This invention relates to power sources for electrical devices. The invention relates specifically to power sources that comprise fuel cells for generating electrical power.
Fuel cells employ an electrochemical reaction to convert a fuel, such as hydrogen, and an oxidant, such as oxygen directly (without combustion) into electricity.
Many fuel cells and fuel cell systems are designed as large automotive or stationary systems. These systems typically have significant amounts of balance of plant components, such as compressors, humidifiers, heaters, coolers, and other such components. Such systems are large, complex and expensive to operate.
There have been a number of attempts to produce portable power sources incorporating fuel cell technology. However, these attempts suffer from a number of disadvantages. For example, some of these portable power sources are too large to be conveniently carried and transported. In some cases, the portable power source is not re-usable and must be disposed of after a single use. This generates a large amount of garbage and wasted materials, similar to disposable batteries. In another attempt, the power source is reusable but in order to refuel the power source, the fuel reservoir must be taken out of the power source before it can be refilled. This is inconvenient and makes the system more difficult to use.
Small portable devices such as cellular telephones, radios, portable lights, games, music players, digital cameras, and many other types of portable devices are typically powered by batteries. Battery technology has limits and is not keeping up with the demand for power.
A need therefore exists for portable power sources capable of powering or charging the batteries in portable electronic devices while overcoming the above disadvantages. A need exists for extending the run time of portable electronic devices and for increasing the operating range of portable devices while away from an electrical power grid.
One aspect of the present invention provides a portable fuel cell power source that can be used for powering a wide variety of portable electronic devices and for other applications. The power source can be used either to provide power to a portable electronic device directly, or it can be used to charge a battery in a portable electronic device. The power source can be run as an external unit or it can be adapted such that it is or can be integrated into a portable device. Power sources according to some embodiments of the invention can be refueled using a variety of refueling devices.
Further aspects of the invention and features of embodiments of the invention are described below.
In drawings that illustrate non-limiting embodiments of the invention:
In some embodiments, power source 10 comprises an array of fuel cells 26 that operate in a passive, air-breathing manner. Fuel cells 26 of this embodiment obtain oxygen from the ambient environment (air) as the oxidant in the fuel cell reaction. In some such embodiments, upper case part 12A has a grille 16 disposed such that air can enter through grille 16 to allow fluidic communication between ambient air and the passive air-breathing fuel cells 26 located inside case 12.
Fuel cells 26 may consume any suitable fuel. In some embodiments fuel cells 26 consume hydrogen as a fuel. In other embodiments, the fuel cells consume other fuels. Non-limiting examples of other fuels that may be consumed by fuel cells 26 are: methanol; formic acid; butane; and borohydride compounds.
Grille 16 may be attached to upper case part 12A and can be made from perforated stainless steel. The perforated stainless steel materials used in this embodiment have holes in the range of about 0.010″ to 0.5″ in diameter. The open area of grille 16 in some embodiments comprises from 5% to 95% of the total area of grille 16. In some such embodiments, the open area of grille 16 comprises 20% to 85% of the total area of grille 16. Other dimensions and materials for grille 16 are also possible, as long as grille 16 permits sufficient air access to fuel cells 26. Other possible materials for grille 16 include, but are not limited to, expanded steel mesh, or other perforated metals such as aluminum, plastic grilles, porous plastics, etc. Where power source 10 will be used in conditions such that it is necessary or desirable to protect fuel cells 26 from contaminants, then grille 16 may comprise or be augmented by a layer of a porous plastic, such as porous Teflon®.
The embodiment of FIGS. 1 to 4 comprises an on-off switch 17 that turns power source 10 on and off. The on-off switch may be actuated mechanically or electrically.
In the embodiment illustrated in FIGS. 1 to 4, on-off switch 17 is a fluidic switch which can be switched to either open or cut off the fuel supply to fuel cells 26. On-off switch 17 is not an electrical on-off switch in this embodiment. Electrical switches which operate solely to switch on or off the electrical output from a fuel cell do not prevent fuel from flowing into fuel cells 26 and can therefore allow wastage of fuel. By cutting off the fuel supply to fuel cells 26, a fluidic switch 17 can reduce wastage of fuel and thus promote overall higher power generating efficiency.
An indicator light 18 may be provided to provide user feedback, indicate when power source 10 has power, or combinations thereof. Indicator light 18 may comprise a light source, such as an LED. In the illustrated embodiment, a light pipe 44 transmits light from a LED mounted on a circuit board inside power source 10. If power source 10 is out of fuel, indicator light 18 will not illuminate even if on-off switch 17 is on. In the illustrated embodiment, indicator light 18 will stay lit for a while even after on-off switch 17 is shut off because residual fuel remains in the system. The indicator light 18 will stay lit until the residual fuel is used up.
A refueling port 20 is provided on power source 10. Refueling port 20 permits replenishing of the supply of fuel for power source 10. The fuel is stored on-board power source 10 in a fuel reservoir 22. Fuel reservoir 22 may be integral with power source 10 or may be designed to be removable. The design of fuel reservoir 22 may depend upon the nature of the fuel used by power source 10.
As discussed in more detail below, power source 10 can be refueled in a variety of different ways through refueling port 20. One way of refueling power source 10 is through the use of a refueling station 56. One or more notches 24 or other locating features may be provided on case 12 or in refueling port 20 for holding power source 10 when refueling in refueling station 56. Another way of refueling power source 10 is through the use of a portable refueling cartridge 58. In some embodiments, fuel reservoir 22 and refueling port 20 are as described in the commonly-owned co-pending United States patent application entitled “METHODS AND APPARATUS FOR REFUELING REVERSIBLE HYDROGEN-STORAGE SYSTEMS” being filed simultaneously herewith, which is hereby incorporated herein by reference. Where hydrogen fuel is used by fuel cells 26, power source 10 may be refueled in the manner described in that application.
Power source 10 can be used for charging the batteries of a portable electronic device, or it can be used for running a portable electronic device directly. As discussed below, power source 10 is provided with an electrical connector 52 for use in connecting power source 10 to an external electronic device. An electrical output of fuel cells 26 may be connected to electrical connector 52 directly or by way of suitable power conditioning electronics 28.
The output of power source 10 in an example embodiment is a 5 V DC output. However, the output can be any other DC output. For example, power source 10 could be configured to provide a direct current output voltage in the range of 0.5 V to 60 V by making an appropriate selection of fuel cells 26. Other voltages as well as non-DC voltages such as AC voltages may be achieved through the use of appropriate power conditioning electronics 28. DC-to-DC converters and inverters which convert DC power to AC power are well known to those skilled in the art and may be included in power conditioning electronics 28.
Reversible hydrogen-storage materials have the advantage of being able to store hydrogen quite densely from a volumetric point of view. Volumetric energy density is important for portable electronic devices since maintaining relatively small sizes of such devices may be important in some applications. Embodiments where hydrogen fuel is supplied from a reversible hydrogen-storage material can offer the advantage of storing pure dry hydrogen for delivery to fuel cells 26.
Fuel reservoir 22 may be integrated into power source 10 or may be removable. Fuel reservoir 22 may have any of a wide range of constructions. For example, fuel reservoir 22 may comprise a cellular reservoir as disclosed in U.S. provisional patent application No. 60/757,782 entitled “Cellular reservoir and methods related thereto” filed 9 Jan. 2006, which is hereby incorporated by reference.
Fuel reservoir 22 may optionally be segmented into a number of compartments which store reversible hydrogen-storage material. Internal structures may be provided in fuel reservoir 22 to provide mechanical strength, provide segmentation of fuel reservoir 22, assist in heat transfer, or the like. Such internal structure, if present, may be cellular, honeycomb, or have some other configuration.
A pressure relief valve 29 prevents pressure inside fuel reservoir 22 from building up too high. Pressure relief valve 29 may also act as a safety mechanism to prevent excessive pressure build-up in fuel reservoir 22 or in a refueling cartridge 58 while fuel reservoir 22 is in fluid communication with portable refueling cartridge 58 as discussed in more detail below.
In some embodiments, a pressure regulator 30 is disposed between fuel reservoir 22 and fuel cells 26. In such embodiments, pressure regulator 30 regulates the pressure of fuel supplied from fuel reservoir 22 to fuel cells 26. In one example embodiment, fuel reservoir 22 contains hydrogen as a fuel stored in a reversible hydrogen-storage material having a charge pressure of about 150 psi and a plateau (or “desorption”) pressure of roughly 30 psi. Other charge and plateau pressures are also possible by appropriate selection of hydrogen-storage material in fuel reservoir 22.
Pressure regulator 30, when present, controls the flow of fuel from outlet 34 of fuel reservoir 22. Pressure regulator 30 steps the pressure from fuel reservoir 22 down to a pressure suitable for fuel cells 26. For example, various fuel cells 26 can be operated with hydrogen supply pressures in the range of approximately: 0.1 to 100 psi or 0.3 to 30 psi or 0.5 to 5 psi. Pressure regulator 30 may regulate the pressure of fuel being supplied to fuel cells 26 to be within one of these ranges. Other fuel cells may require fuel to be supplied at a pressure within some other range of pressure pressures.
As shown schematically in
In the illustrated embodiment, the array of fuel cells 26 comprises eight fuel cell modules, two rows of four fuel cell modules each, arranged electrically in parallel (
Suitable fuel cell modules are made by Angstrom Power Inc., of North Vancouver, Canada. Each fuel cell module may have an open circuit voltage (OCV) of approximately 9 V and an operating voltage of approximately 5 to 6 V, for example. Different voltages are possible by using different fuel cell modules or by combining fuel cell modules in different series and parallel connections.
Fuel cells 26 may have any of a wide range of constructions and configurations. Some non-limiting examples of fuel cells that may be used as fuel cells 26 are described in the following United States patents and patent applications:
In the embodiment illustrated in
An output flow restrictor 50 may be provided in order to limit the flow rate of fuel to fuel cells 26. Output flow restrictor 50 can be in the form of an orifice, a laminar flow element, a porous material, a valve, or some other type of flow-restricting element. In the illustrated embodiment, output flow restrictor 50 is shown between pressure regulator 30 and fuel on-off switch 17. The output flow restrictor 50 could be located between fuel reservoir 22 and pressure regulator 30, or between fuel on-off switch 17 and fuel cells 26, or it could be omitted altogether. An output flow restrictor could be integrated into pressure regulator 30, if present.
As discussed above, the fuel on-off switch 17 selectively allows or inhibits the flow of fuel to fuel cells 26. In this embodiment, no additional compressors, humidifiers, or heaters are typically required for the fuel as in some other fuel cell systems.
Fuel cells 26 use fuel from fuel reservoir 22 and ambient air from the environment to create electricity through an electrochemical reaction. Where the fuel is hydrogen, the reaction produces water vapour as its byproduct. The electrical output from fuel cells 26 is fed into power conditioning electronics 28 and is regulated to an output voltage. Some of the electricity is used to power indicator light 18. The regulated output can be directed to an electrical connector 52 that allows for connection to external portable electronic devices as described in U.S. patent application Ser. No. 11/342,005 entitled Fuel cell charger filed 27 Jan. 2006, which is hereby incorporated by reference. As disclosed in U.S. Ser. No. 11/342,005, electrical connector 52 may be a standard or universal type of port found on many electronic devices. For example, electrical connector 52 may be a communications port, such as a Universal Serial Bus (USB) port, which is incorporated into many electronic devices. Electrical connector 52 comprising such a port allows power source 10 to charge a variety of electronic devices without the need for specific chargers or adapters. The system can be used to charge the battery in an external electronic device, or it can be used to power a load directly.
As best seen in
In some embodiments, the array of fuel cells 26 comprises a plate 27 that contacts face 25 of fuel reservoir 22. Plate 27 may perform one or more of the following functions:
In some embodiments, plate 27 comprises a printed circuit board carrying metal traces that serve as heat conductors and/or electrical conductors. Plate 27 may comprise through-holes containing plated metal or other thermally-conductive materials to provide a path of high thermal conductivity between fuel cells 26 and fuel reservoir 22. If it is desired that fuel cells 26 and fuel reservoir 22 be thermally insulated from one another then a layer of insulating material may be provided between plate 27 and fuel reservoir 22.
In other embodiments face 25 and fuel cells 26 may be thermally-insulated from one another. In such embodiments there may be electrical circuitry, insulating material, a gap or the like between face 25 and fuel cells 26.
Fuel reservoir 22 may be constructed in a prismatic form. A prismatic form can permit power source 10 to have a more ergonomic flattened form factor than would be possible if fuel reservoir 22 were cylindrical.
In an example embodiment in which refueling station 56 supplies hydrogen fuel, hydrogen may be supplied at or above the charging pressure of an on-board reversible hydrogen-storage material contained in fuel reservoir 22. In one such embodiment, refueling station 56 supplies hydrogen gas at 150 psi in order to charge the onboard reversible hydrogen-storage material in fuel reservoir 22 of power source 10. Other charge pressures are also possible.
The portable refueling cartridge 58 does not necessarily need to have a regulator in it. For example, portable refueling cartridge 58 could contain hydrogen compressed at a high pressure (e.g., 500-5000 psi). Inlet flow restrictor 48 of power source 10 restricts the flow of hydrogen gas into a reversible hydrogen-storage material of fuel reservoir 22 in order to prevent excessive pressure build-up inside fuel reservoir 22.
If the pressure does build up too high, or if a user attempts to refuel fuel reservoir 22 when it is already full, pressure relief valve 29 in power source 10 will activate and relieve any excess pressure. This is because fuel reservoir 22 and portable refueling cartridge 58 are in fluid communication when the two are engaged for refueling. Thus, pressure relief valve 29 acts as a safety mechanism to prevent excessive pressure build-up in fuel reservoir 22 both when it is on its own and while being refueled by portable refueling cartridge 58.
In the illustrated embodiment, fuel reservoir 22 is in fluid communication with refueling port 20 through a charging valve 66 disposed in power source 10 between fuel reservoir 22 and refueling port 20. Charging valve 66 enables fuel to flow from portable refueling cartridge 58 to fuel reservoir 22 when portable refueling cartridge 58 is connected to power source 10, but prevents the discharge of fuel from refueling port 20 after portable refueling cartridge 58 has been disconnected. Portable refueling cartridge 58 provides fuel to power source 10 through a discharge port 68 disposed on the shell of portable refueling cartridge 58. Discharge port 68 comprises a valve, septum or rupture disc that is opened by an actuating mechanism 70. Actuating mechanism 70 may be associated with refueling port 20 so that connecting portable refueling cartridge 58 to refueling port 20 automatically opens discharge port 68 to allow fuel to flow from portable refueling cartridge 58 to fuel reservoir 22.
In the illustrated embodiment, the engagement of power source 10 to refueling station 56 within slot 59 is similar to the engagement of power source 10 to portable refueling cartridge 58. Power source 10 slides into slot 59 and notch 24 is engaged by mechanism 54 in refueling station 56. Slot 59 locates power source 10 so that its refueling port 20 is aligned with a discharge port similar to discharge port 68 of portable refueling cartridge 58. The slot discharge port may comprise a valve, septum or the like that is opened by actuating mechanism 70. As power source 10 is slid into slot 59, a seal is made between refueling port 20 and the discharge port. Further motion of power source 10 into slot 59 causes actuating mechanism 70 to operate so that fuel is transferred into the on-board fuel reservoir of power source 10.
Refueling port 20 of power source 10, including seal 64 and actuating mechanism 70 interacts with the discharge mechanism of slot 59 and discharge port 68 of portable refueling cartridge 58 in similar ways. In the illustrated embodiment, the tip of the discharge port that engages seal 64 of refueling port 20 is small enough in diameter to fit inside the female screw thread that are provided on the illustrated refueling port 20 to engage screw threads of a portable cartridge 58.
Refueling port 20 of power source 10 can be engaged with the discharge port in the illustrated refueling station 56 with a substantially linear motion whereas engaging refueling port 20 with discharge port 68 of the portable refueling cartridge 58 illustrated in FIGS. 6 to 8 requires a relative rotary motion to engage the screw threads of holding mechanism 62. Thus, one advantage of power source 10 is that it is adapted to be interfaced to a plurality of different extrinsic refueling sources (such as portable cartridges and stationary refueling stations) that may have different configurations using the same refueling port 20.
In accordance with an embodiment of this invention, portable fuel cell power source 10 comprises the combination of fuel reservoir 22 for storage of fuel which is provided to fuel cells 26 for generating electricity. The fuel supply is controlled by fuel supply on-off switch 17 and the electricity produced is modulated by power conditioning electronics 28 before being supplied to an external electronic device through electrical connector 52. Electrical connector 52 may be of a standard or universal type that is found in or may be incorporated into many different types of electronic devices. Fuel is supplied to fuel reservoir 22 via a refueling port 20 which is adapted to be connected to different extrinsic refueling sources, such as stationary refueling station 56 or portable refueling cartridge 58.
A portable power source as described herein can have a number of advantages over batteries. It can be used to charge portable electronic devices or directly run portable electronic devices while away from an electrical power grid connection or some other source of power. The power source itself is small and portable and can be conveniently carried to wherever it is required. Example embodiments use air from the ambient environment and contain much less balance of plant components than traditional stationary fuel cell systems. The compressors, humidifiers, heaters, coolers, and other such balance of plant components typically found in other large fuel cell systems are eliminated. This makes for a much simpler, more robust system, and also greatly improves the total volumetric energy density of the system.
As will be apparent to those skilled in the art in the light of the foregoing disclosure, many alterations and modifications are possible in the practice of this invention without departing from the spirit or scope thereof. For example, the features of the embodiments described above may be combined in combinations or sub-combinations that are not explicitly described above or elements of the described embodiments may be substituted by functional equivalents thereof. Accordingly, the scope of the invention is to be construed in accordance with the substance defined by the following claims.
This application claims the benefit under 35 U.S.C. §119 of U.S. provisional patent applications No. 60/719,605 entitled “Portable Fuel Cell Power Source” filed 23 Sep. 2005, No. 60/719,603 entitled “Method and Apparatus for Refueling Reversible Metal Hydride Hydrogen Storage System” filed 23 Sep. 2005, and No. 60/757,782 entitled “Cellular Reservoir and Methods Related Thereto” filed 9 Jan. 2006, all of which are hereby incorporated by reference.
Number | Date | Country | |
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60719605 | Sep 2005 | US | |
60719603 | Sep 2005 | US | |
60757782 | Jan 2006 | US |