Claims
- 1. A process for the manufacture of compounds of the formula I ##STR9## in which R.sub.1 denotes a straight-chain or branched alkyl group, a cycloalkyl group or an aralkyl group, R.sub.2 denotes hydrogen, a straight-chain or branched alkyl group, a cycloalkyl group or an aralkyl group, R.sub.3 and R'.sub.3 independently of one another denote hydrogen or a lower alkyl group, or R.sub.1 conjointly with R'.sub.3, or R.sub.2 conjointly with R.sub.3, denote tetramethylene, R.sub.4 and R.sub.5 independently of one another denote hydrogen, phenyl or alkyl or conjointly denote alkylene, R.sub.6 denotes alkyl, phenyl or alkylphenyl, or, conjointly with R.sub.4 and R.sub.5, denotes alkanetriyl, characterised in that 1 mol of a compound of the formula II ##STR10## wherein R.sub.1, R.sub.2, R.sub.3 and R'.sub.3 have the meaning indicated above and R.sub.7 and R.sub.8 independently of one another denote a straight-chain or branched alkyl group, or conjointly, with the inclusion of the nitrogen atom, denote a saturated, heterocyclic ring, is reacted in the presence of a base selected from an alkali metal hydroxide or alcoholate at a temperature of -20.degree. C. to +150.degree. C. with one mol of a compound of the formula III ##STR11## wherein R.sub.4, R.sub.5 and R.sub.6 have the meaning indicated above.
- 2. Process according to claim 1, characterised in that, in the formula I, R.sub.1 and R.sub.2 independently of one another denote a straight-chain or branched alkyl group having 1-4 carbon atoms, or a cycloalkyl group having 6-8 carbon atoms, R.sub.3 and R'.sub.3 independently of one another denote hydrogen or methyl, R.sub.4 and R.sub.5 independently of one another denote hydrogen, phenyl or alkyl having 1-8 carbon atoms, or conjointly denote alkylene having 4-11 carbon atoms, and R.sub.6 denotes alkyl having 1-17 carbon atoms, phenyl or alkylphenyl having 7-14 carbon atoms, or conjointly with R.sub.4 and R.sub.5, denotes alkylene having 3 or 4 carbon atoms, or, conjointly with R.sub.4 and R.sub.5, denotes alkanetriyl having 5 to 8 carbon atoms.
- 3. Process according to claim 1, characterised in that, in the formula I, R.sub.1 and R.sub.2 independently of one another denote a straight-chain or branched alkyl group having 1-4 carbon atoms, R.sub.3 and R'.sub.3 denote hydrogen, R.sub.4 and R.sub.5 independently of one another denote hydrogen or alkyl having 1-8 carbon atoms or conjointly denote alkylene having 4 or 5 carbon atoms, and R.sub.6 denotes alkyl having 1-17 carbon atoms, or phenyl or, conjointly with R.sub.4 or R.sub.5, denotes alkylene having 3 or 4 carbon atoms.
- 4. Process according to claim 1, characterised in that, in the formula II, R.sub.1 and R.sub.2 independently of one another denote a straight-chain or branched alkyl group having 1-4 carbon atoms, or a cycloalkyl group having 6-8 carbon atoms, R.sub.3 and R'.sub.3 independently of one another denote hydrogen or methyl, and R.sub.7 and R.sub.8 independently of one another denote a straight-chain alkyl group having 1-8 carbon atoms, or conjointly, with the inclusion of the nitrogen atom, denote a saturated, heterocyclic 6-membered ring.
- 5. Process according to claim 1, characterised in that the base is alkali metal hydroxide.
Priority Claims (1)
Number |
Date |
Country |
Kind |
15404/73 |
Nov 1973 |
CHX |
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Parent Case Info
This is a continuation of application Ser. No. 682,000 filed on Apr. 30, 1976, now abandoned, which is a continuation-in-part of application Ser. No. 517,356 filed on Oct. 23, 1974, now abandoned.
US Referenced Citations (2)
Number |
Name |
Date |
Kind |
3678095 |
Dexter |
Jul 1972 |
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3821334 |
Schmidt et al. |
Jun 1974 |
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Continuations (1)
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Number |
Date |
Country |
Parent |
682000 |
Apr 1976 |
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Continuation in Parts (1)
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Number |
Date |
Country |
Parent |
517356 |
Oct 1974 |
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