This invention relates to printheads.
Ink jet printers typically include an ink path from an ink supply to a nozzle path. The nozzle path terminates in a nozzle opening from which ink drops are ejected. Ink drop ejection is controlled by pressurizing ink in the ink path with an actuator, which may be, for example, a piezoelectric deflector, a thermal bubble jet generator, or an electro statically deflected element. A typical printhead has an array of ink paths with corresponding nozzle openings and associated actuators, and drop ejection from each nozzle opening can be independently controlled. In a drop-on-demand printhead, each actuator is fired to selectively eject a drop at a specific pixel location of an image as the printhead and a printing substrate are moved relative to one another. In high performance printheads, the nozzle openings typically have a diameter of 50 micron or less, e.g. around 25 microns, are separated at a pitch of 100–300 nozzles/inch, have a resolution of 100 to 3000 dpi or more, and provide drop sizes of about 1 to 70 picoliters (pl) or less. Drop ejection frequency is typically 10 kHz or more.
Hoisington et al. U.S. Pat. No. 5,265,315, the entire contents of which is hereby incorporated by reference, describes a printhead that has a semiconductor printhead body and a piezoelectric actuator. The printhead body is made of silicon, which is etched to define ink chambers. Nozzle openings are defined by a separate nozzle plate, which is attached to the silicon body. The piezoelectric actuator has a layer of piezoelectric material, which changes geometry, or bends, in response to an applied voltage. The bending of the piezoelectric layer pressurizes ink in a pumping chamber located along the ink path.
The amount of bending that a piezoelectric material exhibits for a given voltage is inversely proportional to the thickness of the material. As a result, as the thickness of the piezoelectric layer increases, the voltage requirement increases. To limit the voltage requirement for a given drop size, the deflecting wall area of the piezoelectric material may be increased. The large piezoelectric wall area may also require a correspondingly large pumping chamber, which can complicate design aspects such as maintenance of small orifice spacing for high-resolution printing.
Printing accuracy is influenced by a number of factors, including the size and velocity uniformity of drops ejected by the nozzles in the head and among multiple heads in a printer. The drop size and drop velocity uniformity are in turn influenced by factors such as the dimensional uniformity of the ink paths, acoustic interference effects, contamination in the ink flow paths, and the actuation uniformity of the actuators.
In an aspect, the invention features a printhead having a monolithic semiconductor body with an upper face and a lower face. The body defines a fluid path including a pumping chamber, a nozzle flow path, and a nozzle opening. The nozzle opening is defined in the lower face of the body and the nozzle flow path includes an accelerator region. A piezoelectric actuator is associated with the pumping chamber. The actuator includes a piezoelectric layer having a thickness of about 50 micron or less.
In another aspect, the invention features a printhead having a monolithic semiconductor body with a buried layer and an upper face and a lower face. The body defines a plurality of fluid paths. Each fluid path includes a pumping chamber, a nozzle opening, and a nozzle path between the pumping chamber and the nozzle opening. The nozzle path includes an accelerator region. The pumping chamber is defined in the upper face of the body, the nozzle opening is defined in the lower face of the body, and the accelerator region is defined between the nozzle opening and the buried layer. A piezoelectric actuator is associated with the pumping chamber. The actuator includes a layer of piezoelectric material having a thickness of about 25 micron or less.
In another aspect, the invention features a printhead including a monolithic semiconductor body having an upper face and a substantially parallel lower face, the body defining a fluid path including an ink supply path, a pumping chamber, and a nozzle opening, wherein the pumping chamber is defined in the upper face and the nozzle opening is defined in the lower face.
In another aspect, the invention features a printhead with a semiconductor body defining a fluid flow path, a nozzle opening, and a filter/impedance feature having a plurality of flow openings. The cross-section of the flow openings is less than the cross section of the nozzle opening and the sum of the areas of the flow openings is greater than the area of the nozzle opening.
In another aspect, the invention features a printhead including a monolithic semiconductor body defining a flow path and a filter/impedance feature. In embodiments, a nozzle plate defining nozzle openings is attached to the semiconductor body. In embodiments, the semiconductor body defines nozzle openings.
In another aspect, the invention features a filter/impedance feature including a semiconductor having a plurality of flow openings. In embodiments, the cross-section of the openings is about 25 microns or less.
In another aspect, the invention features a printhead including a body with a flow path and a piezoelectric actuator having a pre-fired piezoelectric layer in communication with the flow path and having a thickness of about 50 micron or less.
In another aspect, the invention features a printhead with a piezoelectric layer having a surface Ra of about 0.05 microns or less.
In another aspect, the invention features a printhead having a piezoelectric actuator including a piezoelectric layer having a thickness of about 50 micron or less and having at least one surface thereof including a void-filler material.
In another aspect, the invention features a method of printing, including providing a printhead including a filter/impedance feature having a plurality of flow openings, and ejecting fluid such that t/(flow development time) is about 0.2 or greater, where t is the fire pulse width and the flow development time is (fluid density) r2/(fluid viscosity), where r=cross-section dimension of at least one of the flow openings.
In another aspect, the invention features a method including providing a piezoelectric layer having a thickness of about 50 micron or less, providing a layer of filler material on at least one surface of the layer, reducing the thickness of the filler layer to expose the piezoelectric material, leaving voids in the surface of piezoelectric material including the filler material.
In another aspect, the invention features a method of forming a printhead by providing a body, attaching to the body a piezoelectric layer, reducing the thickness of said fixed piezoelectric layer to about 50 micron or less and utilizing the piezoelectric layer to pressurize fluid in the printhead.
In another aspect, the invention features a method of forming a printhead, including providing a piezoelectric layer, providing a membrane, fixing the piezoelectric layer to the membrane by anodic bonding, and/or fixing the membrane to a body by anodic bonding and incorporating the actuator in a printhead.
In another aspect, the invention features a nozzle plate including a monolithic semiconductor body including a buried layer, an upper face, and a lower face. The body defines a plurality of fluid paths, each including a nozzle path and a nozzle opening. The nozzle path includes an accelerator region. The nozzle opening is defined in the lower face of the body and the accelerator region is between the lower face and the buried layer.
In another aspect, the invention features a nozzle plate, including a monolithic semiconductor body including a plurality of fluid paths, each including a nozzle path, a nozzle opening, and a filter/impedance feature.
Other aspects or embodiments may include combinations of the features in the aspects above and/or one or more of the following.
The piezoelectric layer has a thickness of about 25 micron or less. The piezoelectric layer has a thickness of about 5 to 20 micron. The density of the piezoelectric layer is about 7.5 g/cm3 or more. The piezoelectric layer has a d31 coefficient of about 200 or more. The piezoelectric layer has a surface with an Ra of about 0.05 micron or less. The piezoelectric layer is composed of pre-fired piezoelectric material. The piezoelectric layer is a substantially planar body of piezoelectric material. The filler material is a dielectric. The dielectric is selected from silicon oxide, silicon nitride, or aluminum oxide or paralyne. The filler material is ITO.
A semiconductor body defines a filter/impedance feature. The filter/impedance feature defines a plurality of flow openings in the fluid path. The filter/impedance feature has a plurality of projections in the flow path. At least one projection defines a partially enclosed region, e.g. defined by a concave surface. The projections are posts. At least one post includes an upstream-facing concave surface. The feature includes a plurality of rows of posts. A first upstream row and a last downstream row and posts in the first row have an upstream-facing convex surface and posts in the last row have downstream-facing convex surfaces. The posts between the first and second row include an upstream-facing concave surface. The posts have upstream-facing concave surfaces adjacent said posts having downstream-facing concave surfaces. The feature comprises a plurality of apertures through a wall member. The cross-sectional dimension of the openings is about 50% to about 70% of the cross-sectional dimension of the nozzle opening. The filter/impedance feature is upstream of the pumping chamber. The filter/impedance feature is downstream of the pumping chamber.
The cross-sectional dimension of the flow opening is less than the cross-sectional dimension of the nozzle opening. A filter/impedance feature has a concave surface region. The cross-section of the flow openings is about 60% or less than the cross-section of the nozzle opening. The sum of the area of the flow openings is about 2 or more times the cross section of the nozzle opening.
Flow is substantially developed in a time corresponding to the fire pulse width, e.g. flow development at the center of the opening reaches about 65% or more of the maximum. The t/(flow development time) is about 0.75 or greater. The fire pulse width is about 10 micro-sec, or less. The pressure drop across the feature is less than, e.g. 0.5 to 0.1, of the pressure drop across the nozzle flow path.
The actuator includes an actuator substrate bonded to the semiconductor body. The actuator substrate is attached to the semiconductor body by an anodic bond. The actuator substrate is selected from glass, silicon, alumina, zirconia, or quartz. The actuator substrate has a thickness of about 50 micron or less, e.g. 25 microns or less, e.g. 5 to 20 microns. The actuator substrate is bonded to the piezoelectric layer by an anodic bond. The actuator substrate is bonded to the piezoelectric layer through an amorphous silicon layer. The piezoelectric layer is bonded to the actuator substrate by organic adhesive. The actuator substrate extends along the fluid path beyond the piezoelectric layer. A portion of the actuator substrate extends along the fluid path beyond the pumping chamber has reduced thickness. The actuator substrate is transparent.
The semiconductor body includes at least two differentially etchable materials. The semiconductor body includes at least one buried layer, the nozzle flow path includes a varying cross-section and a buried layer is between regions of different cross-section regions. The pumping chamber is defined in the upper face of the body. The nozzle flow path includes a descender region for directing fluid from the pumping chamber toward the lower face and an accelerator region directing fluid from the descender region to the nozzle opening. The buried layer is at the junction of the descender region and the accelerator region. The cross-section of the accelerator region and/or the descender regions and/or accelerator region is substantially constant. The cross-section of the accelerator region decreases toward the nozzle opening. The cross-section has a curvilinear region. The ratio of the length of the accelerator region to the nozzle opening cross-section is about 0.5 or more, e.g. about 1.0 or more. The ratio is about 5.0 or less. The length of the accelerator region is about 10 to 50 micron. The nozzle opening has a cross-section of about 5 to 50 micron.
The pumping chambers are defined between substantially linear chamber sidewalls and the nozzle flow path is defined by a substantially collinear extension of one of the side walls. The body defines a plurality of pairs of flow paths, wherein the pairs of flow paths have adjacent nozzles and the pumping chamber sidewalls are substantially collinear. The nozzle flow paths in said pairs of nozzles are interdigitated. The nozzles in said plurality of pairs define a substantially straight line. The nozzle flow paths have a region with long cross-section and a short cross-section and the short cross-section is substantially parallel with the line of nozzle openings.
The thickness of the piezoelectric layer and/or the membrane is reduced by grinding. The piezoelectric layer is fired prior to attachment to the body. The piezoelectric layer is attached to an actuator substrate and the actuator substrate is attached to the body. The piezoelectric layer is attached to the actuator substrate by anodic bonding. The piezoelectric layer is attached to the actuator substrate by an organic adhesive. The actuator substrate is attached to the body prior to attaching the piezoelectric layer to the actuator substrate. The thickness of the actuator substrate is reduced after attaching the actuator substrate to the body. The actuator substrate is attached to the body by anodic bonding. The body is a semiconductor and the actuator substrate is glass or silicon. The piezoelectric actuator includes a piezoelectric layer and a membrane of glass or silicon and anodically bonding said membrane to the body. The piezoelectric layer is anodically bonded to the membrane. The piezoelectric actuator includes a metalized layer over the piezoelectric layer and a layer of silicon oxide or silicon over said metalized layer.
The method includes providing a body defining a flow path, and attaching the actuator to the body by an anodic bond. Flow path features such as ink supply paths, filter/impedance features, pumping chambers, nozzle flow paths, and/or nozzle openings are formed by etching semiconductor, as described below.
Aspects and features related to piezoelectric materials can be used with printheads including flow paths defined by non-monolithic and/or non-semiconductor bodies. Aspects and features related to use of monolithic bodies defining flow paths can be used with non-piezoelectric actuators, e.g. electrostatic or bubble-jet actuators. Aspects and features related to filter/impedance can be utilized with non-piezoelectric or piezoelectric actuators and monolithic or non-monolithic bodies.
Still further aspects, features, and advantages follow.
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Module Substrate
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The spaces between the posts define flow openings. The size and number of the flow openings can provide desirable impedance and filtering performance. The impedance of a flow opening is dependent on the flow development time of a fluid through the opening. The flow development time relates to the time it takes a fluid at rest to flow at a steady velocity profile after imposition of pressure. For a round duct, the flow development time is proportional to:
(fluid density)*r2/(fluid viscosity)
where r is the radius of the opening. (For rectangular openings, or other opening geometries, r is one-half the smallest cross-sectional dimension.) For a flow development time that is relatively long compared to the duration of incident pulses, the flow opening acts as an inductor. But for a flow development time that is relatively short compared to the duration of incident pressure pulses, the flow opening acts as a resistor, thus effectively dampening the incident pulses.
Preferably, the flow is substantially developed in times corresponding to the fire pulse width. Referring to
As
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The number of flow openings in the feature can be selected so that a sufficient flow of ink is available to the pumping chamber for continuous high frequency operation. For example, a single flow opening of small dimension sufficient to provide dampening could limit ink supply. To avoid this ink starvation, a number of openings can be provided. The number of openings can be selected so that the overall flow resistance of the feature is less than the flow resistance of the nozzle. In addition, to provide filtering, the diameter or smallest cross sectional dimension of the flow openings is preferably less than the diameter (the smallest cross-section) of the corresponding nozzle opening, for example 60% or less of the nozzle opening. In a preferred impedance/filtering feature, the cross section of the openings is about 60% or less than the nozzle opening cross section and the cross sectional area for all of the flow openings in the feature is greater than the cross sectional area of the nozzle openings, for example about 2 or 3 times the nozzle cross sectional area or more, e.g. about 10 times or more. For a filter/impedance feature in which flow openings have varying diameters, the cross sectional area of a flow opening is measured at the location of its smallest cross sectional dimension. In the case of a filter/impedance feature that has interconnecting flow paths along the direction of ink flow, the cross-sectional dimension and area are measured at the region of smallest cross-section. In embodiments, pressure drop can be used to determine flow resistance through the feature. The pressure drop can be measured at jetting flow. Jetting flow is the drop volume/fire pulse width. In embodiments, at jetting flow, the pressure drop across the impedance/filter feature is less than the pressure drop across the nozzle flow path. For example, the pressure drop across the feature is about 0.5 to 0.1 of the pressure drop across the nozzle flow path.
The overall impedance of the feature can be selected to substantially reduce acoustic reflection into the ink supply path. For example, the impedance of the feature may substantially match the impedance of the pumping chamber. Alternatively, it may be desirable to provide impedance greater than the chamber to enhance the filtering function or to provide impedance less than the chamber to enhance ink flow. In the latter case, crosstalk may be reduced by utilizing a compliant membrane or additional impedance control features elsewhere in the flow path as will be described below. The impedance of the pumping chamber and the filter/impedance feature can be modeled using fluid dynamic software, such as Flow 3D, available from Flow Science Inc., Santa Fe, N. Mex.
In a particular embodiment, the posts have a spacing along the flow path, S1, and a spacing across the flow path, S2, of about 15 micron and the nozzle opening is about 23 micron (
Referring particularly to
Referring back to
The accelerator region illustrated in
In particular embodiments, the ratio of the length of the accelerator region to the diameter of the nozzle opening is typically about 0.5 or greater, e.g., about 1 to 4, preferably about 1 to 2. The descender has a maximum cross-section of about 50 to 300 micron and a length of about 400–800 micron. The nozzle opening and the accelerator region have a diameter of about 5 to 80 micron, e.g. about 10 to 50 micron. The accelerator region has a length of about 1 to 200 micron, e.g., about 20 to 50 micron. The uniformity of the accelerator region length may be, for example, about ±3% or less or ±2 micron or less, among the nozzles of the module body. For a flow path arranged for a 10 pl drop, the descender has a length of about 550 micron. The descender has a racetrack, ovaloid shape with a minor width of about 85 micron and a major width of about 160 micron. The accelerator region has a length of about 30 micron and a diameter of about 23 microns.
Actuator
Referring to
Thin layers of prefired piezoelectric material can be formed by reducing the thickness of a relatively thick wafer. A precision grinding technique such as horizontal grinding can produce a highly uniform thin layer having a smooth, low void surface morphology. In horizontal grinding, a workpiece is mounted on a rotating chuck and the exposed surface of the workpiece is contacted with a horizontal grinding wheel. The grinding can produce flatness and parallelism of, e.g., 0.25 microns or less, e.g. about 0.1 micron or less and surface finish to 5 nm Ra or less over a wafer. The grinding also produces a symmetrical surface finish and uniform residual stress. Where desired, slight concave or convex surfaces can be formed. As discussed below, the piezoelectric wafer can be bonded to a substrate, such as the module substrate, prior to grinding so that the thin layer is supported and the likelihood of fracture and warping is reduced.
Referring particularly to
A suitable precision grinding apparatus is Toshiba Model UHG-130C, available through Cieba Technologies, Chandler, Ariz. The substrate can be ground with a rough wheel followed by a fine wheel. A suitable rough and fine wheel have 1500 grit and 2000 grit synthetic diamond resinoid matrix, respectively. Suitable grinding wheels are available from Adoma or Ashai Diamond Industrial Corp. of Japan. The workpiece spindle is operated at 500 rpm and the grinding wheel spindle is operated at 1500 rpm. The x-axis feed rate is 10 micron/min for first 200–250 micron using the rough wheel and 1 micron/min for last 50–100 micron using the fine wheel. The coolant is 18 m Ω deionized water. The surface morphology can be measured with a Zygo model Newview 5000 interferometer with Metroview software, available from Zygo Corp, Middlefield, Conn. The density of the piezoelectric material is preferably about 7.5 g/cm3 or more, e.g., about 8 g/cm3 to 10 g/cm3. The d31 coefficient is preferably about 200 or greater. HIPS-treated piezoelectric material is available as H5C and H5D from Sumitomo Piezoelectric Materials, Japan. The H5C material exhibits an apparent density of about 8.05 g/cm3 and d31 of about 210. The H5D material exhibits an apparent density of about 8.15 g/cm3 and a d31 of about 300. Wafers are typically about 1 cm thick and can be diced to about 0.2 mm. The diced wafers can be bonded to the module substrate and then ground to the desired thickness. The piezoelectric material can be formed by techniques including pressing, doctor blading, green sheet, sol gel or deposition techniques. Piezoelectric material manufacture is discussed in Piezoelectric Ceramics, B. Jaffe, Academic Press Limited, 1971, the entire contents of which are incorporated herein by reference. Forming methods, including hot pressing, are described at pages 258–9. High density, high piezoelectric constant materials are preferred but the grinding techniques can be used with lower performance material to provide thin layers and smooth, uniform surface morphology. Single crystal piezoelectric material such as lead-magnesium-niobate (PMN), available from TRS Ceramics, Philadelphia, Pa., can also be used.
Referring back to
The metalized piezoelectric layer is fixed to the actuator membrane 70. The actuator membrane 70 isolates the lower electrode layer 74 and the piezoelectric layer 76 from ink in the chamber 33. The actuator membrane 70 is typically an inert material and has compliance so that actuation of the piezoelectric layer causes flexure of the actuator membrane layer sufficient to pressurize ink in the pumping chamber. The thickness uniformity of the actuator membrane provides accurate and uniform actuation across the module. The actuator membrane material can be provided in thick plates (e.g. about 1 mm in thickness or more) which are ground to a desired thickness using horizontal grinding. For example, the actuator membrane may be ground to a thickness of about 25 micron or less, e.g. about 20 micron.
In embodiments, the actuator membrane 70 has a modulus of about 60 gigapascal or more. Example materials include glass or silicon. A particular example is a boro-silicate glass, available as Boroflot EV 520 from Schott Glass, Germany. Alternatively, the actuator membrane may be provided by depositing a layer, e.g. 2 to 6 micron, of aluminum oxide on the metalized piezoelectric layer. Alternatively, the actuator membrane may be zirconium or quartz.
The piezoelectric layer 76 can be attached to the actuator membrane 70 by a bonding layer 72. The bonding layer 72 may be a layer of amorphous silicon deposited onto the metal layer 74, which is then anodically bonded to the actuator membrane 70. In anodic bonding, the silicon substrate is heated while in contact with the glass while a negative voltage is applied to the glass. Ions drift toward the negative electrode, forming a depletion region in the glass at the silicon interface, which forms an electrostatic bond between the glass and silicon. The bonding layer may also be a metal that is soldered or forms a eutectic bond. Alternatively, the bonding layer can be an organic adhesive layer. Because the piezoelectric material has been previously fired, the adhesive layer is not subject to high temperatures during assembly. Organic adhesives of relatively low melting temperatures can also be used. An example of an organic adhesive is BCB resin available from Dow Chemical, Midland, Mich. The adhesive can be applied by spin-on processing to a thickness of e.g. about 0.3 to 3 micron. The actuator membrane can be bonded to the module substrate before or after the piezoelectric layer is bonded to the actuator membrane.
The actuator membrane 70 may be bonded to the module substrate 26 by adhesive or by anodic bonding. Anodic bonding is preferred because no adhesive contacts the module substrate features adjacent the flow path and thus the likelihood of contamination is reduced and thickness uniformity and alignment may be improved. The actuator substrate may be ground to a desired thickness after attachment to the module substrate. In other embodiments, the actuator does not include a membrane between the piezoelectric layer and the pumping chamber. The piezoelectric layer may be directly exposed to the ink chamber. In this case, both the drive and ground electrodes can be placed on the opposite, back side of the piezoelectric layer not exposed to the ink chamber.
Referring back to
Manufacture
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In step 312, the actuator substrate is cleaned. The actuator substrate may be cleaned in an ultrasonic bath and plasma etched as described above. In step 314, the piezoelectric blank is precision ground on both sides to provide smooth surface morphology. In step 316, one side of the piezoelectric blank is metalized. In step 318, the metalized side of the piezoelectric blank is bonded to the actuator substrate. The piezoelectric blank may be bonded using a spun on adhesive. Alternatively, a layer of amorphous silicon may be deposited on the metalized surface of the blank and the blank then anodically bonded to the actuator substrate.
In step 320, the piezoelectric blank is ground to a desired thickness using a precision grinding technique. Referring as well to
In step 322, edge cuts for the ground electrode contacts are cut to expose the ground electrode layer 74. In step 324, the wafer is cleaned. In step 326, the backside of the wafer is metalized, which provides a metal contact to the ground layer, as well as provides a metal layer over the back surface of the actuator portion of the piezoelectric layer. In step 228, separation and isolation cuts are sawed. In step 330, the wafer is again cleaned.
In step 334, the modules are separated from the wafer by dicing. In step 336, the modules are attached to the manifold frame. In step 338, electrodes are attached. Finally, in step 340, the arrangement is attached to an enclosure.
The front face of the module may be provided with a protective coating and/or a coating that enhances or discourages ink wetting. The coating may be, e.g., a polymer such as Teflon or a metal such as gold or rhodium. A dicing saw can be used to separate module bodies from a wafer. Alternatively or in addition, kerfs can be formed by etching and separation cuts can be made in the kerfs using a dicing saw. The modules can also be separated manually by breaking along the kerfs.
Referring to
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In other embodiments, the etched module body or nozzle plates described above can be utilized with actuator mechanisms other than piezoelectric actuators. For example, thermal bubble jet or electrostatic actuators can be used. An example of an electrostatic actuator can be found in U.S. Pat. No. 4,386,358, the entire contents of which is incorporated herein by reference. Other etchable materials can be used for the module substrate, nozzle plates, and impedance/filter features, for example, germanium, doped silicon, and other semiconductors. Stop layers can be used to define thicknesses of various features, such as the depth, uniformity, and shape the pumping chamber. Multiple stop layers can be provided to control the depth of multiple features.
The piezoelectric actuators described above can be utilized with other module substrates and substrate systems. Piezoelectric layers formed of piezoelectric material that has not been prefired can be used. For example, a thin piezoelectric film can be formed on a glass or silicon substrate by techniques, such as sol gel deposition or a green sheet technique and subsequently fired. The surface characteristics and/or thickness can be modified by precision grinding. The high temperature resistance of these actuator substrate materials can withstand the firing temperatures of the ceramic precursors. While a three-layer SOI substrate is preferred, semiconductor substrates having two layers of differentially-etchable semiconductor material, such as a layer of silicon oxide on silicon, can be used to form module body substrates or nozzle plates and control feature depths by differential etching. For example, a monolithic body of silicon oxide on silicon can be used. An accelerator region can be defined between a nozzle opening on the silicon face of a substrate and the interface between the silicon and silicon oxide layer.
Use
The printhead modules can be used in any printing application, particularly high speed, high performance printing. The modules are particularly useful in wide format printing in which wide substrates are printed by long modules and/or multiple modules arranged in arrays.
Referring back to
The modules can be used in printers for offset printing replacement. The modules can be used to selectively deposit glossy clear coats applied to printed material or printing substrates. The printheads and modules can be used to dispense or deposit various fluids, including non-image forming fluids. For example, three-dimensional model pastes can be selectively deposited to build models. Biological samples may be deposited on an analysis array.
Still further embodiments are in the following claims.
Number | Name | Date | Kind |
---|---|---|---|
4005440 | Amberntsson | Jan 1977 | A |
4106976 | Chiou et al. | Aug 1978 | A |
4158847 | Heinzl et al. | Jun 1979 | A |
4480259 | Kruger et al. | Oct 1984 | A |
4504845 | Kattner et al. | Mar 1985 | A |
4528574 | Boyden | Jul 1985 | A |
4620123 | Farrall et al. | Oct 1986 | A |
4627138 | Im | Dec 1986 | A |
4641153 | Cruz-Uribe | Feb 1987 | A |
4665409 | Behrens et al. | May 1987 | A |
4670074 | Broussoux et al. | Jun 1987 | A |
4672398 | Kuwabara et al. | Jun 1987 | A |
4680595 | Cruz-Uribe et al. | Jul 1987 | A |
4703333 | Hubbard | Oct 1987 | A |
4728969 | Le et al. | Mar 1988 | A |
4730197 | Raman et al. | Mar 1988 | A |
4774530 | Hawkins | Sep 1988 | A |
4789425 | Drake et al. | Dec 1988 | A |
4812199 | Sickafus | Mar 1989 | A |
4835554 | Hoisington et al. | May 1989 | A |
4863560 | Hawkins | Sep 1989 | A |
4899178 | Tellier | Feb 1990 | A |
4966037 | Sumner et al. | Oct 1990 | A |
5000811 | Campanelli | Mar 1991 | A |
5041190 | Drake et al. | Aug 1991 | A |
5096535 | Hawkins et al. | Mar 1992 | A |
5124717 | Campanelli et al. | Jun 1992 | A |
5202703 | Hoisington et al. | Apr 1993 | A |
5204690 | Lorenze, Jr. et al. | Apr 1993 | A |
5227813 | Pies et al. | Jul 1993 | A |
5235352 | Pies et al. | Aug 1993 | A |
5265315 | Hoisington et al. | Nov 1993 | A |
5278585 | Karz et al. | Jan 1994 | A |
5374332 | Koyama et al. | Dec 1994 | A |
5376856 | Takeuchi et al. | Dec 1994 | A |
5385635 | O'Neill | Jan 1995 | A |
5387314 | Baughman et al. | Feb 1995 | A |
5402926 | Takeuchi et al. | Apr 1995 | A |
5406682 | Zimnicki et al. | Apr 1995 | A |
5408739 | Altavela et al. | Apr 1995 | A |
5414916 | Hayes | May 1995 | A |
5430344 | Takeuchi et al. | Jul 1995 | A |
5446484 | Hoisington et al. | Aug 1995 | A |
5459501 | Lee et al. | Oct 1995 | A |
5463413 | Ho et al. | Oct 1995 | A |
5463414 | Temple et al. | Oct 1995 | A |
5475279 | Takeuchi et al. | Dec 1995 | A |
5477344 | Lubinsky et al. | Dec 1995 | A |
5484507 | Ames | Jan 1996 | A |
5489930 | Anderson | Feb 1996 | A |
5500988 | Moynihan et al. | Mar 1996 | A |
5501893 | Laermer et al. | Mar 1996 | A |
5502471 | Obermeier et al. | Mar 1996 | A |
5512793 | Takeuchi et al. | Apr 1996 | A |
5518952 | Vonasek et al. | May 1996 | A |
5581286 | Hayes et al. | Dec 1996 | A |
5592042 | Takuchi et al. | Jan 1997 | A |
5605659 | Moynihan et al. | Feb 1997 | A |
5617127 | Takeuchi et al. | Apr 1997 | A |
5622748 | Takeuchi et al. | Apr 1997 | A |
5631040 | Takuchi et al. | May 1997 | A |
5643379 | Takeuchi et al. | Jul 1997 | A |
5655538 | Lorraine et al. | Aug 1997 | A |
5658471 | Murthy et al. | Aug 1997 | A |
5659346 | Moynihan | Aug 1997 | A |
5665249 | Burke et al. | Sep 1997 | A |
5666143 | Burke et al. | Sep 1997 | A |
5670999 | Takeuchi et al. | Sep 1997 | A |
5691593 | Takeuchi et al. | Nov 1997 | A |
5691594 | Takeuchi et al. | Nov 1997 | A |
5691752 | Moynihan et al. | Nov 1997 | A |
5704105 | Venkataramani et al. | Jan 1998 | A |
5710584 | Suzuki et al. | Jan 1998 | A |
5718044 | Baughman et al. | Feb 1998 | A |
5734399 | Weber et al. | Mar 1998 | A |
5736993 | Regimbal et al. | Apr 1998 | A |
5745131 | Kneezel et al. | Apr 1998 | A |
5752303 | Thiel et al. | May 1998 | A |
5757400 | Hoisington | May 1998 | A |
5790156 | Mutton et al. | Aug 1998 | A |
5793394 | Kato | Aug 1998 | A |
5818476 | Mey et al. | Oct 1998 | A |
5818482 | Ohta et al. | Oct 1998 | A |
5821841 | Furlani et al. | Oct 1998 | A |
5821972 | Mey et al. | Oct 1998 | A |
5825385 | Silverbrook | Oct 1998 | A |
5834880 | Venkataramani et al. | Nov 1998 | A |
5841452 | Silverbrook | Nov 1998 | A |
D402687 | Sabonis | Dec 1998 | S |
5850241 | Silverbrook | Dec 1998 | A |
5852860 | Lorraine et al. | Dec 1998 | A |
5855049 | Corbett, III et al. | Jan 1999 | A |
5861902 | Beerling | Jan 1999 | A |
D405822 | Sabonis | Feb 1999 | S |
5870123 | Lorenze, Jr. et al. | Feb 1999 | A |
5870124 | Silverbrook | Feb 1999 | A |
5871656 | Silverbrook | Feb 1999 | A |
5880759 | Silverbrook | Mar 1999 | A |
5889544 | Mey et al. | Mar 1999 | A |
5901425 | Bibl et al. | May 1999 | A |
5907340 | Katakura | May 1999 | A |
5927206 | Bacon et al. | Jul 1999 | A |
5933170 | Takeuchi et al. | Aug 1999 | A |
D417233 | Sabonis | Nov 1999 | S |
6012799 | Silverbrook | Jan 2000 | A |
6019457 | Silverbrook | Feb 2000 | A |
6020905 | Cornell et al. | Feb 2000 | A |
6022101 | Sabonis | Feb 2000 | A |
6022752 | Hirsh et al. | Feb 2000 | A |
6030065 | Fukuhata | Feb 2000 | A |
6031652 | Furlani et al. | Feb 2000 | A |
6033060 | Minami | Mar 2000 | A |
6036874 | Farnaam | Mar 2000 | A |
6037957 | Granet et al. | Mar 2000 | A |
6042219 | Higashino et al. | Mar 2000 | A |
6044646 | Silverbrook | Apr 2000 | A |
6045710 | Silverbrook | Apr 2000 | A |
6047600 | Ottosson | Apr 2000 | A |
6047816 | Moghadam et al. | Apr 2000 | A |
6062681 | Field et al. | May 2000 | A |
6067183 | Furlani et al. | May 2000 | A |
6070310 | Ito et al. | Jun 2000 | A |
6071750 | Silverbrook | Jun 2000 | A |
6071822 | Donohue et al. | Jun 2000 | A |
6087638 | Silverbrook | Jul 2000 | A |
6088148 | Furlani et al. | Jul 2000 | A |
6089696 | Lubinsky | Jul 2000 | A |
6097406 | Lubinsky et al. | Aug 2000 | A |
6108117 | Furlani et al. | Aug 2000 | A |
6109746 | Jeanmaire et al. | Aug 2000 | A |
6126846 | Silverbrook | Oct 2000 | A |
6127198 | Coleman et al. | Oct 2000 | A |
6143190 | Yagi et al. | Nov 2000 | A |
6143432 | deRochemont et al. | Nov 2000 | A |
6143470 | Nguyen et al. | Nov 2000 | A |
6161270 | Ghosh et al. | Dec 2000 | A |
6176570 | Kishima et al. | Jan 2001 | B1 |
6179978 | Hirsh et al. | Jan 2001 | B1 |
6186610 | Kocher et al. | Feb 2001 | B1 |
6186618 | Usui et al. | Feb 2001 | B1 |
6188416 | Hayes | Feb 2001 | B1 |
6190931 | Silverbrook | Feb 2001 | B1 |
6209999 | Wen et al. | Apr 2001 | B1 |
6213588 | Silverbrook | Apr 2001 | B1 |
6214192 | Hawkins et al. | Apr 2001 | B1 |
6214244 | Silverbrook | Apr 2001 | B1 |
6214245 | Hawkins et al. | Apr 2001 | B1 |
6217153 | Silverbrook | Apr 2001 | B1 |
6217155 | Silverbrook | Apr 2001 | B1 |
6218083 | McCullough et al. | Apr 2001 | B1 |
6220694 | Silverbrook | Apr 2001 | B1 |
6227653 | Silverbrook | May 2001 | B1 |
6227654 | Silverbrook | May 2001 | B1 |
6228668 | Silverbrook | May 2001 | B1 |
6234608 | Genovese et al. | May 2001 | B1 |
6234611 | Silverbrook | May 2001 | B1 |
6235211 | Silverbrook | May 2001 | B1 |
6235212 | Silverbrook | May 2001 | B1 |
6238044 | Silverbrook et al. | May 2001 | B1 |
6238115 | Silverbrook et al. | May 2001 | B1 |
6238584 | Hawkins et al. | May 2001 | B1 |
6239821 | Silverbrook | May 2001 | B1 |
6241342 | Silverbrook | Jun 2001 | B1 |
6241904 | Silverbrook | Jun 2001 | B1 |
6241905 | Silverbrook | Jun 2001 | B1 |
6241906 | Silverbrook | Jun 2001 | B1 |
6244691 | Silverbrook | Jun 2001 | B1 |
6245246 | Silverbrook | Jun 2001 | B1 |
6245247 | Silverbrook | Jun 2001 | B1 |
6247790 | Silverbrook | Jun 2001 | B1 |
6247791 | Silverbrook | Jun 2001 | B1 |
6247793 | Silverbrook | Jun 2001 | B1 |
6247794 | Silverbrook | Jun 2001 | B1 |
6247795 | Silverbrook | Jun 2001 | B1 |
6247796 | Silverbrook | Jun 2001 | B1 |
6248248 | Silverbrook | Jun 2001 | B1 |
6248249 | Silverbrook | Jun 2001 | B1 |
6248505 | McCullough et al. | Jun 2001 | B1 |
6251298 | Silverbrook | Jun 2001 | B1 |
6252697 | Hawkins et al. | Jun 2001 | B1 |
6254793 | Silverbrook | Jul 2001 | B1 |
6255762 | Sakamaki et al. | Jul 2001 | B1 |
6256849 | Kim | Jul 2001 | B1 |
6258284 | Silverbrook | Jul 2001 | B1 |
6258285 | Silverbrook | Jul 2001 | B1 |
6258286 | Hawkins et al. | Jul 2001 | B1 |
6260953 | Silverbrook | Jul 2001 | B1 |
6263551 | Lorraine et al. | Jul 2001 | B1 |
6264306 | Silverbrook | Jul 2001 | B1 |
6264307 | Silverbrook | Jul 2001 | B1 |
6264849 | Silverbrook | Jul 2001 | B1 |
6267905 | Silverbrook | Jul 2001 | B1 |
6273552 | Hawkins et al. | Aug 2001 | B1 |
6274056 | Silverbrook | Aug 2001 | B1 |
6276774 | Moghadam et al. | Aug 2001 | B1 |
6276782 | Sharma et al. | Aug 2001 | B1 |
6280643 | Silverbrook | Aug 2001 | B1 |
6281912 | Silverbrook | Aug 2001 | B1 |
6283575 | Hawkins et al. | Sep 2001 | B1 |
6286935 | Silverbrook | Sep 2001 | B1 |
6291317 | Salatino et al. | Sep 2001 | B1 |
6293658 | Silverbrook | Sep 2001 | B1 |
6294101 | Silverbrook | Sep 2001 | B1 |
6296346 | Seo et al. | Oct 2001 | B1 |
6299289 | Silverbrook | Oct 2001 | B1 |
6299300 | Silverbrook | Oct 2001 | B1 |
6299786 | Silverbrook | Oct 2001 | B1 |
6303042 | Hawkins et al. | Oct 2001 | B1 |
6305788 | Silverbrook | Oct 2001 | B1 |
6305791 | Hotomi et al. | Oct 2001 | B1 |
6306671 | Silverbrook | Oct 2001 | B1 |
6309048 | Silverbrook | Oct 2001 | B1 |
6309054 | Kawamura et al. | Oct 2001 | B1 |
6312114 | Silverbrook | Nov 2001 | B1 |
6312615 | Silverbrook | Nov 2001 | B1 |
6315399 | Silverbrook | Nov 2001 | B1 |
6315914 | Silverbrook | Nov 2001 | B1 |
6318849 | Silverbrook | Nov 2001 | B1 |
6322194 | Silverbrook | Nov 2001 | B1 |
6322195 | Silverbrook | Nov 2001 | B1 |
6328399 | Wen | Dec 2001 | B1 |
6328417 | Silverbrook | Dec 2001 | B1 |
6328425 | Silverbrook | Dec 2001 | B1 |
6328431 | Silverbrook | Dec 2001 | B1 |
6331258 | Silverbrook | Dec 2001 | B1 |
6336715 | Hotomi et al. | Jan 2002 | B1 |
6338548 | Silverbrook | Jan 2002 | B1 |
6340222 | Silverbrook | Jan 2002 | B1 |
6345424 | Hasegawa | Feb 2002 | B1 |
6350019 | Shingai et al. | Feb 2002 | B1 |
6352337 | Sharma | Mar 2002 | B1 |
6352814 | McCullough et al. | Mar 2002 | B1 |
6364459 | Sharma et al. | Apr 2002 | B1 |
6378989 | Silverbrook | Apr 2002 | B1 |
6378996 | Shimada et al. | Apr 2002 | B1 |
6382767 | Greive | May 2002 | B1 |
6382779 | Silverbrook | May 2002 | B1 |
6382782 | Anagnostopoulos et al. | May 2002 | B1 |
6383833 | Silverbrook | May 2002 | B1 |
6386679 | Yang et al. | May 2002 | B1 |
6393980 | Simons | May 2002 | B1 |
6394581 | Silverbrook | May 2002 | B1 |
6398344 | Silverbrook | Jun 2002 | B1 |
6398348 | Haluzak et al. | Jun 2002 | B1 |
6402282 | Webb | Jun 2002 | B1 |
6402300 | Silverbrook | Jun 2002 | B1 |
6402303 | Sumi | Jun 2002 | B1 |
6406129 | Silverbrook | Jun 2002 | B1 |
6406607 | Hirsh et al. | Jun 2002 | B1 |
6409316 | Clark et al. | Jun 2002 | B1 |
6409323 | Silverbrook | Jun 2002 | B1 |
6412908 | Silverbrook | Jul 2002 | B1 |
6412912 | Silverbrook | Jul 2002 | B1 |
6412914 | Silverbrook | Jul 2002 | B1 |
6413700 | Hallman | Jul 2002 | B1 |
6416168 | Silverbrook | Jul 2002 | B1 |
6416932 | Ray et al. | Jul 2002 | B1 |
6420196 | Silverbrook | Jul 2002 | B1 |
6422677 | Deshpande et al. | Jul 2002 | B1 |
6425651 | Silverbrook | Jul 2002 | B1 |
6425661 | Silverbrook et al. | Jul 2002 | B1 |
6425971 | Silverbrook | Jul 2002 | B1 |
6428133 | Silverbrook | Aug 2002 | B1 |
6428134 | Clark et al. | Aug 2002 | B1 |
6428146 | Sharma et al. | Aug 2002 | B1 |
6428147 | Silverbrook | Aug 2002 | B1 |
6439695 | Silverbrook | Aug 2002 | B1 |
6439699 | Silverbrook | Aug 2002 | B1 |
6439701 | Taneya et al. | Aug 2002 | B1 |
6439703 | Anagnostopoulos et al. | Aug 2002 | B1 |
6439704 | Silverbrook | Aug 2002 | B1 |
6450615 | Kojima et al. | Sep 2002 | B1 |
6450619 | Anagnostopoulos et al. | Sep 2002 | B1 |
6450627 | Moynihan et al. | Sep 2002 | B1 |
6450628 | Jeanmaire et al. | Sep 2002 | B1 |
6451216 | Silverbrook | Sep 2002 | B1 |
6453526 | Lorraine et al. | Sep 2002 | B1 |
6454396 | Silverbrook | Sep 2002 | B1 |
6457795 | Silverbrook | Oct 2002 | B1 |
6457807 | Hawkins et al. | Oct 2002 | B1 |
6460778 | Silverbrook | Oct 2002 | B1 |
6463656 | Debesis et al. | Oct 2002 | B1 |
6467885 | Tanaka | Oct 2002 | B1 |
6471336 | Silverbrook | Oct 2002 | B1 |
6474781 | Jeanmaire | Nov 2002 | B1 |
6474789 | Ishinaga et al. | Nov 2002 | B1 |
6474794 | Anagnostopoulos et al. | Nov 2002 | B1 |
6474795 | Lebens et al. | Nov 2002 | B1 |
6481835 | Hawkins et al. | Nov 2002 | B1 |
6485130 | DeLouise et al. | Nov 2002 | B1 |
6488361 | Silverbrook | Dec 2002 | B1 |
6488367 | Debesis et al. | Dec 2002 | B1 |
6491362 | Jeanmaire | Dec 2002 | B1 |
6491376 | Trauernicht et al. | Dec 2002 | B1 |
6491385 | Anagnostopoulos et al. | Dec 2002 | B1 |
6491833 | Silverbrook | Dec 2002 | B1 |
6494566 | Kishino et al. | Dec 2002 | B1 |
6497019 | Yun | Dec 2002 | B1 |
6502306 | Silverbrook | Jan 2003 | B1 |
6502925 | Anagnostopoulos et al. | Jan 2003 | B1 |
6503408 | Silverbrook | Jan 2003 | B1 |
6505922 | Hawkins et al. | Jan 2003 | B1 |
6507099 | Silverbrook | Jan 2003 | B1 |
6508532 | Hawkins et al. | Jan 2003 | B1 |
6508543 | Hawkins et al. | Jan 2003 | B1 |
6508947 | Gulvin et al. | Jan 2003 | B1 |
6513903 | Sharma et al. | Feb 2003 | B1 |
6513908 | Silverbrook | Feb 2003 | B1 |
6521513 | Lebens et al. | Feb 2003 | B1 |
6526658 | Silverbrook | Mar 2003 | B1 |
6527357 | Sharma et al. | Mar 2003 | B1 |
6527365 | Silverbrook | Mar 2003 | B1 |
6530653 | Le et al. | Mar 2003 | B1 |
6533390 | Silverbrook | Mar 2003 | B1 |
6536874 | Silverbrook | Mar 2003 | B1 |
6536883 | Hawkins et al. | Mar 2003 | B1 |
6537735 | McCullough et al. | Mar 2003 | B1 |
6540319 | Silverbrook | Apr 2003 | B1 |
6540332 | Silverbrook | Apr 2003 | B1 |
6546628 | Silverbrook | Apr 2003 | B1 |
6547364 | Silverbrook | Apr 2003 | B1 |
6547371 | Silverbrook | Apr 2003 | B1 |
6550895 | Silverbrook | Apr 2003 | B1 |
6553651 | Reznik et al. | Apr 2003 | B1 |
6554410 | Jeanmaire et al. | Apr 2003 | B1 |
6557967 | Lee | May 2003 | B1 |
6557978 | Silverbrook | May 2003 | B1 |
6561625 | Maeng et al. | May 2003 | B1 |
6565193 | Silverbrook et al. | May 2003 | B1 |
6565762 | Silverbrook | May 2003 | B1 |
6566858 | Silverbrook et al. | May 2003 | B1 |
6568797 | Yamauchi et al. | May 2003 | B1 |
6572215 | Sharma | Jun 2003 | B1 |
6572715 | Komine et al. | Jun 2003 | B1 |
6575549 | Silverbrook | Jun 2003 | B1 |
6578245 | Chatterjee et al. | Jun 2003 | B1 |
6581258 | Yoneda et al. | Jun 2003 | B1 |
6582059 | Silverbrook | Jun 2003 | B1 |
6588882 | Silverbrook | Jul 2003 | B1 |
6588884 | Furlani et al. | Jul 2003 | B1 |
6588888 | Jeanmaire et al. | Jul 2003 | B1 |
6588889 | Jeanmaire | Jul 2003 | B1 |
6588890 | Furlani et al. | Jul 2003 | B1 |
6588952 | Silverbrook et al. | Jul 2003 | B1 |
6594898 | Yun | Jul 2003 | B1 |
6595617 | Sharma et al. | Jul 2003 | B1 |
6629756 | Wang | Oct 2003 | B1 |
6641744 | Kawamura et al. | Nov 2003 | B1 |
6767085 | Murai | Jul 2004 | B1 |
20010001458 | Hashizume et al. | May 2001 | A1 |
20010002135 | Milligan et al. | May 2001 | A1 |
20010015001 | Hashizume et al. | Aug 2001 | A1 |
20010023523 | Kubby et al. | Sep 2001 | A1 |
20010028378 | Lee et al. | Oct 2001 | A1 |
20010032382 | Lorraine et al. | Oct 2001 | A1 |
20010038404 | Kitahara et al. | Nov 2001 | A1 |
20020008738 | Lee et al. | Jan 2002 | A1 |
20020018105 | Usui et al. | Feb 2002 | A1 |
20020051039 | Moynihan et al. | May 2002 | A1 |
20020051042 | Takagi et al. | May 2002 | A1 |
20020075360 | Maeng et al. | Jun 2002 | A1 |
20020096488 | Gulvin et al. | Jul 2002 | A1 |
20020096489 | Lee et al. | Jul 2002 | A1 |
20020097303 | Gulvin et al. | Jul 2002 | A1 |
20020122100 | Nordstrom et al. | Sep 2002 | A1 |
20020129478 | Kishima | Sep 2002 | A1 |
20020139235 | Nordin et al. | Oct 2002 | A1 |
20020184907 | Vaiyapuri et al. | Dec 2002 | A1 |
20030016272 | Anagnostopoulos et al. | Jan 2003 | A1 |
20030058309 | Haluzak et al. | Mar 2003 | A1 |
20030081073 | Chen et al. | May 2003 | A1 |
20030107622 | Sugahara | Jun 2003 | A1 |
20030131475 | Conta | Jul 2003 | A1 |
20030132823 | Hyman et al. | Jul 2003 | A1 |
20030136002 | Nishikawa et al. | Jul 2003 | A1 |
20030156158 | Hirota et al. | Aug 2003 | A1 |
20030156159 | Kobayashi | Aug 2003 | A1 |
20030156162 | Hirota et al. | Aug 2003 | A1 |
Number | Date | Country |
---|---|---|
100 11 366 | Jan 2001 | DE |
0 413 340 | Feb 1991 | EP |
0 709 200 | May 1996 | EP |
0 736 915 | Oct 1996 | EP |
0916500 | May 1999 | EP |
0 949 079 | Oct 1999 | EP |
0969530 | Jan 2000 | EP |
0980103 | Feb 2000 | EP |
0985534 | Mar 2000 | EP |
1 138 492 | Oct 2001 | EP |
0963296 | Jan 2002 | EP |
1241009 | Sep 2002 | EP |
1284188 | Feb 2003 | EP |
1321294 | Jun 2003 | EP |
61-37438 | May 1994 | JP |
10-264385 | Oct 1998 | JP |
2001010040 | Jan 2001 | JP |
WO 0021755 | Oct 1999 | WO |
Number | Date | Country | |
---|---|---|---|
20040004649 A1 | Jan 2004 | US |