow of current to the inductor coil 84 resulting in the opening of the switches 72, 74 and the halt of power flow to the electrodes 31 and the pump 56.
The control circuit 68 of the present disclosure provides a simple, cost effective way to control operation of the electrolyzing system 10, in particular to control the flow of electricity and fluid to the cartridges 30. The control system does not require any complicated electronics, such as microelectronic controls are necessary. Likewise, no complicated flow control valves are required so long as the pump 56 produces sufficient flow of fresh water to and through the cartridges 30.
To operate the electrolyzing system 10 of the present disclosure, a user may manually fill the fresh water compartment 22 with fresh water from a separate supply thereof. Any supply of fresh water can be used including, for example, tap or bottled water. The fresh water can be introduced into the fresh water compartment 22 through the fill opening 26 in the cover 18 of the housing 12. Once filled, the operator may replace the cap 28 in the fill opening 26. While the fresh water compartment 22 will generally need to be filled prior to each operating cycle of the electrolyzing system 10, the brine in the brine compartment 20 is usable for multiple cycles of the electrolyzing system 10. If it is necessary to refill or replace the brine in the brine compartment 20, salt can be mixed with water to produce brine for the brine compartment 20. The brine may be mixed in a container outside of the electrolyzing system 10 and then poured by the user into the brine compartment 20 by lifting the cover 18 off of the housing 12. The salt for preparing the brine may be provided in a package or bag that may be supplied with the electrolyzing system 10.
In order to provide an operator with an indication of the fluid levels in the brine compartment 20 and the fresh water compartment 22, the housing 12 of the electrolyzing system 10 may optionally include level indicator windows. In particular, separate level indicator windows could be provided on the housing so as to allow an operator to see the amount of fluid in the brine compartment 20 and the fresh water compartment. One convenient location for the level indicator windows may be in the recessed portion 50 of the exterior wall 16 at the forward end of the housing that defines the dispensing station 48 as this is a location that is readily visible to an operator using the electrolyzing system 10. Of course, the level indicator windows could be provided in other locations as well.
Prior to actuating the electrolyzing system 10, the user may also position containers on the dispensing station platform 52 to receive the aqueous chemical solutions produced by the electrolyzing system. For example, the user may position one container to receive acidic electrolyzed water and one container to receive alkaline electrolyzed water. Once the containers have been placed and the fresh water compartment 22 filled, the user may actuate the electrolyzing system 10 via the on/off switch 78. As noted above, upon actuation the electrolyzing system 10 will operate until the fresh water compartment 22 is empty at which time the flow switch 80 will deactivate the relay control circuit 77 cutting off the flow of power to the electrodes 31 and the pump 56.
According to an alternative embodiment, the electrolyzing system may optionally be configured to automatically refill the fresh water compartment 22, for example either at the end of or at the start of each operating cycle. For instance, when the flow switch 80 signals that power should be cut off to the electrodes 31 and the pump 56 because the fresh water compartment 22 is empty, a solenoid valve could open in a pressurized fresh water supply line that communicates with the fresh water compartment 22. Fresh water would then flow into the fresh water compartment 22 until a sensor, such as a fluid level sensor, indicated that the fresh water compartment 22 was filled with fresh water. The fluid level sensor would then send a signal that would deactivate or close the solenoid valve in the fresh water supply line. Alternatively, the automatic filling of the fresh water compartment could occur at the start of each operating cycle before the pump 56 starts the flow of water to the cartridges 30.
In one embodiment, fresh water that is relatively soft may provide improved operation of the electrolyzing system 10. To account for this, information regarding the hardness and/or softness of the water to be used in the fresh water compartment 22 may be gathered prior to operating the electrolyzing system 10. If this information indicates that the water to be used is too hard, provision may be made to soften the water that will be used in the electrolyzing system 10. For example, prior to using the system a test may be performed on the water supply that will be used to provide fresh water for the electrolyzing system. If the water is too hard, for example below approximately 10 grains of hardness per gallon, a sodium carbonate may be added to the water to be used in the fresh water compartment. Moreover, the sodium carbonate may be provided in small, premeasured packages that are included with the electrolyzing system 10 and can be added to the water at the time of use by an operator. Alternatively, a commercially available water softening system may be provided on the water source that will be used to provide fresh water for the electrolyzing system.
Since both the fresh water compartment 20 and the brine compartment 22 may be filled manually, the electrolyzing system 10 need not be attached to any fixed plumbing. Thus, the electrolyzing system is completely portable. Moreover, the configuration of the housing 12 provides a compact, space-saving design that can fit into a small space. As the electrolyzing system 10 can be used only on an as needed basis to make a single batch of aqueous chemical solutions at a time, it is much more efficient than large scale electrolyzing systems. The small size, portability and on-demand operation of the electrolyzing system 10 of the present disclosure provides on-the-spot convenience that makes the electrolyzing system of the present disclosure well suited for use in applications such as restaurants, grocery stores or other establishments where food is handled, service stations, retail stores, smaller hotels and nursing homes and even households. However, the electrolyzing system 10 is not limited to these applications. For example, multiple units of the electrolyzing system of the present disclosure could be provided in a larger facility.
All references, including publications, patent applications, and patents, cited herein are hereby incorporated by reference to the same extent as if each reference were individually and specifically indicated to be incorporated by reference and were set forth in its entirety herein.
The use of the terms “a” and “an” and “the” and similar referents in the context of describing the invention (especially in the context of the following claims) are to be construed to cover both the singular and the plural, unless otherwise indicated herein or clearly contradicted by context. The terms “comprising,” “having,” “including,” and “containing” are to be construed as open-ended terms (i.e., meaning “including, but not limited to,”) unless otherwise noted. Recitation of ranges of values herein are merely intended to serve as a shorthand method of referring individually to each separate value falling within the range, unless otherwise indicated herein, and each separate value is incorporated into the specification as if it were individually recited herein. All methods described herein can be performed in any suitable order unless otherwise indicated herein or otherwise clearly contradicted by context. The use of any and all examples, or exemplary language (e.g., “such as”) provided herein, is intended merely to better illuminate the invention and does not pose a limitation on the scope of the invention unless otherwise claimed. No language in the specification should be construed as indicating any non-claimed element as essential to the practice of the invention.
Preferred embodiments of this invention are described herein, including the best mode known to the inventors for carrying out the invention. Variations of those preferred embodiments may become apparent to those of ordinary skill in the art upon reading the foregoing description. The inventors expect skilled artisans to employ such variations as appropriate, and the inventors intend for the invention to be practiced otherwise than as specifically described herein. Accordingly, this invention includes all modifications and equivalents of the subject matter recited in the claims appended hereto as permitted by applicable law. Moreover, any combination of the above-described elements in all possible variations thereof is encompassed by the invention unless otherwise indicated herein or otherwise clearly contradicted by context.
Filing Document | Filing Date | Country | Kind |
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PCT/US17/21885 | 3/10/2017 | WO | 00 |
Number | Date | Country | |
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62307002 | Mar 2016 | US |