Patent Application
20150377551
1. Field of the Invention
The present invention is generally related to processes and systems for recovering a liquid natural gas (“LNG”) from a hydrocarbon-containing gas. More particularly, the present invention is generally related to processes and systems for removing nitrogen from a hydrocarbon-containing gas and producing a LNG stream.
2. Description of the Related Art
Due to the increased demand for methane, unconventional gas sources have been increasingly utilized as feed streams to produce LNG. However, such unconventional gas sources can contain high concentrations of nitrogen, which can cause several operational problems as the gases are subjected to liquefaction in a LNG facility. For example, the presence of high concentrations of nitrogen in the gas feed streams can prevent the methane from fully condensing and can negatively affect the quality of the produced LNG stream.
Due to the commercial value of methane, it can be desirable in some cases to remove at least a portion of the nitrogen from the gas feed streams during processing. However, some conventional processes for removing nitrogen can only be commercially viable for certain types of feed streams depending on their nitrogen concentration. Furthermore, many of the conventional nitrogen removal processes are not particularly suited for removing smaller concentrations of nitrogen from gas feed streams during processing. Moreover, it can be difficult to regulate temperature and other operating conditions during many of these conventional nitrogen removal processes, which can negatively impact the ability to effectively remove nitrogen from the resulting LNG stream and to produce a specification LNG product.
Therefore, there is a need for processes and systems that can more effectively remove lower concentrations of nitrogen from hydrocarbon-containing gases when producing LNG.
One or more embodiments described herein concern a process for recovering methane from a hydrocarbon-containing gas. The process comprises: (a) cooling and at least partially condensing a feed stream comprising the hydrocarbon-containing gas to thereby provide a cooled feed stream, wherein the hydrocarbon-containing gas comprises in the range of 0.5 to 30 mole percent of nitrogen; (b) fractionating at least a portion of the cooled feed stream in a distillation column to thereby form a nitrogen-poor bottom stream and a nitrogen-rich overhead stream, wherein the fractionating occurs at a pressure in the range of 1 to 8 MPa and the nitrogen-rich overhead stream comprises at least 75 percent of the nitrogen originally present in the hydrocarbon-containing gas; and (c) recovering at least a portion of the nitrogen-poor bottom stream to thereby form an LNG-enriched stream.
One or more embodiments described herein concern a process for recovering methane from a hydrocarbon-containing gas. The process comprises: (a) cooling and at least partially condensing a feed stream comprising the hydrocarbon-containing gas to thereby provide a cooled feed stream, wherein the hydrocarbon-containing gas comprises in the range of 0.5 to 30 mole percent of nitrogen; (b) fractionating at least a portion of the cooled feed stream in a distillation column to thereby form a nitrogen-poor bottom stream and a nitrogen-rich overhead stream, wherein the nitrogen-rich overhead stream comprises at least 75 percent of the nitrogen originally present in the hydrocarbon-containing gas; (c) cooling at least a portion of the nitrogen-rich overhead stream to thereby form a cooled nitrogen-rich overhead stream; (d) separating the cooled nitrogen-rich overhead stream into a liquid reflux stream and a vapor byproduct; (e) introducing at least a portion of the liquid reflux stream into the distillation column; and (f) cooling at least a portion of the nitrogen-poor bottom stream to thereby form an LNG-enriched stream.
One or more embodiments described herein concern a facility for recovering methane from a hydrocarbon-containing gas. The facility comprises: (a) a primary heat exchanger having a first cooling pass disposed therein, wherein the first cooling pass is configured to cool the hydrocarbon-containing gas into a cooled hydrocarbon-containing gas; (b) a distillation column in fluid communication with the first cooling pass, wherein the distillation column comprises a first inlet to receive the cooled hydrocarbon-containing gas, wherein the distillation column is configured to separate the cooled hydrocarbon-containing gas into a nitrogen-rich overhead stream and a nitrogen-poor bottom stream; (c) a second cooling pass disposed within the primary heat exchanger in fluid communication with the distillation column, wherein the second cooling pass is configured to cool the nitrogen-poor bottom stream into an LNG-enriched liquid stream; (d) a third cooling pass disposed within the primary heat exchanger in fluid communication with the distillation column, wherein the third cooling pass is configured to cool the nitrogen-rich overhead stream into a cooled nitrogen-rich stream; (e) a reflux system in fluid communication between the third cooling pass and the distillation column, wherein the reflux system is configured to separate the cooled nitrogen-rich stream into a liquid reflux stream and a vapor byproduct; and (f) a single closed-loop mixed refrigeration cycle at least partially disposed within the primary heat exchanger.
Embodiments of the present invention are described herein with reference to the following drawing figures, wherein:
The following detailed description of embodiments of the invention references the accompanying drawing. The embodiments are intended to describe various aspects of the invention in sufficient detail to enable those skilled in the art to practice the invention. Other embodiments can be utilized and changes can be made without departing from the scope of the claims. The following detailed description is, therefore, not to be taken in a limiting sense. The scope of the present invention is defined only by the appended claims, along with the full scope of equivalents to which such claims are entitled.
The present invention is generally directed to processes and systems for removing nitrogen from a hydrocarbon-containing gas and recovering an LNG stream comprising methane. As described below, these processes and systems can utilize a refrigerant system to assist in the removal of nitrogen and recovery of methane from the hydrocarbon-containing gases. Although
Turning now to
As shown in
Depending on its source, the hydrocarbon-containing gas can comprise varying amounts of methane, nitrogen, hydrogen, carbon monoxide, and other hydrocarbons. For example, the hydrocarbon-containing gas can comprise at least 1, 5, 10, 15, or 25 and/or not more than 90, 80, 70, 60, 50, or 40 mole percent of methane. More particularly, the hydrocarbon-containing gas can comprise in the range of 1 to 90, 5 to 70, 10 to 60, 15 to 50, or 25 to 40 mole percent of methane. It should be noted that all mole percentages are based on the total moles of the hydrocarbon-containing gas.
Furthermore, in various embodiments, the hydrocarbon-containing gas can comprise at least 0.5, 1, 2, 3, or 5 and/or not more than 40, 35, 30, 20, or 15 mole percent of nitrogen. More particularly, the hydrocarbon-containing gas can comprise in the range of 0.5 to 40, 1 to 35, 2 to 30, 3 to 20, or 5 to 15 mole percent of nitrogen. In certain embodiments, the hydrocarbon-containing gas comprises lower concentrations of nitrogen in order to better facilitate the nitrogen removal process described below.
Additionally or alternatively, the hydrocarbon-containing gas can comprise at least 25, 40, or 50 and/or not more than 99, 90, or 75 mole percent of hydrogen. More particularly, the hydrocarbon-containing gas can comprise in the range of 25 to 99, 40 to 90, or 50 to 70 mole percent of hydrogen. In certain embodiments, the hydrocarbon-containing gas comprises little to no hydrogen. For example, the hydrocarbon-containing gas can comprise less than 10, 5, 1, or 0.5 mole percent of hydrogen.
In various embodiments, the hydrocarbon-containing gas can comprise little to no carbon monoxide. For example, the hydrocarbon-containing gas can comprise not more than 20, 10, 5, or 1 mole percent of carbon monoxide.
Furthermore, the hydrocarbon-containing gas can comprise some amount of C2-C5 components, which includes paraffinic and olefinic isomers thereof. For example, the hydrocarbon-containing gas can comprise less than 15, 10, 5, or 2 mole percent of C2-C5 components.
As shown in
The treated gas stream exiting pretreatment zone 16 via conduit 112 can then be routed to a dehydration unit 18, wherein substantially all of the residual water can be removed from the feed gas stream. Dehydration unit 18 can utilize any known water removal system, such as, for example, beds of molecular sieve. Once dried, the gas stream in conduit 114 can have a temperature of at least 5, 10, or 15° C. and/or not more than 100, 75, or 40° C. More particularly, the gas stream in conduit 114 can have a temperature in the range of 5 to 100° C., 10 to 75° C., or 15 to 40° C. Additionally or alternatively, the gas stream in conduit 114 can have a pressure of at least 1.5, 2.5, 3.5, or 4 and/or not more than 9, 8, 7.5, or 7 MPa. More particularly, the gas stream in conduit 114 can have a pressure in the range of 1.5 to 9, 2.5 to 8, 3.5 to 7.5, or 4 to 7 MPa.
As shown in
The hydrocarbon-containing feed gas stream passing through the cooling pass 22 of primary heat exchanger 20 can be cooled and at least partially condensed via indirect heat exchange with refrigerant and/or residue gas streams in respective passes 26 and 42, which are described below in further detail. During cooling, a substantial portion of the methane components in the feed gas stream can be condensed out of the vapor phase to thereby provide a cooled, two-phase gas stream in conduit 116. In one or more embodiments, at least 10, 25, 50, 60, 70, 80, or 90 percent of the total amount of methane introduced into primary exchanger 20 via conduit 114 can be condensed within cooling pass 22.
The cooled gas stream in conduit 116 can have a temperature of −5, −10, −20, or −30° C. and/or not colder than −200, −150, −100, or −75° C. More particularly, the cooled gas stream in conduit 116 can have a temperature in the range of −5 to −200° C., −10 to −150° C., −20 to −100° C., or −30 to −75° C. In certain embodiments, the cooled gas stream in conduit 116 can have a temperature of about −33° C. Additionally or alternatively, the cooled gas stream in conduit 116 can have a pressure of at least 1.5, 2.5, 3.5, or 4 and/or not more than 9, 8, 7.5, or 7 MPa. More particularly, the gas stream in conduit 116 can have a pressure in the range of 1.5 to 9, 2.5 to 8, 3.5 to 7.5, or 4 to 7 MPa.
As shown in
While in the reboiler 28, the cooled gas stream from conduit 116 can be further cooled by the liquid stream from conduit 118. For example, while in the reboiler 28, the temperature of the cooled gas stream from conduit 116 can be lowered by at least 10, 20, 30, 40, or 50° C. and/or not more than 100, 80, 70, or 60° C. More particularly, while in the reboiler 28, the temperature of the cooled gas stream from conduit 116 can be lowered in the range of 20 to 100° C., 30 to 80° C., 40 to 70° C., or 50 to 60° C.
Upon exiting the reboiler 28, the cooled gas stream in conduit 120 can have a temperature of at least −30, −50, −65, or −80 and/or not colder than −200, −175, −150, or −100° C. More particularly, the cooled gas stream in conduit 120 can have a temperature in the range of −30 to −200° C., −50 to −175° C., −65 to −150° C., or −80 to −100° C.
Furthermore, in various embodiments, the cooled gas stream in conduit 120 can have a pressure of at least 1.5, 2.5, 3.5, or 4.5 and/or not more than 9, 8, 7, or 6 MPa. More particularly, the gas stream in conduit 120 can have a pressure in the range of 1.5 to 9, 2.5 to 8, 3.5 to 7, or 4.5 to 6 MPa. It should be noted that the only pressure drop at this point in the system can be generally attributed to inefficiencies associated with the piping, heat exchanger, and other processing units.
Turning again to
The cooled gas stream in conduit 122 can have a temperature of at least −30, −50, −80, or −100 and/or not colder than −200, −175, −150, or −120° C. More particularly, the cooled gas stream in conduit 122 can have a temperature in the range of −30 to −200° C., −50 to −175° C., −80 to −150° C., or −100 to −120° C. In certain embodiments, the cooled gas stream in conduit 122 can have a temperature of about −110° C. Additionally or alternatively, the cooled gas stream in conduit 122 can have a pressure of at least 1.5, 2.5, 3.5, or 4.5 and/or not more than 9, 8, 7, or 6 MPa. More particularly, the gas stream in conduit 122 can have a pressure in the range of 1.5 to 9, 2.5 to 8, 3.5 to 7, or 4.5 to 6 MPa.
As shown in
In various embodiments, the distillation column 30 can be operable to separate at least 65, 75, 85, 90, or 99 percent of the methane present in the fluid streams introduced thereto. The distillation column 30 can operate at a pressure of at least 1, 1.5, 2, or 2.4 and/or not more than 7, 6, 5, or 4.2 MPa. More particularly, the distillation column 30 can operate at a pressure in the range of 1 to 7, 1.5 to 6, 2 to 5, or 2.4 to 4.2 MPa. In certain embodiments, the distillation column 30 can operate at a pressure of about 2.6 MPa or at a pressure of about 4.2 MPa depending on the nitrogen content of the hydrocarbon-containing gas used as the feed stream.
The temperature of the distillation column 30 can vary depending on the contents of the hydrocarbon-containing gas introduced into the system. In various embodiments, the top half of the distillation column 30 can operate at a temperature of at least −75, −100, −120, or −155° C. and/or not colder than −215, −200, −190, or −180° C. More particularly, the top half of the distillation column 30 can operate at a temperature in the range of −75 to −215° C., −100 to −200° C., −120 to −190° C., or −155 to −180° C. Furthermore, the bottom half of the distillation column 30 can operate at a temperature of at least −35, −50, −65, or −85° C. and/or not colder than −200, −175, −150, or −110° C. More particularly, the bottom half of the distillation column 30 can operate at a temperature in the range of −35 to −200° C., −50 to −175° C., −65 to −150° C., or −85 to −110° C.
As depicted in
As used herein, “nitrogen-poor” and “nitrogen-rich” refer to the nitrogen content of the separated components relative to the nitrogen content of the original component from which the separated components are derived. Thus, a nitrogen-rich component contains a greater mole percentage of nitrogen than the component from which it is derived, while a nitrogen-poor component contains a lesser mole percentage of nitrogen than the component from which it is derived. In the present case, the nitrogen-rich overhead stream contains a higher mole percentage of nitrogen compared to the stream from conduit 122, while nitrogen-poor bottom stream contains a lower mole percentage of nitrogen compared to the stream from conduit 122. The amounts of the nitrogen-rich overhead stream and the nitrogen-poor bottom stream can vary depending on the contents of the hydrocarbon-containing gas in conduit 110 and the operating conditions of the distillation column 30.
The nitrogen-poor bottom stream in conduit 124 can be in the form of a liquid and comprise a significant amount of methane. For example, the nitrogen-poor bottom stream in conduit 124 can comprise at least 60, 75, 80, 85, 90, 95, 96, or 97.5 mole percent of methane. Additionally or alternatively, the nitrogen-poor bottom stream in conduit 124 can comprise not more than 99.9, 99, or 98 mole percent of methane.
Due to the fractionating in the distillation column 30, the nitrogen-poor bottom stream in conduit 124 can contain residual amounts of nitrogen. For example, the nitrogen-poor bottom stream in conduit 124 can contain at least 50, 60, 70, 80, 85, 90, or 95 percent less nitrogen than the hydrocarbon-containing gas based on mole percentage of nitrogen. In various embodiments, the nitrogen-poor bottom stream in conduit 124 can comprise less than 10, 8, 6, 5, 4, 3, 2, or 1 mole percent of nitrogen.
The nitrogen-poor bottom stream in conduit 124 can also comprise some residual hydrogen and carbon monoxide. For example, the nitrogen-poor bottom stream in conduit 124 can comprise less than 1, 0.5, 0.1, or 0.01 mole percent of hydrogen. Additionally or alternatively, the nitrogen-poor bottom stream in conduit 124 can comprise less than 1, 0.5, 0.1, or 0.01 mole percent of carbon monoxide. In certain embodiments, the nitrogen-poor bottom stream in conduit 124 comprises substantially no hydrogen and/or carbon monoxide.
Furthermore, in various embodiments, the nitrogen-poor bottom stream in conduit 124 can comprise at least 0.5, 1, 1.5, or 2 and/or not more than 20, 10, 8, 6, or 4 mole percent of C2-C6 hydrocarbons. More particularly, the nitrogen-poor bottom stream in conduit 124 can comprise in the range of 0.5 to 20, 1 to 10, 1.5 to 6, or 2 to 4 mole percent of C2-C6 hydrocarbons.
As shown in
Turning back to the nitrogen-rich overhead stream in conduit 126, this stream can be in the form of a vapor and can contain most of the nitrogen originally found in the hydrocarbon-containing gas in conduit 110. For example, the nitrogen-rich overhead stream in conduit 126 can comprise at least 60, 75, 80, 85, 90, 95, or 98 percent of the nitrogen originally present in the hydrocarbon-containing gas. In various embodiments, the nitrogen-rich overhead stream in conduit 126 can comprise at least 5, 10, 25, 50, 75, 80, 85, 90, or 95 mole percent of nitrogen.
Furthermore, the nitrogen-rich overhead stream in conduit 126 can comprise most of the hydrogen and/or carbon monoxide originally found in the hydrocarbon-containing gas. For example, the nitrogen-rich overhead stream in conduit 126 can comprise at least 40, 55, 75, 85, or 99 percent of the hydrogen and/or carbon monoxide originally present in the hydrocarbon-containing gas.
In various embodiments, the nitrogen-rich overhead stream in conduit 126 can comprise at least 5, 15, 25, or 30 and/or not more than 75, 65, 50, or 40 mole percent of hydrogen. Alternatively, the nitrogen-rich overhead stream in conduit 126 can comprise substantially no hydrogen. For example, the nitrogen-rich overhead stream in conduit 126 can comprise less than 25, 15, 10, 5, or 1 mole percent of hydrogen. Additionally or alternatively, the nitrogen-rich overhead stream in conduit 126 can comprise less than 25, 15, 10, 5, or 1 mole percent of carbon monoxide.
Moreover the nitrogen-rich overhead stream in conduit 126 can comprise some residual methane. For instance, the nitrogen-rich overhead stream in conduit 126 can comprise less than 10, 5, 4, 3, 2, or 1 mole percent of methane.
As shown in
The cooled stream in conduit 130 can then be routed to a reflux condenser drum 38, wherein at least a portion of the cooled stream in conduit 130 can be divided into a nitrogen-poor liquid reflux stream and an overhead nitrogen-rich stream. The nitrogen-poor liquid reflux stream exits the reflux condenser drum 38 via conduit 132 and the overhead nitrogen-rich stream exits the reflux condenser drum 38 via conduit 134.
The reflux condenser drum 38 can separate the cooled stream in conduit 130 at a pressure of at least 1, 1.5, 2, or 2.4 and/or not more than 8, 6, 5, or 4.2 MPa. More particularly, the reflux condenser drum 38 can operate at a pressure in the range of 1 to 8, 1.5 to 6, 2 to 5, or 2.4 to 4.2 MPa. In certain embodiments, the pressure in the reflux condenser drum 38 can be the same as or substantially same as the pressure in the distillation column 30. As used herein, “substantially same as” means that the pressure varies by less than 5 percent.
The nitrogen-poor liquid reflux stream in conduit 132 can comprise most of the methane originally present in the cooled stream in conduit 130. For example, the nitrogen-poor liquid reflux stream in conduit 132 can comprise at least 50, 65, 75, or 95 percent of the methane originally present in the cooled stream in conduit 130. In various embodiments, the nitrogen-poor liquid reflux stream in conduit 132 can comprise at least 10, 25, 40, or 65 and/or not more than 99, 95, 85, or 80 mole percent of methane. More particularly, the nitrogen-poor liquid reflux stream in conduit 132 can comprise in the range of 10 to 99, 25 to 95, 40 to 85, or 65 to 80 mole percent of methane.
Additionally or alternatively, the nitrogen-poor liquid reflux stream in conduit 132 can comprise residual amounts of nitrogen. For example, the nitrogen-poor liquid reflux stream in conduit 132 can comprise less than 40, 25, 15, 5, or 2 mole percent of nitrogen.
Furthermore, in certain embodiments, nitrogen-poor liquid reflux stream in conduit 132 can comprise hydrogen if present in the original hydrocarbon-containing gas. For example, the nitrogen-poor liquid reflux stream in conduit 132 can comprise at least 0.1, 0.5, 1, or 3 and/or not more than 20, 15, 10, or 5 mole percent of hydrogen. More particularly, the nitrogen-poor liquid reflux stream in conduit 132 can comprise in the range of 0.1 to 20, 0.5 to 15, 1 to 10, or 3 to 5 mole percent of hydrogen. In certain embodiments, the nitrogen-poor liquid reflux stream in conduit 132 can comprise substantially no hydrogen.
At least a portion of the nitrogen-poor liquid reflux stream in conduit 132 can be pumped via reflux pump 40 to conduit 136 where it can be transferred to distillation column 30 to be used as a reflux stream. The use of the nitrogen-poor liquid reflux stream in conduit 132 as a reflux stream can help minimize methane losses in the facility 10. Furthermore, the use of the nitrogen-poor liquid reflux stream in conduit 132 as a reflux stream can allow greater control over temperature conditions in the distillation column 30, which can increase the efficiency of separating nitrogen and methane in the distillation column 30.
Turning again to
Furthermore, the overhead nitrogen-rich stream in conduit 134 can comprise residual amounts of methane. For example, the overhead nitrogen-rich stream in conduit 134 can comprise less than 10, 6, 5, 3, 2, or 1 mole percent of methane.
Additionally or alternatively, the overhead nitrogen-rich stream in conduit 134 can comprise hydrogen if present in the hydrocarbon-containing gas. For example, the overhead nitrogen-rich stream in conduit 134 can comprise at least 15, 25, 35, or 50 and/or not more than 99, 95, 85, or 80 mole percent of hydrogen. More particularly, the overhead nitrogen-rich stream in conduit 134 can comprise in the range of 15 to 99, 25 to 95, 35 to 85, or 50 to 80 mole percent of hydrogen. In certain embodiments, the overhead nitrogen-rich stream in conduit 134 can comprise substantially no hydrogen.
As shown in
Turning now to refrigeration cycle 12 of the LNG recovery facility 10 depicted in
The resulting two-phase stream in conduit 146 can be introduced into interstage accumulator 50, wherein the vapor and liquid portions can be separated. A vapor stream withdrawn from accumulator 50 via conduit 148 can be routed to the inlet of the second (high pressure) stage of refrigerant compressor 46, wherein the stream can be further compressed. The resulting compressed refrigerant vapor stream can be recombined with a portion of the liquid phase refrigerant withdrawn from interstage accumulator 50 via conduit 150 and pumped to pressure via refrigerant pump 58, as shown in
The combined refrigerant stream in conduit 152 can then be routed to refrigerant condenser 52, wherein the pressurized refrigerant stream can be cooled and at least partially condensed via indirect heat exchange with a cooling medium (e.g., cooling water) before being introduced into refrigerant accumulator 54 via conduit 154. As shown in
As the compressed refrigerant stream flows through refrigerant cooling pass 24, the stream is condensed and sub-cooled, such that the temperature of the liquid refrigerant stream withdrawn from primary heat exchanger 20 via conduit 160 is well below the bubble point of the refrigerant mixture. The sub-cooled refrigerant stream in conduit 160 can then be expanded via passage through an expansion device 62 (illustrated herein as Joule-Thompson valve 62, although other types of expansion devices may be used), wherein the pressure of the stream can be reduced, thereby cooling and at least partially vaporizing the refrigerant stream. The cooled, two-phase refrigerant stream in conduit 162 can then be routed through a refrigerant warming pass 26, wherein a substantial portion of the refrigeration generated via the expansion of the refrigerant can be recovered as cooling for one or more process streams, including the refrigerant stream flowing through cooling pass 24, as discussed in detail previously. The warmed refrigerant stream withdrawn from primary heat exchanger 20 via conduit 164 can then be routed to refrigerant suction drum 56 before being compressed and recycled through closed-loop refrigeration cycle 12 as previously discussed.
According to various embodiments, during each step of the above-discussed refrigeration cycle, the temperature of the refrigerant can be maintained such that at least a portion, or a substantial portion, of the methane originally present in the feed gas stream can be condensed in primary exchanger 20. For example, in various embodiments, at least 50, 65, 75, 80, 85, 90, or 95 percent of the total methane originally present in the feed gas stream introduced into primary exchanger 20 can be condensed. In some embodiments, operating refrigeration cycle 12 at warmer temperatures may decrease the formation of one or more undesirable by-products within the feed gas stream, such as, for example nitrogen oxide gums (e.g., NOx gums) which can form at temperatures below about −100° C. According to embodiments of the present invention, formation of such byproducts can be minimized or nearly eliminated.
In one embodiment, the refrigerant utilized in the closed-loop refrigeration cycle 12 can be a mixed refrigerant. As used herein, the term “mixed refrigerant” refers to a refrigerant composition comprising two or more constituents. In one embodiment, the mixed refrigerant utilized by refrigeration cycle 12 can comprise two or more constituents selected from the group consisting of methane, ethylene, ethane, propylene, propane, isobutane, n-butane, isopentane, n-pentane, and combinations thereof. In some embodiments, the refrigerant composition can comprise methane, ethane, propane, normal butane, and isopentane and can substantially exclude certain components, including, for example, nitrogen or halogenated hydrocarbons. According to one or more embodiments, the refrigerant composition can have an initial boiling point of at least −80, −85, or −90° C. and/or not more than −50, −55, or −60° C. Various specific refrigerant compositions are contemplated according to embodiments of the present invention. Table 1, below, summarizes broad, intermediate, and narrow ranges for several exemplary refrigerant mixtures.
In some embodiments of the present invention, it may be desirable to adjust the composition of the mixed refrigerant to thereby alter its cooling curve and, therefore, its refrigeration potential. Such a modification may be utilized to accommodate, for example, changes in composition and/or flow rate of the feed gas stream introduced into LNG recovery facility 10. In one embodiment, the composition of the mixed refrigerant can be adjusted such that the heating curve of the vaporizing refrigerant more closely matches the cooling curve of the feed gas stream. One method for such curve matching is described in detail in U.S. Pat. No. 4,033,735, the disclosure of which is incorporated herein by reference in its entirety.
Thus, the above described processes and systems can be utilized to remove nitrogen from a hydrocarbon-containing gas, thereby allowing the recovery of an LNG stream.
The preferred forms of the invention described above are to be used as illustration only, and should not be used in a limiting sense to interpret the scope of the present invention. Modifications to the exemplary embodiments, set forth above, could be readily made by those skilled in the art without departing from the spirit of the present invention.
The inventors hereby state their intent to rely on the Doctrine of Equivalents to determine and assess the reasonably fair scope of the present invention as it pertains to any apparatus not materially departing from but outside the literal scope of the invention as set forth in the following claims.
It should be understood that the following is not intended to be an exclusive list of defined terms. Other definitions may be provided in the foregoing description, such as, for example, when accompanying the use of a defined term in context.
As used herein, the terms “a,” “an,” and “the” mean one or more.
As used herein, the term “and/or,” when used in a list of two or more items, means that any one of the listed items can be employed by itself or any combination of two or more of the listed items can be employed. For example, if a composition is described as containing components A, B, and/or C, the composition can contain A alone; B alone; C alone; A and B in combination; A and C in combination, B and C in combination; or A, B, and C in combination.
As used herein, the terms “comprising,” “comprises,” and “comprise” are open-ended transition terms used to transition from a subject recited before the term to one or more elements recited after the term, where the element or elements listed after the transition term are not necessarily the only elements that make up the subject.
As used herein, the terms “having,” “has,” and “have” have the same open-ended meaning as “comprising,” “comprises,” and “comprise” provided above.
As used herein, the terms “including,” “include,” and “included” have the same open-ended meaning as “comprising,” “comprises,” and “comprise” provided above.
As used herein, references to “one embodiment,” “an embodiment,” or “embodiments” mean that the feature or features being referred to are included in at least one embodiment of the technology. Separate references to “one embodiment,” “an embodiment,” or “embodiments” in this description do not necessarily refer to the same embodiment and are also not mutually exclusive unless so stated and/or except as will be readily apparent to those skilled in the art from the description. Thus, the present invention can include a variety of combinations and/or integrations of the embodiments described herein.
As used herein, the term “about” means that the associated value can vary by 10 percent from its recited value.
The present description uses numerical ranges to quantify certain parameters relating to the invention. It should be understood that when numerical ranges are provided, such ranges are to be construed as providing literal support for claim limitations that only recite the lower value of the range as well as claim limitations that only recite the upper value of the range. For example, a disclosed numerical range of 10 to 100 provides literal support for a claim reciting “greater than 10” (with no upper bounds) and a claim reciting “less than 100” (with no lower bounds).
