The present invention relates generally to power plants. More particularly, the invention is directed to sourcing a supply of steam for use in flue-gas treatment.
Power plants may combust various fuels, such as coal, hydrocarbons, bio-mass, waste products, and the like, in boilers, for example, to generate steam and electricity. Exhaust streams (i.e., flue gas) of such combustion processes may be treated to neutralize or remove various compounds, such as sulfur oxides, nitrogen oxides, and particulate matter, prior to discharge of the flue gas to the environment. These downstream processes may include post-combustion carbon capture systems. For example, a compound that may be separated from the flue gas is carbon dioxide (CO2).
An aspect of the present invention is a power plant having: a boiler to combust fuel, vaporize liquid water into steam, and discharge a combustion exhaust; a treatment unit to process combustion exhaust discharged from the boiler; a steam turbine to receive steam from the boiler and having a shaft, an intermediate pressure section, and a low pressure section, wherein the steam turbine is configured to provide steam from the low pressure section to the separation unit; and a load coupled to the shaft of the steam turbine and configured to be driven by the steam turbine to generate electricity.
An aspect of the present invention is a method of operating a power plant, including: feeding liquid water and fuel to a boiler; combusting the fuel in the boiler to generate steam; discharging a combustion exhaust from the boiler; supplying steam from the reboiler to a steam turbine; processing the combustion exhaust in a treatment unit; and supplying steam from a low pressure section of the steam turbine to the separation unit.
An aspect of the present invention is a method including configuring a steam turbine in a power plant to supply steam from a low pressure section of the steam turbine to a flue-gas processing unit in the power plant, wherein configuring the steam turbine involves installing a steam turbine at the power plant or retrofitting an existing steam turbine disposed at the power plant.
An aspect of the present invention includes a steam turbine having at least a shaft, an intermediate pressure section, and a low pressure section with a steam extraction to provide steam to a flue-gas processing unit.
These and other features, aspects, and advantages of the present invention will become better understood when the following detailed description is read with reference to the accompanying drawings in which like characters represent like parts throughout the drawings, wherein:
One or more specific embodiments of the present invention will be described below. In an effort to provide a concise description of these embodiments, all features of an actual implementation may not be described in the specification. It should be appreciated that in the development of any such actual implementation, as in any engineering or design project, numerous implementation-specific decisions must be made to achieve the developers' specific goals, such as compliance with system-related and business-related constraints, which may vary from one implementation to another. Moreover, it should be appreciated that such a development effort might be complex and time consuming, but would nevertheless be a routine undertaking of design, fabrication, and manufacture for those of ordinary skill having the benefit of this disclosure.
When introducing elements of various embodiments of the present invention, the articles “a,” “an,” “the,” and “said” are intended to mean that there are one or more of the elements. The terms “comprising,” “including,” and “having” are intended to be inclusive and mean that there may be additional elements other than the listed elements. Any examples of operating parameters are not exclusive of other parameters of the disclosed embodiments.
Combustion product gases (e.g., flue gases) in power plants and other facilities may be exhausted to the outside air. Flue gases are produced when coal, oil, natural gas, wood, or other fuel is combusted in an industrial furnace, a power plant's steam-generating boiler, or other combustion device. Flue gas may be composed of carbon dioxide (CO2) and water vapor, as well as nitrogen and oxygen remaining from the intake combustion air. It may also contain a relatively small percentage of pollutants, such as particulate matter, carbon monoxide, nitrogen oxides, sulfur oxides, and the like.
The present technique may provide for an efficient source of steam for the processing and treatment of post-combustion streams (i.e., flue gas) in power plants and other facilities. Steam may be employed in the processing of flue gas in a variety of ways, such as in the regeneration of solvent for the absorption of CO2 from power-plant flue gas in CO2 removal systems. One source of steam is intermediate pressure exhaust of a steam turbine in the power plant. Another source, in accordance with aspects of the present technique, is to supply steam from a low-pressure section of the steam turbine.
The steam turbine system in a power plant may be configured or modified to supply steam. Such steam may be provided, for example, to where the flue gas or combustion exhaust gas is treated, such as where carbon dioxide is extracted from the flue gas of the plant. In general, the present technique may provide a solution to the source of steam energy for post-combustion carbon capture systems and other post-combustion systems. The technique may provide increased efficiency and decreased power loss for the power plant and the post-combustion system. In addition, the technique may beneficially provide for new designs of steam turbines and retrofits of steam turbines.
Referring to
In the boiler 20, the fuel 22 is combusted, such as in a furnace of the boiler 20. Heat from the combustion vaporizes or boils the boiler feed water 24 in the boiler 20, and steam 25 is generated and supplied to the steam turbine 16. Combustion exhaust 26 (i.e., flue gas) exits from the boiler 20. As indicated, the combustion exhaust 26 may include nitrogen, oxygen, CO2, nitrogen oxides, sulfur oxides (e.g., sulfur dioxide or SO2), and particulate matter. The nitrogen oxides may be derived from the nitrogen in the ambient air used in the combustion and from any nitrogen-containing compounds in the fuel 22. The sulfur oxides are generally derived from sulfur-containing compounds in the fuel 22. The particulate matter may be composed of small particles of solid materials and small liquid droplets.
The combustion exhaust 26 may be processed in a variety of exemplary treatment processes, which are represented by treatment unit 19. In treatment units 19, certain compounds of the combustion exhaust 26, such as the sulfur oxides, nitrogen oxides, and so forth, may be altered or removed in scrubbers, bag filters, electrostatic precipitators, activated carbon, catalytic reduction systems, calcium-based reagent treaters, and so on. In one example, sulfur trioxide (SO3) is converted to sulfur dioxide (SO2). In another example, SO2 is removed form the exhaust 26. Flue gas treatment has become a focus of electric utilities and industrial operations due to air quality standards. As companies seek to comply with air quality regulations and to use more economical fuel sources, the need for effective flue gas treatment options has increased. However, it should be emphasized that the present technique is not limited to satisfying any particular standard or regulation.
In the depicted embodiment of
In the exemplary CO2 separation unit 18, the CO2 is separated from the exhaust 26, as indicated by reference numeral 30. The CO2 may be further processed, such as being compressed and sequestered. Further, an exhaust 32 may exit the CO2 separation unit and be discharged to the environment. On the other hand, the exhaust 32 may be further processed prior to discharge to the environment or elsewhere.
The steam 25 provided by the boiler 20 is fed to the steam turbine 16 at the high pressure section 34. In a general case, the steam turbine 16 also includes an intermediate pressure section 36, the low pressure section 14, and a shaft 38. A load 40, such as a generator, is driven by a shaft 38 to produce electricity. In operation, the steam 25 may be fed initially to the high pressure section 34. Steam is generally also fed from the high pressure (HP) section 34 to the intermediate pressure (IP) section 36, as indicated by reference numeral 42. The steam from the HP section 34 may be sent through a reheater 43 prior to entry to the IP section 36. It should be noted that alternate configurations (not depicted) of steam turbine 16 may not include a high pressure section 34, for example, if the available pressure of the inlet steam 25 is low. In this alternate case, the steam 25 from the boiler may be fed to the IP section 36, and the reheater 43 not employed.
In the illustrated embodiment, steam is further fed to the low pressure (LP) section 14 from the IP section 36, as indicated by reference numeral 44. It should be emphasized that the present technique is not limited to steam turbines having a particular number of sections or configuration. For example, the present technique may apply to steam turbines having only two sections (e.g., an IP section and a LP section). Further, the steam turbine may have multiple sections in parallel at the same pressure.
Steam 46 exiting the LP section 14 is fed to a condenser 48 where the steam is condensed. The condensed steam may be pumped via pump 50 as recovered boiler feed water 52 to the boiler 20. The boiler feed water system (not depicted) may include a variety of heat exchangers and other equipment to process and heat the water 52 prior to its entry to the boiler 20 as boiler feed water 24. In addition, as appreciated by the skilled artisan, the steam turbine 16 may be equipped with appropriate instruments and alarms to monitor operating conditions including speed, vibration, shell and rotor expansions, steam and metal temperatures, rotor straightness, turning gear operation, and various steam, oil, and hydraulic system pressures. Tools, lifting bars, and related items may be employed for erection and maintenance of the steam turbine 16. Moreover, in general, there are a variety of emission control technologies for steam systems. Such technologies may include flue-gas recirculation, low excess firing, combustion control, using low nitrogen fuel oil, inserting water/steam to lower NOx, selective non-catalytic reduction, selective catalytic reduction, and others.
In sum, the present technique provides extraction of steam from a number of points in the LP section 14 of the steam turbine 16 in order to provide steam 12 to flue-gas treatment units (e.g., units 18 and 19). In certain embodiments, steam 12 is fed to the CO2 separation unit 18, such as to a stripper reboiler in the unit 18. In one such example, the steam 12 may be beneficially supplied at temperatures and pressures effective for operation of the stripper reboiler. In other words, the operating pressures and temperatures of the LP section steam may be relatively close or in sync with the demands of the CO2 stripper reboiler. This is in contrast to alternate approaches of sourcing the steam (e.g., used for the stripper unit) via a slipstream of steam from the exhaust of the IP pressure section 36 of a steam turbine 16. Unfortunately, in configuring or retrofitting a steam turbine 16 to supply such IP steam, the IP steam may exceed the pressure and temperature effective for operation of the steam boiler. Thus, while retrofits cost may be relatively low with use of IP steam, the operation may be inefficient
Interest in recovery of CO2 from flue gases may be propelled by multiple factors including the merchant CO2 market, renewed interest in enhanced oil recovery (EOR), and the desire to reduce greenhouse gas emissions. Carbon dioxide may be used in the food industry in carbonated beverages, brewing, and flash drying. Its industrial uses include enhanced oil recovery (EOR), welding, chemical feedstock, inert gas, firefighting, and solvent extraction as a supercritical fluid. It is an ingredient in medical oxygen, where in low concentrations CO2 acts as a breathing stimulant. Flue gases have long been a source of CO2 for the merchant CO2 market, and typically more so in remote locations where by-product CO2 sources are unavailable, for example. In the simplest case, fuel is combusted to produce flue gas. CO2 is then extracted from the flue gas using a solvent, and heat from the upstream combustion process to support the heat required for the CO2 capture.
In the illustrated embodiment of
In the CO2 separation system 18, solvent 74 rich in CO2 may exit the bottom of the absorber 72 and be delivered via pump 76 to a stripper 77. Solvent 78 lean in CO2 exits a bottom portion of the stripper 77 and is fed back to an upper portion of the absorber 72. The absorber 72 and stripper 77 may incorporate a variety of internal components, such as trays, packing, supports, and so on. The absorber 72 is configured to absorb CO2 (e.g., via countercurrent flow) from the entering exhaust 26. The stripper 77 is configured to remove the CO2 from the solvent. Make-up solvent 80 may be fed to the absorber 72. The sizes of the absorber 72 and stripper 77 may generally be a function of the amount of CO2 to be removed, and may be sized (e.g., height, diameter, etc.) according to various engineering design equations. Moreover, it should be noted that a single stripper 77 may server multiple absorbers 72, for example.
The solvent may be a solution or dispersion, typically in water, of one or more absorbent compounds, that is, compounds which in water create an absorbent fluid that compared to water alone increases the ability of the fluid to preferentially remove carbon dioxide from the exhaust 26. Examples of such compounds are well known in this art and can readily be ascertained by the practitioner. Examples for the solvent include organic amines, alkanolamines, diethyanolamine (DEA), monethanolamine (MEA) and other primary amines, hindered amines, piperazine, pyrrolidine, methyldiethanolamine (MDEA), diethyanolamine (DEA), disoprpanolamine (DIPA), triethyanolamine (TEA), potassium carbonate, sodium hydroxide, ammonia, various weak acid-alkali salts, etc. Inhibitors may be included in the solvent to inhibit degradation of the solvent.
The absorber 72 can be of any construction typical for providing gas-liquid contact and absorption. In certain examples, the absorber 72 may operate at slightly above ambient pressure. The temperature in the absorber 72 can vary, depending on the technology and solvent employed. In one example with an absorber 72 employing an alkanolamine solvent, the temperature in the absorber 72 ranges form 40° C. to 45° C. at the top of the absorber 72 to 50° C. to 60° C. at the bottom of the absorber 72. Optionally, a mist eliminator at the top of the absorber 72 traps entrained solvent in the absorber vent gas (exhaust 32), which may be essentially enriched nitrogen. The CO2 from the exhaust 26 is preferentially absorbed by the solvent (i.e., the percentage of the carbon dioxide in the incoming exhaust 26 that is absorbed is greater than the percentage of other gases present in the exhaust 26), producing a CO2-enriched liquid solvent stream 74 which, as mentioned, emerges from the bottom of the absorber 72 and is fed to the rich solvent pump 76.
Pump 76 compresses the carbon dioxide enriched liquid absorbent stream 74 to a pressure which is sufficient to enable the stream 74 to reach the top of stripper 77 at the desired pressure (e.g., up to 15 psia, 5 psia to 30 psia, 35 psia or greater, and so on). The CO2-rich stream 74 may be preheated in the countercurrent heat exchanger 79 by the hot regenerated or lean solvent 78 (e.g., heated to a temperature of 100 to 110° C.) and is subsequently fed to the top portion of the stripper 77. Alternatively, this stream can be heated before it is compressed in pump 76. The stripper 77 may be a pressurized unit in which carbon dioxide is recovered from the carbon dioxide enriched liquid solvent stream 74. As indicated, the pressures in the stripper 77 (and in the reboiler 82) may be maintained (e.g., at 35 psia or more). In one example, the solvent employed includes monoethanolamine, and the pressure in the stripper 77 and reboiler 82 is maintained in the range of 40 to 55 psia.
The stripper 77 generally incorporates a reboiler 82 which receives a portion of lean liquid solvent 78 exiting the bottom portion of the stripper 77. The reboiler 82 vaporizes the liquid solvent and provides solvent vapor 84 back to the stripper 77. A single stripper may include more than one reboiler 82. In the illustrated embodiment, the reboiler 82 receives steam from the low pressure section 14 of stream turbine 16 (see
In general, it should be noted that gas-liquid absorption systems may be used in the removal of carbon dioxide from power-plant flue gases. Gas-liquid contactors, such as an absorber 72, are used to selectively absorb carbon dioxide from combustion or flue gases produced by utility and industrial plants. The flue gas is usually counter-currently contacted with an absorption fluid (e.g., solvent), such that carbon dioxide is selectively absorbed in the absorption fluid. This carbon-dioxide rich solvent is heated and directed to a stripper unit, such as stripper 77, which operates at an elevated temperature in order to remove carbon dioxide from the solvent. Energy is provided to the stripper to elevate the temperature in the stripper 77 to facilitate transport of the carbon dioxide to the gaseous phase for transfer to sequestration processes. It should be emphasized that other unit operations and systems other than gas-liquid absorption systems may be employed separate CO2 from flue gas. Such alternate systems may also benefit from lower pressure steam (e.g., 30-70 psig at about 230-250° F. or higher) found as LP steam and not need higher pressure steam, such as with IP steam.
As mentioned, a source for the steam used by the stripper 77 can be a slipstream of steam from the exhaust of the IP section (e.g., section 36 in
The LP sections 14 of exemplary steam turbines 16 have a number of stages, generally ranging from about 5 stages to about 40 stages. Moreover, as indicated, steam turbines 16 may have one or more LP sections 14 in series and/or parallel. Extraction of steam 12 from the LP section 14 may be from one or more places or stages of the LP section 14, such as in up to four stages or more. The casing of the LP pressure section(s) 14 may be modified or tapped into to extract or bleed the steam 12. Pipe, valves, and various pipe fittings may be used to extract or bleed the steam 12 from the casing of various stages of the LP section 14. Such piping and fittings may be sized and design based on the hydraulic requirements, for example, to supply steam 12 to unit 18 and/or treatment units 19. In the design, construction, and/or retrofit of the LP section 14, stages subsequent to steam 12 extraction or bleed points, may be smaller due to the subsequent lower flow of steam through the LP section. Beneficially, smaller subsequent stages in the LP section may reduce the cost to manufacture the LP section because less material (i.e., metal) is utilized.
In this example, the extractions 98 are symmetrically arranged. However, symmetry of the extractions is not generally required, but may pose advantages in design of the LP turbine. Additional extractions 98 or fewer number of extractions 98 may exist, depending on the requirements of the cycle including the flue gas treatment system, for example. In a multiple LP element arrangement such as with the configurations 116 and 118 of
In
In summary, the present technique may be directed to an exemplary power plant having a boiler configured to combust fuel, vaporize liquid water into steam, and discharge a combustion exhaust (e.g., flue gas). The boiler provides steam to a steam turbine for generating electricity. The steam turbine may have two sections (e.g., IP section and LP section), three sections (e.g., HP section, IP section, and LP section), and so on. In certain embodiments, the steam turbine is configured to provide steam from the LP section to a flue-gas treatment unit, such as to a carbon dioxide separation unit. The LP steam may be supplied to a stripper reboiler in the separation unit, as discussed above, for example. A conduit may couple the LP section of the steam turbine with a stripper reboiler in a carbon dioxide separation unit.
Configuring the steam turbine to supply steam from a low pressure section of the steam turbine to a flue-gas treatment or processing unit may include installing a steam turbine at the power plant or retrofitting an existing steam turbine disposed at the power plant. Retrofit may involve replacing or modifying a low pressure section of the steam turbine. The low pressure section of the configured steam turbine comprises one or more steam extractions sized collectively to extract 10% to 25%, by weight, of the total steam entering the low pressure section. Other exemplary ranges, by weight, for steam extracted from the total steam through the LP section 14B include 5% to 30%, 12% to 22%, and 15% to 20%, and so on.
The one or more steam extractions may be uncontrolled or controlled extractions, or a combination thereof. The steam turbine may be configured such that the size of stages subsequent to a steam extraction is reduced correlative with an amount of steam to be extracted via the steam extraction.
In operation of the power plant, fuel (e.g., coal) is fed to the boiler and combusted in the boiler. A combustion exhaust is discharged from the boiler and processed in one or more treatment units. Liquid water is fed to the boiler and is vaporized into steam via heat generated by combusting the fuel. Steam is supplied from the boiler to a steam turbine. The steam may be supplied to a IP section or HP section of the steam turbine, for example. Steam is then supplied from a LP section of the steam turbine to one or more treatment units of the combustion exhaust. In one example, processing of the combustion exhaust includes recovering carbon dioxide from the combustion exhaust in the treatment unit.
While only certain features of the invention have been illustrated and described herein, many modifications and changes will occur to those skilled in the art. It is, therefore, to be understood that the appended claims are intended to cover all such modifications and changes as fall within the true spirit of the invention.