The present invention relates to a printing device and a printing method. Particularly, the present invention relates to a printing device and a printing method using a transfer roller.
There has been a method (Patent Documents 1, 2) of using a transfer roller as a printing device. Various patterns can be printed without exposure and development.
However, in the methods of Patent Documents 1, 2, misalignment is caused due to significant unevenness in the rotation speed of the roll.
For this reason, the object of the present application is to provide a printing device and a printing method with less misalignment in the case of a printing device using a transfer roller.
In order to solve the above-described problems, a printing device is used, which includes a substrate table having a flat surface and holding a target, an arc table having a curved portion, and a controller and configured such that the controller swings the arc table in a state in which the curved portion holding ink faces the substrate table and causes the arc table to contact the target to transfer the ink onto the target.
Moreover, a printing method is used, which includes an application step of applying ink to an arc table, a receiving step of receiving part of the ink by a printing plate on a printing plate table by contact between the ink on the arc table and the printing plate, and a transfer step of transferring the ink remaining on the arc table onto a target on a substrate table.
According to the printing device of the present invention, the printing device and the printing method with less misalignment can be provided.
First, a printing device 100 will be described as one example.
The printing device 100 includes a mount 19 as a base for the entire printing device 100. A conveyor 16 is located on the mount 19, and an application table 11, a printing plate table 12, an arc swing unit 13, an alignment unit 14, and a substrate table 15 are located on the conveyor 16.
The conveyor 16 includes, e.g., two rails, and the application table 11, the printing plate table 12, and the substrate table 15 move thereon. The arc swing unit 13 and the alignment unit 14 are placed over the conveyor 16, and are fixed to the mount 19. The application table 11, the printing plate table 12, and the substrate table 15 can pass under the arc swing unit 13 and the alignment unit 14.
A controller 34 controls the entirety of the printing device 100. The controller 34 is, e.g., a personal computer. The controller 34 has a program, and for example, saves and controls various types of data. The controller 34 controls the entirety of the printing device 100. A mechanism, a motor, etc. for moving each table are not shown.
An X-direction is a direction in which the application table 11, the printing plate table 12, and the substrate table 15 move. A Y-direction is a direction perpendicular to the X-direction in the horizontal direction, and is the width direction of the application table 11, the printing plate table 12, and the substrate table 15. A Z-direction is the vertical direction (direction perpendicular to the X-direction and the Y-direction).
The printing device 100 is a printing device using a method of forming a reverse pattern by partially removing an ink film (solid film), which has a uniform thickness on the surface of an arc table 23 of the arc swing unit 13, by a printing plate 22 and subsequently transferring the reverse pattern onto a target 25.
That is, the printing device 100 forms the reverse pattern of the ink on the surface of the arc table 23 by contact between the arc table 23 and the printing plate 22. Thereafter, the ink on the arc table 23 is printed onto the target 25.
The printing device 100 can be used, for example, as a printing device when an electronic device pattern (e.g., printed electronic device) is manufactured. Moreover, the printing device 100 can also be used, for example, as a semiconductor manufacturing device when a pattern such as a wiring layer, an insulating layer, a plating seed layer, a semiconductor thin film layer, or a resist layer is formed on the target 25 (substrate) in a semiconductor manufacturing step. For example, silver nano ink or copper nano ink can be used as the material of the wiring layer.
Note that a unit that cleans the surfaces of the arc table 23 and the printing plate 22 on regular basis or every time may be provided.
For example, as another form of the printing device 100, the application table 11, the printing plate table 12, and the substrate table 15 may be integrated. That is, the application table 11, the printing plate table 12, and the substrate table 15 may be moved integrally.
Alternatively, the arc swing unit 13 and the alignment unit 14 may be placed on the conveyor 16, and the application table 11, the printing plate table 12, and the substrate table 15 may be fixed. That is, the application table 11, the printing plate table 12, and the substrate table 15 may be fixed, and the arc swing unit 13 and the alignment unit 14 may be moved thereon.
The arc table 23 may have a curved surface of part of a circular column or a curved surface of part of an elliptical column. The arc table 23 is shown in a plan view of
The arc table 23 may be part of a circular column or part of an elliptical column. In order to enhance printing position accuracy, a change in a printing position in association with a printing pressure decreases as the curvature radius of the arc table increases, and for example, the curvature radius is 1000 mm or more and preferably 2000 mm or more. The arc table 23 has, on the surface thereof, a transfer sheet 31, and the surface of the transfer sheet 31 handles the ink. In a case where the arc table 23 itself or the surface of the arc table 23 is made of a material similar to that of the transfer sheet 31, the transfer sheet 31 is not necessary.
The transfer sheet 31 is, e.g., a silicone water-repellent blanket. For example, the arc table 23 is configured such that a metal body is wrapped with the transfer sheet 31.
A top view of the printing plate 22 is shown in
The printing plate 22 has, on the surface thereof, a raised portion 28 corresponding to the reverse pattern of the pattern printed on the target 25. The raised portion 28 of the printing plate 22 contacts the surface of the arc table 23, and in this manner, the ink is partially removed from the ink film on the surface of the arc table 23 and a printing pattern 29 which is a reverse pattern corresponding to a recessed portion 27 is formed.
The target 25 is a target on which the pattern is formed. For example, a flat plate-shaped, film-shaped, or sheet-shaped printing target is used as the target 25. Moreover, the target 25 is mounted on the substrate table 15. Further, the target 25 is moved in the X-direction by the conveyor 16 with mounted on the substrate table 15.
The reverse pattern (printing pattern 29) formed on the surface of the arc table 23 is transferred onto the target 25. That is, the desired printing pattern 29 is printed onto the target 25.
The printing plate 22 is mounted on the printing plate table 12, and the printing plate table 12 fixes the printing plate 22. The printing plate table 12 fixes the printing plate 22, for example, using an electrostatic chuck, a porous chuck, or a vacuum chuck. Moreover, the printing plate table 12 is moved in a conveying direction (X-direction in
The substrate table 15 has a flat upper surface, and the target 25 is mounted thereon. The substrate table 15 fixes the target 25. As in the printing plate table 12, the substrate table 15 fixes the target 25, for example, using an electrostatic chuck, a porous chuck, or a vacuum chuck. Moreover, the substrate table 15 is moved in the conveying direction (X-direction in
Note that each of the printing plate table 12 and the substrate table 15 may include a mechanism (not shown) that slightly moves the mounted printing plate 22 or target 25 in the X-direction, the Y-direction, the Z-direction, a rotation direction about the X-direction, a rotation direction about the Y-direction, and a rotation direction about the Z-direction. With this configuration, the printing plate table 12 and the substrate table 15 can adjust misalignment of the printing plate 22 or the target 25.
The application table 11 has, on the upper surface thereof, a die coater 21 (nozzle). A discharge port of the die coater 21 (nozzle) faces up. A not-shown ink supplier is provided to apply the ink to the arc table 23. The application table 11 has a second recognizer 24b, and can measure the shape and swing of the arc swing unit 13. The printing plate table 12 may have the second recognizer 24b. The second recognizer 24b is, e.g., a laser displacement meter.
The alignment unit 14 has a first recognizer 24a, and detects the positions of the printing plate 22 and the target 25.
The first recognizer 24a is a photographing device such as a digital camera or an image sensor, and detects the position of the pattern on the printing plate 22 and the target 25.
The controller 34 is a unit that controls operation of each table, discharge of the ink from the die coater, alignment operation, and operation of the arc table 23, and controls the entirety of the printing device 100.
The conveyor 16 is a mechanism that moves the printing plate table 12, the substrate table 15, and the application table 11 (in the X-direction in
The preparation step is a step of performing, e.g., position adjustment and measurement before the printing step. In a start state, the application table 11, the printing plate table 12, and the substrate table 15 are at standby positions. The positions of these tables on the conveyor 16 are in this order in the X-axis direction.
A: Measurement of Shape of Arc Table 23: the shape of the arc table 23 on the arc swing unit 13 is measured. The laser displacement meter as the second recognizer 24b is mounted on a back portion of the application table 11, and the application table 11 is moved such that the laser displacement meter measures the shape of the arc table 23 from below. The printing plate table 12 may have the second recognizer 24b, and the shape of the arc table 23 may be measured while the printing plate table 12 is moving in a manner similar to that described above. In a case where the shape of the arc table 23 is known in advance, such measurement may be omitted.
B: Measurement of Swing of Arc Table 23: by <Trochoid Control> described below, the arc table 23 is swung to a specific position, the application table 11 or the printing plate table 12 equipped with the laser displacement meter is moved in synchronization with such swing, and the height of the arc table 23 is measured by the laser displacement meter. A: the above-described synchronous measurement is performed for the lowest point of the arc table 23 obtained in advance in measurement of the shape of the arc table 23 so that the amount of variation in the amount of contact (printing pressure) between the arc and the substrate can be estimated. A: in a case where the measurement of the shape of the arc table 23 is omitted, the lower point estimated from a design drawing may be used as a substitute. In a case where a variation in the measurement value is great, the arc swing is adjusted by <Correction Method> described below.
A: Measurement of Shape of Arc Table 23 and B: Measurement of Swing of Arc Table 23 are performed mainly for determining a control parameter for swinging the arc table 23, and are not necessarily performed in every printing and it is enough to perform such measurement, e.g., at the time of starting the device.
Further, as described later, the arc swing can be adjusted without the laser displacement meter, and in this case, A: Measurement of Shape of Arc Table 23 and B: Measurement of Swing of Arc Table 23 may be omitted.
C: Alignment of Substrate Table: the substrate table 15 passes under the alignment unit 14, and the position of the target 25 on the substrate table 15 is recognized. The position of the target 25 is adjusted to a certain reference. The substrate table 15 has a mechanism capable of moving the substrate table 15 in the horizontal (X, Y) direction and a θ-direction. This mechanism may be omitted, e.g., in a case where there is no pattern for the target 25. That is, the mechanism may be omitted, e.g., in a case where printing is performed on an arbitrary position on the target 25.
D: Alignment of Printing Plate Table: the printing plate table 12 passes under the alignment unit 14, and the position of the printing plate 22 on the printing plate table 12 is recognized. The position of the printing plate 22 is adjusted to a certain reference. The printing plate table 12 has a mechanism capable of moving the printing plate table 12 in the horizontal (X, Y) direction and the θ-direction. This mechanism is effective, e.g., in a case where the printing plate 22 is detached and cleaned outside the device. This mechanism may be omitted if the position of the printing plate 22 is not changed.
Note that needless to say, each stage, each table, the conveyor, etc. are placed horizontally. That is, these components are placed perpendicularly to the Z-direction (height direction).
The printing step is a step of performing printing on the printing target. In the preparation step, each position has been already adjusted.
E: Application Step: the application table 11 moves to below the arc table 23 of the arc swing unit 13. Then, by <Trochoid Control> described below, the application table 11 moves while the arc table 23 is swinging, and in this manner, the die coater 21 applies the ink to the transfer sheet 31. The ink is applied not as a pattern, but as a uniform film over the entire transfer sheet 31.
At this time, the arc table 23 may move up and down as described below.
F: Receiving Step: the printing plate table 12 moves to below the arc table 23 of the arc swing unit 13. The arc table 23 moves in the Z-direction and the X-direction, and swings by <Trochoid Control> described below. Accordingly, the solid film on the transfer sheet 31 contacts the printing plate 22, and the ink is removed. The remaining pattern is the printing pattern 29 to be printed.
G: Transfer Step: the substrate table 15 moves to below the arc table 23. The arc table 23 moves in the Z-direction and the X-direction, and swings by <Trochoid Control> described below. Accordingly, the arc table 23 is pressed against the target 25, and the ink of the printing pattern 29 is printed thereon.
In the case of subsequently performing printing, the printing plate 22 and the arc table 23 are preferably cleaned.
Note that the substrate table 15, the arc table 23, and the controller 34 are essential components and other components may be omitted. The problems of the present application can be solved by these essential components. The other components have been described above as examples, but components other than above may be employed.
Swing of the arc table 23 in the B, E, F, and G steps described in <Printing Method> will be described.
In the arc swing unit 13, the arc table 23 is held by four drivers 22a to 22d. Each driver can move in the X-direction and the Z-direction. Each driver and the arc table 23 are connected to each other through shafts 32a to 32d. The arc table 23 is rotatable about the shafts 32a to 32d. Hereinafter, in a case where the shafts 32a to 32d are not distinguished from each other, these shafts will be referred to as a shaft(s) 32.
The drivers 22a to 22d including the shafts 32 have three degrees of freedom in X-axis translation, Z-axis translation, and rotation about the Y-direction as a rotation center axis. The arc table 23 is regarded as a rigid body, and therefore, the drivers 22a to 22d are constrained as a result of connection with the arc table 23 and have three degrees of freedom at each end. Thus, the drivers 22a to 22d may be driven, at each end, using three types of positioning devices only for translation or a combination of rotation and translation.
For example, three axes including the Z-axis and rotation center axis of the driver 22a and the Z-axis of the driver 22d are controlled by a drive device such as a motor, and other axes may be freely controlled using, e.g., a bearing or a linear guide. However, higher-accuracy positioning is available by the positioning devices only for translation, and therefore, three axes including the X-axis and Z-axis of the driver 22a and the Z-axis of the driver 22d or three axes including the Z-axis of the driver 22a and the X-axis and Z-axis of the driver 22d are preferably controlled by the drive device, and other axes are preferably freely controlled using, e.g., a bearing or a linear guide. The same also applies to a combination of the driver 22b and the driver 22c.
Note that as shown in
In swing of the arc table 15 in the B, E, F, and G steps, the shafts 32a to 32d holding both ends of the arc table 15 may swing along a trochoid curve 40. That is, the shafts 32a to 32d swing along the trochoid curves 40 (movement paths of the shafts 32a, 32d from
The trochoid curve is a curve traced out by a fixed point inside or outside a circle when the circle rolls along a certain curve (circle or straight line in a special case) without sliding.
Specific description will be made with reference to
The control along the trochoid curves allows the surface of the transfer sheet 31 to move with a constant amount of pressing without sliding on the surface of the target 25. Thus, the printing pattern 29 can be formed with less misalignment. As described in <Swing>, the shafts 32 can move along the trochoid curves, for example, only by translation of the drivers 22a to 22d in the X-direction and the Z-direction. Moreover, the arc table 23 with a great curvature radius can be used, and therefore, an effect of reducing the amount of dimensional change in the printing pattern can be produced even in the case of a great amount of pressing and high positioning accuracy can be provided. Note that an device that performs printing by rotating a cylindrical roll by a rotating motor requires a rotating motor with a higher torque as the curvature radius of the roll increases. Further, due to variation in the rotation speed of the rotating motor, roll surface positioning accuracy is lowered in proportion to the radius of the roll. According to the present invention, a positioning error in such a roll rotation type printing device can be avoided.
Regarding the trochoid curve control of the shafts 32d, 32a, a combination of the drivers 22d, 22a will be described as an example. For the sake of simplicity in description, it is assumed that the surface of the target 25 is a horizontal flat surface and the height thereof is z=0.
The X-axis and Z-axis of the driver 22d are moved according to the following expressions:
The X-axis and Z-axis of the driver 22a are moved according to the following expressions (note that as described in <Swing>, for example, the X-axis of the driver 22a may only follow the linear guide without being controlled in order to avoid excessive constraint, and in this case, xB shown in Expression (3) only indicates the position of the linear guide and is not used for the control):
Here, R and L are the curvature radius and arc length of the arc table 23. WA and HA are horizontal and vertical distances from an intersection between a perpendicular line passing through the center of the arc and the surface of the circle to the shaft 32d of the driver 22d when the arc is in the horizontal posture. Similarly, WB and HB are horizontal and vertical distances from the intersection between the perpendicular line passing through the center of the arc and the surface of the circle to the shaft 32a of the driver 22a when the arc is in the horizontal posture. Moreover, rA, θA, rB, θB, and θC are variables determined by the following expressions:
p is the mediator variable of the trochoid curve, can be the value of a virtual axis for synchronously controlling the shafts 32a to 32d of the drivers 22a to 22d, and is in a relationship of p=VPt=xP with the speed (translational component) VP of the arc swinging on the line of z=0 and a time t. Here, xP is an x component of an intersection between the arc and the line of z=0 and an x component of the lowest point PP of the arc.
Other variables starting with Δ are correction parameters having the meanings of Table 1, are used for changing the path of the shaft 32 for finely adjusting the positioning accuracy of the printing pattern 29, and is zero in a case where correction is not necessary. MxA, MzA, MxB, and MzB are also correction parameters, are also used for changing the path of the shaft 32, and are one in a case where correction is not necessary.
The value of the correction parameter is preferably settable independently in the application step, the receiving step, and the transfer step. For example, even in a case where the flatness and posture of the printing plate table 12 and the substrate table 15 vary, the printing pressure can be brought close to a constant pressure by the correction parameter.
Similarly, the trochoid control is performed on the drivers 22b, 22c in a similar manner so that the arc swing unit 13 can be swung. In a case where the surface of the target 25 is curved, Expressions (1) to (4) for the trochoid curve control may be changed according to such a curved surface.
It is assumed that the drivers 22a to 22d are moved with R, L, WA, HA, WB, and HB as input values according to Expressions (1) to (4) above while the mediator variable p is changing, but true values are R*, L*, WA*, HA*, WB*, and HB* which are different from the input values. In this case, the arc swing does not coincide with ideal motion. A method of properly determining the correction parameters to bring the arc swing close to the ideal swing in this case will be described. Note that the true value changes due to a machining error, a measurement error, an assembly error, and strain caused over time, such as creep, and cannot be easily measured. For this reason, the correction method described here is particularly important to accurately perform printing and solve the problems according to the present invention.
First, end portions of the shafts 32d, 32a will be described. A true inter-shaft distance between the shafts 32d, 32a is as follows:
For the sake of convenience, the following expressions are defined:
As a result of movement of the shafts 32d, 32a, the inclination angle of the arc is as follows:
Further, angles determined by the true values are defined as follows:
In this case, the coordinates of the lowest point PP of the arc are as follows:
As described above, the deviation between the true value and the input value and the path through which the lowest point of the arc passes can be associated with each other. Specifically, the laser measurement described above in “B: Measurement of Swing of Arc Table 23” may be performed on the surface of the arc table 23 close to the end portions of the shafts 32d, 32a, the result thereof may be compared with Expression (6), and the correction parameters of (2) and (4) may be changed such that zP of the lowest point of the arc table 23 is maintained constant. Operation similar to that described above is also performed on end portions of the shafts 32b, 32c.
In a case where correction is made also in consideration of influence of posture errors in the printing plate table 12 and the substrate table 15, for example, a pressure sensitive film (for example, PRESCALE 5LW manufactured by FUJIFILM corporation) or a pressure sensor sheet may be placed on the surface of the substrate table 15, and the correction parameters may be changed such that pressure distribution is brought uniform. In this case, the measurement by the laser displacement meter is not necessary. In a case where there is no laser displacement meter, an inclinometer may be placed on the upper surface of the arc table 23, and the correction parameters may be changed in comparison with α(zA, zB). However, the measurement by the laser displacement meter is preferable in terms of quantitativeness.
It is difficult to measure the coordinates xP of the lowest point PP of the arc in the X-direction by the method described above in “B: Measurement of Swing of Arc Table 23,” but after correction has been made by the above-described method such that the coordinates zP of the lowest point PP in the Z-direction is brought constant, an actual amount of elongation of the printing pattern 29 in the X-direction may be obtained, and the scale factor thereof may be substituted into MxA. As described above, according to the correction method of the present invention, a printing method capable of obtaining, without the need for essential human experience, a correction value with high accuracy, less machine error, and excellent reproducibility can be provided.
Note that the correction parameters are not necessarily limited to only the functional types defined in Expressions (1) to (4), and for example, higher-order correction may be made, for example, using the correction parameters as the function of p.
Under the following conditions, overprinting was actually performed (the same pattern was printed in an overlapping manner). Results are shown in
Example 1 is an example in a case (results are shown in
Example 2 is an example in a case where the input values of Expressions (1) to (4) for the trochoid curve control were machine design values (specifically, R=2000 mm, L=320 mm, WA=160 mm, HA=90 mm, WB=160 mm, and HB=90 mm) and printing was performed by swinging the arc table 23 by trochoid control without correction except that ΔR=1.264 mm was set as a correction parameter for taking the thickness of the transfer sheet 31 into consideration.
A comparative example is an example in a case where printing was performed using a printing device different from those of the examples by normal control in which a circular columnar roll having a diameter of 255 mm is rotated in synchronization with translation of various tables. In this case, in order to reduce misalignment as much as possible, printing was performed after the printing pressure in the receiving step and the transfer step had been carefully adjusted with the circular columnar roll synchronized with translation of various tables.
In Example 1, Example 2, and the comparative example, printing was performed, in which a complementary pattern in the shape of a grid with a pitch of 5 mm is overprinted using nano silver ink by reverse offset printing on a chrome pattern of a photomask in the form of a grid with a pitch of 5 mm. As the printing plate 22, a silicon wafer embossed by dry etching was used. The photomask was aligned, and it was confirmed such that an error due to alignment is sufficiently small. The positions of the centers of gravity of the photomask pattern and the printing pattern were determined by image analysis, and misalignment was measured for the pattern at each grid point. Assuming that misalignment in the X-direction at each grid point defined when an address in the X-direction is i and an address in the Y-direction is j is Δxi,j and misalignment in the Y-direction is Δyi,j, the square root of the mean squared error was obtained:
Here, n=ij is the total number of grid points, and in this pattern, 324.
is the average of Δxi,j and the average of Δyi,j. RMSEx<0.7 μm and RMSEy<0.7 μm were taken as acceptable.
From Table 3, Example 1 is the most preferable. Since the arc table 23 was controlled by the corrected trochoid control, there was almost no misalignment.
In Example 2, misalignment was slightly caused as compared to Example 1.
In the comparative example, since rotation of the circular columnar roll and translation of the table are merely synchronized with each other, misalignment due to uneven rotation was caused, and misalignment in a direction in which printing progresses was particularly great.
ΔzB = 0
In the printing device 100 of the embodiment, printing can be performed with favorable position accuracy because of the following reasons.
(1) Since not the circular columnar roll but the arc table is used, the curved surface with a great curvature radius can be used and the misalignment of the printing pattern 29 due to the printing pressure is reduced. The circular columnar roll having the curved surface with a great curvature radius is heavy.
(2) The circular columnar roll is not rolled by the rotation mechanism. The error caused in proportion to the curvature radius of the circular columnar roll, such as an angular transmission error or angular velocity variation, is eliminated, and the misalignment of the roll surface due to such an error is eliminated.
(3) The number of shafts for controlling the arc swing is great, and correction is facilitated.
(4) The entire printing step can be performed on one conveyor 16.
(5) During the receiving step and the transfer step, only the arc table 23 is moved, and the printing plate table 12 and the substrate table 15 are fixed. There is no need for the control in which rotation of the circular columnar roll and translation of the printing plate table are synchronized with each other, which is necessary for the mechanism that rotates the circular columnar roll.
The above-described embodiments can be combined.
The transfer sheet 31 is set on the arc table 23, and the printing plate 22 is set on the printing plate table 12. However, the transfer sheet 31 may be set on the printing plate table 12, and the printing plate 22 may be set on the arc table 23. In this case, the printing plate 22 is a printing plate having the printing pattern 29. The ink is supplied from the transfer sheet 31 to the printing plate 22, and the pattern is printed onto the target 25 from the printing plate 22.
Note that in the trochoid control, the circle moves, but an ellipse may move. In this case, the ratio or sizes of the long side and short side of the ellipse are adjusted so that printing can be performed with higher accuracy.
In the above-described embodiments, the transfer sheet 31 is set on the arc table 23, the target 25 is set on the substrate table 15, and the ink of the transfer sheet 31 is transferred onto the target 25.
However, the transfer sheet 31 may be set on the substrate table 15, the target 25 may be set on the arc table 23, and the ink of the transfer sheet 31 may be transferred onto the target 25. In this case, the printing pattern 29 needs to be formed in the transfer sheet 31 on the substrate table 15. For example, a uniform ink layer may be formed on the transfer sheet 31, and the ink other than the printing pattern 29 may be removed by the printing plate 22. The die coater 21 and the printing plate table 12 can be positioned above the transfer sheet 31. Alternatively, for example, the printing pattern 29 may be formed at another position in the transfer sheet 31 on the substrate table 15, and the substrate table 15 may be disposed on the conveyor 16.
The printing device of the invention of the present application can be used for manufacturing various devices, such as electrode formation. The reverse offset printing has been described in detail, but the mechanism that performs printing by swinging the arc by the trochoid control is also applicable to other transfer printing methods in nature. The device configuration is changed as necessary so that the printing device can also be used, e.g., for relief printing, flexographic printing, adhesion contrast printing, and gravure offset printing.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2022-033170 | Mar 2022 | JP | national |
This application is the U.S. national phase of International Application No. PCT/JP2023/007220 filed Feb. 28, 2023 which designated the U.S. and claims priority to JP 2022-033170 filed Mar. 4, 2022, the entire contents of each of which are hereby incorporated by reference.
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/JP2023/007220 | 2/28/2023 | WO |