Patent Application
20130239810
1. Technical Field
The invention pertains to the technical field of coal chemical engineering, and in particular, relates to a process for optimized combination of purification and separation of MTO reaction gas containing catalyst fine powder. Specifically, the invention relates to a process for scrubbing, purifying and cooling MTO reaction gas containing catalyst fine powder, separating and recovering the mist entrained in reaction gas exiting a scrubbing tower (quench tower/water scrubbing tower) and catalyst fine powder that is not scrubbed off, purifying and recycling scrubbing liquid containing catalyst (quench water/scrubbing water), and recovering catalyst fine powder in solid particle form from scrubbing liquid (quench water/scrubbing water). The invention further relates to an apparatus for optimized combination of purification and separation of MTO reaction gas containing catalyst fine powder.
2. Background
MTO (Methanol To Olefins) refers to a technology for manufacturing lower olefin (ethylene, propylene, butene, etc.) from methanol, the main principle of which is production of methanol from synthetic gas originating from coal, and subsequent conversion of methanol to lower olefin (with ethylene and propylene as the major components). Lower olefin is the most important fundamental raw material for organic chemical engineering, with vigorous market demand. The traditional production approach of lower olefin (by cracking refined oil to produce light hydrocarbons and naphtha) is to be challenged by the tight supply of raw material due to depleting oil resource and stubbornly high oil price. Successful industrialization of MTO technology would open a totally new technical route for modern coal chemical engineering. Owing to resource and economic advantages, this technology is quite significant for energy development. The reaction part of MTO comprises a reactor and a regenerator, and the product purifying part comprises a quench tower, a water scrubbing tower, an alkali scrubbing tower and a drying tower, with the remaining being the product separation part. The reactor commonly used is a fluid bed reactor in which methanol as the reactant and the olefin products are present in gas phase, and the reaction gas entraining catalyst goes to the product purifying part after passing through three or four levels of cyclone separators at the top of the reactor. Due to the limitation of the cyclone separators, the reaction gas still entrains a small amount of catalyst fine powder with particle size of less than 10 m or 5 m even after it has been separated by cyclone separation. The catalyst fine powder has to be removed effectively at the product purifying part. Moreover, MTO catalyst is relatively expensive. Thus, it is desirable to recover the catalyst by an effective means.
U.S. Pat. No. 6,166,282 discloses a MTO fluid bed reactor wherein a set of cyclone separators are installed on the top of the reactor to separate solid catalyst particles from the product effluent and thus prevent the catalyst particles from being carried out of the reactor. Albeit the reaction gas stream passes through several cyclone separating devices, there are still catalyst particles that leave the reactor together with the product effluent. In a quench tower and a water scrubbing tower, this catalyst fine powder is separated from the reaction gas product along with the quench water and the scrubbing water respectively, and enters the water circulating system with the quench water and the scrubbing water, leading to abrasion and clogging of downstream devices, as well as shortened operating cycle of the apparatus.
U.S. Pat. No. 5,744,680A discloses a process for preparing light hydrocarbons from oxides wherein the stream containing catalyst is discharged in a wet scrubbing step. U.S. Pat. No. 6,870,072 also discloses removal of catalyst from a product effluent using a wet scrubbing zone. This patent application uses a method wherein a concentrated liquid containing catalyst is discharged from the apparatus. This not only results in waste of scrubbing liquid (quench water/scrubbing water), but also fails in effective recovery of catalyst fine powder.
For MTO quench water, U.S. Pat. No. 0,234,281 and CN 1942558A disclose an apparatus combining one or more solid-liquid cyclone separators or hydrocyclone separators working in series or in parallel, to separate and recycle catalyst. Since the product stream from the reactor has already passed through several gas-solid cyclone separating devices in the reactor, the particle size of the catalyst particles in the MTO quench water is quite small (typically no more than 5 μm), and the particles in the scrubbing water are even smaller (smaller than 3 μm). However, the size of the particles that can be captured effectively by a conventional solid-liquid cyclone or hydrocyclone separator is about 5-10 μm. This means that the apparatus can only remove the catalyst which runs off under abnormal operating conditions wherein the cyclone separators on the top of the reactor fail or work unsteadily, etc. In other words, solid particles smaller than 5 μm are difficult to remove under normal operating conditions of the cyclone separators when the facility runs steadily. Therefore, the solid-liquid cyclone or hydrocyclone separators in the above mentioned patent applications can only be used in an accident of catalyst run-off, and the predicted effect does not occur in normal operation.
All of the foregoing patent applications relate to a process or apparatus for controlling the catalyst fine powder entrained in the reaction gas or purifying the scrubbing liquid (quench water/scrubbing water) after the reaction gas entraining catalyst fine powder is scrubbed. An economic and effective process featuring simple operation and long operating cycle for purifying and cooling reaction gas entraining catalyst fine powder, separating, clarifying and recycling scrubbing liquid (quench water/scrubbing water), and recovering and reusing catalyst fine powder in solid form is not available yet in the art.
Therefore, it is an urgent need in the art to develop an economic and effective process featuring simple operation and long operating cycle for purifying and cooling reaction gas entraining catalyst fine powder, separating, clarifying and recycling scrubbing liquid (quench water/scrubbing water), and recovering and reusing catalyst fine powder in solid form.
The invention provides a novel process and apparatus for optimized combination of purification and separation of MTO reaction gas containing catalyst fine powder, so as to overcome the drawbacks in prior art.
In one aspect, the invention provides a process for optimized combination of purification and separation of MTO reaction gas containing catalyst fine powder, comprising:
(a) scrubbing, purifying and cooling the MTO reaction gas containing catalyst fine powder, and separating and recovering the mist entrained in the scrubbed reaction gas and the catalyst fine powder that is not scrubbed off;
(b) subjecting the scrubbing liquid containing catalyst fine powder to solid-liquid separation, and the purified scrubbing liquid after separation to repeated use after subsequent heat exchange and stripping treatment; and
(c) subjecting the scrubbing liquid containing catalyst fine powder to solid-liquid separation, and further concentrating the scrubbing liquid containing catalyst fine powder after separation before the catalyst fine powder is recovered in solid form by centrifugal dewatering or drying.
In an embodiment, the catalyst fine powder entrained in the MTO reaction gas containing catalyst fine powder has a content of 1-500 mg/m3 and a particle size of 0.1-30 μm, and the catalyst skeletal density is 1.1-3 kg/m3.
In another embodiment, the scrubbing, purification and cooling of the MTO reaction gas containing catalyst fine powder is carried out by spray scrubbing with atomized liquid drops or dynawave scrubbing; and, the separation and recovery of the mist entrained in the scrubbed reaction gas and the catalyst fine powder that is not scrubbed off is carried out using a cyclone tube or a cyclone plate.
In another embodiment, the solid-liquid separation of the scrubbing liquid containing catalyst fine powder is carried out by micro-cyclone separation or filtration, wherein the solid content of the scrubbing liquid before separation is 30-400 mg/L, and that after separation is 10-50 mg/L.
In another embodiment, the purified scrubbing liquid after separation is reused after removing methanol by subsequent heat exchange, stripping and cooling, and the scrubbing liquid containing catalyst fine powder after separation is further concentrated, wherein the scrubbing liquid containing catalyst fine powder after separation is 1-10 vol. % of the flow of the scrubbing liquid containing catalyst fine powder.
In another embodiment, the scrubbing liquid containing catalyst fine powder after separation is further concentrated to a solid content of 30-70 vol. % by coupled separation of micro-cyclone separation with gravity settling or micro-cyclone separation with filtration and gravity settling.
In another embodiment, the concentrated scrubbing liquid containing catalyst fine powder after separation with a solid content of 30-70 vol. % is dried or dewatered in a centrifuge, wherein the drying is spray granulation drying or steam rotary tube drying, the dried catalyst is recovered, and the dried gas is sent to a torch or recovered after condensed.
In another embodiment, after the concentrated scrubbing liquid containing catalyst fine powder after separation with a solid content of 30-70 vol. % is dried, the water content of the catalyst particles is no more than 5 vol. %; alternatively, after the concentrated scrubbing liquid containing catalyst fine powder after separation with a solid content of 30-70 vol. % is dewatered in a centrifuge, the water content of the catalyst particles is no more than 10 vol. %.
In another embodiment, using this method, more than 99% of the catalyst particles in the MTO reaction gas containing catalyst fine powder is removed, more than 98% of the purified scrubbing liquid after separation is recycled, more than 96% of the catalyst fine powder in the scrubbing liquid containing catalyst fine powder after separation is recovered, and the energy consumption for operating the system is no more than 0.6 MPa.
In another aspect, the invention provides an apparatus for optimized combination of purification and separation of MTO reaction gas containing catalyst fine powder, comprising:
a scrubbing tower for scrubbing, purifying and cooling the MTO reaction gas containing catalyst fine powder;
a gas-solid/liquid separator for separating and recovering the mist entrained in the scrubbed reaction gas and the catalyst fine powder that is not scrubbed off;
a micro-cyclone clarifier for solid-liquid separation of the scrubbing liquid containing catalyst fine powder;
a heat exchanger and a stripper for subsequent heat exchange and stripping of the purified scrubbing liquid after separation;
a micro-cyclone concentrator for concentrating the scrubbing liquid containing catalyst fine powder after separation; and
a centrifugal dehydrator or dryer for recovering the catalyst fine powder in solid form.
This summary provides only a general outline of some embodiments of the invention. Many other objects, features, advantages and other embodiments of the invention will become more fully apparent from the following detailed description, the appended claims and the accompanying drawings.
A further understanding of the various embodiments of the present invention may be realized by reference to the figures which are described in remaining portions of the specification. In the figures, like reference numerals are used throughout several figures to refer to similar components. In some instances, a sub-label consisting of a lower case letter is associated with a reference numeral to denote one of multiple similar components. When reference is made to a reference numeral without specification to an existing sub-label, it is intended to refer to all such multiple similar components.
After extensive and intensive study, the inventors have made the following findings. For the catalyst fine powder entrained in MTO reaction gas during purifying operation, which is characterized by small particle size (1-10 m under normal operation state and 1-50 m under abnormal state), small amount of solid particles and high demand for purification (no less than 98% of the catalyst particles are required to be removed), a scrubbing-cycloning coupled separation method is first used to separate the catalyst fine powder entrained in the reaction gas. Since the catalyst fine powder entrained in the reaction gas is the catalyst fine powder that can not be separated by the third stage cyclone in a catalytic cracking unit, and the reaction gas has high flow and high temperature, neither an electrostatic method nor a precision filtration method can be used to remove the dust (catalyst particles). Therefore, the catalyst fine powder has to be removed by a wet scrubbing method. Study on the phenomenon that the catalyst particles which have not been scrubbed off will be encapsulated by liquid membrane during scrubbing has enlightened the inventors on the use of a gas-liquid cyclone separation method to separate the mist and catalyst particles entrained in the reaction gas before it leaves the scrubbing tower (quench tower/water scrubbing tower), as further separation of the reaction gas. Secondly, as to the purification process of the scrubbing liquid (quench water/scrubbing water), study has been made on the characteristics of the scrubbing liquid (quench water/scrubbing water), a solid-liquid system which has high operating flux and small solid particle size (1-10 μm, most smaller than 5 μm), and it has been found that the most cost-effective method is the use of a cyclone separator. However, due to its cut diameter which is larger than 5 μm, it is very difficult for a conventional cyclone or hydrocyclone separator to remove solid particles smaller than 5 μm under normal operating conditions. On the other hand, a high precision backwash filter with a separation precision of 1-2 μm has the problems of high manufacturing cost, large occupation area, easy clogging and the like, leading to undesirable effect of use under such operating conditions. Fortunately, a micro-cyclone separator has the advantages of wide applicability, simple structure, strong adaptability, easy maintenance, high reliability, etc. Its separation efficiency (d75<3 μm) is much higher than that of a common cyclone separator. A micro-cyclone separator predominates over both a high-speed centrifugal separator and a precision backwash filter in investment cost, maintenance, operating cost, etc. Therefore, micro-cyclone separation technology is used to purify and separate scrubbing liquid (quench water/scrubbing water), so as to recycle the purified scrubbing liquid (quench water/scrubbing water). Thirdly, in response to the requirements of economy, high efficiency and operational simplicity, a coupled separation method of micro-cyclone concentration plus gravity settling is used to concentrate the catalyst concentrated liquid. Finally, the catalyst concentrated liquid is dewatered by drying or centrifugal separation to achieve recovery of the catalyst particles in solid form. The present invention has thus been accomplished on the basis of the foregoing findings.
In a first aspect of the invention, there is provided a method for purifying and separating MTO reaction gas containing catalyst fine powder, purifying scrubbing liquid (quench water/scrubbing water) and recovering catalyst fine powder, comprising:
scrubbing, purifying and cooling the MTO reaction gas containing catalyst fine powder, and separating and recovering the mist entrained in the scrubbed reaction gas before it leaves the scrubbing tower (quench tower/water scrubbing tower) and the catalyst fine powder that is not scrubbed off, so as to purify the reaction gas containing catalyst fine powder;
subjecting the scrubbing liquid (quench water/scrubbing water) containing catalyst after the scrubbing to solid-liquid separation in a sealed enclosure, so as to remove the catalyst particles in the scrubbing liquid (quench water/scrubbing water);
treating the purified scrubbing liquid (quench water/scrubbing water) after the solid-liquid separation in subsequent devices and then recycling the liquid, so as to ensure the continuous and steady operation of subsequent heat exchangers and strippers;
further concentrating the concentrated liquid containing catalyst after the solid-liquid separation, so as to obtain higher concentration of catalyst slurry;
treating the further concentrated catalyst slurry by drying or centrifugal dewatering, so as to recover the catalyst fine powder in solid form;
sending the reaction gas generated by drying to a torch for burning or recovering it by condensation in a condenser; and
sending the purified scrubbing liquid (quench water/scrubbing water) generated in the process of centrifugal dewatering to the scrubbing tower (quench tower/water scrubbing tower) for repeated use.
Preferably, the particle content of the catalyst fine powder entrained in the MTO reaction gas is 1-500 mg/m3, the catalyst particle size is 0.1-30 m, and the catalyst skeletal density is 1.1-3 kg/m3.
Preferably, the purification and cooling of the reaction gas is carried out by scrubbing with atomized liquid drops or dynawave scrubbing.
Preferably, the mist entrained in the scrubbed reaction gas before it leaves the scrubbing tower (quench tower/water scrubbing tower) and the catalyst fine powder that is not scrubbed off may be separated and recovered using a cyclone gas-solid/liquid separator or a cyclone plate gas-liquid separator. During separation, since the solid particles are encapsulated by liquid membrane, fine catalyst particles smaller than 3 m may also be removed effectively, and the energy consumption for separation is no more than 0.005 MPa.
Preferably, no less than 99% of the catalyst particles are removed after the catalyst fine powder particles entrained in the MTO reaction gas are scrubbed and cyclone separated on top of the tower.
Preferably, all or part of the scrubbing liquid (quench water/scrubbing water) containing catalyst fine powder is first clarified, wherein the solid-liquid separation in the clarification process may be carried out by a micro-cyclone separation method.
Preferably, the solid-liquid separation in the clarification process of all or part of the scrubbing liquid (quench water/scrubbing water) containing catalyst fine powder may also be carried out by direct filtration separation using a high precision filter directly.
Preferably, the solid content of the scrubbing liquid (quench water/scrubbing water) is 30-400 mg/L before clarification, the solid content of the scrubbing liquid (quench water/scrubbing water) is 10-50 mg/L after clarification, and the energy consumption of the separation process is no more than 0.2 MPa.
Preferably, all of the scrubbing liquid (quench water/scrubbing water) containing catalyst fine powder is subjected to micro-cyclone separation or precision filtration separation, and the purified scrubbing liquid (quench water/scrubbing water) is sent to subsequent devices for heat exchange, stripping, etc. before returned for recycling.
Preferably, part of the scrubbing liquid (quench water/scrubbing water) containing catalyst fine powder is subjected to micro-cyclone separation or precision filtration separation, and the purified scrubbing liquid (quench water/scrubbing water) is returned to the upper part of the bottom liquid phase in the quench tower. After an equilibrium concentration is reached, the scrubbing liquid is sent to subsequent devices for heat exchange, stripping, etc. before returned for recycling.
Preferably, the catalyst-containing solid phase concentrated liquid resulting from the clarification process is further treated in a subsequent separation and concentration device, wherein the solid phase concentrated liquid is 1-10 vol. % of the flow of the scrubbing liquid (quench water/scrubbing water) for clarifying treatment.
Preferably, the catalyst-containing solid phase concentrated liquid may be further concentrated by a coupled separation method of micro-cyclone separation and gravity settling.
Preferably, the catalyst-containing solid phase concentrated liquid may also be further concentrated by a coupled separation method of micro-cyclone separation, filtration and gravity settling.
Preferably, the further concentration of the catalyst-containing solid phase concentrated liquid results in a catalyst slurry with a solid content of 30-70 vol. %, wherein the clear liquid generated in the separation process is returned to the bottom of the scrubbing tower (quench tower/water scrubbing tower), and the energy consumption of this separation process is no more than 0.25 MPa.
Preferably, the catalyst slurry of 30-70 vol. % is further dewatered so as to recover the catalyst in solid phase state.
Preferably, the dewatering process may be carried out by spray granulation drying or steam rotary tube drying, and the water content of the catalyst particles after the drying treatment is no more than 5%.
Preferably, the gas generated in the drying and dewatering process may be sent to a torch directly for burning.
Preferably, the gas generated in the drying and dewatering process may be alternatively condensed by a condenser and then returned to the scrubbing tower (quench tower/water scrubbing tower) for reuse.
Preferably, the dewatering process may be alternatively carried out by centrifugal dewatering, and the water content of the catalyst particles after dewatering is no more than 10 vol. %.
Preferably, the purified scrubbing liquid (quench water/scrubbing water) resulting from the centrifugal dewatering is returned to the scrubbing tower (quench tower/water scrubbing tower) for recycling.
Preferably, after a combinatorial separation process of micro-cyclone separation, precision filtration separation, gravity settling, drying dewatering or centrifugal dewatering, etc., more than 96% of the catalyst fine powder in the scrubbing liquid (quench water/scrubbing water) is recovered, and the energy consumption for operating the system is no more than 0.6 MPa.
Specifically, the method for purifying and separating MTO reaction gas containing catalyst fine powder, purifying scrubbing liquid (quench water/scrubbing water), and dewatering and recovering catalyst fine powder according to the invention comprises the following steps.
First, the MTO reaction gas containing catalyst fine powder is scrubbed with atomized liquid drops or dynawave, purified and cooled, wherein the content of the catalyst particles entrained in the reaction gas is 1-500 mg/m3, the catalyst particle size is 0.1-10 m, and the catalyst skeletal density is 2.1-2.5 kg/m3. Then, the mist entrained in the scrubbed reaction gas before it leaves the scrubbing tower (quench tower/water scrubbing tower) and the catalyst fine powder that is not scrubbed off are separated and recovered. The above processes remove no less than 99% of the catalyst fine powder particles entrained in the reaction gas.
Secondly, the catalyst that enters the scrubbing liquid (quench water/scrubbing water) is separated to prevent the catalyst fine powder entrained in the scrubbing liquid (quench water/scrubbing water) from entering and clogging subsequent devices for heat exchange, stripping, etc., and thus interfering the long cycle operation of the whole system. In this process, a micro-cyclone separation method is used to purify and separate 35% of the circulating scrubbing liquid (quench water/scrubbing water) (wherein the solid content of the circulating scrubbing liquid (quench water/scrubbing water) is 200-300 mg/L, that of the clarified and purified scrubbing liquid (quench water/scrubbing water) is 20-30 mg/L, and the energy consumption of the separation process is no more than 0.2 MPa). The clarified and purified liquid is returned to the upper part of the liquid phase space in the scrubbing tower (quench tower/water scrubbing tower), and then pumped to subsequent devices for heat exchange and stripping before it is returned for recycling (wherein the equilibrium concentration of the scrubbing liquid (quench water/scrubbing water) in the whole circulation system is about 210-230 mg/L).
Finally, the catalyst that enters the scrubbing liquid (quench water/scrubbing water) is separated and recovered, so that the environmental problem resulting from diffusion of fine solid particles is avoided, and recovery of relevant resource is achieved. In this process, the catalyst concentrated liquid generated in the micro-cyclone clarification is first further concentrated to a solid content of 30-70% by a coupled separation method of micro-cyclone concentration and gravity settling, and finally the resulting catalyst concentrated slurry is dewatered in a centrifuge. After dewatering, the catalyst particles (with a water content of no more than 10%) are recovered in solid form, and the clear scrubbing liquid (quench water/scrubbing water) generated during dewatering is returned to the scrubbing tower (quench tower/water scrubbing tower) for reuse.
Preferably, after the MTO reaction gas containing catalyst fine powder is treated by the wet scrubbing plus the cyclone liquid removal and then the micro-cyclone separation, no less than 99% of the catalyst fine powder particles entrained in the reaction gas are removed, and the energy consumption of the cyclone separation is no more than 0.005 MPa.
Preferably, no less than 90% of the catalyst fine powder is removed in the micro-cyclone separation process for purifying the scrubbing liquid (quench water/scrubbing water), and the separation precision is 1-2 m.
Preferably, after the micro-cyclone separation of the catalyst-containing scrubbing liquid (quench water/scrubbing water) that is 35% of the circulating amount of the scrubbing liquid (quench water/scrubbing water), the solid content of the final circulating scrubbing liquid (quench water/scrubbing water) is no more than 250 mg/L, and no less than 98% of the scrubbing liquid (quench water/scrubbing water) is recycled.
According to this flow, only a portion of the scrubbing liquid (quench water/scrubbing water) needs to be subjected to solid-liquid micro-cyclone separation, and a part of the quench water is drawn from the bottom of the scrubbing tower (quench tower/water scrubbing tower) to be put into circulation directly.
Now that a part of the solid particles are discharged from the apparatus all along with the discharge of a part of the solution in the scrubbing tower (quench tower/water scrubbing tower) for cyclone separation, the solid content of the circulating scrubbing liquid (quench water/scrubbing water) in the whole apparatus is kept at an equilibrium level to the extent that the requirement of circulating use is satisfied. This leads to reduced processing throughput of the micro-cyclone separator for the scrubbing liquid (quench water/scrubbing water) and lowered energy consumption for separation.
Since quench water is generally water that is atomized and sprayed for scrubbing and cooling, micro-cyclone separation of a part of the quench liquid may not only ensure that the solid content of the circulating scrubbing liquid (quench water/scrubbing water) is kept at a suitable equilibrium level, but also reduce the energy consumption for separation and the occupation area. Therefore,
According to some embodiments of the present invention, a coupled method of counter-current scrubbing and cyclone liquid removal is used to cool and purify MTO reaction gas containing catalyst fine powder, wherein the method takes advantage of the feature that the fine catalyst particles are encapsulated by the atomized liquid drops, so that the removal rate of the catalyst particles is promoted effectively. Secondly, a micro-cyclone separation method is used to separate and purify the circulating scrubbing liquid (quench water/scrubbing water), so that the efficiency of circulating use of the scrubbing liquid (quench water/scrubbing water) is enhanced, and the use cycle of the apparatus is prolonged. Finally, the concept of coupling stages of concentration and dewatering steps is used for effective recovery of the catalyst fine powder, leading to recovery of the resource, reduced investment and maintenance cost, as well as lowered energy consumption. According to the invention, a coupled process comprised of scrubbing/cooling and cyclone gas-solid (liquid) separation is used for treating MTO reaction gas containing catalyst fine powder, and a coupled process comprised of once clarification, twice concentration and final drying or centrifugal dewatering for recovery of the catalyst is used for treating scrubbing liquid (quench water/scrubbing water), so that the catalyst entrained in the MTO reaction gas can be removed effectively. In addition, the treatment processes are carried out in a sealed enclosure. Thus, the risk of methanol in the scrubbing liquid (quench water/scrubbing water) is eliminated, the continuous circulation of the scrubbing liquid (quench water/scrubbing water) is ensured, the catalyst fine powder is recovered efficiently, and the continuous and steady operation of subsequent devices for heat exchange and stripping is guaranteed. Owing to simple operation, low energy consumption and high recovery of resources, the invention is suitable for use in purification and separation processes for treating MTO reaction gas as well as other fume and reaction gas entraining fine solid particles. Based upon the disclosure provided herein, one of ordinary skill in the art will recognize other advantages either in place of the aforementioned or in addition to the aforementioned that may be achieved in accordance with different embodiments of the present invention.
All of the literatures mentioned in the invention are incorporated herein by reference, as if each of them were independently incorporated herein by reference. In addition, it is to be understood that, after reading the above teachings of the invention, persons skilled in the art can make various changes or modifications to the invention, and these equivalents are to be included in the scope defined by the appended claims as well.
It will be appreciated that various modifications can be made to the described embodiments without departing from the spirit and scope of the present invention. In conclusion, the invention provides novel systems, devices, methods and arrangements for optimized combination of purification and separation of MTO reaction gas containing catalyst fine powder. While detailed descriptions of one or more embodiments of the invention have been given above, various alternatives, modifications, and equivalents will be apparent to those skilled in the art without varying from the spirit of the invention. Therefore, the above description should not be taken as limiting the scope of the invention, which is defined by the appended claims.
| Number | Date | Country | Kind |
|---|---|---|---|
| 201010533902.3 | Nov 2010 | CN | national |
The present application claims priority to (is a national stage filing of) PCT Application PCT/CN2011/072708 filed Apr. 13, 2011. The entirety of each of the aforementioned reference is incorporated herein by reference for all purposes.
| Filing Document | Filing Date | Country | Kind | 371c Date |
|---|---|---|---|---|
| PCT/CN11/72708 | 4/13/2011 | WO | 00 | 11/26/2012 |
