Claims
- 1. A method for the production of a gamma-butyrolactone comprising the step of reacting, at a temperature between 20.degree. C. and 250.degree. C.:
- an olefin selected from the group consisting of acyclic monoolefins having 2 to 92 carbon atoms, acyclic diolefins having 3 to 8 carbon atoms, cyclic monoolefins having 5 to 8 carbon atoms and cyclic diolefins having 5 to 8 carbon atoms;
- an acid having the formula ##STR46## wherein one or both of the R's are selected from the group consisting of hydrogen, straight or branched chain alkyl or alkenyl group having one to ten carbon atoms, cyano and alkyl carboxy having the formula ##STR47## wherein R" is hydrogen or CH.sub.3 and n has a value of one to six; and at least two equivalents per mole of said olefin of an ion of manganese or cerium, the ion being in a valency state higher than its lowest valency state.
- 2. The method of claim 1 wherein said olefin is an acyclic monoolefin having from 2 to 92 carbon atoms and said acid is acetic acid.
- 3. The method of claim 1 wherein said step of reaction is conducted in the presence of potassium acetate.
- 4. The method of claim 1 wherein said ion in a valency state higher than its lowest valency state is an ion of manganese.
- 5. The method of claim 4 wherein said ion of manganese is in a valency state of +3.
- 6. The method of claim 4 wherein said ion of manganese is provided by manganic acetate, manganese dioxide or potassium permanganate.
- 7. The method of claim 1 wherein said ion in a valency state higher than its lowest valency state is cerium in a valency state of four.
- 8. The method of claim 1 wherein said olefin is an acyclic diolefin having 3 to 8 carbon atoms and said acid is acetic acid or cyanoacetic acid.
- 9. The method of claim 8 wherein the acyclic diolefin is isoprene.
- 10. The method of claim 8 wherein the acyclic diolefin is 2,5-dimethylhexadiene-1,5.
- 11. The method of claim 8 wherein the acyclic diolefin is butadiene.
- 12. The method of claim 1 wherein said olefin is an acyclic monoolefin having 2 to 10 carbon atoms.
- 13. The method of claim 1 wherein said olefin is styrene, .alpha.-methylstyrene or beta-methyl-styrene.
- 14. The method of claim 1 wherein said olefin is a hydrocarbon olefin and said acid is acetic acid.
CROSS REFERENCE TO RELATED APPLICATIONS
This application is a continuation-in-part of our copending application Ser. No. 30,582, filed Apr. 21, 1970 now abandoned. The latter application is a continuation-in-part of our application Ser. No. 714,447, filed Mar. 20, 1968, which application was pending at the time application Ser. No. 30,582 was filed but which has since been abandoned.
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2476668 |
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Jul 1949 |
|
2986568 |
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|
3470219 |
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|
Foreign Referenced Citations (1)
Number |
Date |
Country |
1902329 |
Nov 1969 |
DEX |
Non-Patent Literature Citations (5)
Entry |
R. E. van der Ploeg, Aromatische Substitutie Door Middel Van Marganiacetat in Ijsazijn, Sep. 27, 1967, Phd. Thesis, University of Leiden. |
R. E. van der Ploeg et al., Journal of Catalysis, vol. 10, 52-59 (1968). |
Bush et al., JACS, Oct. 1968, pp. 5903-5905. |
Heiba et al., JACS, Oct. 1968, pp. 5905-5906. |
Chemical Abstracts, vol. 72, 1970, 78456j relied on. |
Continuation in Parts (2)
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Number |
Date |
Country |
Parent |
30582 |
Apr 1970 |
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Parent |
714447 |
Mar 1968 |
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