This application is a U.S. national stage application of PCT/JP2007/054123 filed on Feb. 26, 2007, and claims priority to, and incorporates by reference, Japanese Patent Application No. 2006-49555, filed on Feb. 27, 2006.
The present invention relates to a powder based granules disintegrating and sizing device which regulates, to a prescribed particle size, various types of wet or dry material such as pharmaceuticals, food products, feed materials, chemicals, fertilizers, fine coals, limestone, ceramic materials or the like, which have been granulated or molded articles by various types of devices. More specifically, the present invention relates to a powder based granules disintegrating and sizing device which disintegrates granular material (lumps) having a particle size that is equal to or larger than a target particle size, such as wet agglomerated material or dry block material that has been granulated or molded articles by various types of devices, and regulates the material to a prescribed particle size range.
Nowadays, the operations of mixing, granulating and regulating the particle size of power material are carried out in a broad range of fields, such as pharmaceuticals and foodstuffs. Therefore, the particle size adjustment operation carried out in a product manufacture process is an important unit operation in improving the quality of the powder based granules, improving the flowability during fluidized drying and improving the handling properties.
Here, in powder based granules disintegrating and sizing devices which have been used in the prior art, the particle size is regulated by the use of screens. Consequently, there is a possibility that with continuous use, the screen will become worn and damaged, and worn particles or broken shards of the screen may become mixed into the product powder based granules. Furthermore, in the case of a wet material, depending on the physical properties of the material being processed, blocking of the screen mesh holes occurs due to the adherence of material, and there is a risk that material being processed may become clogged into the screen. Moreover, there has also been a problem in that particles which are of a suitable particle size are also disintegrated due to the force of impact of the disintegrating blade, and hence a large amount of fine-particles are generated, resulting in a decline in the yield rate.
Therefore, the present applicants have previously developed a powder based granules disintegrating and sizing device which does not use a screen, and have filed patent applications in this respect (Japanese Patent Application Publication No. 2000-117131 (hereinafter, Patent Document 1), Japanese Patent Application Publication No. 2005-131609 (hereinafter, Patent Document 2), and WO 2004/085069 A1 publication (hereinafter, Patent Document 3).
These powder based granules disintegrating and sizing devices are devices which regulate the size of the particles of a wet or dry material supplied via a material supply port by passing the material through a prescribed settlement region, a gap region being formed by providing a rotating body and an opposing surface section which opposes the rotating body and is separated from same by a prescribed gap, inside a casing which constitutes the device, and this gap region being constituted as a particle size adjustment region which allows the passage of particles that conform to the prescribed gap setting but does not permit the passage of particles that do not conform to same, in such a manner that the particles which are not able to pass through the gap region are brought into contact with the opposing surface section due to the rotational movement of the rotating body, in the input section or surface section of the gap region, and are thereby disintegrated so as to be able to pass through the gap region and are then output through the output port.
In the gap region, the rotating body and the opposing surface section are provided with a planar section or a linear section which is set so as to form a narrowest gap section, in such a manner that the particles are disintegrated in this narrowest gap region or in the vicinity thereof.
More specifically, in the powder based granules disintegrating and sizing devices described in Patent Document 1 and Patent Document 2, a rotating body fixed to a drive shaft provided in a vertical direction is formed in a substantially circular conical shape, the casing is formed in a substantially hollow circular conical shape, and a settlement region for the powder based granules material is formed between the inner wall of the casing and the circumferential surface of the rotating body, the narrowest gap region being formed by the lower circumferential edge of the rotating body and the inner wall of the casing.
Furthermore, in the powder based granules disintegrating and sizing device described in Patent Document 3, a drive shaft is provided in a horizontal direction inside a casing, and a plurality of circular plates (rotating bodies) fixed at intervals to the drive shaft are provided, together with sizing stators, which are disposed to the lower side of the circular plates so as to create resistance with respect to the surface of the plate in the circumferential edge portion thereof and which have an inclined surface that reduces the gap with respect to the plate surface of the circular plate toward the circumferential edge plurality of same, gap sections in which the powder based granules particles settle being formed by the plate surfaces of the circular plates and the inclined surfaces of the sizing stator, and disintegrating and sizing sections being formed by the narrowest gap regions between the circumferential edges of the circular plates and the sizing stators.
However, firstly, in the powder based granules disintegrating and sizing devices described in Patent Document 1 and Patent Document 2, since the drive shaft is disposed in the vertical direction, then the direction of the centrifugal force applied to the powder based granules particles by the rotating body which is caused to rotated by the drive shaft is a horizontal direction which is perpendicular to the direction of gravity. Therefore, the powder based granules particles, from the time that they are supplied and subjected to disintegrating and sizing until the time that they are output, receive forces in various directions from the rotating body, the internal walls of the casing, and the like, thus acquiring a complicated motion, and hence a smooth flow of powder based granules particles is not formed inside those machines. As a result of this, in a disintegrating and sizing process for a dried powder based granules, for example, the settlement time of the powder based granules inside the device becomes long and there is a tendency for a large number of fine-particles to be generated. Furthermore, in a disintegrating and sizing process for a wet powder based granules material, since a smooth flow cannot be formed, then there is a drawback in that a large amount of material adheres to the internal walls of the device.
Moreover, in the powder based granules disintegrating and sizing device described in Patent Document 3, a sizing stator is provided only on the lower side of the circular plates, and therefore no disintegrating and sizing action occurs on the upper side of the circular plates, and the efficiency is poor. Furthermore, since the powder based granules material being processed is supplied from the upper side of the circular plates, then it rebounds due to the centrifugal force of the circular plates and does not enter readily into the device. Moreover, since the drive shaft disposed in the horizontal direction has a structure which is supported at either end, then the size of the device increases, and furthermore, there is a risk that oil and the like from the supporting sections will enter into the casing, in other words, into the powder based granules processing chamber, thus making this device unsuitable for the processing of powder based granules where infiltration of impurities is to be avoided, such as pharmaceuticals, food products, or the like.
Furthermore, in all of the powder based granules disintegrating and sizing devices described in the Patent Documents mentioned above, the gap in the sizing section, in other words, the particle size, is adjusted by means of an operator observing the particle size of the product and then selecting a member of a suitable thickness from a plurality of types of ring members or size regulating stators having different thicknesses, and installing the selected ring member or size regulating stator. Consequently, this adjustment task takes time, and skill and physical strength are required in order to replace the ring member or size regulating stator. Furthermore, since it is necessary to prepare a plurality of ring members and size regulating stators having different thicknesses, then the management of these members or stators becomes complicated.
The present invention was devised in view of the aforementioned problems of the prior art, an object thereof being to provide a powder based granules disintegrating and sizing device whereby the flow of powder based granules material supplied into the device is improved, adherence of material to the internal walls of the device and excessive disintegrating are prevented, and furthermore, the processing amount can be increased.
Moreover, it is an object of the present invention to provide a powder based granules disintegrating and sizing device capable of achieving a disintegrating and sizing process in which impurities are not liable to infiltrate, and in which the particle size can be adjusted readily.
In order to achieve the aforementioned objects, the present invention provides a powder based granules disintegrating and sizing device having the following composition.
(1) A powder based granules disintegrating and sizing device, having a drive shaft which is provided in a horizontal direction inside a casing, a rotor which is fixed to the drive shaft, and a sizing stator which is provided so as to oppose a plate surface of a circumferential edge portion of the rotor and has an inclined surface which reduces a gap with respect to the plate surface of the rotor toward the circumferential edge thereof, a gap section where the powder based granules settles being formed by the plate surface of the rotor and the inclined surface of the sizing stator, and a disintegrating and sizing section being formed by a narrowest gap section between the circumferential edge of the rotor and the sizing stator, wherein the drive shaft is supported in a cantilever fashion, the rotor is fixed to an open side end portion thereof, the sizing stator is installed over the whole circumference of the rotor, a raw material supply port is opened in the vicinity of the central portion of the rotor, and a product output port is opened in the vicinity of a position directly below the rotor.
According to the powder based granules disintegrating and sizing device described in (1) above, a disintegrating and sizing section is formed over the whole circumference of the rotor, and the powder based granules can be disintegrating and regulated in size efficiently. Moreover, since the powder based granules being processed is supplied in the vicinity of the center of the rotor, flows due to the centrifugal force of the rotor from the center toward the outer circumference of the rotor, where it receives a disintegrating and sizing action, and is then output directly in the outer circumferential direction, then the flow of powder based granules inside the device is smooth, adherence of the processed material to the internal walls of the device can be prevented, excessive disintegrating can be avoided, and furthermore, the processing amount can be increased.
(2) The powder based granules disintegrating and sizing device according to (1) above, wherein the casing is constituted by a casing main body having a bottomed cylindrical shape and a front cover which seals the open end of the casing main body, the raw material supply port is opened in the central portion of the front cover, and the product output port is opened in the lower circumferential surface portion of the casing main body.
According to the powder based granules disintegrating and sizing device described in (2) above, it is possible to form the casing to a compact size, the interior of the casing can be cleaned and inspected, etc., easily, and the flow of processed material can be made even smoother.
(3) The powder based granules disintegrating and sizing device according to (2) above, wherein the sizing stator is installed on the front cover in such a manner that the projecting position thereof can be adjusted.
According to the powder based granules disintegrating and sizing device described in (3) above, it is possible to adjust the gap between the sizing stator and the circumferential edge section of the rotor, in other words, the gap of the disintegrating and sizing section, by adjusting the projecting position of the sizing stator, and therefore the particle size of the processed material can be adjusted readily.
(4) The powder based granules disintegrating and sizing device according to any one of (1) to (3) above, wherein a cutaway section is formed in the circumferential edge of the rotor on the front side thereof, and a sizing ring is installed in the cutaway section.
According to the powder based granules disintegrating and sizing device described in (4) above, it is possible to adjust the gap of the disintegrating and sizing section by altering the thickness of the sizing ring, and it is also possible to carry out a suitable disintegrating and sizing process in accordance with the powder based granules material, by altering the shape of the sizing ring in accordance with the properties of the powder based granules being processed.
(5) The powder based granules disintegrating and sizing device according to (4) above, wherein two types of sizing stator are provided, one having a flat sizing surface and one having a sizing surface formed with projecting portions, and three types of sizing ring are provided, one having a flat sizing surface, one having a sizing surface formed with grooves and one having a sizing surface formed with projecting portions, the sizing stator and the sizing ring being installed on the front cover and the rotor respectively, in accordance with the properties of the powder based granules which is subjected to sizing processing.
According to the powder based granules disintegrating and sizing device described in (5) above, since sizing stators and sizing rings with sizing surfaces which are flat, grooved or have projecting portions are prepared as the sizing stator and the sizing ring that constitute the disintegrating and sizing section, then it is possible to adapt suitably to powder based granules having various properties, by means of the combination of the stator and ring used. Furthermore, since respective sizing stators and sizing rings having different shapes are prepared, one of each shape respectively, then they can be managed easily.
(6) The powder based granules disintegrating and sizing device according to any one of (1) to (5) above, wherein an air seal section is provided between a bearing section of the drive shaft and the casing.
According to the powder based granules disintegrating and sizing device described in (6) above, since oil and the like from bearing sections does not infiltrate into the casing, in other words, into the powder based granules processing chamber, then the device is suitable for use in a disintegrating and sizing processing for material where admixture of impurities must be avoided, such as pharmaceuticals, food products, and the like.
(7) The powder based granules disintegrating and sizing device according to any one of (1) to (6) above, wherein disintegrating pins which roughly crush the powder based granules are provided on a front side plate surface of the rotor.
According to the powder based granules disintegrating and sizing device described in (7) above, even in cases where the powder based granules settles in between the plate surface of the rotor and the inclined surface of the sizing stator, or the like, the disintegrating pins provided on the plate surface of the rotor roughly crush the powder based granules and are therefore able to aid the disintegrating and sizing action performed by the narrowest gap section, and the like.
(8) The powder based granules disintegrating and sizing device according to any one of (1) to (7) above, wherein auxiliary pins which press the powder based granules in the direction of the disintegrating and sizing section are provided on a front side plate surface of the rotor.
According to the powder based granules disintegrating and sizing device described in (8) above, the auxiliary pins provided on the plate surface of the rotor have an action of pushing the powder based granules out into the disintegrating and sizing section, and therefore the powder based granules is not liable to settle and the processing amount can be increased yet further.
Hereinafter, the powder based granules disintegrating and sizing device relating to the present invention which was described above will be explained in detail on the basis of embodiments which are shown in the accompanying drawings.
The powder based granules disintegrating and sizing device 1 relating the present invention which is shown in the drawings has a casing 2 which comprises a casing main body 3 in the form of a bottomed circular tube, and a front cover 4 which seals off the open end of this casing main body 3. As shown in
A drive shaft 9 is provided in a horizontal direction inside the casing 2, and one end of this drive shaft 9 is extended to the exterior through the bottom wall 3a of the casing main body 3, as shown in
A rotor (circular plate) 16 is fixed to the open side end portion of the drive shaft 9 which is disposed inside the casing 2. A U-shaped disintegrating bar 17 is installed on the front end of the drive shaft 9. A cutaway section 16a is formed in the outer edge of the front side of the rotor 16, and a sizing ring 18 is installed in this cutaway section 16a. Furthermore, as shown in
A raw material supply port 24 is provided in the central portion of the front cover 4, and the chute 26 of a hopper 25 is connected to this raw material supply port 24. Moreover, as described in detail in
As shown in
The gap of the disintegrating and sizing section (narrowest gap section) B is set as desired in accordance with the target maximum particle size or average particle size of the powder based granules being processed. In general, the gap of the disintegrating and sizing section (narrowest gap section) B is set to approximately 0.8 to 1 times the target maximum particle size or to approximately 1.5 to 3 times the target average particle size of the powder based granules being processed. The gap of the disintegrating and sizing section (narrowest gap section) B can be adjusted readily, by altering the projecting position of the sizing stator 28 which is installed on the front cover 4. In other words, in the present embodiment, as shown in detail in
As shown in
For example, as shown in
Furthermore, as shown in
Moreover, it is also possible to use a sizing ring 18S having projecting portions 37 as described above for the sizing ring 18 which is installed on the rotor 16, and to use a standard flat sizing stator 28F for the sizing stator 28 which opposes the sizing ring 18S. If a ring and a stator which both have spike-shaped projecting portions as described above are used, then the maximum gap becomes larger and there is a risk of larger particles escaping, but in the case of a combination of a sizing ring 18S having these projecting portions and a flat sizing stator 28F, the escape of these particles is restricted and it is possible to narrow the particle size distribution even when processing a dry block material, or the like. Therefore, a combination of this kind is suitable when it is necessary to obtain a narrow particle size distribution.
Furthermore, if the supplied material comprises large coarse and dry particles, for example, then the disintegrating pins 19 attached to the front side plate surface of the rotor 16 have the action of roughly disintegrating the large coarse dry particles, and preventing the large coarse dry particles from settling in the gap section A. However, if the material being processed does not require rough disintegrating, then it is also possible to remove these disintegrating pins 19. Moreover, the auxiliary pins 20 also have the action of pushing the powder based granules, which enters into the gap section A that forms a settlement region for the powder based granules due to the centrifugal force caused by the rotation of the rotor 16, rapidly into the disintegrating and sizing section B, rather than settling in the gap section A. When the shape of these auxiliary pins 20 was changed as appropriate to a circular shape, rectangular shape, square shape, triangular shape, or the like, when observed in plan view, and the installation angle of these pins was also modified accordingly and their effect in pushing out the powder based granules material was observed, it was found that a desirable configuration is one where the pins are substantially triangular in shape and are installed in such a manner that one apex of this triangular shape faces in the direction of rotation of the rotor 16. If the powder based granules being processed is wet and there seems to be a risk that these auxiliary pins 20 may knead the powder based granules, then adherence of material tends to be promoted starting from these auxiliary pins 20, and it may be preferable to omit the auxiliary pins 20.
The powder based granules disintegrating and sizing device relating to the present invention which has the composition described above operates in the following manner.
Firstly, a sizing ring 18 and a sizing stator 28 are installed on the rotor 16 and the front cover 4 respectively, using a combination of a sizing ring 18 and a sizing stator 28 which are respectively flat, grooved or provided with projecting portions, in accordance with the properties of the powder based granules being processed. Subsequently, the projecting position adjustment mechanism 35 of the sizing stator 28 is operated and the gap of the disintegrating and sizing section (narrowest gap section) B is adjusted in accordance with the target particle size of the powder based granules being processed.
The front cover 4 is then closed, the electromagnetic lock safety door switch 7 is released, and the motor 13 which turns the drive shaft 9 is driven, in addition to which compressed air is supplied to the air supply port 14a of the air seal section 15.
Once the flow of air created inside the casing 2 by the rotation of the rotor 16 has stabilized, then a powder based granules raw material such as a wet agglomerated material which is granulated or molded by one of various types of device, is supplied from the hopper 25. The powder based granules raw material thus supplied flows down the chute 26 and enters into the casing 2 via the raw material supply port 24. The powder based granules raw material which has flowed into the casing 2 receives a centrifugal force created by the rotation of the rotor 16 and is propelled in a radial direction from the center of the rotor, is firstly disintegrated roughly by the disintegrating pins 19. The powder based granules which arrives at the gap section A between the front side plate surface 16b of the rotor 16 and the inclined surface 28a of the sizing stator 28 is pushed out rapidly into the disintegrating and sizing section B, rather than settling in the gap section A, due to the centrifugal force created by the rotation of the rotor 16 and the extruding force created by the action of the auxiliary pins 20, and so on.
The powder based granules which is pushed out into the disintegrating and sizing section B, particles which match the gap settings are allowed to pass directly, but non-matching particles are disintegrated between the sizing ring 18 installed on the rotor 16 and the vertical surface 28b of the sizing stator 28. In particular, if the sizing ring 18S and the sizing stator 28S which have projecting portions 37 and 38 are used, then even if the material being processed is a dry block material which is entirely hard, or which has a hard core, this material can be disintegrated and regulated in size efficiently by the projecting portions 37 and 38 provided in the disintegrating and sizing section B. Furthermore, the powder based granules does not settle in the disintegrating and sizing section B, but rather is output smoothly in the direction of the outer circumference of the rotor 16. The output material travels on the flow of air formed inside the casing 2 by the rotation of the rear vanes 21, and exits to the exterior of the system from the product outlet port 22 provided in the lower circumferential surface portion of the casing 2 and via the output chute 23, without adhering to the inner walls of the casing 2.
Above, preferred embodiments of a powder based granules disintegrating and sizing device relating to the present invention were described, but the present invention is not limited to any of the embodiments described above, and it is of course possible for various modifications or changes to be implemented within the technical scope of the present invention as described in the claims.
For example, the projecting position adjustment mechanism 35 of the sizing stator 28 described in the present embodiment is no more than an example, and any structure which is capable of adjusting the position of the sizing stator 28 disposed inside the casing 2, from the outside of the casing 2, is included in the technical scope of the present invention.
Moreover, the structure of the air seal section 15 between the bearings 11, 11 of the drive shaft 9 and the casing 2 described in the aforementioned embodiments is not limited to the structure of any of the embodiments described above, and it is also possible to employ various currently known structures for the air seal section 15.
Furthermore, as shown in
A disintegrating and sizing process was carried out on the raw material described below, under the conditions described below, using a prior art device as described in Patent Document 2 (Japanese Patent Application Publication No. 2005-131609).
Raw material: churned lactose—corn starch granules
Rotor diameter: 235 mm
Narrowest gap section: 0.5 mm
Speed of rotor: 3500 rpm
Type of sizing surface: both flat
A disintegrating and sizing process was carried out on the raw material described below, under the conditions described below, using an device according to the present invention as shown in
Raw material: churned lactose—corn starch granules
Rotor diameter: 235 mm
Narrowest gap section: 0.5 mm
Number of rotations of rotor: 3500 rpm
Type of sizing surface: both flat
A disintegrating and sizing process was carried out on the raw material described below, under the conditions described below, using a prior art device as described in Patent Document 2 (Japanese Patent Application Publication No. 2005-131609).
Raw material: churned lactose—corn starch granules
Rotor diameter: 235 mm
Narrowest gap section: 0.5 mm
Number of rotations of rotor: 3500 rpm
Type of sizing surface: both spiked
A disintegrating and sizing process was carried out on the raw material described below, under the conditions described below, using an device according to the present invention as shown in
Raw material: churned lactose—corn starch granules
Rotor diameter: 260 mm
Narrowest gap section: 0.5 mm
Number of rotations of rotor: 3500 rpm
Type of sizing surface: both spiked
The results of these experiments are shown in Table 1.
In experimental example 1 (prior art device), the presence of fine-particles was approximately 5%, but in the experimental example 2 (the device of the present invention), the amount of fine-particles had reduced to approximately 2%. Furthermore, in the experimental example 2 (the device of the present invention), it was also possible to reduce the ratio of large coarse particles having a size of 850 μm or greater. From this, it could be confirmed that a narrow particle size distribution is obtained with the device according to the present invention.
Moreover, similarly, in the experimental example 3 (the device according to the present invention), the presence of fine-particles was 5%, whereas in the experimental example 4 (the device according to the present invention), the amount of fine-particles was reduced to approximately 4%. Furthermore, in the experimental example 4 (the device according to the present invention), the amount of large coarse particles having a size of 850 μm or greater was also reduced. From these findings, it could be confirmed that a relatively narrow particle size distribution is obtained, regardless of the form of the sizing surfaces.
A disintegrating and sizing process was carried out on the raw material described below, under the conditions described below, using a prior art device as described in Patent Document 2 (Japanese Patent Application Publication No. 2005-131609).
Raw material: herbal medicine
Rotor diameter: 235 mm
Narrowest gap section: 0.9 mm
Number of rotations of rotor: 3500 rpm
Type of sizing surface: both flat
A disintegrating and sizing process was carried out on the raw material described below, under the conditions described below, using an device according to the present invention as shown in
Raw material: herbal medicine
Rotor diameter: 235 mm
Narrowest gap section: 0.9 mm
Number of rotations of rotor: 3500 rpm
Type of sizing surface: both flat
The results of the experiments are shown in Table 2 and
In experimental example 5 (the device according to the prior art), the effective load current value rose suddenly with the increase in the processing capacity, but in experimental example 6 (the device according to the present invention), the effective load current value did not increase significantly at a processing capacity equal to or greater than that in the experimental example 5. Furthermore, for example, from
A disintegrating and sizing process was carried out on the raw material described below, under the conditions described below, using an device according to the present invention as shown in
Raw material: herbal medicine
Rotor diameter: 235 mm
Narrowest gap section: 1.0 mm
Number of rotations of rotor: 3500 rpm
Type of sizing surface: both flat
A disintegrating and sizing process was carried out on the raw material described below, under the conditions described below, using an device according to the present invention as shown in
The results of the experiments are shown in Table 3.
In experimental example 7, the load current value rises due to the occurrence of adhesion of material as the processing advances, and hence a stable experiment could not be carried out. However, in experimental example 8, there was no change in the current value even after three minutes had elapsed under the same processing conditions, and hence a stable experiment could be carried out. From these findings, it could be confirmed that for the sizing surfaces, a combination of a grooved surface (sizing ring) and a flat surface (sizing stator) is suitable for processing a powder based granules which has strong adhesive properties.
A disintegrating and sizing process was carried out on the raw material described below, under the conditions described below, using an device according to the present invention as shown in
Raw material: herbal medicine
Rotor diameter: 235 mm
Narrowest gap section: 0.5 mm
Number of rotations of rotor: 3500 rpm
Type of sizing surface: both flat
A disintegrating and sizing process was carried out on the raw material described below, under the conditions described below, using an device according to the present invention as shown in
The results of the experiments are shown in Table 4 and
In the experimental example 9, processing did not advance due to the fact that the raw material comprises hard particles, and the load current value increased due to the low processing capacity. However, in the experimental example 10, the load current value was low under the same processing conditions, and hence processing of a large volume of material was possible, and there were no effects on the particle size of the final product. From this, it could be confirmed that for the sizing surfaces a combination of a spiked surface (sizing ring) and a flat surface (sizing stator) is suitable for the processing of hard powder based granules material.
According to the powder based granules disintegrating and sizing device according to the present invention which was described above, a disintegrating and sizing section is formed over the whole circumference of the rotor and therefore it is possible to disintegrate and regulate the size of the powder based granules efficiently. Furthermore, since the processed powder based granules is supplied in the vicinity of the center of the rotor and flows due to the centrifugal force of the rotor from the center toward the outer circumference of the rotor, where it receives a disintegrating and sizing action and is then output directly in the direction of the outer circumference, the flow of the powder based granules inside the device is smooth and it is possible to prevent adherence of the processed material to the internal walls of the device as well as avoiding excessive disintegrating, in addition to which the processing amount can be increased. Therefore, the powder based granules disintegrating and sizing device according to the present invention is appropriate for use in regulating the various wet or dry materials to a prescribed particle size, such as pharmaceuticals, food products, feed materials, chemicals, fertilizers, fine coals, limestone, ceramic materials or the like, which have been granulated or molded articles by various types of devices.
Number | Date | Country | Kind |
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2006-049555 | Feb 2006 | JP | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/JP2007/054123 | 2/26/2007 | WO | 00 | 10/9/2008 |
Publishing Document | Publishing Date | Country | Kind |
---|---|---|---|
WO2007/097475 | 8/30/2007 | WO | A |
Number | Name | Date | Kind |
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1682377 | Jackson | Aug 1928 | A |
2013800 | Daniels | Sep 1935 | A |
4081147 | Seifert et al. | Mar 1978 | A |
4171101 | Seifert et al. | Oct 1979 | A |
4214716 | Jadouin | Jul 1980 | A |
4619414 | Kirchner et al. | Oct 1986 | A |
4783014 | Fredriksson et al. | Nov 1988 | A |
20060124788 | Nara et al. | Jun 2006 | A1 |
Number | Date | Country |
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01-321989 | Dec 1989 | JP |
06-200493 | Jul 1994 | JP |
2000-117131 | Apr 2000 | JP |
2001-149804 | Jun 2001 | JP |
2005-131609 | May 2005 | JP |
Number | Date | Country | |
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20090026297 A1 | Jan 2009 | US |