Claims
- 1. A process for the production of bis(fluoromethyl) ether which comprises reacting formaldehyde with hydrogen fluoride in a distillation column operated at a temperature in the reaction section of from about 50.degree. C. to about 80.degree. C. to produce bis(fluoromethyl) ether and water and withdrawing from the column a vapour in which the mole ratio of bis(fluoromethyl) ether to water is greater than 1.
- 2. A process for the production of bis(fluoromethyl) ether which comprises reacting formaldehyde with hydrogen fluoride in a distillation column within which the temperature profile is from 20.degree. C. to 40.degree. C. at the top of the column to 115.degree. C. to 140.degree. C. at the bottom of the column to produce bis(fluoromethyl) ether and water and withdrawing from the column a vapour in which the mole ratio of bis(fluoromethyl) ether to water is greater than 1.
- 3. A process as claimed in claim 1 or 2 wherein the bis(fluoromethyl) ether is withdrawn from the top of the column and water is withdrawn from the bottom of the column.
- 4. A process as claimed in claim 1 in which the formaldehyde and hydrogen fluoride are caused to flow in counter-current in the column.
- 5. A process as claimed in claim 4 in which the formaldehyde and at least a part of the hydrogen fluoride are fed to the column through different inlets.
- 6. A process as claimed in claim 5 in which formaldehyde is fed to the distillation column at a position above that at which at least a part of the hydrogen fluoride is fed to the column.
- 7. A process as claimed in any one of claims 4 to 6 in which the formaldehyde is fed to the column as a solution of formaldehyde in hydrogen fluoride.
- 8. A process for the production of difluoromethane which comprises reacting formaldehyde with hydrogen fluoride in a distillation column as defined in claim 1 or 2 and heating the bis(fluoromethyl) ether withdrawn from the column in the vapour phase at a temperature of from 200.degree. C. to 450.degree. C. in the presence of a catalyst selected from the group consisting of nickel, chromium, aluminum and iron or an alloy of at least one of these metals or an oxide, fluoride or oxyfluoride thereof.
- 9. A process for the production of difluoromethane which comprises reacting formaldehyde with hydrogen fluoride in a distillation column as defined in claim 1 or 2 and heating the bis(fluoromethyl) ether withdrawn from the column at elevated temperature of from 200.degree. C. to 400.degree. C. in the vapour phase in the presence of a catalyst selected from the group consisting of nickel, chromium, aluminum and iron or an alloy of at least one of these metals or an oxide, fluoride or oxyfluoride thereof.
Priority Claims (1)
Number |
Date |
Country |
Kind |
9124087 |
Nov 1991 |
GBX |
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Parent Case Info
This is a continuation of application No. 07/974,710, filed on Nov. 12, 1992, which was abandoned upon the filing hereof.
US Referenced Citations (3)
Number |
Name |
Date |
Kind |
3377394 |
Boudakian et al. |
Apr 1968 |
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4143078 |
Gibbs et al. |
Mar 1979 |
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5073236 |
Gelbein et al. |
Dec 1991 |
|
Foreign Referenced Citations (2)
Number |
Date |
Country |
1025856 |
Mar 1958 |
DEX |
2126216 |
Mar 1984 |
GBX |
Non-Patent Literature Citations (3)
Entry |
Weinmayr, Hydrogen Fluoride as a Condensing Agent, VI. Reactions of Fluoroolefins with Formaldehyde in . . . , The Journal of Organic Chemistry, vol. 28, No. 2, Feb., 1963, pp. 492-494. |
West German Published Patent Application 1 025 856, Production of Bis-Methyl Chloride Ether. |
Weinmayr, J. Org. Chem., vol. 28, pp. 492-494, 1963. |
Continuations (1)
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Number |
Date |
Country |
Parent |
974710 |
Nov 1992 |
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