The invention relates to a powder hopper for feeding powdered electrode precursor material into a nip of a dry electrode calender for producing a dry electrode web.
Electrodes can be used in electrical energy storage cells, which are widely used to power electronic, electromechanical, electrochemical, and other useful devices. Such cells include batteries such as primary chemical cells and secondary (rechargeable) cells, fuel cells, and various types of capacitors, including ultracapacitors. Electrodes can also be used in water treatment plants. Electric mobility in particular is clearly growing. The energy source in electrically powered vehicles, the battery, accounts for a large part of the costs. This is directly related to their production. This requires efficient and cost-effective production with a simultaneous increase in energy density. The calendering process within the process chain for producing lithium-ion battery cells is crucial for this.
The key components for the storage potential of an energy storage device are the electrodes. The electrochemical capabilities of electrodes, such as the capacity and efficiency of battery electrodes, are determined by various factors. These include the distribution of the active material, the binder, and the additives, the physical properties of the materials contained therein, such as particle size and surface area of the active material, the surface properties of the active materials and the physical properties of the electrode film, such as density, porosity, cohesion, and adhesion to a conductive element. Dry processing systems and methods traditionally use a processing step with high shear and/or high pressure to break up and mix the electrode film materials. Such systems and methods can contribute to structural advantages over wet-produced electrode films. However, the high processing pressures and large system dimensions (and thus the large space requirement) required for the production of dry, self-supporting electrode films and dry electrodes leave room for improvements.
A device and a method for producing a dry electrode are known from US 2020/0 072 612 A1, which on the one hand describes manual feeding of powdered electrode precursor material into a nip and on the other hand the use of powder hoppers for feeding the material. However, the solutions described have the disadvantage that the feed of the material in this way is inaccurate and can result in an inhomogeneously formed electrode track which has variations in its thickness and width.
It is therefore the object of the present invention to improve a powder hopper for feeding powdered electrode precursor material into a nip in such a way that the feed of the material can be better metered.
The invention is achieved by the features of the independent claims. Advantageous embodiments are described in the dependent claims.
Accordingly, a powder hopper for gravity-driven feeding of powdered electrode precursor material into a nip of a dry electrode calender is provided, having a powder feed opening for feeding powdered electrode precursor material into the powder hopper and a powder outlet opening for metering the powdered electrode precursor material from the powder hopper into a nip, wherein the cross section of the powder hopper tapers between the powder feed opening and the powder outlet opening, characterized in that the powder hopper has a level detection device for determining the powder level of the powder hopper. The powder hopper can be aligned so that the powder feed opening is located above the powder outlet opening, in particular is arranged vertically above it. The powder feed opening and/or the powder outlet opening can have a rectangular cross section.
In relation to the solution known from the prior art, the invention has the advantage that the fill level of the powder hopper can be continuously monitored during the process. This makes it possible to improve the homogeneity of the electrode track produced, in particular to produce a homogeneous thickness and/or a homogeneous track width. Furthermore, the fill level monitoring enables timely detection of errors in the operating process, for example if there is too little or too much powder in the hopper, so that the system can be switched off in time if necessary to avoid serious damage to the system.
It can be provided that the powder hopper furthermore comprises a weight detection device for determining the weight of the powder in the powder hopper. It can be provided that the level detection device and the weight detection device are connected to a control unit of the system and send the determined level and weight data to the control unit. The control unit can continuously determine the density of the powder in the hopper by comparing the fill level data with the weight data. This has the advantage that the powder feed into the hopper can be controlled based on the determined density and thus the powder fed into the nip has a constant density. This is particularly important because the powdered electrode precursor material is already compacted in the hopper, which continuously increases in the direction of the powder outlet opening due to the powder material pressing down on the lower powder layers from above. The compaction is further increased by simply feeding the powder into the powder hopper, wherein the powder falls, for example, from a feed device into the powder hopper and the vertical distance of the feed device from the powder hopper or from the powder contained therein influences the degree of compaction of the powder in the hopper.
It can be provided that the weight detection device comprises at least one load cell on which the powder hopper is supported. It can be provided that the powder hopper has at least one first and at least one second load cell as well as at least two support tabs which project laterally on opposite sides of the powder hopper, wherein the powder hopper is supported via one of the tabs on the at least one first load cell and via the opposite other tab on the at least one second load cell. To detect the powder weight in the powder hopper, the at least one load cell can send the measured weight to the control unit, in which the tare weight of the powder hopper is then subtracted from the measured value.
It can be provided that the powder hopper has a width extending transversely to the nip and a length extending along the nip, wherein the width of the powder hopper decreases between the powder feed opening and the powder outlet opening and the length of the powder hopper is constant between the powder feed opening and the powder outlet opening. In particular, it can be provided that the powder feed opening and the powder outlet opening are vertically spaced apart from one another. The powder hopper can have two opposite side walls which delimit the length of the hopper and which can in particular be aligned vertically. The support tabs can be bent away from the side walls, in particular from the upper edge of the side walls. The powder hopper can have two opposite side walls which delimit the width of the powder hopper and which are adjacent to the powder feed opening. These walls adjacent to the powder feed opening can be aligned substantially vertically. Immediately adjacent to the powder outlet opening, there may be two further opposite wall sections which delimit the width of the powder hopper, one of which may be aligned substantially vertically and the other may be aligned inclined and tapering in cross section towards the powder outlet opening.
The fill level detection device can have at least one first fill level sensor in the area above the powder outlet opening. The first fill level sensor can, for example, be arranged in the vertical wall section adjacent to the powder outlet opening. The first fill level sensor can, for example, be arranged in a range of 2 cm-10 cm above the powder outlet opening.
The fill level detection device can have at least one second fill level sensor in the area below the powder feed opening. The second fill level sensor can, for example, be arranged in the vertical wall section adjacent to the powder feed opening. The second fill level sensor can, for example, be arranged in a range of 2 cm-10 cm below the powder feed opening.
For example, the fill level detection device can comprise at least one capacitive fill level sensor. The principle of capacitive fill level measurement is based on the capacitance change of a capacitor. The capacitive sensor and the powder hopper wall form a capacitor whose capacitance depends on the amount of powder in the hopper, wherein an empty hopper has a lower capacitance and a filled hopper has a higher capacitance. It can be provided that the fill level sensor has a plurality of sensor units distributed over the length of a side wall of the powder hopper and arranged at substantially the same height. The sensor units can be, for example, light barriers or capacitive sensors. By distributing the sensors over the length of the powder hopper, it can be determined whether the powder hopper is evenly filled with powder over its entire length. For example, the powder hopper can have multiple measuring levels, in each of which a plurality of fill level sensors can be arranged horizontally spaced apart from one another, i.e., at the same height. For example, four or more fill level sensors can be provided per measuring level.
It can be provided that the side wall of the powder hopper which has the plurality of sensor units is arranged essentially vertically. Accordingly, it can be provided that in the case of multiple measuring levels, the side wall sections having the sensors are each aligned vertically and the hopper can therefore have multiple vertical wall sections. If multiple measuring planes are provided, the sensors can all be located on the same side of the hopper, so that the side of the hopper opposite to the sensors has only a single inclined wall section.
The first fill level sensor can thus have a first plurality of sensor units distributed over the length of a first substantially vertical side wall of the powder hopper and arranged at substantially the same height, and the second fill level sensor can have a second plurality of sensor units distributed over the length of a second substantially vertical side wall of the powder hopper and arranged at substantially the same height, wherein an inclined side wall connecting the first and the second side walls can be arranged between the first and the second side walls, which tapers the width of the powder hopper in the direction of the powder outlet opening.
The fill level detection device can furthermore comprise an optical fill level sensor additionally or alternatively to the capacitive fill level sensor. The optical fill level sensor can be directed spaced apart from the powder hopper through the powder feed opening onto the interior of the powder hopper. The optical fill level sensor can be arranged above the powder hopper. The detection range of the optical fill level sensor can comprise at least the entire length and the entire width of the powder hopper. The optical fill level sensor can be configured to detect the filling volume of the powder hopper with powdered electrode precursor material. For this purpose, the optical fill level sensor can have a camera which detects the surface relief of the powder in the hopper and compares it with a value of the total volume of the powder hopper stored in the control unit. The optical fill level sensor can thus also be configured to detect powder fill levels that are unevenly distributed over the length of the powder hopper.
The invention furthermore relates to an assembly comprising a powder hopper according to one of the preceding claims and a first and a second roll forming a nip, wherein the powder outlet opening of the powder hopper is arranged above and along the nip, so that the powdered electrode precursor material can be metered into the nip over this entire length of the powder outlet opening.
It can be provided that the assembly furthermore comprises a feed conveyor arranged above the powder hopper, by means of which powdered electrode precursor material can be conveyed into the nip. It can be provided that the feed conveyor is height-adjustable. It can be provided that the feed conveyor is a belt conveyor. It can furthermore be provided that the vertical adjustment device for adjusting the height of the feed conveyor is coupled to the control unit, and the control unit regulates the vertical position of the feed conveyor depending on the determined powder fill level in the powder hopper so that the distance between the feed conveyor and the powder surface in the hopper always remains constant. Alternatively, it can be provided that the control unit controls the vertical adjustment device in such a way that the density determined in the powder hopper always remains constant, so that the distance of the feed conveyor to the hopper is increased when the density falls below a target density and is reduced when the target density is exceeded. This allows the effect of compaction in the hopper caused by feeding the powder to be utilized in order to achieve a constant material density at the powder outlet opening.
The conveying speed of the feed conveyor can be regulated depending on the powder density determined in the powder hopper, wherein the powder density is calculated on the basis of the powder filling height determined via the fill level sensor and the powder mass determined via the weight detection device. It can be provided that the conveying speed is increased when the calculated powder density exceeds a first threshold value of a target range, and wherein the conveying speed is slowed down when the calculated powder density falls below a second threshold value of the target range.
The invention furthermore relates to a method for operating a powder hopper, comprising the following steps:
It can be provided that regulating the flow of powdered electrode material conveyed into the powder hopper comprises regulating a conveying speed of a feed conveyor connected upstream of the powder hopper. It can furthermore be provided that regulating the flow of powdered electrode material conveyed into the powder hopper comprises regulating a vertical distance between a feed device and the powder hopper.
Furthermore, it can be provided that determining the fill level of the powder hopper comprises determining using a capacitive and/or optical sensor. In this case, determining the fill level of the powder hopper can comprise determining the presence of powdered electrode precursor material on a first powder hopper level and determining the presence of powdered electrode precursor material on a second powder hopper level, wherein the height of the first powder hopper level can differ from the height of the second powder hopper level.
Furthermore, it can be provided that determining the weight of the powdered electrode precursor material located in the powder hopper comprises weighing the powder hopper minus the powder hopper weight.
Further details of the invention are explained using the figures below. In the figures:
The illustration shown in
As shown in
The features of the invention disclosed in the above description, in the figures and in the claims can be essential for the implementation of the invention both individually and in any combination.
Y2 conveying direction of the second electrode film
Filing Document | Filing Date | Country | Kind |
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PCT/DE2022/100315 | 4/28/2022 | WO |
Number | Date | Country | |
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63275863 | Nov 2021 | US |