The present invention relates to a pressure equalization element for a housing having a water-impermeable membrane, a housing having a pressure equalization element, a lithium ion accumulator having a housing, and a motor vehicle.
In devices such as batteries, which have a housing with an enclosed air volume that is subject to temperature changes and hence to changes in volume, a pressure equalization element (PEE) is normally used. This is a microporous membrane, e.g. one made of polytetrafluoroethylene, such as a Gore-Tex membrane, which is permeable to air but watertight. This PEE ensures complete pressure equalization, that is to say the same air pressure is established inside and outside the housing with a short delay. This pressure equalization is necessary if the housing cannot withstand the possible difference between the internal and the external pressure. A pressure difference of up to 1 bar is possible due to changes in temperature and external pressure during transportation by aircraft, for example.
One problem with the use of such pressure equalization elements with water-impermeable membranes, such as a Gore-Tex® membrane, is that, although they are impermeable to water in the liquid state of aggregation, they are not permeable to water vapor. If the external atmosphere is humid, moist air can penetrate the housing. If there is a region within the device which is cooled to temperatures below the external temperature, there may be condensation of this atmospheric moisture on the cooled regions. This condensation can lead to failures of the device.
According to the invention, a pressure equalization element (PEE) is made available for a housing having a water-impermeable membrane, preferably one made of polytetrafluoroethylene, wherein a pressure relief valve acting in two directions or a combination of two pressure relief valves acting in opposite directions is arranged upstream or downstream of the membrane.
Suitable materials for such membranes, which are permeable to air but prevent liquids from passing through, are known to a person skilled in the art from the prior art.
Suitable pressure relief valves, e.g. duckbill valves, are likewise known to a person skilled in the art from the prior art.
The subject matter of the invention also includes a housing for a device, e.g. for a lithium ion accumulator having active climate control, which is equipped with the abovementioned pressure equalization element.
The statements below relate equally to the pressure equalization element and to the housing equipped therewith.
The pressure relief valve or pressure relief valves is/are set in such a way that pressure equalization takes place only when the pressure difference between the interior of the housing and the surroundings becomes so large that it approaches the stability limits of the housing. This critical pressure can be different for excess pressure and reduced pressure. This advantageously prevents the entry of air and hence moisture into the housing due to frequent small pressure differences, owing to slight changes in the external temperature for example. Only in the case of pressure differences which are relatively large but generally only occur infrequently would an exchange of air then take place.
Reducing the volume of air exchanged as far as possible is at the heart of the present invention. This also reduces the amount of atmospheric moisture carried into the housing.
In addition, the housing preferably has conventional means for removing atmospheric moisture, e.g. a desiccant, thus allowing the small amount of atmospheric moisture which nevertheless enters the housing during a pressure equalization to be reliably removed. These means are known to a person skilled in the art from the prior art.
The membrane and the pressure relief valve or pressure relief valves are preferably combined into a closed unit, which is integrated into the wall of the housing. By way of example, the closed unit can be formed by a tube structure in which the membrane is arranged in one end region and the valve or valves is/are arranged in the opposite end region of the tube structure.
The unit is preferably integrated into the wall of the housing in such a way that, when viewed from the interior, the membrane comes first and is then followed by the pressure relief valve or pressure relief valves. By means of this preferred embodiment, the adiabatic expansion can advantageously be used for additional dehumidification of the air as air flows in.
Thus, the pressure relief valve opens in the presence of an external excess pressure and, upon entry, the air expands and cools as a result. In the process, its capacity to absorb moisture decreases and, in the event of high relative air humidity, some of the atmospheric moisture will condense in the region of the closed unit, and can no longer pass through the membrane. Thus, the condensate does not enter the interior of the housing.
In order to discharge the condensed water back out of the closed unit, the outward-opening pressure relief valve should be arranged in such a way that the water can collect in the region of the pressure relief valve. In the event of an excess pressure in the interior of the housing and the equalization thereof by the pressure relief valve, the condensed water is carried outward. Since the water in the closed unit moves in the direction of gravity, the corresponding pressure relief valve is preferably arranged at the lowest point of the closed unit. A depression to hold the water can additionally be provided in this region.
A condensation plate is preferably arranged in the inflow region, behind the pressure relief valve, in the interior of the closed unit, preventing the condensate from spreading throughout the interior of the closed unit. Moreover, the condensation plate is advantageously provided with a slope in the direction of the lowest point of the closed unit, with the result that the condensate drips off in that part of the valve through which the air flows in the direction of the exterior. When this valve is next opened, condensed water is carried outward as well, as already explained. However, it is also possible to transfer the condensate into some other suitable position for rapid discharge through an appropriate choice of dripping point.
Depending on the positioning of the closed unit on the housing, the tube structure can be adapted to transfer the condensate in an optimum manner in the interior. If the pressure equalization element is arranged at the bottom, for instance, the tube structure can extend in a straight line and, given lateral mounting, the tube structure can be angled in the direction of gravity.
According to another embodiment of the invention, it is also possible to reverse this abovementioned sequence of the membrane and the pressure relief valves, so that, when viewed from the interior, the pressure relief valve or pressure relief valves comes/come first, followed by the membrane, thus making it possible to prevent the entry of dirt into the closed unit.
It is likewise possible to arrange a membrane on both sides of the pressure relief valve or pressure relief valves. In order also to be able to make use of the adiabatic effect for dehumidification of the air in this arrangement, the outer membrane is preferably arranged exclusively in the region of the inward-acting pressure relief valve or of the corresponding part of the pressure relief valve, thus allowing the outflowing air to carry away condensed water through the outward-acting pressure relief valve or the corresponding part of a pressure relief valve.
The invention furthermore relates to lithium ion accumulators with active internal cooling, which are arranged in a housing according to the invention.
The subject matter of the invention furthermore includes a motor vehicle having an electric drive motor for driving the motor vehicle and having a lithium ion accumulator according to the invention, which is connected or can be connected to the electric drive motor and is configured in accordance with the invention.
Advantageous developments of the invention are described in the subclaims.
An illustrative embodiment of the invention is explained in greater detail by means of a drawing and of the following description. In the drawing:
A housing 10 for a device (not shown), e.g. a lithium-ion accumulator, having a pressure equalization element 11 is shown schematically in
Number | Date | Country | Kind |
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10 2011 005 916.4 | Mar 2011 | DE | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/EP2012/054241 | 3/12/2012 | WO | 00 | 11/27/2013 |