Patent Application
20170248129
The present invention relates to the field of dispensing fluid products such as paints, colorants and the like. The invention has been developed with particular regard to the dispensing machines used in order to discharge fluid products such as paints, colorants and the like. In greater detail, the invention relates to a positive-displacement pump for discharging such fluid products. The invention further relates to a pumping group which comprises a positive-displacement pump of that type. Furthermore, the invention relates to the method for using the positive-displacement pump and the pumping group for dispensing such fluid products.
Machines for dispensing colorants comprise a plurality of tanks which contain fluid colorants. In order to obtain a paint of a specific colour, a dispensing machine provides for discharging predetermined quantities of the various colorants which are added to and mixed with a base paint which is contained in a can. The discharge of the colorants is brought about by means of the actuation of one or more positive-displacement pumps which take desired quantities of colorant from the respective tanks and transfer them to a dispensing nozzle, below which the can is positioned with the base paint.
The discharge of fluid colorant products poses some problems which are unknown in other fields of use of positive-displacement pumps, such as the field of discharging drinks or the field of injecting plastics materials. The fluid colorant products in fact have specific chemico-physical properties which require special arrangements. Many colorants are aggressive and corrosive, for which the pumps have to be resistant to wear. The fluid colorant products are further rather viscous and tend to enclose air at the inner side thereof, which has to be discharged before the start of the discharge operation proper, in order not to compromise the accuracy and the repeatability of the discharge operation.
In the field of dispensing machines for colorants, there are used various types of positive-displacement pumps. WO 1986/02320 sets out a dispensing machine of known type. This type of dispensing machine is generally provided with positive-displacement pumps of the gear type. Gear pumps allow high discharge volumes to be reached and are typically used for industrial type plants. This type of pump is particularly subject to wear, especially in the case where the fluid colorant products contain granular particles, such as, for example, in the case of metallic paints for bodies of motor vehicles.
U.S. Pat. No. 5,511,695 sets out a dispensing machine with positive-displacement pumps of the piston type. This type of pump has a rather large spatial requirement in addition to problems of wear and tightness in the region of the sliding seals.
WO 2000/46506 sets out an injection type pump for a dispensing machine comprising a pumping chamber with a variable volume defined by a bellows. The bellows extends and contracts under the thrust of a stepping motor. The extension of the bellows determines the intake of fluid product inside the pumping chamber through a non-return intake valve while the contraction of the bellows urges the fluid product towards the discharge pipe via a second non-return discharge valve. In this type of pump, the construction of the bellows is critical in order to ensure the reliability and repeatability and for this reason the pump is particularly expensive. Furthermore, the colorant tends to stop in the folds of the bellows, settling and reducing the performance levels and precision of the pump over time.
WO 2008/105007 sets out a pumping group for a dispensing machine for colorants. In this case, the discharge of colorant is brought about by means of a single screw pump having a helical rotor and a rubber stator. This pump has a limited capacity and cannot be operated at excessive speeds because it becomes heated and tends to seize.
EP2174009 sets out another type of positive-displacement pump for dispensing machines for colorants. In this case, a piston moves alternately inside a jacket in order to define a variable cylindrical volume. Behind the piston there is arranged an elongate element which is configured in the manner of a bellows and which acts as a seal and guide on the jacket. In this pump, the colorant tends to retain air therein; because the air is compressible, the precision and repeatability of the discharge of colorant by means of this pump are very unsatisfactory. Furthermore, in this pump the colorant tends to settle on the head.
An object of the present invention is to provide a positive-displacement pump and a pumping group which solve the problems of the prior art, and which in particular provide a high level of precision and repeatability for dispensing fluid products such as paints, colorants and the like. Another object of the invention is to provide a positive-displacement pump and a pumping group which are economical, reliable and which can ensure a long service-life with the nominal characteristics. Another object of the invention is to provide a positive-displacement pump and a pumping group which have compact dimensions and which are easy to assemble and maintain on a dispensing machine.
Another object of the invention is to provide a pump and a pumping group which can also discharge very small quantities of fluid product with precision and repeatability in order to allow a high level of precision in the reproduction of a great range of gradations of colour in the finished paints. Another object of the invention is to provide a pump and a pumping group which can readily be assembled in different configurations for volume and principle of use so as to be versatile in accordance with the specific characteristics of the fluid to be moved.
In order to achieve those objects, the invention relates to a pump, a pumping group and a method for the use thereof having the features defined in the appended claims.
According to one aspect, the positive-displacement pump for fluid products, in particular paints, colorants and the like, comprises a pump body in which a pumping chamber is formed. A piston is mounted for sliding in the pumping chamber. The piston is controlled so as to advance and withdraw in order to vary the useful volume of the pumping chamber. The pumping chamber is placed in communication with at least one intake pipe of a fluid product. The pumping chamber is placed in communication with at least one discharge pipe of a fluid product. The intake and discharge pipes are preferably formed so as to be integral in a head body which is mounted on the pump body. The construction of the positive-displacement pump as two main components allows use of the same pump body for different configurations of the intake and discharge pipes, with particular reference to the interception means of those pipes.
Preferably, the interception means of the intake pipe are mounted on the head body.
Advantageously, the interception means of the discharge pipe are mounted on the head body.
Preferably, a three-way valve is mounted on the head body incorporating the interception means of the intake pipe and the interception means of the discharge pipe.
Preferably, the three-way valve comprises an actuator member which is mounted on the head body.
Preferably, the piston is operationally connected to a motor which is mounted on a support which is fixed to the pump body.
Preferably, a single pumping pipe which branches off into the intake pipe and the discharge pipe leads from the pumping chamber.
Preferably, the single pumping pipe leads into the pumping chamber at an upper region thereof.
An adapter can be mounted inside the pumping chamber in order to reduce the volume thereof and therefore the cylindrical capacity. This allows the construction of a single pump body which can be used for different fluids and applications which require different cylindrical capacities.
Preferably, the pumping chamber comprises a substantially cylindrical portion with a constricted end. The adapter also comprises a cylindrical portion with a constricted end, whose geometry and external dimensions correspond substantially to the geometry and the internal dimensions of the pumping chamber so that the adapter is suitable for covering the internal walls of the pumping chamber in order to produce a smaller pumping chamber. In other words, the adapter fits completely with respect to the housing thereof which is constituted by the pumping chamber having greater dimensions.
Preferably, the external covering of the piston of the positive-displacement pump is of bellows-like form. The adapter has at the bottom an annular step which at the outer side moves into abutment with an abutment member at the end of the pumping chamber and at the inner side acts as an abutment for an annular portion having a greater diameter of a sleeve of a piston. The piston has a total diameter which is smaller than a piston which can be used in the pumping chamber without an adapter. The formation of the adapter and the reduced piston allow optimum performance levels in terms of sealing, precision and repeatability of the pump having a reduced cylindrical capacity.
Advantageously, the pumping chamber has a pumping opening which communicates with at least one intake pipe of a fluid product. The adapter comprises an opening which is placed in correspondence with the pumping opening of the pumping chamber. The fluid passage from and through the reduced pumping chamber is not therefore obstructed in spite of the presence of the adapter.
Preferably, the pumping opening and the opening of the adapter are positioned in an upper region of the pumping chamber and the reduced pumping chamber, respectively, which are positioned at a greater height with respect to a horizontal plane in order to promote the discharge of air from the reduced pumping chamber, in the same manner as that provided for the pumping chamber in terms of the greater dimensions thereof.
According to another aspect, the positive-displacement pump for fluid products comprises a pumping chamber, in which there is mounted in a sliding manner a piston which is controlled so as to advance and withdraw by a motor in order to vary the useful volume of the pumping chamber. The pumping chamber can communicate with a three-way valve. The three-way valve can be actuated in selective communication with an intake pipe and a discharge pipe. The independent actuation of the motor and the three-way valve allows the elimination of the air which may be contained in the fluid product to be brought about before starting the discharge operation proper, and further allows the recovery of the mechanical play of the pump and the start of the discharge operation without any resilient recovery thereof. In this manner, there is brought about a high level of precision and repeatability during operation of the positive-displacement pump.
Preferably, the pumping chamber extends in accordance with a longitudinal axis which is inclined with respect to a horizontal plane. Preferably, the longitudinal axis is not vertical. Even more preferably, the inclination is less than approximately 60° and even more preferably less than approximately 45°. This allows the air which may be enclosed in the fluid product to migrate naturally towards an upper region of the pumping chamber, which is positioned at a greater height with respect to a horizontal plane. Advantageously, the pumping chamber is placed in communication with the three-way valve at the upper region in order to promote the discharge of the air which may be contained in the fluid product and the introduction thereof into the tank before the discharge operation proper.
Advantageously, the pumping chamber of the positive-displacement pump comprises a substantially cylindrical portion with a constricted end. Preferably, the constricted end is substantially frustoconical. In this manner, the upper region may be positioned near or in the region of the constricted end, which is preferably substantially frustoconical, in order to produce a constructive simplicity of the pump, which is particularly compact.
According to another aspect of the positive-displacement pump, the outer skirt of the piston is in the form of a bellows. In this manner, there is produced a fluid-tightness without seals in the interface between the piston and the internal wall of the pumping chamber. The absence of seals makes it possible to use processing tolerances which are less extreme than those currently used in the pumps currently in use in the sector of dispensing colorants, paints and the like, which use materials such as glass, steel or ceramic material with lapped contact surfaces. In the positive-displacement pump which is described here, it is possible to use a more economical moulding operation of plastics material.
According to another aspect, the three-way valve of the positive-displacement pump comprises a valve chamber which is provided above the pumping chamber. Preferably, the intake pipe of the positive-displacement pump is inclined with respect to a horizontal plane from the valve chamber as far as the tank containing the fluid product. In this manner, there is obtained a spontaneous migration of the air from the pumping chamber as far as the tank, in a recirculation configuration of the pump.
According to another aspect, the positive-displacement pump comprises a pump body in which the pumping chamber is formed. The three-way valve comprises an actuation member which is mounted on a pump body for easier and more convenient assembly of the pump. Even more advantageously, the actuation member is inclined with respect to the vertical in order to reduce the spatial requirement.
Advantageously, the valve chamber, the intake pipe and the discharge pipe are formed so as to be integral in a head body which is mounted on the pump body, for ease of construction, assembly and maintenance.
According to another aspect, the valve chamber, the intake pipe and the discharge pipe are formed so as to be integral in a head body which is mounted on the pump body. In this manner, there is obtained great flexibility of use of the positive-displacement pump. For example, it is possible to produce a single pump body for various configurations of the positive-displacement pump, individually or in a pumping group with a single common three-way valve.
According to another aspect, the volume of the pumping chamber can be reduced by using a reduction adapter and a piston having dimensions which are correspondingly smaller. In this case, there is also produced a great flexibility and standardization of the pump which can be readily brought to various cylindrical capacities with limited costs.
According to another aspect, at least two positive-displacement pumps define a pumping group in which the positive-displacement pumps are operationally connected in such a manner that the withdrawal of the piston of another positive-displacement pump corresponds to the advance movement of the piston of one of the at least two positive-displacement pumps. Such a pumping group allows the production of a discharge which is almost continuous of a volume of fluid product greater than the cylindrical capacity of each positive-displacement pump of the pumping group.
Advantageously, in the pumping group the at least two positive-displacement pumps are connected by means of a gear mechanism controlled by a single motor. In this manner, there is ensured complete synchronization between the positive-displacement pumps.
According to another aspect, there is described a method for using a positive-displacement pump in which the intake pipe is connected to a tank of fluid product. The pump comprises a discharge pipe and interception members which can be selectively controlled in order to open and close the intake pipe and the discharge pipe. The method comprises the steps of:
Such a method allows any air which may be contained in respect of the pumping chamber and which has accumulated at the upper region thereof to be urged and to be returned to the tank before the discharge operation proper of fluid product begins, the precision and repeatability of which would be compromised by the significant presence of air in the fluid product.
Additional features and advantages will be appreciated from the following detailed description of some preferred embodiments of the invention, given purely by way of non-limiting example and with reference to the appended drawings, in which:
With reference now to
At the opposite side to the pumping chamber 3, the central shaft 8 of the piston 5 extends into a handling shank 19 with a longitudinal guiding fin 20 which is inserted in a slot 21 of the support group 16 of the motor 22. An extension piece 24 projects radially from the handling shank 19 in order to interact with a sensor 25 which is mounted on a support plate 26 which is fixedly joined to the support group 16. The handling shank 19 is connected to the stepping motor 22 by means of a handling screw 31 which allows a conversion of the rotational movement of the stepping motor 22 into a translation movement of the handling shank 19 and therefore of the piston 5 inside the pumping chamber 3.
There is formed in the pump body 2 an intake pipe 30 which comprises an intake coupling 32 for a pipe which communicates with a tank of fluid product which is not illustrated and which is positioned at a greater height with respect to the positive-displacement pump 1 so as to produce a hydraulic shutter and a fluid travel with a constant descent from the tank, for reasons of elimination of the air, in accordance with the methods which will become clearer below. From the intake coupling 32, the intake pipe 30 comprises a slightly inclined portion 33 which descends with respect to a horizontal plane. The portion 33 leads into a chamber 34 of a three-way valve 35 which is illustrated more clearly in the enlarged illustration of
The three-way valve 35 is controlled by an actuator 36 which is mounted on the pump body 2, preferably a solenoid valve actuator. The actuator 36 is connected in known manner to a valve closure member 37. There also leads into the chamber 34 a pumping pipe 38 which communicates with the pumping chamber 3 and a discharge pipe 39 which communicates with a discharge nozzle 40 which is carried by a discharge head 41 which is mounted on the pump body 2. The valve closure member 37 can be moved in the chamber 34 between two positions: a lowered intake position, in which the valve closure member 37 closes the discharge pipe 39 and allows the fluid communication between the intake pipe 30 and the pumping pipe 38, and a raised discharge position, in which the valve closure member 37 closes the intake pipe 30 and allows fluid communication between the pumping pipe 38 and the discharge pipe 39.
The pumping pipe 38 leads into the pumping chamber 3 in an upper region 42 which is placed in the region of the connection or transition between the cylindrical jacket 3a and the substantially frustoconical end 4. The relationship between the inclination of the longitudinal axis X-X with respect to a horizontal plane and the inclination of the lateral wall of the substantially frustoconical end 4 is selected in such a manner that the upper region 42 into which the pumping pipe 38 leads is located at the highest location of the pumping chamber 3. In this manner, any air contained in the fluid product which is intended to be pumped and which is contained in the pumping chamber 3 spontaneously ascends upwards in order to accumulate in the upper region 42 and to ascend from there into the pumping pipe 38 as far as the chamber 34 of the three-way valve 35 which is placed in an upper position with respect to the upper region 42. When the valve closure member 37 is in the intake position, the air is then capable of migrating towards the inclined portion 33 of the intake pipe 30 and of returning at that location to the tank connected thereto. This configuration allows the spontaneous elimination of any air which may be contained in the fluid product inside the pumping chamber 3, without any need for costly recirculation operations or additional forced extraction systems.
During use, the positive-displacement pump 1 is connected to a tank which is located above fluid product, such as a colorant or paint or the like, by means of a pipe which is connected to the intake coupling 32. For the reasons set out above with regard to the spontaneous elimination of the air, it is desirable for the connection pipe of the tank to the positive-displacement pump 1 to be inclined downwards from the tank to the positive-displacement pump 1. In a dispensing machine for fluid products, there are provided a plurality of positive-displacement pumps 1 for discharging fluid products in accordance with a discharge programme which is controlled by an electronic logic unit which controls the stepping motor 22 which moves the piston 5, and the actuator 36 which controls the opening and closing of the three-way valve 35. The electronic logical unit receives feedback information from the sensor 25 in order to control the positioning of the piston 5.
During operation of the positive-displacement pump 1, the piston 5 can be moved in translation for intake operation, by controlling the stepping motor 5 so as to rotate in a first direction and thereby actuating the control screw 31 which withdraws the piston 5, moving the head 6 thereof away from the end 4 of the pumping chamber 3, so as to increase the useful internal volume thereof. During the withdrawal of the piston 5, the corrugations 10 of the sleeve 9 move together. Furthermore, the three-way valve 35 is controlled into the intake position so as to place in communication the intake pipe 30, and therefore the tank of fluid product, with the pumping pipe 38. The fluid contained in the tank can thereby fill the additional volume produced in the pumping chamber 3. The shutter pressure which is established by the depth of the tank, the intake speed of the piston 5 and the speed of the fluid product processed, as well as the diameters of the various pipes, are parameters which are considered in the projection of the dispensing system and the electronic logic unit in order to ensure correct priming of the positive-displacement pump 1 at the first actuation thereof, with an empty pumping chamber 3.
When the pumping chamber 3 is full of fluid product and the piston 5 is in the maximum withdrawal position thereof, the piston 5 can be actuated in the opposite direction, that is to say, in the advance direction, as a result of a reversal of the rotation direction of the stepping motor 22. In this case, the positive-displacement pump 1 can operate with recirculation or discharge of the fluid product, in accordance with the position taken up by the three-way valve 25. If the three-way valve 25 is maintained in the intake position, in which the pumping pipe 38 is in communication with the intake pipe 30 and the discharge pipe 39 is closed, then the fluid product contained in the pumping chamber 3 is urged again towards the tank which is connected to the intake pipe 30. That is a recirculation or movement condition of the fluid product which allows it to be kept moving in order to prevent sediments or dry matter in the pipes which extend from the tank to the pumping chamber 3. Furthermore, the movement of the piston 5 in an advance direction allows recovery of the mechanical play in order to bring the system into a zero predetermined condition, which is important for the precise and repeatable adjustment of the discharge of fluid product. Finally, the advance movement of the piston 5 with recirculation promotes the discharge of any air which may be contained in the fluid product and which has been accumulated naturally in the upper region 42 or in the pumping pipe 38 and which is urged back towards the tank through the intake pipe 30.
The switching of the three-way valve 35 during the operation of the piston 5 in an advance direction allows a change from the above-described recirculation condition to the discharge condition, in which the fluid product contained in the pumping chamber 3 is urged through the pumping pipe 38 and redirected into the discharge pipe 39 as far as the nozzle 40, while the intake pipe 30 is closed by the valve closure member 37. In the positive-displacement pump 1 of the present invention, it is particularly advantageous that the change to the discharge condition does not involve the interruption of the pressure applied by the piston 5 to the fluid product. This allows the fluid product to be maintained under pressure in such a manner that the influence of the air which may still be contained in the fluid product on the volume of the system is minimized, thereby reducing to a minimum the volumetric variations of the fluid product which would otherwise cause a low level of repeatability of the discharge in subsequent pumping operations. The first step of the advance travel of the piston 5, in the recirculation condition of the three-way valve 35, contributes to the elimination of any air contained in the fluid product. Subsequently, in the discharge condition, the pressure of the piston 5 on the fluid product during the advance travel may typically reach from 10 to 15 bar and at this pressure the influence of any residual air enclosed in the fluid product becomes almost insignificant from the point of view of volume. The result is that the performance levels in terms of volume and the precision of discharge of the positive-displacement pump 1 of the present invention are predictable, measurable and repeatable with a very high level of precision. In other words, the first step of the advance travel of the piston compresses the air enclosed in the fluid product and makes the system particularly immune to the influence thereof on the discharge performance levels of the positive-displacement pump. In the first advance step of the piston, therefore, the air present at the upper portion of the pump is discharged from the pumping chamber 3; the air remaining in the fluid product which is not discharged in this manner is compressed to a pressure which is in accordance with the shutter, the connections and the ambient pressure but which is still far greater than ambient pressure.
Furthermore, the fact that the piston 5 remains under compression during the switching to the discharge condition of the fluid product prevents any relaxation of the mechanical play which is taken up during the first step of the advance travel thereof, in the recirculation condition, substantially thereby also improving the precision and the repeatability of discharge of the fluid product.
The positive-displacement pump 1 described above can be produced with construction variants which make the production, maintenance and use thereof advantageous.
Advantageously, the head group 2″ can be interchanged with a head group which is similar to the one in
The cylindrical capacity of the positive-displacement pump 1 is given by the maximum useful volume of the pumping chamber 3 when the piston 5 is in the zero position, which is found, for example, by the sensor 25, and corresponds to the position in which the three-way valve 35 or 35′ can be switched from the recirculation condition to the discharge condition after the mechanical play has been taken up and the air in the fluid product contained in the pumping chamber 3 has been eliminated or compressed.
The maximum quantity of fluid product which can be discharged in a single advance travel of the piston 5 is proportional to the cylindrical capacity of the positive-displacement pump 1.
The resolution of the positive-displacement pump, that is to say, the minimum quantity of fluid product which can be discharged per single step of the stepping motor 22, is instead inversely proportional to the cylindrical capacity of the positive-displacement pump. The optimum cylindrical capacity of a positive-displacement pump depends on the intrinsic characteristics of the fluid product to be discharged, for example, the viscosity thereof, and on subjective characteristics in terms of consumption of the fluid product. For example, in the field of colorant dispensing machines, the dispensing of yellow colorant is normally far greater than the dispensing of the colour viola. For those reasons, it is advantageous to be able to provide a positive-displacement pump which, with little effort and cost, can be produced with a cylindrical capacity which is different in accordance with the use for which it is intended.
When it is desirable to provide a positive-displacement pump with a smaller cylindrical capacity, for example, in order to change from a cylindrical capacity of 5 cc to a cylindrical capacity of 1.7 cc, it is possible to reduce the volume of the pumping chamber 3 by means of the adapter 55 which has a substantially cylindrical form with a constricted end 4′ and which is preferably substantially frustoconical and which is suitable for covering the internal walls of the pumping chamber 3 so as to produce a reduced pumping chamber 3′. The adapter has an opening 57 which is placed in correspondence and preferably substantially aligned with the pumping opening 56 of the pumping chamber 3. The adapter 55 has at the bottom an annular step 58 which, at the outer side thereof, moves into abutment with the abutment member 14 while, at the inner side thereof, it acts as an abutment for the annular portion 13′ having a greater diameter of a sleeve 9′ of a piston 5′ which has a total diameter which is smaller with respect to the piston 5 in order to adapt to the smaller volume of the pumping chamber 3′.
If the quantity of fluid product to be discharged is greater than the cylindrical capacity of the positive-displacement pump, the discharge operation which can be actuated with a single positive-displacement pump is necessarily discontinuous, because at the end of the advance travel of the piston 5 it is necessary to switch the three-way valve into the intake condition and to move back the piston 5 until the pumping chamber 3 moves back to fill with fluid product from the tank which is connected to the intake pipe 30, 30′. In some cases, there is a need to improve and make faster the discharge of the complete quantity of the fluid product, avoiding down times as a result of the filling of the pumping chamber 3. In those cases, it is advantageous to mount a pair of positive-displacement pumps which act in a non-parallel manner in such a manner that each of them takes fluid product from the same tank (or from an individual tank containing the same fluid product which is also charged in the tank of the other pump) when the other positive-displacement pump is in the discharge condition.
This continuous discharge behaviour for a fluid product can be brought about by means of the synchronized control of the pair of positive-displacement pumps by means of the electronic logic control unit, which provides for the synchronization of the movement of the respective stepping motors 22 and the three-way valves 35, 35′ of the two positive-displacement pumps, or also as a result of a configuration of a mechanical connection which will be described below with reference to
In greater detail, two positive-displacement pumps 1a, 1b each comprise a pumping chamber 3a, 3b which is similar to the pumping chamber 3 of the pump described above, in which there are mounted in a sliding manner respective pistons 5a, 5b which are capable of moving in a non-parallel manner: when the piston 5a advances in the pumping chamber 3a, the piston 3b moves back in the pumping chamber 3b thereof, and vice versa. Each piston 5a, 5b has a respective central shaft 8a, 8b which extends into a respective handling shank 19a, 19b which is connected to a respective handling screw 31a, 31b which is mounted on a transmission casing 60 in which there is received a gear mechanism 61 comprising two toothed wheels 62a, 62b having a gearing ratio of 1. Each toothed wheel 62a, 62b is supported in the transmission casing 60 by bearings 63 and is fitted to a handle 64a, 64b of a respective handling screw 31a, 31b. The handle 64a of one of the two handling screws 31a extends and is fixed to the drive shaft 65 of a single stepping motor 66 which is fixed to the transmission casing 60. The mutual angular position of the toothed wheels 62a, 62b is such that, when the handling shank 19a of one of the two pumps 1a is at the maximum extent thereof, the handling shank 19b of the other pump 1b is in the position of maximum withdrawal thereof. The actuation of the stepping motor 66 brings about the non-parallel movement of the two handling shanks 19a, 19b and therefore of the pistons 5a, 5b of the two pumps 1a, lb.
Naturally, the principle of the invention remaining the same, the forms of embodiment and construction details may be varied widely with respect to those described and illustrated, without thereby departing from the scope of the present invention.
| Number | Date | Country | Kind |
|---|---|---|---|
| BO2014A000555 | Oct 2014 | IT | national |
| BO2014A000556 | Oct 2014 | IT | national |
| BO2014A000557 | Oct 2014 | IT | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/IB2015/057831 | 10/13/2015 | WO | 00 |
