1. Field of the Invention
The present invention relates to a probe that is used as a photoacoustic probe and includes a capacitive electromechanical transducer having an optical reflection member, and an object information acquisition apparatus using the same.
2. Description of the Related Art
Conventionally, micro-machine components manufactured by micromachining technologies can be processed in a micrometer order. Use of these components has realized various micro-functional elements. Capacitive electromechanical transducers using these technologies have been studied as alternatives to electromechanical transducers adopting piezoelectric elements. Such a capacitive electromechanical transducer can transmit and receive acoustic waves, such as ultrasonic wave, (hereinafter, may be typified as “ultrasound”) through use of a vibration film. Particularly, in liquid, excellent wide-band characteristics can be easily acquired. In this specification, the acoustic waves are any of sound waves, ultrasonic wave, and photoacoustic waves. For instance, the photoacoustic waves are caused by irradiating the inside of an object with light (electromagnetic waves), such as visible or infrared light.
Meanwhile, there is a capacitive micromachined ultrasonic transducer that irradiates a measurement target (object) with illumination light and receives photoacoustic waves emitted from the inside of the object (Japanese Patent Application Laid-Open No. 2010-075681). This transducer includes an optical reflection member for reflecting light. The optical reflection member is disposed on a receiving surface for receiving photoacoustic waves. The optical reflection member has a configuration of covering the entire receiving surface. Furthermore, there is a capacitive micromachined ultrasonic transducer including a protection film (Japanese Patent Application Laid-Open No. 2009-272824). This transducer has a configuration including the protection film on an upper electrode. The protection film may be made of insulating organic material.
The capacitive micromachined ultrasonic transducer receiving photoacoustic waves can suitably include the optical reflection member. The optical reflection member includes a support layer and a reflection layer. However, formation of the reflection layer on the support layer sometimes warps the optical reflection member. A resin film is employed as the support layer; a suitable film has an acoustic impedance close to that of an object. The acoustic impedance is defined as the product between a density and a sonic velocity. Instead, the acoustic impedance can be represented using a modulus of volume elasticity, a stiffness modulus and a density. The resin film having an acoustic impedance close to that of the object tends to have a low density and a low stiffness. Accordingly, formation of a metal film, which is to be the reflection layer, on the support layer sometimes warps the support layer. The warp of the support layer may exfoliate the optical reflection member. In particular, in the case where an acoustic impedance matching layer is provided between the support layer and the element, the adhesive property between the acoustic impedance matching layer and the support layer is insufficient. Accordingly, there is a possibility that the optical reflection member exfoliates.
To solve the problem, the present invention has an object to provide a probe that includes an optical reflection member having low warp.
A probe of the present invention to solve the problem is a probe receiving an acoustic wave from an object, including: an element having at least one cell in which a vibration film containing one electrode out of two electrodes that are provided so as to interpose a space therebetween is supported in a manner allowed to vibrate owing to the acoustic wave; an optical reflection layer that is provided closer to the object than the element is; a support layer that is provided closer to the element than the optical reflection layer is, and supports the optical reflection layer; and a warp suppressing layer to suppress the warp of the support layer, that is provided on at least one of a surface of the support layer closer to the optical reflection layer and a surface of the support layer closer to the element.
Further features of the present invention will become apparent from the following description of exemplary embodiments with reference to the attached drawings.
Preferred embodiments of the present invention will now be described in detail in accordance with the accompanying drawings.
A probe of this embodiment includes a capacitive electromechanical transducer as a detection unit of receiving acoustic waves from an object. An optical reflection member provided on the vibration film (i.e., on a side that is closer to the object than the element is) includes a warp suppressing layer provided on at least one of surfaces of a support layer made of resin and an optical reflection layer and both surfaces of the support layer. In this configuration, the support layer has a sufficiently high acoustic wave transparency, and the optical reflection layer of the optical reflection member that is for reflecting irradiation light on an object and scattered light thereof has a sufficiently high optical reflectivity. The warp suppressing layer has a sufficiently high acoustic wave transparency and an appropriate hardness (Young's modulus), and can be provided at a position suppressing the warp of the optical reflection member (particularly, the support layer) owing to the stiffness. To suppress the warp, for instance, a thin film that is made of hard material, i.e., inorganic material, such as SiO2, and provided on at least one of both the surfaces of the support layer can be employed. For instance, a cell of the electromechanical transducer includes: a second electrode formed, via a space, on a first electrode formed in contact with a substrate; a vibration film on which the second electrode is provided; and a vibration film supporter that supports the vibration film such that a space is formed between the first electrode and the vibration film. The cell can be fabricated according to a method of manufacturing any of types called a sacrificial layer type and a bonding type. An example of
Next, an example of a photoacoustic probe according to the present invention will be described. FIG. 6 is a schematic diagram of the photoacoustic probe. The probe includes: a device substrate 400 including a CMUT (Capacitive Micromachined Ultrasonic Transducer) as an ultrasonic sensor; an acoustic impedance matching layer 402 having functions of protecting the CMUT and transmitting ultrasonic wave 416; and an optical reflection member 404 for reflecting a laser beam 414 at a high reflectance. These components are accommodated in a case 406. The case 406 and the optical reflection member 404 are sealed to each other with adhesive 408, which prevents an acoustic medium 410 from entering the case 406.
The capacitive electromechanical transducer included in the probe of the embodiment of the present invention will be described.
As illustrated in
The probe of this embodiment can be formed using the method of manufacturing a bonding type. A cell 7 having the bonding type configuration illustrated in
A principle of driving the probe of this embodiment will be described. The cell is formed of the first electrode 2 and the vibration film that interpose the space 5. Accordingly, to receive acoustic waves, a direct current voltage is applied to one of the first electrode 2 and the second electrode 6. When the acoustic waves are received, the acoustic waves vibrate the vibration film to change the distance (height) of the space. Accordingly, the capacitance between the electrodes is changed. The change in capacitance is detected from one of the first electrode 2 and the second electrode 6, thereby allowing the acoustic waves to be detected. The element can also transmit acoustic waves by applying an alternating voltage to one of the first electrode 2 and the second electrode 6 to vibrate the vibration film.
Referring to
For instance, the CMUT substrate 100 includes a membrane made of one of Si and SiN on a cavity formed on an Si substrate. The acoustic impedance matching layer 102 is formed on an element 8 of the CMUT substrate 100 (specifically, on the vibration film including the membrane), and has a function of protecting the membrane, and a function of efficiently transmitting ultrasonic wave 116 from the optical reflection member 110 to the CMUT substrate 100. The acoustic impedance matching layer 102 can suitably be made of what has a low Young's modulus that does not largely change mechanical characteristics, such as the spring constant of the membrane. More specifically, a suitable Young's modulus is 50 MPa or less. The Young's modulus of 50 MPa or less alleviates adverse effects on the vibration film due to the stress of optical reflection layer 11. Since the stiffness (Young's modulus) is sufficiently low, the substantial mechanical property of the vibration film 4 is not changed. Furthermore, the acoustic impedance matching layer 102 is suitably made of material having an acoustic impedance equivalent to that of the membrane. More specifically, the suitable acoustic impedance ranges from 1 MRayls to 2 MRayls, inclusive (1 MRayls=1×106 kg·m−2·s−1). For instance, such an acoustic impedance matching layer may be made of polydimethylsiloxane (PDMS). Furthermore, any of PDMS to which silica particles are added, fluorosilicone in which part of hydrogens of PDMS are replaced with fluorines, and fluorosilicone to which silica particles are added can be adopted. Addition of silica particles is adjusted to efficiently transmit ultrasonic wave.
The optical reflection layer 108 is for reflecting a laser beam 114, and provided closer to an object than the element 8 is. More specifically, this layer reflects light emitted on the object and the scattered light. Especially in the case of diagnosing a living body, a near-infrared region of wavelengths from 700 to 1000 nm is often used as the laser beam 114. The optical reflection layer 108 can use a metal film having a high reflectance (suitably, 80% and more, and more suitably 90% and more) in the wavelength region (e.g., 700 to 1000 nm) to be used. For example, a film of one of Au, Ag and Al can suitably be used.
The suitable film thickness of the optical reflection layer 108 can be equal to or less than 1/30 of the wavelength of acoustic waves. More specifically, the thickness can be equal to or less than 10 μm in consideration of acoustic impedance. For instance, Au has a high acoustic impedance of about 63×106 [kg·m−2·s−1] (=63 MRayls). Accordingly, to prevent reflection of ultrasonic wave due to acoustic impedance inconsistency, the thickness is required to be sufficiently small. The suitable thickness of Au is equal to or less than 10 μm. In actuality, in consideration of cost, the suitable thickness is between 0.1 and 1 μm, inclusive. Moreover, a dielectric multilayer film is formed on the metal film made of Au can be formed thereby allowing the reflectance to be further improved. The optical reflection layer may be a dielectric multilayer film.
The support layer 104 is a layer for supporting such an optical reflection layer 108, and provided closer to the element 8 than the optical reflection layer 108 is. The optical reflection layer 108 can be formed directly on the acoustic impedance matching layer 102. However, this reflection layer can suitably be formed on the support layer 104. The acoustic impedance matching layer 102 is made of material having a low Young's modulus. Accordingly, in the case of forming the optical reflection layer 108 directly on the acoustic impedance matching layer, there is a possibility that the stress from the optical reflection layer deforms the acoustic impedance matching layer. The acoustic impedance matching layer 102 is made of material having a low Young's modulus. It is therefore difficult to reduce the surface roughness. Furthermore, it is difficult to increase the reflectance of the optical reflection layer on the acoustic impedance matching layer. Thus, the optical reflection layer 108 can be suitably formed on the support layer 104 having a higher stiffness than the acoustic impedance matching layer 102. More specifically, the acoustic impedance of the support layer 104 can be between 1 and 5 MRayls, inclusive. The Young's modulus of the support layer 104 is larger than that of the acoustic impedance matching layer 102, and more specifically, between 100 MPa and 20 GPa, inclusive. The acoustic impedance of the support layer 104 is configured close to the value of the acoustic impedance of the acoustic impedance matching layer 102, thereby allowing the amount of reflection of acoustic waves to be reduced at the interface between the support layer 104 and the acoustic impedance matching layer 102. Material suitable for support layer 104 is material that has an acoustic impedance equivalent to that of the acoustic medium and a favorable ultrasound transparency. For instance, olefin resin can be suitably adopted. Among olefin resins, polymethylpentene resin can be suitably adopted. In consideration of forming the optical reflection layer and adhesion to the CMUT substrate 100, appropriate flexibility of support layer 104 is suitable. What have a thickness of about 10 to 150 μm can suitably be used.
The warp suppressing layer 106 is a layer provided for suppressing the warp of the support layer 104 and suppresses the warp of the support layer in the case of forming the optical reflection layer on the support layer, i.e., the Young's modulus of the warp suppressing layer 106 is more than the Young's modulus of the support layer 104. Meanwhile, the warp suppressing layer 106 has a sufficiently small thickness with respect to the wavelength of ultrasonic wave to achieve a favorable ultrasound transparency. More specifically, the suitable thickness of the warp suppressing layer 106 is equal to or less than 100 μm. However, in the case of using material having a high acoustic impedance, the suitable thickness is equal to or less than 10 μm. The more suitable thickness is equal to or less than 1 μm. The suitable Young's modulus of the warp suppressing layer 106 is equal to or more than 100 MPa. The more suitable Young's modulus is equal to or more than 1 GPa. The further suitable Young's modulus is equal to or more than 20 GPa. To achieve the feature, hard material that is any of inorganic materials, such as SiO2 (silicon oxide), Al2O2 (aluminum oxide), TiO2, ZnO, TiN, SiN and AlN, can be suitably adopted. For instance, the thin film includes at least any of silicon oxide and aluminum oxide. Furthermore, for instance, silicon oxide can be formed into a film by one of a CVD method and a sputtering method. The warp suppressing layer suppresses the warp of the optical reflection member owing to the stiffness. The warp suppressing layer can be disposed between the optical reflection layer and the support layer (i.e., the surface of the support layer facing the optical reflection layer). Instead, the warp suppressing layer can be disposed on the surface of the support layer other than that facing the optical reflection layer (i.e., the surface of the support layer facing the element).
Furthermore, the warp suppressing layers can be suitably disposed symmetrically with respect to the support layer. In a certain optical reflection member, the warp suppressing layers can be disposed on both the surfaces of the support layer, and the optical reflection layer can be provided. In another optical reflection member, the warp suppressing layers are disposed on both the surfaces of the support layer, and the optical reflection layer can be stacked thereon.
Examples of the present invention will hereinafter be described.
Next, an oxygen plasma process is applied to the undersurface of the support layer 304. Subsequently, fluorosilicone resin (made by Shin-Etsu Silicone) is applied into a thickness of 50 μm as the acoustic impedance matching layer 302 by a printing method. The CMUT substrate 300 is stacked thereon, and thermoset at 125° C., thereby allowing the acoustic impedance matching layer 302 and the CMUT substrate to adhere to each other and allowing the acoustic impedance matching layer 302 and the support layer to adhere to each other. The warp of the thus formed optical reflection member is suppressed in comparison with the case without the warp suppressing layer. After adhesion, the optical reflection member does not exfoliate.
Example 3 will be described. According to this example, in the configuration in
The probe including the electromechanical transducer described in the embodiments and the examples is applicable to an object information acquisition apparatus using acoustic waves. Acoustic waves from an object are received by the electromechanical transducer. Through use of an output electric signal, object information in which an optical property value of the object, such as the optical absorption coefficient, is reflected can be acquired.
The probe of the present invention includes a warp suppressing layer, such as a thin film layer made of inorganic material that suppresses the warp of the optical reflection member on the receiving surface of the capacitive electromechanical transducer. Accordingly, exfoliation of the optical reflection member due to the warp of this optical reflection member can be suppressed. In the case where a acoustic impedance matching layer is provided on a receiving surface, variation in thickness of the protection film caused by the warp of the acoustic impedance matching layer of the optical reflection member can be reduced. This reduction allows the probe including the optical reflection member to stably receive acoustic waves.
While the present invention has been described with reference to exemplary embodiments, it is to be understood that the invention is not limited to the disclosed exemplary embodiments. The scope of the following claims is to be accorded the broadest interpretation so as to encompass all such modifications and equivalent structures and functions.
This application claims the benefit of Japanese Patent Application No. 2012-083419, filed Mar. 31, 2012, and Japanese Patent Application No. 2013-040133, filed Feb. 28, 2013, which are hereby incorporated by reference herein in their entirety.
Number | Date | Country | Kind |
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2012-083419 | Mar 2012 | JP | national |
2013-040133 | Feb 2013 | JP | national |