The present disclosure relates to the production of cast micro-optic structures, including, without limitation, micro-lenses, micro-reflectors, and diffraction gratings. More specifically, this disclosure relates to improved processes for applying casting media (for example, radiation-curable resinous fluids) used to manufacture micro-optic structures.
Hardening passports, banknotes and other documents (referred to herein as “security documents”) whose constructional features include hard-to-reproduce indicia of the documents' authenticity against counterfeiting remains an ongoing source of technical challenges and opportunities for improvement in the field of security document design. Micro-optic devices, such as holograms, gratings providing color shifts and other optical effects, and synthetic magnifiers, through which a layer of icon material is viewed through an array of thousands or millions of small-scale microlenses (for example, lenses on the order of 50 micrometers in diameter), to produce an image that is dynamic (i.e., its appearance can change with viewing angle) and has the appearance of three-dimensionality, constitute popular and effective forms of hard-to-reproduce indicia of authenticity. Such micro-optic devices are typically produces by casting a casting medium (for example, a radiation-curable polymer) against a casting master with a relief structure corresponding to the lenses and other optical structures of the micro-optic devices. The tiny scale of the relief structures on the casting masters presents significant manufacturing challenges, making the reproduction of casting masters extremely difficult, if not impossible for counterfeiters and other malicious actors.
However, the tiny scale of the relief structures and the nature of the casting media used to produce the above-described micro-optic also presents technical challenges for legitimate manufacturers of micro-optic devices. Traditionally, micro-lenses and other optical structures of micro-optic security devices are produced by coating or transferring continuous layer of casting medium (for example, a UV-curable resin) to a film substrate and then pressing the coated substrate against a casting master. Typically, UV light is used to cure the resin while the coated substrate and master are in contact, causing the resin to cross-link and form a negative of the relief structure of the casting master.
Oxygen inhibition during curing presents chronic technical challenge associated with the above-described method. The presence of oxygen in the casting medium can retard or inhibit cross-linking of photoreactive polymer chains in the casting medium, resulting in pockets of uncured or partially cured casting medium, which is softer, and in some cases, more tacky than fully cured casting medium. Being tacky, partially cured casting medium sticks to the casting master when the substrate is peeled from the casting master following curing, resulting in “dead spots” and other unwanted defects in the micro-optic casting.
Where a rotating, cylindrical casting master is used (for example, as part of a continuous web manufacturing process), air bubbles can be trapped in a wave of resin formed between the casting master and substrate at a pinch point, where the substrate is brought into contact with the roller-style casting master. The bubbles can tumble in the wave of resin, wherein some bubbles become entrapped between the master and substrate. The resin in the area of the trapped bubbles may be susceptible to oxygen inhibition, which can result in tackiness (causing material to stick to the casting master) or regions of comparatively fragile material in the cast micro-structures. Both of these are undesirable. Failure of the cast substrate to fully separate from the casting master can result in both a defect in the cast substrate, as well as a repeating defect in subsequent castings, as the unseparated material remains in the casting master, causing casting defects in subsequent castings. Additionally, accumulation of uncured or partially cured casting medium can cause further turbulence in the wave of resin, causing the accumulation of uncured or partially cured casting medium on the casting master to snowball, forcing operation to stop for cleaning the casting master.
Accordingly, mitigating oxygen inhibition during the casting of micro-structures remains a source of technical challenges and opportunities for improvement in the art.
The present disclosure illustrates embodiments of improved processes for applying resinous fluids for cast micro-optic structures manufacturing.
In a first embodiment, a method of cast curing microstructures of a micro-optic security device according to present disclosure include methods including jetting a first volume of a first radiation-curable resin directly onto a casting master to form a layer of the first radiation-curable resin having a first thickness, bringing the casting master into contact with a substrate along a squeeze line to transfer the first radiation-curable resin to the substrate and applying curing radiation to the transferred first radiation-curable resin.
In a second embodiment, an apparatus for cast curing microstructures of a micro-optic security device according to present disclosure includes a jet dispenser configured to dispense a first radiation-curable resin directly onto a casting master and a controller communicatively connected to the jet dispenser, wherein the controller is configured to control the jet dispenser to dispense a first volume of the first radiation-curable resin directly onto the casting master to form a layer of the first radiation-curable resin having a first thickness.
In a third embodiment, a micro-optic security device, the micro-optic security device includes a substrate and one or more layers of cast-cured microstructures on the substrate, wherein the one or more layers of cast-cured microstructures a first region of cast-cured micro-structures formed of a first cured radiation-curable resin, wherein the cast-cured micro-structures in the first region are free of one or more of voids, tacky spots, or other products of oxygen inhibition.
Other technical features may be readily apparent to one skilled in the art from the following figures, descriptions, and claims.
Before undertaking the DETAILED DESCRIPTION below, it may be advantageous to set forth definitions of certain words and phrases used throughout this patent document. The term “couple” and its derivatives refer to any direct or indirect communication between two or more elements, whether those elements are in physical contact with one another. The terms “include” and “comprise,” as well as derivatives thereof, mean inclusion without limitation. The term “or” is inclusive, meaning and/or. The phrase “associated with,” as well as derivatives thereof, means to include, be included within, interconnect with, contain, be contained within, connect to or with, couple to or with, be communicable with, cooperate with, interleave, juxtapose, be proximate to, be bound to or with, have, have a property of, have a relationship to or with, or the like. The phrase “at least one of,” when used with a list of items, means that different combinations of one or more of the listed items may be used, and only one item in the list may be needed. For example, “at least one of: A, B, and C” includes any of the following combinations: A, B, C, A and B, A and C, B and C, and A and B and C.
Definitions for other certain words and phrases are provided throughout this patent document. Those of ordinary skill in the art should understand that in many if not most instances, such definitions apply to prior as well as future uses of such defined words and phrases.
For a more complete understanding of the present disclosure and its advantages, reference is now made to the following description taken in conjunction with the accompanying drawings, in which like reference numerals represent like parts:
Although the present disclosure has been described with various embodiments, various changes and modifications may be suggested to one skilled in the art. It is intended that the present disclosure encompass such changes and modifications as falling within the scope of the claims.
Referring to the non-limiting example of
According to certain embodiments, plurality of focusing elements 105 comprises a planar array of micro-optic focusing elements. In some embodiments, the focusing elements of plurality of focusing elements 105 comprise micro-optic refractive focusing elements (for example, plano-convex or GRIN lenses). Refractive focusing elements of plurality of focusing elements 105 are, in some embodiments, produced from light cured resins with indices of refraction ranging from 1.35 to 1.7, and have diameters ranging from 5 μm to 200 μm. In various embodiments, the focusing elements of plurality of focusing elements 105 comprise reflective focusing elements (for example, very small concave mirrors), with diameters ranging from 5 μm to 50 μm. While in this illustrative example, the focusing elements of plurality of focusing elements 105 are shown as comprising circular plano-convex lenses, other refractive lens geometries, for example, lenticular lenses, are possible and within the contemplated scope of this disclosure.
As shown in the illustrative example of
As shown in the illustrative example of
According to various embodiments, optical security device 100 comprises one or more regions of light-cured protective material which occupy the spaces between the image icons of arrangement of image icons 121. In some embodiments, the arrangement of image icons 121 is first formed and then a layer of clear, light-curable material is applied to fill spaces between the image icons of arrangement of image icons 121 and then flood-cured to create a protective layer, which protects the image icons from being moved from their positions within the footprints of focusing elements of plurality of focusing elements 105. In certain embodiments, the light-curable material used to form arrangement of image icons 121 is a pigmented, ultraviolet (UV)-curable polymer.
In some embodiments, arrangement of image icons 121 is affixed to a second substrate 130, which operates to protect and secure arrangement of image icons 121 and provide an interface for attaching optical security device 100 to a substrate 150 as part of a security document.
In certain embodiments according to this disclosure, optical security device 100 comprises a seal layer 140. According to certain embodiments, seal layer 140 comprises a thin (for example, a 2 μm to 50 μm thick layer) of substantially clear material which interfaces on a lower surface, with focusing elements of the plurality of focusing elements 105, and comprises an upper surface with less variation in curvature (for example, by being smooth, or by having a surface whose local undulations are of a larger radius of curvature than the focusing elements) than the plurality of focusing elements 105. According to various embodiments, the upper surface of seal layer 140 is formed from a thermoplastic material which can be ultrasonically welded to a surface comprising a cellulosic material.
As shown in the non-limiting example of
While
Referring to the non-limiting example of
As noted elsewhere in this disclosure, traditionally, casting media is introduced to casting masters indirectly, by first applying a layer of casting media to a layer of film (for example, polyethylene terephthalate (PET) film used to form an optical spacer 110 in
Referring to the explanatory example of
As shown in
Once pinched between substrate 210 and section 201 of the casting master, the uncured casting medium is cured with radiation, such as ultraviolet or infrared light, causing a cross-linking reaction within the casting media. Assuming that there are no contaminants or confounding variables, such as oxygen bubbles, exposure to curing radiation causes substantially complete cross-linking of the volume of casting media to itself and substrate 210.
As shown in
Referring to the illustrative example of
As shown in the illustrative example of
Similarly, apparatus 300 further comprises a stepper motor or other apparatus for changing the relative position of micro-scale jet dispenser 305A relative to casting master 301 in a second direction (shown by arrow 315), which is perpendicular to the first direction. Depending on embodiments, micro-scale jet dispenser 305A may be moved, or casting master 301 may be displaced. Alternatively, or additionally, micro-scale jet dispenser 305A may comprise a plurality of nozzles in a grid or raster arrangement, wherein, the area of casting master 301 upon which casting media is jetted is determined by which of the multiple nozzles is fired.
As shown in
In some embodiments, apparatus 300 further comprises a second, downstream vision sensor or camera 319B, which is configured to obtain frames of image data of layer 317 along a squeeze line. By measuring the width of layer 317 along the squeeze line, further information as to whether an appropriate amount of casting media is being applied to casting master 301 is being applied. As noted elsewhere in this disclosure, the viscosity of certain casting media can depend significantly on temperature. Typically, the temperature of the working surfaces (for example, casting master 301 and micro-scale jet dispenser 305A) of apparatus 300 can vary during the start of a production run, and eventually settle into an equilibrium temperature. Prior to reaching equilibrium, the variability in the temperatures of the working surfaces of apparatus 300 can affect the viscosity of applied casting media, leading to variations in width w at micro-scale jet dispenser 305A and downstream, along the squeeze line where the casting media is pressed between a substrate and the casting master. Accordingly, image data from vision sensors 319A and 319B can be used to determine, based on, for example, the observed width of layer 317 whether the working surfaces of apparatus 300 have achieved an equilibrium state (as used in this disclosure, the expression “equilibrium state” encompasses a state wherein a given volume of casting media applied to casting master 301 produces a layer 317 of casting media of consistent width). Where the image data indicates variations in the applied width of casting media, or where the image data indicates excessive or insufficient coverage of one or more regions of casting master 301, one or more casting media application parameters (for example, the temperature of the casting media or volume jetted onto casting master 301) may be adjusted to achieve a desired width at one or more of the point where casting media is applied to the casting master or where the casting media is compressed between a substrate and the casting master.
As shown in
The created image file 409 is then passed to a raster image processing module 411, which renders the image file as a raster of pixels, wherein each pixel corresponds to a unique location to which a nozzle of casting media dispenser 450 can be positioned, and each pixel of the raster specifies a volume of casting media to be dispensed at the location associated with the pixel. According to some embodiments, casting media dispenser 450 moves to the pixel specified in the raster. According to various embodiments, a specific nozzle of the casting media dispenser fires when the casting master is advanced to a location corresponding to the row containing the pixel specified in the raster.
Referring to the non-limiting example of
Examples of methods of cast curing microstructures of a micro-optic security device according to present disclosure include methods including jetting a first volume of a first radiation-curable resin directly onto a casting master to form a layer of the first radiation-curable resin having a first thickness, bringing the casting master into contact with a substrate along a squeeze line to transfer the first radiation-curable resin to the substrate and applying curing radiation to the transferred first radiation-curable resin.
Examples of methods of cast curing microstructures of a micro-optic security device according to present disclosure include methods wherein the first thickness is less than a thickness necessary to wet the casting master when the first radiation-curable resin is applied to the substrate.
Examples of methods of cast curing microstructures of a micro-optic security device according to present disclosure include methods including heating the first radiation-curable resin to a first temperature before jetting the first radiation-curable resin directly onto the casting master.
Examples of methods of cast curing microstructures of a micro-optic security device according to present disclosure include methods including obtaining a width of a first line of the first radiation-curable resin transferred from the casting master to the substrate at a first time, obtaining a width of a second line of the first radiation-curable resin transferred from the casting master to the substrate at a second time and determining, based on the width of the first line and the width of the second line, whether an equilibrium between a volume of first radiation-curable resin jetted onto the casting master and line width has been achieved.
Examples of methods of cast curing microstructures of a micro-optic security device according to present disclosure include methods including responsive to determining that the equilibrium between the volume of the first radiation-curable resin jetted onto the casting master and line width has not been achieved, jetting a second volume of the first radiation-curable resin onto the casting master, wherein the second volume differs from the first volume.
Examples of methods of cast curing microstructures of a micro-optic security device according to present disclosure include methods wherein the first temperature is between 55 and 65 degrees Celsius.
Examples of methods of cast curing microstructures of a micro-optic security device according to present disclosure include methods wherein the first temperature is between 40 and 70 degrees Celsius.
Examples of methods of cast curing microstructures of a micro-optic security device according to present disclosure include methods wherein the first radiation-curable resin is jetted through a nozzle, wherein the nozzle does not touch the casting master.
Examples of methods of cast curing microstructures of a micro-optic security device according to present disclosure include methods wherein the casting master is a cylindrical casting master with a continuous relief pattern around the entire cylinder.
Examples of methods of cast curing microstructures of a micro-optic security device according to present disclosure include methods wherein the casting master is one or more of a cylindrical casting master with a discontinuous relief pattern or a flat casting master.
Examples of method of cast curing microstructures of a micro-optic security device according to the present disclosure include methods wherein the first volume is adjusted to maintain an optimum coverage area.
Examples of methods of cast curing microstructures of a micro-optic security device according to the present disclosure include methods wherein an amount of the first radiation-curable resin applied to the casting master is patterned to compensate for the amount of resin required by relief structures on the casting master.
Examples of apparatuses for cast curing microstructures of a micro-optic security device according to present disclosure include an apparatus including a jet dispenser configured to dispense a first radiation-curable resin directly onto a casting master and a controller communicatively connected to the jet dispenser, wherein the controller is configured to control the jet dispenser to dispense a first volume of the first radiation-curable resin directly onto the casting master to form a layer of the first radiation-curable resin having a first thickness.
Examples of apparatuses for cast curing microstructures of a micro-optic security device according to present disclosure include an apparatus wherein the first thickness is less than a thickness necessary to wet the casting master when the first radiation-curable resin is applied only to a substrate.
Examples of apparatuses for cast curing microstructures of a micro-optic security device according to present disclosure include an apparatus wherein the controller is configured to control the apparatus to heat the first radiation-curable resin to a first temperature before jetting the first radiation-curable resin directly onto the casting master.
Examples of apparatuses for cast curing microstructures of a micro-optic security device according to present disclosure include an apparatus including: an inspection camera configured to obtain image data of the first radiation-curable resin as applied to the casting master, wherein the controller is further configured to obtain a width of a first line of the first radiation-curable resin transferred from the casting master to a substrate at a first time, obtain a width of a second line of the first radiation-curable resin transferred from the casting master to the substrate at a second time, and determine, based on the width of the first line and the width of the second line, whether an equilibrium between a volume of first radiation-curable resin jetted onto the casting master and line width has been achieved.
Examples of apparatuses for cast curing microstructures of a micro-optic security device according to present disclosure include an apparatus wherein the controller is further configured to responsive to determining that the equilibrium between the volume of the first radiation-curable resin jetted onto the casting master and line width has not been achieved, control the jet dispenser to dispense a second volume of the first radiation-curable resin onto the casting master, wherein the second volume differs from the first volume.
Examples of apparatuses for cast curing microstructures of a micro-optic security device according to present disclosure include an apparatus wherein the first temperature is between 55 and 65 degrees Celsius.
Examples of apparatuses for cast curing microstructures of a micro-optic security device according to present disclosure include an apparatus wherein the first radiation-curable resin is dispensed through a nozzle, wherein the nozzle does not touch the casting master.
Examples of micro-optic security devices according to the present disclosure include micro-optic security devices including a substrate, one or more layers of cast-cured microstructures on the substrate, wherein the one or more layers of cast-cured microstructures a first region of cast-cured micro-structures formed of a first cured radiation-curable resin, wherein the cast-cured micro-structures in the first region are free of one or more of voids, tacky spots, or other products of oxygen inhibition.
Examples of micro-optic security devices according to the present disclosure include micro-optic security devices wherein the cast-cured micro-structures in the first region comprise a second cured radiation-curable resin.
Examples of micro-optic security devices according to the present disclosure include micro-optic security devices wherein the cast-cured micro-structures formed of the first cured radiation-curable resin comprises a first layer contacting the substrate, and wherein the cast-cured micro-structures formed of the second cured radiation-curable resin comprises a second layer contacting the first layer.
Examples of micro-optic security devices according to the present disclosure include micro-optic security devices wherein the first radiation-curable resin is one or more of an isodecyl acrylate, dipropylene glycol diacrylate, tripropylene glycol diacrylate, polyeser tetraacrylate, trimethylolpropane triacrylate, hexanediol diacrylate, acrylics, acrylated polyester, acrylated urethane, epoxy, polycarbonate, polypropylene, polyester, urethane, acrylate monomer, acrylate oligomers, O-phenlyphenoxyethyl acrylate, phenylthioethyl acrylate, bis-phenylthioethyl acrylate, cumin phenoxyl ethyl acrylate, a biphenylmethyl acrylate, bisphenol A epoxy acrylate, fluorene-type acrylate, brominated acrylate, halogenated acrylates, or a melamine acrylate.
The present disclosure should not be read as implying that any particular element, step, or function is an essential element, step, or function that must be included in the scope of the claims. Moreover, the claims are not intended to invoke 35 U.S.C. § 112(f) unless the exact words “means for” are followed by a participle.
This application is a 371 National Stage of International Application No. PCT/US2022/071877, filed Apr. 22, 2022, which claims priority to U.S. Provisional Patent Application No. 63/178,844, filed Apr. 23, 2021, the disclosures of which are incorporated herein by reference.
Filing Document | Filing Date | Country | Kind |
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PCT/US2022/071877 | 4/22/2022 | WO |
Number | Date | Country | |
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63178844 | Apr 2021 | US |