Claims
- 1. A molded synthetic resin article having a layer of an organosiloxy titanic acid ester having the average formula
- (R.sup.1 O).sub.4-n Ti (OSiR.sup.2 R.sup.3 R.sup.4).sub.n
- where R.sup.1 is a monovalent hydrocarbon radical having from 1 to 18 carbon atoms; R.sup.2, R.sup.3 and R.sup.4 are the same or different monovalent organic radicals selected from the group consisting of monovalent hydrocarbon radicals having from 1 to 6 carbon atoms and organosiloxy radicals having the average formula
- (R.sup.5).sub.a SiO.sub.4-a/2
- where R.sup.5 is the same or different monovalent organic radicals selected from the group consisting of hydrocarbon and alkoxy radicals having from 1 to 6 carbon atoms and a is a positive number of from 1.5 to 3; and n is a number of from 0.3 to 3.2.
- 2. The article of claim 1 wherein n is from 0.4 to 2.5.
- 3. The article of claim 1 wherein said molded synthetic resin products are made of silicone resins and rubbers, epoxy resins and polyethylene.
- 4. The article of claim 1 wherein said organosiloxy titanic acid ester is Ti[OSi(C.sub.6 H.sub.5).sub.2 CH.sub.3 ][OC.sub.2 H.sub.5 ].sub.3.
- 5. The article of claim 1 wherein said organosiloxy titanic acid ester is a compound prepared by co-condensation of dimethylvinyl silanol with tetrabutyl titanic acid ester.
- 6. The article of claim 1 wherein said organosiloxy titanic acid ester is a compound prepared by co-condensation of dimethylphenyl silanol with tetraisopropyl titanic acid ester.
- 7. The article of claim 1 wherein said organosiloxy titanic acid ester is a compound prepared by co-condensation of tripropylsilyl acetate with tetrastearyl titanic acid ester.
- 8. The article of claim 1 wherein said organosiloxy titanic acid ester is a compound prepared by co-condensation of trimethylsilyl acetate with tetraisopropyl titanic acid ester.
- 9. The article of claim 1 wherein said organosiloxy titanic acid ester is a compound prepared by co-condensation of trimethylsilyl acetate and dimethylvinylsilyl acetate, on one part, with tetraphenyl titanic acid ester, on the other part.
- 10. The article of claim 1 wherein said organosiloxy titanic acid ester is a compound prepared by co-condensation of trimethylsilyl acetate, methylphenylmethoxy siloxane and methylvinylmethoxy siloxane, on one part, with tetrabutyl titanic acid ester, on the other part.
- 11. The article of claim 1 wherein said organosiloxy titanic acid ester is a compound prepared by co-condensation of trimethylacetoxy silane with tetraisopropyl titanic acid ester.
Priority Claims (1)
Number |
Date |
Country |
Kind |
47-73948 |
Jul 1972 |
JA |
|
CROSS-REFERENCE TO RELATED APPLICATIONS
This is a continuation of application Ser. No. 381,032 filed July 20, 1973, now abandoned.
US Referenced Citations (6)
Non-Patent Literature Citations (1)
Entry |
Chemical Reviews, vol. 61, No. 1, Feb., 1961, "The Organic Chemistry of Titanium," Shiihara et al., pp. 1 and 19-30. |
Continuations (1)
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Number |
Date |
Country |
Parent |
381032 |
Jul 1973 |
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