Patent Application
20220282834
The present invention relates to a pressure vessel that achieves improvement in flame retardancy and fire safety through structural characteristics thereof, and a method of manufacturing the same.
A pressure vessel means a closed container that receives a constant fluid pressure on an inner or outer surface of the container. Such a pressure vessel is typically used as a fluid handling vessel for various chemical processes. Fluid handling containers in chemical processes include towers, reactors, mixing tanks, heat exchangers, and storage containers as facilities for storing, separating, transporting, and mixing fluids for chemical processes, such as evaporation, absorption, distillation, drying, adsorption, and the like.
In recent years, facilities provided with the pressure vessel have been miniaturized together with increase in application of the pressure vessel to mobile devices, such as automobiles and the like. Accordingly, various methods of manufacturing a pressure vessel capable of guaranteeing light weight and improvement in properties while satisfying predetermined standards have been proposed.
In addition, various studies have also been made to develop a manufacturing method that can prevent fire and explosion due to overpressure in a pressure vessel in abnormal situations, such as fire or excessive reaction in chemical processes.
A typical pressure vessel is manufactured by forming a nozzle boss and a liner connected thereto using a metallic material, followed by winding or stacking fibers around the nozzle boss and the line. However, the pressure vessel formed of the metallic material has problems, such as difficulty in weight reduction, low corrosion resistance, low moldability, and high manufacturing costs, due to characteristics of metal.
To solve such problems, a synthetic resin can be used as the liner of the pressure vessel. In general, the liner formed of the synthetic resin is reinforced by forming a fiber layer on the liner through a loop winding method in which fibers are wound almost at right angles to an axis of a body of the liner, a helical winding method in which fibers are wound in an oblique direction to the axis of the body of the liner, or the like, as known in the art.
However, when the synthetic resin is used as the liner of the pressure vessel, it is still difficult to improve mechanical strength and shape uniformity of the pressure vessel, which can be poorer than a pressure vessel including a metal liner.
Therefore, there is increasing need for a technique capable of improving stability, moldability, and mechanical strength of the pressure vessel while satisfying preset standards.
The background technique of the present invention is disclosed in Korean Patent Laid-open Publication No. 10-2002-0095773.
It is one aspect of the present invention to provide a pressure vessel that can guarantee good properties in terms of flame retardancy, mechanical strength and shape uniformity through structural characteristics thereof while achieving significant improvement in heat insulating properties, and a method of manufacturing the same.
It is another aspect of the present invention to provide a pressure vessel that can realize cost reduction while satisfying light weight, pressure resistance and fire safety, and a method of manufacturing the same.
1. One embodiment of the present invention relates to a pressure vessel including: a plastic liner; and a flame retardant composite resin layer formed on the plastic liner, wherein the flame retardant composite resin layer includes a first composite layer having resin-impregnated fiber aligned in a first direction and a second composite layer having resin-impregnated fiber aligned in a second direction different from the first direction; the resin-impregnated fiber aligned in the first direction and the resin-impregnated fiber aligned in the second direction form a contact region and an open region therebetween; and the contact region and the open region are formed in an area ratio of 1:0.2 to 1.5.
In one embodiment, the resin-impregnated fiber may be wound to have a ratio of width to winding pitch in the range of 1:0.2 to 1:1.5.
In one embodiment, the plastic liner may include at least one thermoplastic resin selected from among a Nylon resin, an ethylene vinyl alcohol resin, a polyamide resin, a polyester resin, a polyolefin resin, a polycarbonate resin, a polyphenylene ether resin, and a polystyrene resin.
In one embodiment, the resin-impregnated fiber may be prepared by impregnating at least one of carbon fiber and glass fiber with a thermosetting resin.
In one embodiment, the thermosetting resin may include at least one selected from among an epoxy resin, a urethane resin, a phenolic resin, and an acrylic resin.
In one embodiment, the flame retardant composite resin layer may have a thickness of 0.1 μm to 5 μm.
In one embodiment, the resin-impregnated fiber may be impregnated with 20 vol % or more of the resin.
Another embodiment of the present invention relates to a method of manufacturing a pressure vessel, including: forming a flame retardant composite resin layer by winding resin-impregnated fiber on an outer surface of a plastic liner, wherein the flame retardant composite resin layer includes a first composite layer having resin-impregnated fiber aligned in a first direction and a second composite layer having resin-impregnated fiber aligned in a second direction different from the first direction; the resin-impregnated fiber aligned in the first direction and the resin-impregnated fiber aligned in the second direction form a contact region and an open region therebetween; and the contact region and the open region are formed in an area ratio of 1:0.2 to 1.5.
In one embodiment, the flame retardant composite resin layer may be formed under a winding tension of 500 g to 10,000 g.
In one embodiment, the resin-impregnated fiber may be impregnated with 20 vol % or more of the resin.
In one embodiment, the plastic liner may include at least one thermoplastic resin selected from among a Nylon resin, an ethylene vinyl alcohol resin, a polyamide resin, a polyester resin, a polyolefin resin, a polycarbonate resin, a polyphenylene ether resin, and a polystyrene resin.
In one embodiment, the resin-impregnated fiber may be prepared by impregnating at least one of carbon fiber and glass fiber with a thermosetting resin.
In one embodiment, the thermosetting resin may include at least one selected from among an epoxy resin, a urethane resin, a phenolic resin, and an acrylic resin.
The present invention provides a pressure vessel that can guarantee good properties in terms of flame retardancy, mechanical strength and shape uniformity through structural characteristics thereof while achieving significant improvement in heat insulating properties, and can realize cost reduction while satisfying light weight, pressure resistance and fire safety, and a method of manufacturing the same.
One embodiment of the present invention relates to a pressure vessel including: a plastic liner; and a flame retardant composite resin layer formed on the plastic liner, wherein the flame retardant composite resin layer includes a first composite layer having resin-impregnated fiber aligned in a first direction and a second composite layer having resin-impregnated fiber aligned in a second direction different from the first direction; the resin-impregnated fiber aligned in the first direction and the resin-impregnated fiber aligned in the second direction form a contact region and an open region therebetween; and the contact region and the open region are formed in an area ratio of 1:0.2 to 1.5.
With this structure, the present invention can guarantee good properties in terms of flame retardancy, mechanical strength and shape uniformity through structural characteristics thereof while achieving significant improvement in heat insulating properties, and can realize cost reduction while satisfying light weight, pressure resistance and fire safety, and a method of manufacturing the same.
Hereinafter, embodiments of the present invention will be described with reference to the accompanying drawings.
The plastic liner 10 is a container constituting the innermost layer of the pressure vessel 1 and provides a filling space to be filled with the fluid. In the pressure vessel 1 provided with the nozzle boss 30, the nozzle boss 30 may be integrally formed with the plastic liner 10 or may be coupled to an end portion of the plastic liner 10 through a fastening portion, such as a flange and the like.
Although not shown in the drawings, the nozzle boss 30 may be further provided with a thermal pressure relief device (TPRD), which is operated by heat upon generation of a fire. With this structure, the pressure vessel can further reduce a possibility of explosion in the event of significant damage to the flame retardant composite resin layer 20.
The plastic liner 10 may be formed of any plastic materials so long as the plastic materials are neither eroded by nor react with a target fluid. By use of a suitable plastic material, it is possible to achieve further improvement in weight reduction, pressure resistance and fire safety of the pressure vessel while reducing manufacturing costs thereof.
Specifically, the plastic liner 10 may be formed of at least one thermoplastic resin selected from among a Nylon resin, an ethylene vinyl alcohol resin, a polyamide resin, a polyester resin, a polyolefin resin, a polycarbonate resin, a polyphenylene ether resin, and a polystyrene resin. When these materials are used for the plastic material, the plastic liner can prevent deformation and damage to the pressure vessel due to pressure generated upon filling the plastic vessel with the fluid while realizing good mechanical strength.
The plastic liner 10 may have any shape so long as the plastic liner 10 can be applied to the pressure vessel. Specifically, the plastic liner may have a cylindrical shape with a dome shape at at least one end thereof. This structure is advantageous in uniform winding of a composite material, such as resin-impregnated fiber, on an outer peripheral surface of the plastic liner, and further improves pressure resistance of the pressure vessel.
The plastic liner 10 may have any thickness satisfying the manufacturing standards for the pressure vessel, which are consistent with the purpose of use thereof. Specifically, the plastic liner may have a thickness of 0.5 mm to 10 mm, more specifically 1 mm to 8 mm. Within this range, the plastic vessel can further reduce a minute variation in volume caused by the fluid in the plastic vessel while realizing good mechanical strength of the plastic vessel. For example, the plastic liner may have a thickness of 0.5 mm, 1 mm, 2 mm, 3 mm, 4 mm, 5 mm, 6 mm, 7 mm, 8 mm, 9 mm, or 10 mm.
The flame retardant composite resin layer 20 is formed on the outer surface of the plastic liner 10 and serves to reinforce and support the plastic liner while imparting chemical flame retardancy to the plastic liner. In addition, the flame retardant composite resin layer 20 serves to further improve insulating properties of the plastic vessel through structural characteristics in which a contact region and an open region have controlled areas, unlike a typical pressure vessel in the art.
In particular, with the structural characteristics in which the contact region and the open region have controlled areas, the flame retardant composite resin layer 20 includes an insulating layer, thereby suppressing damage to the flame retardant composite resin layer 20 while preventing detrimental local damage thereto upon generation of a fire. In this case, the pressure vessel can effectively reduce the risk of explosion even when a device, such as a safety valve, additionally provided to the pressure vessel does not work, while achieving significant improvement in fire safety.
In each of the first composite layer 21 and the second composite layer 22, the resin-impregnated fiber may be prepared by impregnating fiber with a resin and may be wound in a band shape.
In the first composite layer and the second composite layer, the resin-impregnated fiber forms a contact region and an open region therebetween by different alignment directions thereof. The flame retardant composite resin layer 20 is formed to have an area ratio of the contact region to the open region in the range of 1:0 to 1:1.5, specifically 1:0.2 to 1:1.5, whereby an insulating layer can be structurally formed in the flame retardant composite resin layer 20. If the area ratio of the contact region to the open region exceeds 1:1.5, it is difficult to form a uniform insulating layer due to an excessive area of the open region.
In the flame retardant composite resin layer 20, a difference in alignment angle between the first direction in which the first composite layer 21 is aligned and the second direction in which the second composite layer 22 is aligned may be in the range of 5 degrees to 90 degrees, specifically 10 degrees to 80 degrees, more specifically 20 degrees to 60 degrees. Within this range, it is advantageous to control the areas of the contact region and the open region in the flame retardant composite resin layer.
In each of the first composite layer 21 and the second composite layer 22, the resin-impregnated fiber may be wound to have a ratio of width to winding pitch in the range of 1:0 to 1:1.5, specifically 1:0.2 to 1:1.5. The ratio of width to winding pitch of the resin-impregnated fiber of the first composite layer 21 may be the same as or different from the ratio of width to winding pitch of the resin-impregnated fiber of the second composite layer 22. Within this range, it is advantageous to achieve further improvement in fire safety through control of the areas of the contact region and the open region in the flame retardant composite resin layer.
The resin-impregnated fiber for the first composite layer 21 may be the same as or different from the resin-impregnated fiber for the second composite layer 22. Specifically, the resin-impregnated fiber may be prepared by impregnating at least one of carbon fiber and glass fiber with a thermosetting resin. As a result, the flame retardant composite resin layer can realize good mechanical strength while achieving significant weight reduction of the pressure vessel.
The thermosetting resin may be selected from among any thermosetting resins applicable to the pressure vessel. Specifically, the thermosetting resin may include at least one selected from among an epoxy resin, a urethane resin, a phenolic resin and an acrylic resin. As a result, the flame retardant composite resin layer 20 can realize good flame retardancy of the pressure vessel while securing light weight and mechanical strength of the pressure vessel, and can further improve adhesion between the first composite layer and the second composite layer and between the plastic liner 10 and the flame retardant composite resin layer 20.
In the first composite layer 21 and the second composite layer 22, the resin-impregnated fiber may be cured after winding. Here, curing may be sequentially and/or simultaneously performed for the first composite layer 21 and the second composite layer 22. The first composite layer 21 may have the same degree of curing as or a different degree of curing from the second composite layer 22.
The resin-impregnated fiber may be impregnated with 20 vol % or more of the resin. Within this range, the pressure vessel can achieve further improvement in insulating properties and other properties. For example, the resin may be impregnated in an amount of 20 vol % to 99 vol %.
The flame retardant composite resin layer 20 may have any thickness satisfying the manufacturing standards for the pressure vessel, which are consistent with the purpose of use thereof. Specifically, the flame retardant composite resin layer 20 may have a thickness of 0.1 mm to 5 mm, more specifically 0.5 mm to 3 mm. Within this range, the plastic vessel can further reduce a minute variation in volume caused by the flame retardant composite resin layer while realizing good mechanical strength. For example, the flame retardant composite resin layer may have a thickness of 0.1 mm, 0.2 mm, 0.3 mm, 0.4 mm, 0.5 mm, 0.6 mm, 0.7 mm, 0.8 mm, 0.9 mm, 1 mm, 1.5 mm, 2 mm, 2.5 mm, 3 mm, 3.5 mm, 4 mm, 4.5 mm, or 5 mm.
In another embodiment, the flame retardant composite resin layer may have a thickness of 0.1 μm to 5 μm. Within this range, the plastic vessel can further reduce a minute variation in volume caused by the flame retardant composite resin layer while realizing good mechanical strength. Specifically, the flame retardant composite resin layer may have a thickness of 0.1 μm to 5 μm, more specifically 0.5 μm to 3 μm. For example, the flame retardant composite resin layer may have a thickness of 0.1 μm, 0.2 μm, 0.3 μm, 0.4 μm, 0.5 μm, 0.6 μm, 0.7 μm, 0.8 μm, 0.9 μm, 1 μm, 1.5 μm, 2 μm, 2.5 μm, 3 μm, 3.5 μm, 4 μm, 4.5 μm, or 5 μm.
The flame retardant composite resin layer 20 formed on the outer surface of the plastic liner reinforces and supports the plastic liner while imparting chemical flame retardancy to the plastic liner and further improving insulating properties of the plastic vessel through the structural characteristics in which the contact region and the open region of the flame retardant composite resin layer 20 have controlled areas, thereby further suppressing possibility of fire generation while preventing explosion of the pressure vessel upon fire generation. As a result, the pressure vessel can more effectively realize fire safety.
Another embodiment of the present invention relates to a method of manufacturing a pressure vessel. For details of the pressure vessel, refer to the above description.
According to the present invention, the method of manufacturing the pressure vessel includes forming a flame retardant composite resin layer by winding an outer surface of the plastic liner 10 with resin-impregnated fiber. The flame retardant composite resin layer includes a first composite layer having resin-impregnated fiber aligned in a first direction and a second composite layer having resin-impregnated fiber aligned in a second direction different from the first direction; the resin-impregnated fiber aligned in the first direction and the resin-impregnated fiber aligned in the second direction form a contact region and an open region therebetween; and the contact region and the open region are formed in an area ratio of 1:0 to 1:1.5, specifically 1:0.2 to 1:1.5.
In the first composite layer 21, the resin-impregnated fiber may be wound to have a ratio of width W1 to winding pitch D1 in the range of 1:0 to 1:1.5, specifically 1:0.2 to 1:1.5. Within this range, the pressure vessel can reduce the weight while satisfying fire safety through control of the areas of the contact region and the open region in the flame retardant composite resin layer.
The width W1 and the winding pitch D1 of the resin-impregnated fiber mean distances measured in a direction y perpendicular to a central axis direction x of the resin-impregnated fiber.
The first composite layer may be cured after winding. The degree of curing the first composite layer is not particularly limited. Specifically, the first composite layer may have a curing degree of 10% to 90%, more specifically 10% to 60%.
The width W1 and the winding pitch D1 of the resin-impregnated fiber mean distances measured in the direction y perpendicular to the central axis direction x of the resin-impregnated fiber.
The second composite layer may be cured after winding. The degree of curing the second composite layer is not particularly limited. Specifically, the second composite layer may have a curing degree of 10% to 100%, more specifically 50% to 90%.
The flame retardant composite resin layer is formed under a winding tension of 500 g to 10,000 g. Specifically, the winding tension may be in the range of 1,000 g to 8,000 g, more specifically 1,500 g to 5,000 g. Within this range, it is more advantageous to control the areas of the contact region and the open region.
In the method of manufacturing the pressure vessel according to the present invention, the flame retardant composite resin layer 20 has a multilayer structure of the first composite layer and the second composite layer in the contact region Q, thereby further improving pressure resistance in an axial direction and a radial direction while achieving thickness reduction of the pressure vessel. Further, since the area of the open region P of the first composite layer and the second composite layer is controlled, the pressure vessel can achieve further improvement in shape uniformity.
It should be understood that various modifications, changes, alterations, and equivalent embodiments can be made by those skilled in the art without departing from the spirit and scope of the present invention.
| Number | Date | Country | Kind |
|---|---|---|---|
| 10-2019-0095898 | Aug 2019 | KR | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/KR2020/006297 | 5/13/2020 | WO |
