The present disclosure relates generally to a print head and, more particularly, to a print head for use in an additive manufacturing system.
Continuous fiber 3D printing (a.k.a., CF3D™) involves the use of continuous fibers embedded within a matrix discharging from a moveable print head. The matrix can be a traditional thermoplastic, a powdered metal, a liquid resin (e.g., a UV curable and/or two-part resin), or a combination of any of these and other known matrixes. Upon exiting the print head, a cure enhancer (e.g., a UV light, an ultrasonic emitter, a heat source, a catalyst supply, etc.) is activated to initiate and/or complete curing of the matrix. This curing occurs almost immediately, allowing for unsupported structures to be fabricated in free space. When fibers, particularly continuous fibers, are embedded within the structure, a strength of the structure may be multiplied beyond the matrix-dependent strength. An example of this technology is disclosed in U.S. Pat. No. 9,511,543 that issued to Tyler on Dec. 6, 2016 (“the '543 patent”).
Although CF3D™ provides for increased strength, compared to manufacturing processes that do not utilize continuous fiber reinforcement, it may be important to properly compact the material as it is discharged from the print and before the material fully cures. The disclosed print head is uniquely configured to provide this compaction and/or to address other issues of the prior art.
In one aspect, the present disclosure is directed to a print head for an additive manufacturing system. The print head may include a nozzle having a base end, a tip end, and a cylindrical passage extending from the base end to the tip end. The print head may also include a compactor located at least partially inside of the nozzle at the tip end.
In another aspect, the present disclosure is directed to another print head for an additive manufacturing system. This print head may include a nozzle having a base end, a tip end, and a cylindrical passage extending from the base end to the tip end. The print head may also include a compactor captured within a cavity in the nozzle at the tip end. A central axis of the cylindrical passage may pass through the compactor. The print head may further include an orifice connecting the cylindrical passage to the cavity.
In yet another aspect, the present disclosure is directed to an additive manufacturing system. The additive manufacturing system may include a moveable support, and a print head connected to the moveable support. The print head may be configured to discharge a continuous reinforcement that is wetted with a liquid matrix. The print head may include a matrix reservoir, and a nozzle having a base end fluidly connected to the matrix reservoir, a tip end, and a cylindrical passage extending from the base end to the tip end. The print head may also include a compactor captured within a cavity in the nozzle at the tip end. A central axis of the cylindrical passage may pass through the compactor. The print head may further include an orifice connecting the cylindrical passage to the cavity, and a cure enhancer configured to direct cure energy onto the liquid matrix after compression of the reinforcement by the compactor. The additive manufacturing system may additionally include a controller configured to regulate operation of the moveable support and the cure enhancer.
Head 16 may be configured to receive or otherwise contain a matrix. The matrix may include any type of material (e.g., a liquid resin, such as a zero-volatile organic compound resin; a powdered metal; etc.) that is curable. Exemplary matrixes include thermosets, single- or multi-part epoxy resins, polyester resins, cationic epoxies, acrylated epoxies, urethanes, esters, thermoplastics, photopolymers, polyepoxides, thiols, alkenes, thiol-enes, reversible resins (e.g., Triazolinedione, a covalent-adaptable network, a spatioselective reversible resin, etc.) and more. In one embodiment, the matrix inside head 16 may be pressurized, for example by an external device (e.g., an extruder or another type of pump—not shown) that is fluidly connected to head 16 via a corresponding conduit (not shown). In another embodiment, however, the matrix pressure may be generated completely inside of head 16 by a similar type of device. In yet other embodiments, the matrix may be gravity-fed through and/or mixed within head 16. In some instances, the matrix inside head 16 may need to be kept cool and/or dark to inhibit premature curing; while in other instances, the matrix may need to be kept warm for the same reason. In either situation, head 16 may be specially configured (e.g., insulated, chilled, and/or warmed) to provide for these needs.
The matrix may be used to coat, encase, or otherwise at least partially surround any number of continuous reinforcements (e.g., separate fibers, tows, rovings, ribbons, and/or sheets of material) and, together with the reinforcements, make up at least a portion (e.g., a wall) of composite structure 12. The reinforcements may be stored within (e.g., on separate internal spools—not shown) or otherwise passed through head 16 (e.g., fed from external spools). When multiple reinforcements are simultaneously used, the reinforcements may be of the same type and have the same diameter and cross-sectional shape (e.g., circular, square, flat, etc.), or of a different type with different diameters and/or cross-sectional shapes. The reinforcements may include, for example, carbon fibers, vegetable fibers, wood fibers, mineral fibers, glass fibers, metallic wires, optical tubes, etc. It should be noted that the term “reinforcement” is meant to encompass both structural and non-structural types of continuous materials that can be at least partially encased in the matrix discharging from head 16.
The reinforcements may be exposed to (e.g., coated with) the matrix while the reinforcements are inside head 16, while the reinforcements are being passed to head 16 (e.g., as a prepreg material), and/or while the reinforcements are discharging from head 16, as desired. The matrix, dry reinforcements, and/or reinforcements that are already exposed to the matrix (e.g., wetted reinforcements) may be transported into head 16 in any manner apparent to one skilled in the art.
The matrix and reinforcement may be discharged from head 16 via at least two different modes of operation. In a first mode of operation, the matrix and reinforcement are extruded (e.g., pushed under pressure and/or mechanical force) from head 16, as head 16 is moved by support 14 to create the 3-dimensional shape of structure 12. In a second mode of operation, at least the reinforcement is pulled from head 16, such that a tensile stress is created in the reinforcement during discharge. In this mode of operation, the matrix may cling to the reinforcement and thereby also be pulled from head 16 along with the reinforcement, and/or the matrix may be discharged from head 16 under pressure along with the pulled reinforcement. In the second mode of operation, where the matrix is being pulled from head 16, the resulting tension in the reinforcement may increase a strength of structure 12, while also allowing for a greater length of unsupported material to have a straighter trajectory (i.e., the tension may act against the force of gravity to provide free-standing support for structure 12).
The reinforcement may be pulled from head 16 as a result of head 16 moving away from an anchor point 18. In particular, at the start of structure-formation, a length of matrix-impregnated reinforcement may be pulled and/or pushed from head 16, deposited onto anchor point 18, and cured, such that the discharged material adheres to anchor point 18. Thereafter, head 16 may be moved away from anchor point 18, and the relative movement may cause the reinforcement to be pulled from head 16. It should be noted that the movement of the reinforcement through head 16 could be assisted (e.g., via internal feed mechanisms), if desired. However, the discharge rate of the reinforcement from head 16 may primarily be the result of relative movement between head 16 and anchor point 18, such that tension is created within the reinforcement. It is contemplated that anchor point 18 could be moved away from head 16 instead of or in addition to head 16 being moved away from anchor point 18.
One or more cure enhancers (e.g., one or more light sources, ultrasonic emitters, lasers, heaters, catalyst dispensers, microwave generators, etc.) 20 may be mounted proximate (e.g., on and/or trailing from) head 16 and configured to enhance a cure rate and/or quality of the matrix as it is discharged from head 16. Cure enhancer 20 may be controlled to selectively expose internal and/or external surfaces of structure 12 to energy (e.g., light energy, electromagnetic radiation, vibrations, heat, a chemical catalyst or hardener, etc.) during the formation of structure 12. The energy may increase a rate of chemical reaction occurring within the matrix, sinter the material, harden the material, or otherwise cause the material to cure as it discharges from head 16.
A controller 22 may be provided and communicatively coupled with support 14, head 16, and any number and type of cure enhancers 20. Controller 22 may embody a single processor or multiple processors that include a means for controlling an operation of system 10. Controller 22 may include one or more general- or special-purpose processors or microprocessors. Controller 22 may further include or be associated with a memory for storing data such as, for example, design limits, performance characteristics, operational instructions, matrix characteristics, reinforcement characteristics, characteristics of structure 12, and corresponding parameters of each component of system 10. Various other known circuits may be associated with controller 22, including power supply circuitry, signal-conditioning circuitry, solenoid/motor driver circuitry, communication circuitry, and other appropriate circuitry. Moreover, controller 22 may be capable of communicating with other components of system 10 via wired and/or wireless transmission.
One or more maps may be stored in the memory of controller 22 and used during fabrication of structure 12. Each of these maps may include a collection of data in the form of models, lookup tables, graphs, and/or equations. In the disclosed embodiment, the maps are used by controller 22 to determine desired characteristics of cure enhancers 20, the associated matrix, and/or the associated reinforcements at different locations within structure 12. The characteristics may include, among others, a type, quantity, and/or configuration of reinforcement and/or matrix to be discharged at a particular location within structure 12, and/or an amount, intensity, shape, and/or location of desired curing. Controller 22 may then correlate operation of support 14 (e.g., the location and/or orientation of head 16) and/or the discharge of material from head 16 (a type of material, desired performance of the material, cross-linking requirements of the material, a discharge rate, etc.) with the operation of cure enhancers 20, such that structure 12 is produced in a desired manner.
An exemplary portion of head 16 is disclosed in detail in
Any number of reinforcements (represented as R in
One or more orifices 28 may be located at a tip end of nozzle 24 to accommodate passage of the matrix-wetted reinforcements. In the disclosed embodiment, a single generally circular orifice 28 is shown. It is contemplated, however, that multiple circular orifices could be used. In addition, orifices 28 of another shape (e.g., a rectangular shape) may allow for printing of ribbons and/or sheets. In the embodiment of
The matrix-wetted reinforcement(s) passing through orifice(s) 28 may impinge against an outer annular surface of an integral compactor 30. This impingement may occur prior to complete curing of the matrix material and also prior to the newly discharging material engaging an existing surface (e.g., a build platform or previously discharged material). In other words, compactor 30 may be the first thing engaged by the matrix-wetted reinforcement after discharge from orifice(s) 28.
Compactor 30 may be a rolling-type device configured to both place the matrix-wetted material (e.g., to apply the material to the build platform and/or the previously discharged material) and compress the material. In the example of
The generally spherical ball of compactor 30 may be fabricated from aluminum, steel, Delron, Teflon, Nylon, or another similar material known in the art. The generally spherical ball may have a diameter of about 0.25-5.0″, and an outer annular surface that is smooth, porous, or roughened (e.g., knurled) to reduce drag, inhibit reinforcement breakage, maintain orientation and/or integrity of the reinforcements, and to reduce wear. It is contemplated that, in some instances, a scraper could be associated with compactor 30, if desired, to remove and/or collect excess resin. For example, tip edges of nozzle 24 (e.g., at the opening) may be sharpened and spaced close enough (e.g., angled inward) to the generally spherical ball to knock away hardened resin particles.
The generally spherical ball of compactor 30, in the embodiment of
The disclosed system and print head may be used to continuously manufacture composite structures having any desired cross-sectional size, shape, length, density, and/or strength. The composite structures may include any number of different reinforcements of the same or different types, diameters, shapes, configurations, and consists, each coated with a common matrix. In addition, the disclosed print head may allow for compaction of the reinforcements prior to complete curing. This may increase a strength and reduce a porosity of the resulting composite structures. Operation of system 10 will now be described in detail.
At a start of a manufacturing event, information regarding a desired structure 12 may be loaded into system 10 (e.g., into controller 22 that is responsible for regulating operations of support 14 and/or head 16). This information may include, among other things, a size (e.g., diameter, wall thickness, length, etc.), a contour (e.g., a trajectory), surface features (e.g., ridge size, location, thickness, length; flange size, location, thickness, length; etc.) and finishes, connection geometry (e.g., locations and sizes of couplings, tees, splices, etc.), location-specific matrix stipulations, location-specific reinforcement stipulations, etc. It should be noted that this information may alternatively or additionally be loaded into system 10 at different times and/or continuously during the manufacturing event, if desired. Based on the component information, one or more different reinforcements and/or matrixes may be selectively installed and/or continuously supplied into system 10.
Installation of the reinforcements may be performed by passing the reinforcements down through matrix reservoir 26, and then threading the reinforcements through any nozzles 24 that exist and around compactor 30. Installation of the matrix may include filling reservoir 26 within head 16 and/or coupling of an extruder or external bath (not shown) to head 16. Head 16 may then be moved by support 14 under the regulation of controller 22 to cause matrix-coated reinforcements to be placed against or on a corresponding anchor point 18. Cure enhancers 20 within head 16 may then be selectively activated to cause hardening of the matrix surrounding the reinforcements, thereby bonding the reinforcements to anchor point 18.
The component information may then be used to control operation of system 10. For example, the reinforcements may be pulled and/or pushed from head 16 (along with the matrix), while support 14 selectively moves head 16 in a desired manner during curing, such that an axis of the resulting structure 12 follows a desired trajectory (e.g., a free-space, unsupported, 3-D trajectory). As the separate reinforcements are pulled through head 16, the reinforcements may first contact compactor 30 and be rolled onto and compressed into an existing surface. Once structure 12 has grown to a desired length, structure 12 may be disconnected (e.g., severed) from head 16 in any desired manner.
The disclosed compactor provides many benefits. For example, because compactor 30 fits almost completely inside the point of nozzle 24, head 16 may be small, simple, and self-contained. In addition, because the wetted reinforcements may first contact compactor 30, the compression provided by compactor 30 may be more accurate and less opportunity for misalignment or contamination of the reinforcements may be available. Further, the generally spherical ball embodiment of compactor 30 may allow for omnidirectional movements of head 16 without the need to continuously pivot head 16 about axis 29 (e.g., without the need to ensure that compactor 30 is always at the trailing side of nozzle 24).
It will be apparent to those skilled in the art that various modifications and variations can be made to the disclosed systems and head. Other embodiments will be apparent to those skilled in the art from consideration of the specification and practice of the disclosed systems and heads. For example, it is contemplated that multiple compactors 30 could be co-mounted within a common nozzle 24, if desired, in an end-to-end configuration. This configuration could allow for ribbon- and/or sheet-printing while cornering, where each compactor may need to rotate at a different speed to inhibit bunching of the discharging reinforcement. It is intended that the specification and examples be considered as exemplary only, with a true scope being indicated by the following claims and their equivalents.
This application is based on and claims the benefit of priority from U.S. Provisional Application No. 62/526,448 that was filed on Jun. 29, 2017, the contents of which are expressly incorporated herein by reference.
Number | Name | Date | Kind |
---|---|---|---|
3286305 | Seckel | Nov 1966 | A |
3809514 | Nunez | May 1974 | A |
3956056 | Boguslawski | May 1976 | A |
3984271 | Gilbu | Oct 1976 | A |
3993726 | Moyer | Nov 1976 | A |
4643940 | Shaw et al. | Feb 1987 | A |
4671761 | Adrian et al. | Jun 1987 | A |
4822548 | Hempel | Apr 1989 | A |
4851065 | Curtz | Jul 1989 | A |
5002712 | Goldmann et al. | Mar 1991 | A |
5037691 | Medney et al. | Aug 1991 | A |
5296335 | Thomas et al. | Mar 1994 | A |
5340433 | Crump | Aug 1994 | A |
5746967 | Hoy et al. | May 1998 | A |
5866058 | Batchelder et al. | Feb 1999 | A |
5936861 | Jang et al. | Aug 1999 | A |
6153034 | Lipsker | Nov 2000 | A |
6153238 | Shannon | Nov 2000 | A |
6459069 | Rabinovich | Oct 2002 | B1 |
6501554 | Hackney et al. | Dec 2002 | B1 |
6799081 | Hale et al. | Sep 2004 | B1 |
6803003 | Rigali et al. | Oct 2004 | B2 |
6934600 | Jang et al. | Aug 2005 | B2 |
7039485 | Engelbart et al. | May 2006 | B2 |
7555404 | Brennan et al. | Jun 2009 | B2 |
7795349 | Bredt et al. | Sep 2010 | B2 |
8221669 | Batchelder et al. | Jul 2012 | B2 |
8962717 | Roth et al. | Feb 2015 | B2 |
9126365 | Mark et al. | Sep 2015 | B1 |
9126367 | Mark et al. | Sep 2015 | B1 |
9149988 | Mark et al. | Oct 2015 | B2 |
9156205 | Mark et al. | Oct 2015 | B2 |
9186846 | Mark et al. | Nov 2015 | B1 |
9186848 | Mark et al. | Nov 2015 | B2 |
9327452 | Mark et al. | May 2016 | B2 |
9327453 | Mark et al. | May 2016 | B2 |
9370896 | Mark | Jun 2016 | B2 |
9381702 | Hollander | Jul 2016 | B2 |
9457521 | Johnston et al. | Oct 2016 | B2 |
9458955 | Hammer et al. | Oct 2016 | B2 |
9527248 | Hollander | Dec 2016 | B2 |
9539762 | Durand et al. | Jan 2017 | B2 |
9579851 | Mark et al. | Feb 2017 | B2 |
9688028 | Mark et al. | Jun 2017 | B2 |
9694544 | Mark et al. | Jul 2017 | B2 |
9764378 | Peters et al. | Sep 2017 | B2 |
9770876 | Farmer et al. | Sep 2017 | B2 |
9782926 | Witzel et al. | Oct 2017 | B2 |
20020009935 | Hsiao et al. | Jan 2002 | A1 |
20020062909 | Jang et al. | May 2002 | A1 |
20020113331 | Zhang et al. | Aug 2002 | A1 |
20020165304 | Mulligan et al. | Nov 2002 | A1 |
20030044539 | Oswald | Mar 2003 | A1 |
20030056870 | Comb et al. | Mar 2003 | A1 |
20030160970 | Basu et al. | Aug 2003 | A1 |
20030186042 | Dunlap et al. | Oct 2003 | A1 |
20030236588 | Jang et al. | Dec 2003 | A1 |
20040060650 | Holmes | Apr 2004 | A1 |
20050006803 | Owens | Jan 2005 | A1 |
20050061422 | Martin | Mar 2005 | A1 |
20050104257 | Gu et al. | May 2005 | A1 |
20050109451 | Hauber et al. | May 2005 | A1 |
20050230029 | Vaidyanathan et al. | Oct 2005 | A1 |
20070003650 | Schroeder | Jan 2007 | A1 |
20070228592 | Dunn et al. | Oct 2007 | A1 |
20080176092 | Owens | Jul 2008 | A1 |
20090095410 | Oldani | Apr 2009 | A1 |
20090139654 | Wampler | Jun 2009 | A1 |
20100200168 | Oldani | Aug 2010 | A1 |
20110032301 | Fienup et al. | Feb 2011 | A1 |
20110143108 | Fruth et al. | Jun 2011 | A1 |
20120060468 | Dushku et al. | Mar 2012 | A1 |
20120159785 | Pyles et al. | Jun 2012 | A1 |
20120231225 | Mikulak et al. | Sep 2012 | A1 |
20120247655 | Erb et al. | Oct 2012 | A1 |
20130164498 | Langone et al. | Jun 2013 | A1 |
20130209600 | Tow | Aug 2013 | A1 |
20130233471 | Kappesser et al. | Sep 2013 | A1 |
20130292039 | Peters et al. | Nov 2013 | A1 |
20130337256 | Farmer et al. | Dec 2013 | A1 |
20130337265 | Farmer | Dec 2013 | A1 |
20140034214 | Boyer et al. | Feb 2014 | A1 |
20140061974 | Tyler | Mar 2014 | A1 |
20140159284 | Leavitt | Jun 2014 | A1 |
20140232035 | Bheda | Aug 2014 | A1 |
20140268604 | Wicker et al. | Sep 2014 | A1 |
20140291886 | Mark et al. | Oct 2014 | A1 |
20140361460 | Mark | Dec 2014 | A1 |
20150136455 | Fleming | May 2015 | A1 |
20150367446 | Buller et al. | Dec 2015 | A1 |
20150367576 | Page | Dec 2015 | A1 |
20160012935 | Rothfuss | Jan 2016 | A1 |
20160031155 | Tyler | Feb 2016 | A1 |
20160046082 | Fuerstenberg | Feb 2016 | A1 |
20160052208 | Debora et al. | Feb 2016 | A1 |
20160082641 | Bogucki et al. | Mar 2016 | A1 |
20160082659 | Hickman et al. | Mar 2016 | A1 |
20160107379 | Mark et al. | Apr 2016 | A1 |
20160114532 | Schirtzinger et al. | Apr 2016 | A1 |
20160136885 | Nielsen-Cole et al. | May 2016 | A1 |
20160144565 | Mark et al. | May 2016 | A1 |
20160144566 | Mark et al. | May 2016 | A1 |
20160192741 | Mark | Jul 2016 | A1 |
20160200047 | Mark et al. | Jul 2016 | A1 |
20160243762 | Fleming et al. | Aug 2016 | A1 |
20160257102 | Butler | Sep 2016 | A1 |
20160263806 | Gardiner | Sep 2016 | A1 |
20160263822 | Boyd | Sep 2016 | A1 |
20160263823 | Espiau et al. | Sep 2016 | A1 |
20160271876 | Lower | Sep 2016 | A1 |
20160297104 | Guillemette et al. | Oct 2016 | A1 |
20160311165 | Mark et al. | Oct 2016 | A1 |
20160325491 | Sweeney et al. | Nov 2016 | A1 |
20160332369 | Shah et al. | Nov 2016 | A1 |
20160339633 | Stolyarov et al. | Nov 2016 | A1 |
20160346998 | Mark et al. | Dec 2016 | A1 |
20160361869 | Mark et al. | Dec 2016 | A1 |
20160368213 | Mark | Dec 2016 | A1 |
20160368255 | Witte et al. | Dec 2016 | A1 |
20170007359 | Kopelman et al. | Jan 2017 | A1 |
20170007360 | Kopelman et al. | Jan 2017 | A1 |
20170007361 | Boronkay et al. | Jan 2017 | A1 |
20170007362 | Chen et al. | Jan 2017 | A1 |
20170007363 | Boronkay | Jan 2017 | A1 |
20170007365 | Kopelman et al. | Jan 2017 | A1 |
20170007366 | Kopelman et al. | Jan 2017 | A1 |
20170007367 | Li et al. | Jan 2017 | A1 |
20170007368 | Boronkay | Jan 2017 | A1 |
20170007386 | Mason et al. | Jan 2017 | A1 |
20170008333 | Mason et al. | Jan 2017 | A1 |
20170015059 | Lewicki | Jan 2017 | A1 |
20170015060 | Lewicki et al. | Jan 2017 | A1 |
20170021565 | Deaville | Jan 2017 | A1 |
20170028434 | Evans et al. | Feb 2017 | A1 |
20170028588 | Evans et al. | Feb 2017 | A1 |
20170028617 | Evans et al. | Feb 2017 | A1 |
20170028619 | Evans et al. | Feb 2017 | A1 |
20170028620 | Evans et al. | Feb 2017 | A1 |
20170028621 | Evans et al. | Feb 2017 | A1 |
20170028623 | Evans et al. | Feb 2017 | A1 |
20170028624 | Evans et al. | Feb 2017 | A1 |
20170028625 | Evans et al. | Feb 2017 | A1 |
20170028627 | Evans et al. | Feb 2017 | A1 |
20170028628 | Evans et al. | Feb 2017 | A1 |
20170028633 | Evans et al. | Feb 2017 | A1 |
20170028634 | Evans et al. | Feb 2017 | A1 |
20170028635 | Evans et al. | Feb 2017 | A1 |
20170028636 | Evans et al. | Feb 2017 | A1 |
20170028637 | Evans et al. | Feb 2017 | A1 |
20170028638 | Evans et al. | Feb 2017 | A1 |
20170028639 | Evans et al. | Feb 2017 | A1 |
20170028644 | Evans et al. | Feb 2017 | A1 |
20170030207 | Kittleson | Feb 2017 | A1 |
20170036403 | Ruff et al. | Feb 2017 | A1 |
20170050340 | Hollander | Feb 2017 | A1 |
20170057164 | Hemphill et al. | Mar 2017 | A1 |
20170057165 | Waldrop et al. | Mar 2017 | A1 |
20170057167 | Tooren et al. | Mar 2017 | A1 |
20170057181 | Waldrop et al. | Mar 2017 | A1 |
20170064840 | Espalin et al. | Mar 2017 | A1 |
20170066187 | Mark et al. | Mar 2017 | A1 |
20170087768 | Bheda | Mar 2017 | A1 |
20170106565 | Braley et al. | Apr 2017 | A1 |
20170120519 | Mark | May 2017 | A1 |
20170129170 | Kim et al. | May 2017 | A1 |
20170129171 | Gardner et al. | May 2017 | A1 |
20170129176 | Waatti et al. | May 2017 | A1 |
20170129182 | Sauti et al. | May 2017 | A1 |
20170129186 | Sauti et al. | May 2017 | A1 |
20170136688 | Knecht et al. | May 2017 | A1 |
20170144375 | Waldrop et al. | May 2017 | A1 |
20170151728 | Kunc et al. | Jun 2017 | A1 |
20170157828 | Mandel et al. | Jun 2017 | A1 |
20170157831 | Mandel et al. | Jun 2017 | A1 |
20170157844 | Mandel et al. | Jun 2017 | A1 |
20170157851 | Nardiello et al. | Jun 2017 | A1 |
20170165908 | Pattinson et al. | Jun 2017 | A1 |
20170173692 | Myerberg et al. | Jun 2017 | A1 |
20170173868 | Mark | Jun 2017 | A1 |
20170182712 | Scribner et al. | Jun 2017 | A1 |
20170210074 | Ueda et al. | Jul 2017 | A1 |
20170217088 | Boyd et al. | Aug 2017 | A1 |
20170232674 | Mark | Aug 2017 | A1 |
20170259502 | Chapiro et al. | Sep 2017 | A1 |
20170259507 | Hocker | Sep 2017 | A1 |
20170266876 | Hocker | Sep 2017 | A1 |
20170274585 | Armijo et al. | Sep 2017 | A1 |
20170284876 | Moorlag et al. | Oct 2017 | A1 |
Number | Date | Country |
---|---|---|
4102257 | Jul 1992 | DE |
0198744 | Oct 1986 | EP |
2589481 | Jan 2016 | EP |
3219474 | Sep 2017 | EP |
100995983 | Nov 2010 | KR |
101172859 | Aug 2012 | KR |
2013017284 | Feb 2013 | WO |
2016088042 | Jun 2016 | WO |
2016088048 | Jun 2016 | WO |
2016110444 | Jul 2016 | WO |
2016159259 | Oct 2016 | WO |
2016196382 | Dec 2016 | WO |
2017006178 | Jan 2017 | WO |
2017006324 | Jan 2017 | WO |
2017051202 | Mar 2017 | WO |
2017081253 | May 2017 | WO |
2017085649 | May 2017 | WO |
2017087663 | May 2017 | WO |
2017108758 | Jun 2017 | WO |
2017122941 | Jul 2017 | WO |
2017122942 | Jul 2017 | WO |
2017122943 | Jul 2017 | WO |
2017123726 | Jul 2017 | WO |
2017124085 | Jul 2017 | WO |
2017126476 | Jul 2017 | WO |
2017126477 | Jul 2017 | WO |
2017137851 | Aug 2017 | WO |
2017142867 | Aug 2017 | WO |
2017150186 | Sep 2017 | WO |
Entry |
---|
International Search Report dated Aug. 10, 2018 for PCT/US18/33320 to CC3D LLC Filed May 18, 2018. |
A. Di. Pietro & Paul Compston, Resin Hardness and Interlaminar Shear Strength of a Glass-Fibre/Vinylester Composite Cured with High Intensity Ultraviolet (UV) Light, Journal of Materials Science, vol. 44, pp. 4188-4190 (Apr. 2009). |
A. Endruweit, M. S. Johnson, & A. C. Long, Curing of Composite Components by Ultraviolet Radiation: A Review, Polymer Composites, pp. 119-128 (Apr. 2006). |
C. Fragassa, & G. Minak, Standard Characterization for Mechanical Properties of Photopolymer Resins for Rapid Prototyping, 1st Symposium on Multidisciplinary Studies of Design in Mechanical Engineering, Bertinoro, Italy (Jun. 25-28, 2008). |
Hyouk Ryeol Choi and Se-gon Roh, In-pipe Robot with Active Steering Capability for Moving Inside of Pipelines, Bioinspiration and Robotics: Walking and Climbing Robots, Sep. 2007, p. 544, I-Tech, Vienna, Austria. |
Kenneth C. Kennedy II & Robert P. Kusy, UV-Cured Pultrusion Processing of Glass-Reinforced Polymer Composites, Journal of Vinyl and Additive Technology, vol. 1, Issue 3, pp. 182-186 (Sep. 1995). |
M. Martin-Gallego et al., Epoxy-Graphene UV-Cured Nanocomposites, Polymer, vol. 52, Issue 21, pp. 4664-4669 (Sep. 2011). |
P. Compston, J. Schiemer, & A. Cvetanovska, Mechanical Properties and Styrene Emission Levels of a UV-Cured Glass-Fibre/Vinylester Composite, Composite Structures, vol. 86, pp. 22-26 (Mar. 2008). |
S Kumar & J.-P. Kruth, Composites by Rapid Prototyping Technology, Materials and Design, (Feb. 2009). |
L. Fan, F. Y. C. Boey, & M. J. M. Abadie, UV Curing of a Liquid Based Bismaleimide-Containing Polymer System, eXPRESS Polymer Letters, vol. 1, No. 6, pp. 397-405 (2007). |
M. Llewelly-Jones, Bruce W. Drinkwater, and Richard S. Trask; 3D Printed Components With Ultrasonically Arranged Microscale Structure, Smart Materials and Structures, 2016, pp. 1-6, vol. 25, IOP Publishing Ltd., UK. |
Vincent J. Lopata et al., Electron-Beam-Curable Epoxy Resins for the Manufacture of High-Performance Composites, Radiation Physics and Chemistry, vol. 56, pp. 405-415 (1999). |
Yugang Duan et al., Effects of Compaction and UV Exposure on Performance of Acrylate/Glass-Fiber Composites Cured Layer by Layer, Journal of Applied Polymer Science, vol. 123, Issue 6, pp. 3799-3805 (May 15, 2012). |
Number | Date | Country | |
---|---|---|---|
20190001561 A1 | Jan 2019 | US |
Number | Date | Country | |
---|---|---|---|
62526448 | Jun 2017 | US |