This application claims priority to Japanese Patent Application No. 2013-126400 filed Jun. 17, 2013, the entire contents of which are hereby incorporated by reference.
In a semiconductor manufacturing process for manufacturing semiconductor devices, liquid crystal panels, LEDs or the like, a process gas is introduced into a process chamber which is being evacuated to perform various processes such as an etching process, a CVD process or the like. Further, the process chamber and exhaust apparatuses connected to the process chamber are cleaned periodically by supplying a cleaning gas thereto. Because exhaust gases such as the process gas, the cleaning gas or the like contain a silane-based gas, a halogen gas, a PFC gas or the like, such exhaust gases have negative effects on the human body and on the global environment such as global warming. Therefore, it is not preferable that these exhaust gases are emitted to the atmosphere as they are.
Accordingly, these exhaust gases are made harmless by the exhaust gas treatment apparatus provided at a downstream side of the vacuum pump, and the harmless exhaust gases are emitted to the atmosphere. In the exhaust gas treatment apparatus, in many cases, oxidation reaction treatment by combustion or application of heat from a heater is performed. In such combustion-type or heater-type exhaust gas treatment apparatus, when the exhaust gases containing silane (SiH4) are treated through the oxidation reaction, silica (SiO2) is produced. The produced silica is powdery, and adheres to an inner wall of a treatment chamber and becomes increasingly deposited. Therefore, it is necessary to remove periodically powdery product containing silica which has adhered to and has been deposited in the treatment chamber. Thus, a scraper is installed to scrape off the powdery product from the wall surface of the treatment chamber in the exhaust gas treatment apparatus. A circulating water tank is provided below the treatment chamber, and the powdery product scraped off by the scraper is deposited on the bottom of the circulating water tank.
Conventionally, in order to discharge powder deposited on the bottom of the circulating water tank, a bubbler is provided on the bottom of the circulating water tank and pressurized air is supplied to the bubbler, so that bubbling is performed in the circulating water tank to allow the powder to be floated and agitated, thereby automatically discharging the powder together with drainage water from the circulating water tank.
However, the bubbler tends to be clogged by the powder in structure at a nozzle portion for generating bubbles, and thus there is demand for a system which can discharge the powdery product accumulated on the bottom of the circulating water tank without using the bubbler.
Further, it is problematic that relatively small particles are floated and discharged by the bubbler, but large particles are not floated, thus being accumulated in the circulating water tank.
It is therefore an object to provide a powder discharge system which can increase a discharge rate of powder and can prolong a maintenance period of a circulating water tank by crushing and floating powdery product such as silica deposited in the circulating water tank for a scrubber installed at a downstream side in an exhaust gas treatment apparatus.
Embodiments, which will be described below, relate to a powder discharge system for use in a circulating water tank for a scrubber installed at a downstream side in an oxidation-reaction type exhaust gas apparatus such as a combustion-type or heater-type exhaust gas treatment apparatus for treating an exhaust gas discharged from a semiconductor manufacturing apparatus.
In order to achieve the above object, in an embodiment, there is provided a powder discharge system installed in a circulating water tank for collecting powder generated when an exhaust gas is treated in an exhaust gas treatment apparatus, the powder discharge system comprising: at least one eductor provided in the circulating water tank; the eductor comprising a nozzle configured to throttle a flow of water supplied from a pump for pumping water in the circulating water tank, a suction port configured to suck water in the circulating water tank into the eductor by utilizing a reduction of pressure generated when the flow of water is throttled by the nozzle, and a discharge port configured to eject the water sucked from the suction port together with the water discharged from the nozzle toward a bottom of the circulating water tank.
In an embodiment, the water ejected from the discharge port of the eductor crushes the powder deposited on the bottom of the circulating water tank and floats the powder, and the powder is discharged from the circulating water tank together with drainage water.
According to the embodiment, because the eductor is disposed at a suitable place in the circulating water tank in which the powder is accumulated, and water is ejected from the eductor to the bottom of the circulating water tank, the powder aggregated on the bottom of the circulating water tank is crushed and floated, and thus the powder can be efficiently discharged together with drainage water. Therefore, the discharge rate of the powder can be increased and a maintenance period of the circulating water tank can be prolonged.
In an embodiment, the eductor comprises a substantially cylindrical body part, and when an inner diameter of the body part is d1 (mm), an opening diameter d3 of the nozzle is set to d3=(0.16−0.26) d1 and a diameter d2 of the suction port is set to d2=(0.8−0.95)d1.
In an embodiment, water level of the circulating water tank is controlled to form a state where the water level is lower than the suction port of the eductor and a state where the water level is higher than the suction port of the eductor; when the water level is lower than the suction port of the eductor, only the water discharged from the nozzle is ejected from the eductor toward the bottom of the circulating water tank; and when the water level is higher than the suction port of the eductor, the water discharged from the nozzle and the water sucked from the suction port are ejected from the eductor toward the bottom of the circulating water tank.
According to the embodiment, in the state where water level of the circulating water tank is lower than the suction port of the eductor, i.e., the water level is low, the pump is operated to supply water to the eductor, and only the water discharged from the nozzle is ejected from the eductor toward the bottom of the circulating water tank to crush the aggregated powder on the bottom of the circulating water tank, thus making a diameter of powder smaller. Then, in the state where water level of the circulating water tank is higher than the suction port of the eductor, the water discharged from the nozzle and the water sucked from the suction port are ejected from the eductor toward the bottom of the circulating water tank. Therefore, the powder on the bottom of the circulating water tank is further crushed and water in the circulating water tank is agitated, and thus the powder accumulated on the bottom of the circulating water tank is floated, and is then automatically discharged together with drainage water from a drainage port.
In an embodiment, the powder generated when the exhaust gas is treated is collected in the circulating water tank through a connecting pipe, and the plural eductors are disposed around the connecting pipe.
According to the embodiment, since the plural eductors are disposed around the connecting pipe for introducing the powder into the circulating water tank, the powder accumulated at the position immediately below the connecting pipe can be crushed by the water ejected from the eductors and can be floated.
In an embodiment, the water ejected from the eductor is spreading conically and hits against the bottom surface of the circulating water tank at a circular ejected surface; and the circular ejected surface on the bottom surface of the circulating water tank is set so as to enter into a circle formed by vertically projecting a circle having a diameter equal to an inner diameter of the connecting pipe onto the bottom surface of the circulating water tank.
Since the powdery product generated by the exhaust gas treatment falls onto the bottom surface of the circulating water tank through the connecting pipe, the powdery product which has fallen tends to accumulate in the interior of the circle, immediately below the connecting pipe, having a diameter equal to an inner diameter of the connecting pipe. According to the embodiment, the water ejected from the eductor is spreading conically and hits against the bottom surface of the circulating water tank at a circular ejected surface. The circular ejected surface, on the bottom surface of the circulating water tank, onto which water ejected from the eductor is applied is set so as to enter into the circle formed by vertically projecting the circle having a diameter equal to the inner diameter of the connecting pipe onto the bottom surface of the circulating water tank. Therefore, the powdery product which has fallen onto the bottom surface of the circulating water tank through the connecting pipe and has been accumulated thereon can be crushed by an ejecting and hitting force of water ejected from the eductor, and thus can be floated.
In an embodiment, the circular ejected surfaces of the plural eductors are brought into contact with each other at their outer circumferences or have overlapping portions which overlap with each other.
According to the embodiment, since the circular ejected surfaces of the plural eductors are brought into contact with each other at their outer circumferences or have overlapping portions which overlap with each other, the interior of the circle, immediately below the connecting pipe, having a diameter equal to an inner diameter of the connecting pipe can be substantially covered by the ejected surfaces.
In an embodiment, there is provided an exhaust gas treatment apparatus comprising: a circulating water tank configured to collect powder generated when an exhaust gas is treated; a powder discharge system installed in the circulating water tank; the powder discharge system comprising: at least one eductor provided in the circulating water tank; the eductor comprising a nozzle configured to throttle a flow of water supplied from a pump for pumping water in the circulating water tank, a suction port configured to suck water in the circulating water tank into the eductor by utilizing a reduction of pressure generated when the flow of water is throttled by the nozzle, and a discharge port configured to eject the water sucked from the suction port together with the water discharged from the nozzle toward a bottom of the circulating water tank.
The above-described embodiments offer the following advantages.
A powder discharge system according to embodiments will be described below with reference to
Fuel and oxygen are mixed in a premixer 16 in advance to form mixed fuel, and this mixed fuel is supplied to the burner 11. Further, air as an oxygen source for combusting (oxidizing) the exhaust gas is supplied to the burner 11. The burner 11 combusts the mixed fuel to form swirling flames in the combustion chamber 12, and the exhaust gas is combusted by the swirling flames. A UV sensor (not shown) is disposed inside the burner 11 and it is monitored by the UV sensor whether the swirling flames are formed normally. Air and nitrogen are supplied around the UV sensor as purge gas. Water W1 is supplied to the upper part of the combustion chamber 12. This water W1 flows down along the inner surface of the combustion chamber 12 and a water film is formed on the inner surface of the combustion chamber 12. The combustion chamber 12 is protected from heat of the swirling flames by the water film. Further, a cooling water passage (not shown) through which cooling water W2 for cooling the burner 11 flows is provided between the burner 11 and the combustion chamber 12.
The exhaust gas introduced into the combustion chamber 12 through the burner 11 is combusted by the swirling flames. Thus, combustible gases such as silane, disilane and the like contained in the exhaust gas is oxidatively decomposed. At this time, by combustion of the combustible gases, silica (SiO2) is produced as powdery product. This silica exists in the exhaust gas as fine dust.
A part of such powdery product is accumulated on the burner 11 or the inner surface of the combustion chamber 12. Therefore, the heating treatment unit 10 is configured to operate a scraper (not shown) periodically so that the powdery product accumulated on the burner 11 or the inner surface of the combustion chamber 12 is scraped off. A circulating water tank 20 is disposed below the combustion chamber 12. A weir 21 is provided inside the circulating water tank 20, and the circulating water tank 20 is partitioned by the weir 21 into a first tank 20A at an upstream side and a second tank 20B at a downstream side. The powdery product scraped off by the scraper falls on the interior of the first tank 20A of the circulating water tank 20 through the combustion unit connecting pipe 13 and is accumulated on the bottom of the first tank 20A. Further, the water film which have flowed down along the inner surface of the combustion chamber 12 flows into the first tank 20A. Water in the first tank 20A flows over the weir 21 and flows into the second tank 20B.
The combustion chamber 12 communicates with an exhaust gas cleaning unit 30 through a cooling unit 25. This cooling unit 25 has a piping 26 extending toward the combustion unit connecting pipe 13 and a spray nozzle 27 arranged in the piping 26. The spray nozzle 27 sprays water countercurrently into the exhaust gas flowing in the piping 26. Therefore, the exhaust gas treated by the heating treatment unit 10 is cooled by water sprayed from the spray nozzle 27. The ejected water is recovered to the circulating water tank 20 through the piping 26.
The cooled exhaust gas is then introduced into the exhaust gas cleaning unit 30. This exhaust gas cleaning unit 30 is an apparatus for cleaning the exhaust gas with water and removing fine dust contained in the exhaust gas. This dust is mainly composed of powdery product produced by oxidative decomposition (combustion treatment) in the heating treatment unit 10.
The exhaust gas cleaning unit 30 comprises a wall member 31 for forming a gas passage 32, and a first mist nozzle 33A, a first water film nozzle 33B, a second mist nozzle 34A and a second water film nozzle 34B disposed in the gas passage 32. These mist nozzles 33A and 34A and water film nozzles 33B and 34B are located at the central portion of the gas passage 32, and are arranged substantially linearly. The first mist nozzle 33A and the first water film nozzle 33B constitute a first nozzle unit 33, and the second mist nozzle 34A and the second water film nozzle 34B constitute a second nozzle unit 34. Therefore, in this embodiment, two sets of nozzle units 33 and 34 are provided. One set of nozzle units or three or more sets of nozzle units may be provided.
The first mist nozzle 33A is disposed further upstream in a flowing direction of an exhaust gas than the first water film nozzle 33B. Similarly, the second mist nozzle 34A is disposed further upstream than the second water film nozzle 34B. Specifically, the mist nozzle and the water film nozzle are alternately disposed. The mist nozzles 33A and 34A, the water film nozzles 33B and 34A, and the wall member 31 are composed of corrosion-resistant resin (e.g., PVC: polyvinyl chloride).
A flow control member 40 for regulating flow of an exhaust gas is disposed at an upstream side of the first mist nozzle 33A. This flow control member 40 causes pressure loss of the exhaust gas and uniformizes the flow of the exhaust gas in the gas passage 32. It is preferable that the flow control member 40 is composed of a material other than metal in order to prevent acid corrosion. As an example of the flow control member 40, there is a nonwoven material made of resin or a resin plate having a plurality of openings. A mist nozzle 41 is disposed at an upstream side of the flow control member 40. The mist nozzles 33A, 34A and 41 and the water film nozzles 33B and 34B are attached to the wall member 31.
As shown in
Fine dust having a diameter of less than 1 μm contained in the exhaust gas easily adheres to water particles forming mist by diffusion action (Brownian movement), and thus the fine dust is trapped by the mist. Dust having a diameter of not less than 1 μm is mostly trapped by the water particles in the same manner. Since a diameter of the water particles is approximately 100 μm, the size (diameter) of the dust adhering to these water particles becomes large apparently. Therefore, the water particles containing dust easily hits the water film at the downstream side due to inertial impaction, and the dust is thus removed from the exhaust gas together with the water particles. Dust having a relatively large diameter which has not been trapped by the mist is also trapped by the water film in the same manner and is removed. In this manner, the exhaust gas is cleaned by water and the cleaned exhaust gas is discharged from the upper end of the wall member 31.
As shown in
Water to be supplied to the mist nozzles 33A and 34A and the water film nozzles 33B and 34B is water recovered by the circulating water tank 20 and contains dust (such as powdery product). Therefore, in order to clean the gas passage 32, municipal water is supplied to the gas passage 32 from a shower nozzle 50. A mist trap 51 is provided above the shower nozzle 50. This mist trap 51 has a plurality of baffle plates therein and serves to trap the mist. In this manner, the treated and detoxified exhaust gas is finally released into the atmosphere through the exhaust duct.
A water level sensor 55 is provided in the circulating water tank 20. The water level sensor 55 is configured to monitor water level of the second tank 20B and to control the water level of the second tank 20B within a predetermined range. Further, part of water delivered by the circulating water pump P is supplied to a plurality of eductors 3 installed in the circulating water tank 20 through a water supply pipe 2. The water supply pipe 2 has an opening and closing valve V1, and when the opening and closing valve V1 is opened, water can be supplied to the eductors 3. A drain valve V2 for discharging water in the circulating water tank 20 is provided on the circulating water tank 20.
Next, dimensional relationship of the respective parts of the eductor 3 will be described. As shown in
As shown in
As shown in
As shown in
As shown in
Therefore, according to the embodiment, the circular ejected surface Ar, on the bottom surface of the circulating water tank 20, onto which water ejected from the eductor 3 is applied is set so as to enter into the circle having a diameter of D1 formed by vertically projecting the circle having a diameter equal to the inner diameter D1 of the combustion unit connecting pipe 13 onto the bottom surface of the circulating water tank 20. In this case, by setting the distance L between the centers of the two eductors in the range of 2D1 to 4D1 as described above, the range in the circle having a diameter of D1 into which the ejected surface Ar enters can be suitably enlarged. Therefore, if the two ejected surfaces Ar, Ar come close to each other at their outer circumferences or have overlapping portions which overlap with each other, the interior of the circle having a diameter of D1 can be substantially covered by the ejected surfaces Ar, Ar. By this setting, the powdery product which has fallen onto the bottom surface of the circulating water tank 20 through the combustion unit connecting pipe 13 and has been accumulated thereon can be crushed by an ejecting and hitting force of water ejected from the eductor 3.
Further, by controlling water level of the circulating water tank 20, when the water level of the circulating water tank 20 is low, water is ejected at an amount Q from each eductor 3 to enhance a crushing effect of the powdery product. When the water level of the circulating water tank 20 increases, water is ejected at an amount 5 Q from each eductor 3 to crush the powdery product further and to agitate water in the circulating water tank 20. Thus, the powder accumulated on the bottom of the circulating water tank 20 is floated, and then the powder is automatically discharged together with drainage water from the drainage port 20D.
In this manner, the discharge rate of the powder can be increased to 90% by the powder discharge system using the eductors 3 according to the embodiment, whereas the discharge rate of the powder is 70% in the conventional case using the bubbler.
Further, according to the embodiment, by supplying compressed air from the air supply pipe 4 to the eductor 3 periodically (or as needed), the powder existing in the suction port 3h of the eductor 3 can be discharged, and thus the eductor 3 can be prevented from being clogged with the powder. Therefore, blockade caused by the powder in the nozzle part which has occurred in the bubbler does not occur, and thus the rate-limiting of the maintenance period of the circulating water tank 20 is not determined by maintenance of the bubbler. Therefore, the maintenance period of the circulating water tank 20 can be prolonged more than double.
Although the combustion-type exhaust gas treatment apparatus is illustrated in
Although the preferred embodiments of the present invention have been described above, it should be understood that the present invention is not limited to the above embodiments, but various changes and modifications may be made to the embodiments without departing from the scope of the appended claims.
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