Patent Grant
8536085
The invention relates broadly to supported, cobalt-containing catalysts. More particularly, the invention relates to cobalt-containing catalysts of highly dispersed, small particle-size cobalt crystallites.
Catalysts comprising cobalt on a support such as silica or alumina are known to be useful in hydrogenation reactions such as hydrogenating aldehydes and nitriles. They are also used in hydrocarbon synthesis via the Fischer-Tropsch process.
In the case of the Fischer-Tropsch hydrocarbon synthesis process, especially when conducted in a slurry bubble column reactor, one preferred catalyst comprises cobalt supported on a titania support. Generally, the titania in such catalysts is in its rutile form.
Promoter metals, such as rhenium, zirconium, manganese and Group VIII noble metals are commonly used with cobalt catalysts to improve various aspects of catalytic performance. For example, the presence of Re or a Group VIII metal has a beneficial effect on the dispersion of Co crystallites.
The activity of a cobalt-containing Fischer-Tropsch catalyst has been shown to be proportional to the surface cobalt sites for cobalt particle sizes above 6 nm. See Journal of Catalysis, 1992, 137(1), 212-224. It also has been shown that metal crystallites that have a poor nanoscale homogeneity tend to agglomerate to a more severe degree than those with homogeneous nanoscale distribution. See Stud. Surf Sci. and Catalysis, Vol. 162, 2006, pg 103-110. Purportedly, the optimum cobalt crystallite size for Fischer-Tropsch catalysis is in the range of 6 nm since this provides a larger number of surface cobalt sites than larger crystallites and since crystallites below 6 nm have lower site activity than those of 6 nm and larger. See den Breejen, et al., “On the Origin of the Cobalt Particle Size Effects in Fischer-Tropsch Catalysis”, Journal of American Chemical Society, (2009), 131(20), 7197-7203).
Thus, one object of the present invention is to prepare cobalt-containing catalysts that have an appropriate cobalt crystallite size and good nanoscale homogeneity.
Patent Publication WO 2007/071899 A1 discloses that exposing a silica-supported cobalt nitrate to a gas mixture containing NO and less than 5 vol % O2 in He at the nitrate decomposition temperature and then followed by reduction results in the formation of very small metal particles.
Another object of the present invention is to provide a method for forming a cobalt catalyst having small cobalt crystallite size with good nanoscale distribution without the use of NO and He (or NO with any inert or oxidizing gas).
In U.S. Pat. No. 4,568,663, there is disclosed a Fischer-Tropsch hydrocarbon synthesis process which utilizes a catalyst comprising cobalt, rhenium and titania. This catalyst is made by impregnating a titania support with an aqueous solution of cobalt nitrate and perrhenic acid by the conventional incipient wetness method, drying and then calcining to decompose the cobalt nitrate to the oxide. The presence of rhenium serves several important functions: one is to aid in the dispersion of the cobalt; another is to aid in the reduction of the cobalt oxide when the catalyst is activated (reduced). High dispersion and full reduction of the cobalt results in a highly active catalyst. This result, however, does not come without cost because rhenium is a relatively expensive commodity.
Thus, there exists a need for means to better disperse the cobalt with a lesser amount of rhenium. Indeed, an object of the present invention is to provide a method for preparing a catalyst having highly-dispersed, small particle-size cobalt, with a homogeneous nanoscale cobalt distribution and which contains 0.2 wt % or less of rhenium.
In a first aspect, the present invention comprises a method for preparing a supported cobalt catalyst, preferably a titania- or silica-supported cobalt catalyst, having highly dispersed, small particle size cobalt, with a homogeneous nanoscale cobalt distribution.
In a second aspect, the invention comprises a method for preparing a metal or metal oxide promoted, supported cobalt-containing catalyst having highly-dispersed, small particle size cobalt, with a homogeneous nanoscale cobalt distribution.
In a third aspect, the invention comprises a method for preparing a supported cobalt-containing catalyst having substantially homogeneously dispersed, small cobalt crystallites and from about 0.01 wt % to 0.2 wt % Re, based on the total weight of the catalyst.
Other aspects of the invention will become apparent from the detailed description that follows.
In each of the various aspects of the invention, the catalyst is prepared by depositing cobalt nitrate on a catalyst support. Optionally, a promoter metal solution also may be deposited on the support. If used, the promoter metal may be co-deposited with the cobalt nitrate or subsequent to the deposition of the cobalt nitrate. Preferably, the so treated support is first dried and thereafter subjected to a two-step decomposition protocol. In the first step, the dried support is heated in an oxygen-containing, substantially water-free atmosphere to about 160° C. to partially decompose the cobalt nitrate, thereby forming an intermediate decomposition product. Thereafter, the intermediate product is hydrolyzed, and then reduced. Optionally the catalyst may be calcined in air between such hydrolysis and reduction.
Catalysts prepared by the foregoing method have highly dispersed cobalt with a surface-volume-averaged diameter (Dsv) of about 11 nm and less.
Thus, another aspect of the invention is the use of the catalyst in the Fischer-Tropsch hydrocarbon synthesis process.
a, 4b, 5a, 5b, 5c, 8a, 8b and 10a are microphotographs of titania-supported cobalt catalysts prepared by methods other than those of the present invention, and
a, 6b, 6c, 7a and 9a are microphotographs of titania-supported cobalt catalysts prepared according to the method of the invention, and
Catalyst supports useful in the method of the present invention include titania, silica, chromia, alumina, magnesia, silica-alumina, zirconia and the like. Typically, the support will be titania or silica. For use of this catalyst in the Fischer-Tropsch hydrocarbon synthesis process, it is preferred that the support comprise primarily titania where greater than 50 wt % of the titania is in the rutile phase. A particularly preferred support is disclosed in U.S. Pat. No. 6,124,367, which is incorporated by reference herein in its entirety. That support comprises primarily titania, converted from its anatase form to its rutile form, and a minor amount of a binder comprising alumina and/or silica.
Typically, the titania support used will have a surface area in the range of about 5 m2/g to about 40 m2/g and preferably from 10 m2/g to 30 m2/g. Pore volumes will range from about 0.2 cc/g to about 0.5 cc/g and preferably from 0.3 cc/g to 0.4 cc/g. Typically the silica support used will have a surface area below about 100 m2/g.
The cobalt is loaded on the catalyst support using techniques well known in the art, such as, impregnation of the support with a solution of cobalt nitrate either by spray drying or by the incipient wetness technique. Typically, the concentration and amount of the cobalt solution will be sufficient to provide a cobalt loading in the finished catalyst in the range of about 6 wt % to about 20 wt % and preferably about 8 wt % to about 12 wt % based on the total weight of the catalyst.
In an alternate embodiment of the invention, the support is also treated with a Group IV, VII or VIII promoter metal, and mixtures thereof in an amount sufficient to provide a loading of the promoter metal or mixture of metals in the range of about 0.01 wt % to about 5 wt % based on the total weight of the catalyst composition. In this embodiment, the support may be impregnated with a promoter metal solution subsequent to the impregnation with cobalt nitrate solution, or the support may be co-impregnated with cobalt nitrate and promoter metal solution.
In a preferred embodiment of the invention, the promoter metal is rhenium and the support preferably is treated with sufficient perrhenic acid to provide a loading of rhenium on the catalyst in the range of about 0.01 wt % to about 0.2 wt % based on the total weight of the catalyst.
After depositing the cobalt nitrate and optionally a promoter metal or metals solution, the so treated support is dried by any convenient means, such as, heating the supported catalyst in a rotary calciner to temperatures up to about 120° C. for a time sufficient to dry the treated support, conveniently for a period of from 30 minutes to one or several hours.
Importantly, the dried cobalt nitrate-containing support is subjected to a two-step decomposition protocol. In the first step, the dried cobalt nitrate-containing support is heated to a temperature sufficient for the catalyst to pass through the first endotherm of the nitrate decomposition as measured by thermal gravimetric/differential thermal analysis (TG/DTA) but not the second endotherm and to form a nitrosyl species with peaks in the range of 1820-1877 cm−1 as evidenced by an infrared scan. Typically, the cobalt nitrate-containing support will be heated to 160° C.±5° C. in an O2-containing atmosphere that is substantially free of H2O and is free of added NO. One skilled in the art can readily determine when the cobalt nitrate-containing support has passed through the first endotherm as readily seen in
The significance of the two-step protocol, with the first being conducted in a substantially dry atmosphere, is illustrated by reference to
First,
Returning to the treatment protocol of the method of the invention, it is desirable to maintain the heated cobalt nitrate-containing support at the temperature which forms the first endotherm (160° C.±5° C.) for a time sufficient for the intermediate to form and disperse on the support. The heating time will depend to some extent upon the type of heating system employed. For example, if the heating is conducted in a regular box furnace, heating times may be an hour or more. On the other hand, if heating is conducted in a rotary calciner, heating times may be much shorter. Thus, in the case of a rotary calciner the heated cobalt nitrate-containing support may be maintained at about 160° C. for a period of time which may be less than one minute but preferably for at least one minute and more preferably will be from about 2 mins. to about 10 mins.
After the first decomposition step, the intermediate formed is subject to a second decomposition step in which the intermediate product is hydrolytically decomposed. This second decomposition step is then followed by reduction. Optionally, calcination in air may be practiced before reduction.
Calcination is typically conducted in an oxygen-containing atmosphere, such as flowing air, at temperatures sufficient to pass through the second endotherm of the nitrate decomposition as measured by TG/DTA and form cobalt oxide. Typical temperatures for such calcination are above about 160° C., such as between about 300° C. to about 450° C., for about 1 to about 2 hours.
Reduction typically will be conducted in a flowing H2 atmosphere at temperatures in the range of about 250° C. to about 450° C. for about 1 to 2 hours.
The intermediate typically is hydrolytically decomposed by exposing the intermediate to a humid atmosphere, such as moist air, for a time and at a temperature sufficient for the intermediate to decompose. For example, temperatures may range from a room temperature up to about 160° C. for times ranging from about 5 mins. to 12 hours. Thereafter, the product of the hydrolytic decomposition is subject to reduction under conditions such as those described above.
In a preferred aspect, the process of the invention is particularly preferred in instances where the impregnated support is treated with perrhenic acid in an amount sufficient to provide from 0 wt % to 0.2 wt % Re in the resultant catalyst.
The catalysts prepared by the method of the invention are characterized as having small cobalt particles that are homogeneously distributed on the support surface. Indeed, the surface volume particle size distribution, Dsv, of these catalysts typically is 10 nm or less, i.e., down to about 6 nm.
A cobalt-rhenium, titania supported catalyst prepared according to the invention is particularly suitable for use in hydrocarbon synthesis via the Fischer-Tropsch synthesis process, for as is known in the art, high dispersion and full reduction of the cobalt results in a more active catalyst. Importantly, a catalyst of the invention achieves high dispersion and full reduction of the cobalt and significantly lower rhenium content.
Thus, one embodiment of the invention comprises use of the catalyst prepared as disclosed and claimed herein in the Fischer-Tropsch synthesis process. As is described in the available literature, the Fischer-Tropsch process is conducted at temperatures in the range of about 175° C. to about 400° C. at pressures of from about 1 to 100 bar. The H2/CO ratios range from 0.5/1 to about 4/1. Preferably, the catalyst made according to the invention is used in the process in a slurry bubble column reactor with gas hourly space velocities ranging from about 1,000 to 25,000. A preferred slurry bubble column operation is described in U.S. Pat. No. 5,348,982, incorporated herein by reference.
The Dsv (surface-volume-averaged diameter) data for the catalysts described herein were obtained by collecting about 20 to 80 random images of a given catalyst with a Philips CM 12 or Philips CM 200 transmission electron microscope operated at 120 kV and 200 kV, and at screen magnifications of 53,000× and 54,000× respectively. In all cases, the data were collected as digital images with a Gatan CCD camera system using Gatan's Digital Micrograph program, v. 2.5. The line drawing tool in the Digital Micrograph program was used to mark the diameter of each imaged metal particle from which a statistically determined Dsv is obtained. To calculate the Dsv, a histogram of the distribution of particle sizes is obtained from the TEM (transmission electron microscope) measurements, and from the histogram the Dsv is obtained by the following equation:
Dsv={sum(NiDi3)}/{sum(NiDi2)}
where Ni is the number of particles with a diameter Di
TG/DTA data were collected on a Mettler TA 850 thermal analyzer to which a Balzers mass spectrometer was connected to monitor effluent gases. Samples of the catalysts were heated in flowing air at rates of 1° C./min.
DRIFTS (Diffuse Reflectance Infrared Fourier Transform Spectroscopy) measurements were obtained on a Nicolet 670 FTIR spectrometer equipped with a liquid nitrogen cooled MCT detector.
In the Examples and Comparative Examples which follow, a number of cobalt-rhenium catalysts were prepared. All of the catalysts prepared were made using an identical titania support. In all instances, a cobalt nitrate and perrhenic acid solution was sprayed onto the support in a rotary tumbler to ensure a well-mixed, free-flowing impregnate. Thereafter, the impregnated supports were subjected to different thermal treatments, and the resultant catalysts were subjected to transmission electron microscopic (TEM) characterization and Dsv measurements.
(a) The Titania Support
A titania support was prepared by spray-drying as follows. A slurry feed was prepared by mixing 34.4 parts (by weight) of Degussa P-25 fumed TiO2, 8.8 parts alumina chlorhydrol sol (containing 23.5 wt % Al2O3), 0.6 parts silica sol (Nyacol 2034 DI, containing 35 wt % SiO2), and 56.2 parts water. This mixture was fed to a 9-foot diameter spray-drier at a rate of about 13 lb./minute through a 9-inch wheel atomizer spinning at 10,000 rpm. The spray-drying chamber was operated with an inlet air temperature of about 285° C. and an outlet temperature of about 120° C. while spraying. The product consisted of solid spherical particles with an average size of about 60 microns and a composition of 94% TiO2, 5.4% Al2O3, 0.6% SiO2 by weight.
The spray-dried support was calcined at 1000° C. to produce a support in which 93 wt % of the titania was in the rutile phase as determined by X-ray diffraction (ASTM D 3720-78). The balance of the titania was in the anatase phase. The support had a surface area of 17 m2/g and a water pore volume of 0.33 cc/g.
(b) Cobalt and Rhenium Deposition
The catalyst precursors (dry impregnates) were prepared by spraying the titania support with a cobalt nitrate and perrhenic acid solution in a bench scale rotary tumbler and tumbled for ten minutes to ensure a well-mixed, free flowing impregnate. Two types of samples were prepared: (i) dry impregnates having 6.9% Co and 0.12% Re, hereinafter referred to as “Low Re Impregnates”; (ii) impregnates having 7.0% Co and 0.58% Re, hereinafter referred to as “High Re Impregnates”. In the case of the Low Re Impregnates, the support was impregnated with a 15.8 wt % Co and 0.28 wt % Re solution followed by heating in air at 4° C./min to 121° C. to dry the impregnate. In the case of the High Re Impregnates, the support was impregnated with a 14.7 wt % Co and 1.2 wt % Re solution. After each impregnation, the impregnate was dried by heating in air at 4° C./min to 121° C.
A dried Low Re Impregnate was heated in air at 4° C./min. to 160° C. (to partially decompose the Co nitrate) and held at that temperature for 1 hour, followed by heating at 4° C./min. to 300° C. and holding for 1 hour at that temperature (to form cobalt oxide). This calcined material was reduced in 100% H2 at 375° C. at atmospheric pressure for 90 minutes. After cooling to room temperature, the catalyst was passivated in 1% O2 and then air dried to allow measurement by TEM.
A dried Low Re Impregnate was heated in air at 4° C./min. to 160° C. (to partially decompose the Co nitrate) and held at that temperature for 1 hour. The so treated material was allowed to cool to room temperature in a dry, inert atmosphere and then reduced and passivated as described in Comparative Example 1. The results in comparative example 2 show that the crystallites are poorly distributed and large (>16 nm).
A dried Low Re Impregnate was heated in air at 4° C./min. to 160° C. (to partially decompose the Co nitrate) and held at that temperature for 1 hour. The so heated impregnate was cooled to room temperature and then exposed overnight to a high humidity atmosphere by placing it in a container along with an open beaker of water, thereby hydrolytically decomposing the intermediate.
For example 1, a sample of the hydrolytically decomposed intermediate was reduced in 100% H2 at 375° C., passivated and subjected to TEM analysis. The results are shown in
For example 2, another sample of the hydrolytically decomposed intermediate was heated in air at 4° C./min. to 121° C. and held at that temperature for 1 hour, then heated at 4° C./min. to 160° C. and held at that temperature for 1 hour, and finally heated at 4° C./min. to 300° C. and held at that temperature for 1 hour. This calcined sample was then reduced, passivated and subjected to TEM analysis as described for example 1. The results are shown in
A dried Low Re Impregnate was reduced in 100% H2 at 375° C., passivated and subjected to TEM analysis. The results are shown in
A dried High Re Impregnate was heated in air at 4° C./min. to 160° C. (to partially decompose the Co nitrate) and held at that temperature for 1 hour. The so heated impregnate was cooled to room temperature and then exposed overnight to a high humidity atmosphere by placing it in a container along with an open beaker of water, thereby forming a hydrated intermediate. The hydrated intermediate was then reduced in 100% H2 at 375° C., passivated and subjected to TEM analysis. The results are shown in
A dried High Re Impregnate was heated in air at 4° C./min. to 160° C. (to partially decompose the Co nitrate) and held at that temperature for 1 hour. The so heated impregnate was then reduced in 100% H2 at 375° C., passivated and subjected to TEM analysis. The results are shown in
This application is a divisional of co-pending U.S. application Ser. No. 12/460,714, filed Jul. 23, 2009, which application claims the benefit of U.S. Provisional Application No. 61/135,959, filed Jul. 25, 2008.
| Number | Name | Date | Kind |
|---|---|---|---|
| 4568663 | Mauldin | Feb 1986 | A |
| 4729981 | Kobylinski et al. | Mar 1988 | A |
| 4801573 | Eri et al. | Jan 1989 | A |
| 4857559 | Eri et al. | Aug 1989 | A |
| 5348982 | Herbolzheimer et al. | Sep 1994 | A |
| 6124367 | Plecha et al. | Sep 2000 | A |
| 8148292 | Soled et al. | Apr 2012 | B2 |
| 20020010221 | Ionkina et al. | Jan 2002 | A1 |
| Number | Date | Country |
|---|---|---|
| 1450861 | Oct 1991 | EP |
| 199847618 | Oct 1998 | WO |
| WO 2004045767 | Jun 2004 | WO |
| 2007071899 | Jun 2007 | WO |
| Entry |
|---|
| Journal of Catalysis, 1992, 137 (1), pp. 212-224. |
| STUD, Surf Sci. and Catalysis, vol. 162, 2006, pp. 103-110. |
| Den Breejen, et al., “On the Origin of the Cobalt Particle Size Effects in Fischer-Tropsch Catalysis”, Journal of American Chemical Society, (2009), 131 (20), pp. 7197-7203. |
| Das, “Fischer-Tropsch synthesis: characterization and catalytic properties of rhenium promoted cobalt alumina catalysts”, Fuel (2003), 83 (7), ISSN: 0016-2361. |
| Number | Date | Country | |
|---|---|---|---|
| 20120083410 A1 | Apr 2012 | US |
| Number | Date | Country | |
|---|---|---|---|
| 61135959 | Jul 2008 | US |
| Number | Date | Country | |
|---|---|---|---|
| Parent | 12460714 | Jul 2009 | US |
| Child | 13279709 | US |
