Patent Application
20240325267
The present invention relates to field of coating keratin materials, notably the field of care and/or makeup, and more particularly makeup, and is directed towards proposing a process for coating keratin materials, notably for care and/or makeup, and more particularly for makeup, which consists in applying to said materials a coating agent formed by hydrogen bonding interaction of at least one polyphenol X comprising at least two different phenol groups with at least one monoglycerolated and/or polyglycerolated polyoxyalkylenated nonionic compound Y with a molar mass greater than 200 g/mol.
At the present time on the market for caring for and making up keratin materials, many products claim staying power throughout the day, withstanding external factors such as water, sebum, mechanical friction, etc. (waterproof mascara, food-proof lipsticks, long-lasting foundations). Long-lasting products for the lips, the eyelashes, the eyebrows or the face, which can be used at home, are mainly based on synthetic coating polymers in the presence of organic solvents.
For making up the lips and compositions for making up the face, compositions comprising a silicone resin as coating agent are known, such as the compound having the INCI name: Trimethylsiloxysilicate or a compound having the INCI name: Polypropylsilsesquioxane, or alternatively a silicone acrylate copolymer such as the product having the INCI name: Acrylates/polytrimethylsiloxymethacrylate copolymer). Long-lasting makeup products for the eyelashes and/or the eyebrows (mascaras, eyeliners) use, for their part, waxes or film-forming polymer particles in aqueous suspension of the latex type (i.e.: styrene/acrylate copolymers).
Besides these long-lasting products, the current trend is towards semi-permanent makeup. Specifically, in recent years, conventional makeup products have met with competition from the market of semi-permanent makeup in professional salons. It is encountered in the sector of makeup for the eyes (semi-permanent mascara, permanent eyelash makeup, eyelash extensions, etc.), for the eyebrows (semi-pigmentation known as micro-blading), for the complexion (freckles, beauty spots or the whole face, glowing or healthy-complexion effect) or for the lips (semi-permanent tattooing). This new trend is driving consumers towards seeking increasingly long staying power for greater practicality (avoiding having to apply and remove makeup daily, healthy complexion effect immediately on waking up, etc.).
However, consumers, who are increasingly demanding as regards the composition of their cosmetic products, are also seeking to use products with ingredients that are well tolerated such as natural ingredients, with ingredients which have little or no environmental impact and/or ingredients which are compatible with numerous packagings.
The aim of the present invention is to propose compositions which offer excellent staying power of the expected cosmetic effects, notably the colour of the makeup on keratin materials (skin, lips, nails, hair, eyelashes, eyebrows) which may extend from one day, including makeup removal at the end of the day, to staying power over several days, which is resistant to mechanical friction, water, sweat and perspiration, sebum, oil, cleansing products such as shower gels, shampoos, two-phase products and certain micellar waters.
In addition, the aim of the present invention is to propose compositions which afford staying power of the expected cosmetic effects, notably the colour of the makeup on keratin materials, combined with a good level of comfort in comparison with conventional systems, in particular based on silicone resin. The term “comfort” means absence of tackiness.
In the course of its studies, the Applicant has discovered, unexpectedly, that the objectives as defined previously were achieved with a process for coating keratin materials, notably for care and/or makeup, and more particularly makeup, which consists in applying to said materials a coating agent formed by hydrogen bonding interaction of at least one polyphenol X comprising at least two different phenol groups with at least one monoglycerolated and/or polyglycerolated polyoxyalkylenated nonionic compound Y with a molar mass greater than 200 g/mol.
The inventors have found, unexpectedly, that the coating agent deposited on the upper layers of the keratin materials and resulting from the hydrogen bonding interaction, at room temperature and atmospheric pressure, of at least one polyphenol X comprising at least two different phenol groups with at least one monoglycerolated and/or polyglycerolated polyoxyalkylenated nonionic compound Y with a molar mass greater than 200 g/mol, allowed excellent staying power of the expected cosmetic effects on the keratin materials (skin, lips, nails, hair, eyelashes, eyebrows) which may extend from one day, including makeup removal at the end of the day, to staying power over several days, which is resistant to mechanical friction, water, sebum, oil, cleansing products such as shower gels, shampoos, two-phase products and certain micellar waters.
The inventors have also found that the coating agent obtained according to the invention made it possible to obtain a good level of comfort and notably the absence of a tacky effect.
Furthermore, said coating agent may be obtained with natural compounds or compounds of natural origin which are capable of forming hydrogen bonding with said polyphenols.
This discovery forms the basis of the invention.
Thus, according to one of its aspects, the present invention relates to a process for coating keratin materials, notably for care and/or makeup, and more particularly for makeup, which consists in applying to said materials a coating agent formed by hydrogen bonding interaction of at least one polyphenol X comprising at least two different phenol groups with at least one monoglycerolated and/or polyglycerolated polyoxyalkylenated nonionic compound Y with a molar mass greater than 200 g/mol.
A second subject of the present invention is a cosmetic process for coating keratin materials, notably for care and/or makeup, more particularly for makeup, which consists in applying to said keratin materials:
Another subject of the present invention is a cosmetic kit for coating keratin materials, notably for care and/or makeup, more particularly for makeup, comprising at least:
Another subject of the present invention is a cosmetic process for coating keratin materials, notably for care and/or makeup, more particularly for makeup, which consists in applying to said keratin materials at least one composition (C) comprising, notably in a physiologically acceptable medium, at least one coating agent formed beforehand by hydrogen bonding interaction of at least one polyphenol X comprising at least two different phenol groups with at least one monoglycerolated and/or polyglycerolated polyoxyalkylenated nonionic compound Y with a molar mass greater than 200 g/mol.
Another subject of the present invention is a cosmetic process for coating keratin materials, notably for care and/or makeup, more particularly for makeup, which consists in applying to said keratin materials at least one composition (D) comprising, notably in a physiologically acceptable medium,
Another subject of the present invention is a cosmetic process for making up keratin materials wherein the polyphenol(s) X and/or the nonionic polysaccharide(s) Y or the coating agent formed beforehand by hydrogen bonding interaction between them is (are) in a composition with at least one dyestuff, preferably at least one pigment.
In the context of the present invention, the term “keratin material” notably means the skin such as the face, the body, the hands, the area around the eyes, the lips, keratin fibres such as head hair, the eyelashes, the eyebrows, bodily hair and the nails. For the purposes of the present invention, this term “keratin materials” also extends to synthetic false eyelashes and false eyebrows, and false nails.
The term “physiologically acceptable” means compatible with the skin and/or its integuments, which has a pleasant colour, odour and feel, and which does not cause any unacceptable discomfort (stinging or tautness) liable to discourage the consumer from using this composition.
For the purposes of the invention, the term “hydrogen bonding interaction” means an interaction involving a hydrogen atom of one of the two reagents and an electronegative heteroatom of the other reagent, such as oxygen, nitrogen, sulfur and fluorine. In the context of the invention, the hydrogen bonding forms between the hydroxyl functions (OH) of the reactive phenol groups of the polyphenol X and the reactive hydroxyl groups of the compound Y, which are capable of forming hydrogen bonding with those of said phenol groups of the polyphenol X.
By “coating agent formed by interaction by hydrogen bonds of at least one polyphenol X comprising at least two different phenol groups with the compound Y” means that the conditions are met so that the reaction can be carried out between the two reagents, in particular that:
The term “natural compound” refers to any compound derived directly from a plant without having undergone any chemical modification.
The term “synthetic compound” refers to any compound which neither exists naturally nor is derived from a compound of natural origin.
The term “compound of natural origin” refers to any compound derived from a plant and which has undergone one or more chemical modifications, for example by organic synthesis reaction, without the properties of the natural compound having been modified.
The term “room temperature” means 25° C.
The term “atmospheric pressure” means 760 mmHg, i.e. 105 pascals.
The term “coating agent” refers to any compound which is capable of forming a deposit on the surface of the keratin materials so as to cover them.
The term “hydrogen bonding-inhibiting agent” refers to any compound which is capable of preventing hydrogen bonding interaction between the polyphenol X and the compound Y and/or which is capable of dissociating the complex formed by said interaction by breaking the hydrogen bonding.
The polyphenols X that may be used according to the present invention include in their structure at least two different phenol groups.
The term “polyphenol” refers to any compound containing in its chemical structure at least two and preferably at least three phenol groups.
The term “phenol group” refers to any group comprising an aromatic ring, preferably a benzene ring, including at least one hydroxyl group (OH).
The term “different phenol groups” refers to phenol groups that are chemically different.
The polyphenols X that may be used according to the invention may be synthetic or natural. They may be in isolated form or contained in a mixture, notably contained in a plant extract. Polyphenols are phenols comprising at least two phenol groups that are differently substituted on the aromatic ring.
The two classes of polyphenols are flavonoids and non-flavonoids.
Examples of flavonoids that may be mentioned include chalcones such as phloretin, phloridzin, aspalathin or neohesperidin; flavanols such as catechin, fisetin, kaempferol, myricetin, quercetin, rutin, procyanidins, proanthocyanidins, pyroanthocyanidins, theaflavins or thearubigins (or thearubrins); dihydroflavonols such as astilbin, dihydroquercetin (taxifolin) or silibinin; flavanones such as hesperidin, neohesperidin, hesperetin, naringenin or naringin; anthocyanins such as cyanidin, delphinidin, malvidin, peonidin or petunidin; catechin tannins such as tannic acid; isoflavonoids such as daidzein or genistein; neoflavanoids; lignans such as pyroresorcinol; and mixtures thereof.
Among the natural polyphenols that may be used according to the invention, mention may also be made of lignins.
Examples of non-flavonoids that may be mentioned include curcuminoids such as curcumin or tetrahydrocurcumin; stilbenoids such as astringin, resveratrol or rhaponticin; aurones such as aureusidin; and mixtures thereof.
As polyphenols that may be used according to the invention, mention may also be made of chlorogenic acid, verbascoside; coumarins substituted with phenols.
According to a particular embodiment of the invention, the polyphenol X will be chosen from catechin tannins such as gallotannins chosen from tannic acid; ellagitannins such as epigallocatechin, epigallocatechin gallate, castalagin, vescalagin, vescalin, castalin, casuarictin, castanopsinins, excoecarianins, grandinin, gradinin, roburins, pterocarinin, acutissimin, tellimagrandins, sanguiin, potentillin, pedunculagin, geraniin, chebulagic acid, repandisinic acid, ascorgeraniin, stachyurin, casuarinin, casuariin, punicacortein, coriariin, cameliatannin, isodeshydrodigalloyl, dehydrodigalloyl, hellinoyl, punicalagin and rhoipteleanins.
According to a particular embodiment of the invention, the polyphenol X is epigallocatechin, in particular a green tea extract having the INCI name Green Tea Extract, notably comprising at least 45% epigallocatechin relative to the total weight of said extract, for instance the commercial product sold under the name Dermofeel Phenon 90 M-C® sold by the company Evonik Nutrition & Care or the commercial product sold under the name Tea Polyphenols Green Tea Extract® by the company Tayo Green Power.
According to a particular embodiment of the invention, the polyphenol X is a procyanidin or a mixture of procyanidins, in particular an extract of maritime pine bark having the INCI name Pinus pinaster Bark/Bud Extract, notably comprising at least 65% by weight of procyanidins relative to the total weight of said extract, such as the commercial product sold under the name Pycnogenol® sold by the company Biolandes Arômes.
Tannic acid will be used more particularly as polyphenol X.
According to a particular embodiment, the polyphenol (s) X according to the invention will be present in a content equal or greater than 0.8% by weight, preferably equal or greater than 1.0% by weight, more particularly equal or greater than 2.0% by weight relative to the total weight of the composition containing it (them).
According to a particular embodiment, the polyphenol (s) X according to the invention will be present in a content from 1.0 to 30.0% by weight and more particularly of from 2.0 to 30% relative to the total weight of the composition containing it (them).
Monoglycerolated and/or Polyglycerolated Polyoxyalkylenated Nonionic Compound Y
For the purposes of the present invention, the term “polyoxyalkylenated compound” refers to any molecule comprising in its chemical structure at least one chain comprising oxyalkylene units, in particular oxyethylene units —(OCH2CH2)n and/or oxypropylene units —(OCH2CH2CH2)p.
For the purposes of the present invention, the term “monoglycerolated or polyglycerolated compound” refers to any molecule comprising in its chemical structure a glycerol group or a chain comprising glycerol units —(O—CH2—CHOH—CH2)m
In one preferred embodiment, the molar mass of the nonionic compound Y is greater than 350 g/mol.
As examples of monoglycerolated or polyglycerolated polyoxyalkylenated nonionic compounds Y, mention may be made of:
in particular Dihydrocholeth-30.
According to a preferential embodiment, the compound(s) Y will be chosen from fatty acid esters of polyglycerol, in particular polyglyceryl-10 caprate, polyglyceryl-10 laurate; polyethylene glycols such as PEG-180; PEG-40 hydrogenated castor oil; polysorbates, in particular polysorbate 80; polyoxyethylenated alkylamines such as PEG-2 oleamine; polyoxyalkylenated ester waxes such as polyoxyethylenated (120 OE) jojoba wax; and mixtures thereof.
According to a particular embodiment, the compound(s) Y according to the invention will be present in a content equal or greater than 0.8% by weight, preferably equal or greater than 1.0% by weight, more particularly equal or greater than 2.0% by weight relative to the total weight of the composition containing it (them).
According to a particular embodiment, the compound(s) Y according to the invention will be present in a content from 1.0 to 30.0% by weight and more particularly of from 2.0 to 30% relative to the total weight of the composition containing it (them).
According to a preferential embodiment of the invention, the mole ratio of the reactive hydroxyl groups (OH) of the polyphenol(s) X to the hydroxyl groups of the compound(s) Y that are reactive with those of the polyphenol(s) X preferentially ranges from ⅓ to 20, more preferentially from ½ to 15 and more particularly from ¾ to 3.
According to a particular embodiment, the invention is a cosmetic process for coating keratin materials, notably for care and/or makeup, more particularly for makeup, comprising at least:
According to a particular embodiment, the invention relates to a cosmetic kit for coating keratin materials, notably for care and/or makeup, comprising at least:
According to a particular embodiment of the invention, composition (A) containing the polyphenol(s) X comprises at least one aqueous phase.
The term “aqueous phase” means a phase comprising water and also optionally all the water-soluble or water-miscible solvents and ingredients (miscibility with water of greater than 50% by weight at 25° C.), for instance lower monoalcohols containing from 2 to 5 carbon atoms such as ethanol or isopropanol, polyols containing from 3 to 8 carbon atoms such as propylene glycol, 1,3-butylene glycol, caprylyl glycol, pentylene glycol, glycerol, and dipropylene glycol; C3-C4 ketones and C2-C4 aldehydes.
The aqueous phase may contain a demineralized water or alternatively a floral water such as cornflower water and/or a mineral water such as Vittel water, Lucas water or La Roche Posay water and/or a spring water.
The amount of water is preferably greater than 30% by weight, or even greater than 40% by weight, more preferentially ranging from 30% to 85% relative to the total weight of composition (A).
The amount of aqueous phase is preferably greater than 10% by weight, or even greater than 20% by weight, more preferentially ranging from 20% to 90%, relative to the total weight of composition (A).
The pH of the aqueous composition (A) is preferably less than 8.0, more preferentially less than 7.0, more particularly ranging from 2 to 6.
According to another particular embodiment of the invention, composition (A) comprises an oily phase.
According to another particular embodiment of the invention, composition (A) is anhydrous.
According to another particular embodiment of the invention, composition (A) is anhydrous and comprises at least one oily phase.
The term “anhydrous composition” refers to any composition comprising less than 5% by weight of water, or even less than 2% by weight of water, or even less than 1% by weight of water relative to the total weight of the composition, or even is free of water.
The term “oily phase” refers to a phase which is liquid at room temperature and at atmospheric pressure, comprising at least one fatty substance such as oils, waxes or pasty substances and also optionally all the organic solvents and ingredients that are soluble or miscible in said phase.
The oil(s) may be chosen from mineral, animal, plant or synthetic oils; in particular volatile or non-volatile hydrocarbon-based oils and/or silicone oils and/or fluoro oils, and mixtures thereof.
The term “oil” refers to a fatty substance that is liquid at room temperature (25° C.) and atmospheric pressure (760 mmHg, i.e. 105 Pa). The oil may be volatile or non-volatile.
For the purposes of the present invention, the term “silicone oil” refers to an oil comprising at least one silicon atom, and notably at least one Si—O group, and more particularly an organopolysiloxane.
The term “fluoro oil” refers to an oil comprising at least one fluorine atom.
The term “hydrocarbon-based oil” refers to an oil mainly containing carbon and hydrogen atoms and possibly one or more functions chosen from hydroxyl, ester, ether and carboxylic functions.
For the purposes of the invention, the term “volatile oil” refers to any oil that is capable of evaporating on contact with the skin in less than one hour, at room temperature and atmospheric pressure. The volatile oil is a volatile cosmetic compound, which is liquid at room temperature, notably having a non-zero vapour pressure, at room temperature and atmospheric pressure, notably having a vapour pressure ranging from 2.66 Pa to 40 000 Pa, in particular ranging from 2.66 Pa to 13 000 Pa and more particularly ranging from 2.66 Pa to 1300 Pa.
The term “non-volatile oil” refers to an oil that remains on the skin or the keratin fibre at room temperature and atmospheric pressure for at least several hours, and that notably has a vapour pressure of less than 2.66 Pa, preferably less than 0.13 Pa. By way of example, the vapour pressure may be measured according to the static method or via the effusion method by isothermal gravimetry, depending on the vapour pressure (standard OCDE 104).
As examples of volatile hydrocarbon-based oils that may be used in the invention, mention may be made of:
As examples of non-volatile hydrocarbon-based oils that may be used in the invention, mention may be made of:
Among the non-volatile silicone oils, mention may be made of silicone oils such as non-volatile polydimethylsiloxanes (PDMS); phenyl silicones such as phenyl trimethicones, phenyl dimethicones, diphenyl dimethicones, trimethylpentaphenyltrisiloxanes, tetramethyltetraphenyltrisiloxanes, trimethylsiloxyphenyl dimethicones, diphenylsiloxyphenyl trimethicones, and also mixtures thereof.
Linear volatile silicone oils that may be mentioned include octamethyltrisiloxane, decamethyltetrasiloxane, dodecamethylpentasiloxane and mixtures thereof.
Cyclic volatile silicone oils that may be mentioned include octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane and dodecamethylcyclohexasiloxane, and mixtures thereof.
When composition (A) is anhydrous, the oily phase preferably comprises at least one volatile hydrocarbon-based oil, more preferentially chosen from C8-C16 isoalkanes of petroleum origin (also known as isoparaffins), for instance isododecane (also known as 2,2,4,4,6-pentamethylheptane), isohexadecane and isodecane, and more particularly isododecane.
When composition (A) is anhydrous, the oily phase concentration of the composition of the invention is preferably greater than 10% by weight, or even greater than 20% by weight, more particularly ranging from 30% to 75% by weight, relative to the total weight of composition (A).
According to a particular embodiment of the invention, composition (B) comprising the compound(s) Y comprises at least one aqueous phase.
The amount of water is preferably greater than 30% by weight, or even greater than 40% by weight, more preferentially greater than 65%, relative to the total weight of composition (B).
The amount of aqueous phase is preferably greater than 10% by weight, or even greater than 20% by weight, more preferentially ranging from 20% to 90%, relative to the total weight of composition (B).
The pH of the aqueous composition (B) is preferably less than 8.0, more preferentially less than 7.0, more particularly ranging from 2 to 6.
According to another particular embodiment, composition (B) may comprise at least one oily phase as defined previously.
According to a particular embodiment of the invention, composition (B) is anhydrous.
According to a particular embodiment of the invention, composition (B) is anhydrous and comprises at least one oily phase as defined previously.
When composition (B) is anhydrous, the oily phase preferably comprises at least one volatile hydrocarbon-based oil, more preferentially chosen from C8-C16 isoalkanes of petroleum origin (also known as isoparaffins), for instance isododecane (also known as 2,2,4,4,6-pentamethylheptane), isohexadecane and isodecane, and more particularly isododecane.
When composition (B) is anhydrous, the oily phase concentration of the composition of the invention is preferably greater than 10% by weight, or even greater than 20% by weight, more particularly ranging from 30% to 75% by weight, relative to the total weight of composition (B).
Needless to say, a person skilled in the art will take care to select compositions (A) and (B) so that they are compatible and can be mixed and the amounts for obtaining in the mixture obtained the formation of a coating agent by hydrogen bonding interaction of the polyphenol X with the compound Y.
A cosmetic process for coating keratin materials according to the invention, notably for care and/or makeup, in particular for makeup, consists in applying to said keratin materials at least one composition (C) comprising at least one coating agent formed beforehand by hydrogen bonding interaction of at least one polyphenol X comprising at least two different phenol groups with at least one compound Y including at least two identical or different functional groups Gy, which are capable of forming hydrogen bonding with said polyphenol X.
Another cosmetic process for coating keratin materials according to the invention, notably for care and/or makeup, more particularly for makeup, consists in applying to said keratin materials at least one composition (D) comprising, notably in a physiologically acceptable medium,
The coating agent present in the compositions of the invention is obtained by reacting by hydrogen bonding interaction, at room temperature and atmospheric pressure, at least one polyphenol X comprising at least two different phenol groups with at least one compound Y including at least two identical or different functional groups Gy, which are capable of forming at least two hydrogen bonds with said phenol groups of said polyphenol X.
A cosmetic process for coating keratin materials according to the invention, notably for care and/or makeup, in particular for makeup, consists in applying to said keratin materials at least one composition (C) comprising at least one coating agent formed beforehand by hydrogen bonding interaction of at least one polyphenol X comprising at least two different phenol groups with at least one monoglycerolated and/or polyglycerolated polyoxyalkylenated nonionic compound Y with a molar mass greater than 200 g/mol.
Another cosmetic process for coating keratin materials according to the invention, notably for care and/or makeup, more particularly for makeup, consists in applying to said keratin materials at least one composition (D) comprising, notably in a physiologically acceptable medium,
The coating agent present in the compositions of the invention is obtained by reacting by hydrogen bonding interaction, at room temperature and atmospheric pressure, at least one polyphenol X comprising at least two different phenol groups with at least one monoglycerolated and/or polyglycerolated polyoxyalkylenated nonionic compound Y with a molar mass greater than 200 g/mol.
The reaction medium may be aqueous, hydrophilic or anhydrous. Ideally, the solvent in which the preparation of the resistance agent is prepared is readily evaporable; in particular, it may preferentially be synthesized in water or in a volatile oil such as those indicated previously, preferably isododecane.
The polyphenol X and the compound Y that can form a complex by hydrogen bonding are ideally introduced into the reaction medium with a mole ratio of the reactive hydroxyl groups of the polyphenol X to the hydroxyl groups of the compound Y that are reactive with those of the polyphenol X preferentially ranging from ⅓ to 20, more preferentially from ½ to 15 and more particularly from ¾ to 3.
The order of introduction is unimportant. The contact time may be very short or the mixture may be left to incubate with stirring (for a few hours).
The precipitate obtained corresponding to the coating agent is recovered either by filtration of the solvent or by centrifugation or else by evaporating off the solvent.
The precipitate is then washed several times so as to remove the initial reagents that have not been engaged in forming the precipitate. The washing solvent is chosen so that it is a good solvent for the polyphenol and/or for the associated compound. Ideally, the washing solvent is water.
The number of washes may be determined by assaying the polyphenol recovered in the washing waters. When the content is low, it may be considered that the excess reagent has been removed. The amount of solvent present in the precipitate is less than 40% relative to the weight of precipitate, or even less than 35% relative to the weight of the precipitate.
Next, the precipitate may be dried, notably in the open air, in a heated atmosphere, under vacuum or freeze-dried.
According to a particular embodiment, composition (C) comprises the preformed coating agent in contents ranging from 1% to 60% by weight, more preferentially ranging from 2% to 40% by weight and preferably ranging from 10% to 40% by weight relative to the total weight of composition (C).
According to a particular embodiment of the invention, composition (C) comprises at least one aqueous phase.
According to another particular embodiment, composition (C) may comprise at least one oily phase such as those defined previously.
According to a particular embodiment of the invention, composition (C) is anhydrous.
According to another particular embodiment of the invention, composition (C) is anhydrous and comprises at least one oily phase as defined previously.
According to another particular embodiment, composition (C) may be a multi-phase composition and may notably include at least one aqueous phase and at least one oily phase and may notably be in the form of an oil-in-water emulsion, a water-in-oil emulsion, a multiple emulsion or an aqueous dispersion of wax(es).
It may be in the form of an oil-in-water emulsion (continuous aqueous phase in which is dispersed an oily phase in the form of droplets so as to obtain a macroscopically homogeneous mixture) or a water-in-oil emulsion (continuous oily phase in which is dispersed an aqueous phase in the form of droplets so as to obtain a macroscopically homogeneous mixture).
Depending on the nature of the aqueous composition (C), the amount of water is preferably greater than 30% by weight, or even greater than 40% by weight, more preferentially ranging from 30% to 75% by weight, relative to the total weight of composition (C).
The amount of aqueous phase is preferably greater than 10% by weight, or even greater than 20% by weight, more preferentially ranging from 20% to 90%, relative to the total weight of the composition.
When composition (C) is aqueous, the pH is preferably less than 8.0, more preferentially less than 7.0, more particularly ranging from 2 to 6.
When composition (C) comprises an oily phase, said phase comprises at least one oil.
When composition (C) is anhydrous and comprises an oily phase, the oily phase concentration is preferably greater than 10% by weight, or even greater than 20% by weight, more preferentially ranging from 30% to 75%, relative to the total weight of composition (C).
When composition (C) is an emulsion, it may include one or more emulsifying surfactants.
For the purposes of the present invention, the term “emulsifying surfactant” refers to an amphiphilic surfactant compound, i.e. one which has two parts of different polarity. Generally, one is lipophilic (soluble or dispersible in an oily phase). The other is hydrophilic (soluble or dispersible in water). The emulsifying surfactants are characterized by their HLB (Hydrophilic-Lipophilic Balance) value, the HLB being the ratio between the hydrophilic part and the lipophilic part in the molecule. The term “HLB” is well known to those skilled in the art and is described, for example, in “The HLB system. A time-saving guide to Emulsifier Selection” (published by ICI Americas Inc., 1984). For the emulsifying surfactants, the HLB generally ranges from 3 to 8 for the preparation of W/O emulsions. The HLB is greater than 8 for the preparation of O/W emulsions. The HLB of the surfactant(s) used according to the invention may be determined via the Griffin method or the Davies method.
According to a preferential form of the invention, when composition (C) is anhydrous, the oily phase of composition (C) comprises at least one volatile hydrocarbon-based oil, preferably chosen from hydrocarbon-based oils containing from 8 to 16 carbon atoms, and notably C8-C16 isoalkanes of petroleum origin (also known as isoparaffins), for instance isododecane (also known as as 2,2,4,4,6-pentamethylheptane), isodecane and isohexadecane, and particularly isododecane.
The amount of volatile hydrocarbon-based oil(s) may preferably range from 20% to 80% by weight and even more preferentially from 30% to 70% by weight relative to the total weight of said composition (C).
According to a particular form of the invention, the compositions (C) may include waxes.
The term “wax” means a deformable or undeformable lipophilic compound, which is solid at room temperature (25° C.), with a reversible solid/liquid change of state, having a melting point of greater than or equal to 40° C., which may be up to 120° C. In particular, the waxes that are suitable for use in the invention may have a melting point of greater than or equal to 45° C. and in particular greater than or equal to 55° C.
The term “lipophilic compound” refers to a compound having an acid number and a hydroxyl number of less than 150 mg KOH/g.
For the purposes of the invention, the melting point corresponds to the temperature of the most endothermic peak observed on thermal analysis (DSC) as described in the standard ISO 11357-3; 1999. The melting point of the wax may be measured using a differential scanning calorimeter (DSC), for example the calorimeter sold under the name MDSC 2920® by the company TA Instruments.
The measuring protocol is as follows:
A sample of 5 mg of wax placed in a crucible is subjected to a first temperature rise ranging from −20° C. to 100° C., at a heating rate of 10° C./minute, it is then cooled from 100° C. to −20° C. at a cooling rate of 10° C./minute and is finally subjected to a second temperature rise ranging from −20° C. to 100° C. at a heating rate of 5° C./minute. During the second temperature rise, the variation in the difference in power absorbed by the empty crucible and by the crucible containing the sample of wax is measured as a function of the temperature. The melting point of the compound is the temperature value corresponding to the top of the peak of the curve representing the variation in the difference in power absorbed as a function of the temperature.
The waxes may be hydrocarbon-based waxes, silicone waxes and/or fluoro waxes, and may be of plant, mineral, animal and/or synthetic origin.
The wax(es) are present, preferably, in a content of at least 5% by weight, more preferentially in a content ranging from 5% to 45% by weight, relative to the total weight of composition, better still ranging from 8% to 40% and even better still from 10% to 40% by weight, relative to the total weight of composition (C).
Waxes that may notably be used include hydrocarbon-based waxes, such as beeswax, lanolin wax; rice wax, carnauba wax, candelilla wax, ouricury wax, Japan wax, berry wax, shellac wax and sumac wax; montan wax.
Mention may also be made of waxes obtained by catalytic hydrogenation of animal or plant oils containing linear or branched C8-C32 fatty chains.
Among these waxes, mention may notably be made of hydrogenated jojoba oil, hydrogenated palm oil, hydrogenated sunflower oil, hydrogenated castor oil, hydrogenated coconut kernel oil, hydrogenated lanolin oil and bis(1,1,1-trimethylolpropane) tetrastearate sold under the name Hest 2T-4S® by the company Heterene, and bis(1,1,1-trimethylolpropane) tetrabehenate sold under the name Hest 2T-4B® by the company Heterene.
Use may also be made of the wax obtained by hydrogenation of olive oil esterified with stearyl alcohol, sold under the name Phytowax Olive 18L57®, or the waxes obtained by hydrogenation of castor oil esterified with cetyl alcohol, sold under the names Phytowax Ricin 16L64® and 22L73® by the company Sophim. Such waxes are described in patent application FR-A-2 792 190. Use may also be made of a C20-C40 alkyl (hydroxystearyloxy)stearate (the alkyl group comprising from 20 to 40 carbon atoms), alone or as a mixture, in particular a C20-C40 alkyl 12-(12′-hydroxystearyloxy)stearate of formula (I)
in which n is an integer ranging from 18 to 38, or a mixture of compounds of formula (I). Such a tacky wax is notably sold under the names Kester Wax K 82 P® and Kester Wax K 80 P® by the company Koster Keunen.
Mention may be made of microcrystalline waxes, paraffins and ozokerite, polyethylene waxes, waxes obtained by Fisher-Tropsch synthesis and waxy copolymers and also esters thereof; silicone waxes and fluoro waxes.
Mention may be made of the linear fatty acid monoesters of formula (I) below:
[Chem 3]
R3-O—R4 (1)
in which R3 and R4 are linear and saturated and have, independently of each other, a number of carbon atoms greater than or equal to 20, with R3 representing an acyl radical, and R4 representing an alkyl radical.
In particular, the fatty acid monoester according to the invention is chosen from arachidyl arachidate and behenyl behenate and more particularly behenyl behenate.
According to a preferential embodiment of the invention, in order to improve the dispersibility of the coating agent homogeneously in composition (C), a thickening system (polymers, waxes or pasty substances), a suspension agent or an emulsifying system in particular of lamellar phase type may be added.
Composition (D) according to the invention comprises, notably in a physiologically acceptable medium:
Said polyphenol X and said compound Y are preferably present in composition (D) with a mole ratio of the reactive hydroxyl groups of the polyphenol X to the functional groups Gy of the compound Y that are reactive with said hydroxyl groups preferentially ranging from ⅓ to 20, more preferentially from ½ to 15 and more particularly from ¾ to 3.
According to a particular embodiment of the invention, composition (D) comprises at least one aqueous phase.
According to another particular embodiment, composition (D) may comprise at least one oily phase as defined previously for composition (C).
According to another particular embodiment, composition (D) is anhydrous.
According to another particular embodiment, composition (D) is anhydrous and comprises an oily phase as defined previously.
When composition (D) is anhydrous and comprises at least one oily phase, the oily phase concentration is then preferably greater than 10% by weight, or even greater than 20% by weight, more preferentially ranging from 30% to 75%, relative to the total weight of composition (D).
According to a particular form of the invention, when composition (D) is anhydrous and comprises an oily phase, said oily phase comprises at least one volatile hydrocarbon-based oil, preferably chosen from hydrocarbon-based oils containing from 8 to 16 carbon atoms, and notably C8-C16 isoalkanes of petroleum origin (also known as isoparaffins), for instance isododecane (also known as as 2,2,4,4,6-pentamethylheptane), isodecane and isohexadecane, and particularly isododecane.
The amount of volatile hydrocarbon-based oil(s) may preferably range from 20% to 80% by weight and even more preferentially from 30% to 70% by weight relative to the total weight of said composition (D).
According to another particular embodiment, composition (D) may be a multi-phase composition and may notably include at least one aqueous phase and at least one oily phase and may notably be in the form of an oil-in-water emulsion, a water-in-oil emulsion, a multiple emulsion or an aqueous dispersion of wax(es).
It may be in the form of an oil-in-water emulsion (continuous aqueous phase in which is dispersed an oily phase in the form of droplets so as to obtain a macroscopically homogeneous mixture) or a water-in-oil emulsion (continuous oily phase in which is dispersed an aqueous phase in the form of droplets so as to obtain a macroscopically homogeneous mixture).
When composition (D) is an emulsion, it may include one or more emulsifying surfactants.
Depending on the nature of the aqueous composition (D), the amount of water is preferably less than 40% by weight, or even less than 30% by weight, more preferentially less than 20% by weight, relative to the total weight of composition (D).
According to a particular embodiment, composition (D) is aqueous and its pH is less than 8.0, more preferentially less than 7.0, more particularly ranging from 2 to 6.
According to a preferential embodiment, the composition is anhydrous and comprises at least one monoalcohol including from 2 to 8 carbon atoms, notably from 2 to 6 carbon atoms and in particular from 2 to 4 carbon atoms such as ethanol, isopropanol, propanol or butanol, and mixtures thereof, and more particularly ethanol.
The monoalcohol(s) including from 2 to 8 carbon atoms are then preferably present in contents of greater than 10% by weight, or even greater than 30% by weight, more preferentially ranging from 30% to 75% by weight, relative to the total weight of composition (D).
According to a particular form of the invention, the compositions (D) may include waxes as defined previously.
When composition (D) is aqueous, the hydrogen bonding-inhibiting agent may be chosen from inorganic bases, organic bases, and mixtures thereof.
The organic base(s) may be chosen from alkali metal hydroxides such as sodium hydroxide (NaOH) or potassium hydroxide (KOH) and ammonia (NH3).
The organic base(s) may be chosen from amino acids such as arginine or lysine; alkanolamines such as monoethanolamine, diethanolamine, triethanolamine, triisopropanolamine or aminomethylpropane; primary (poly)hydroxyalkylamines such as 2-amino-2-(hydroxymethyl)propane-1,3-diol (also known as tromethamine) and aminomethylpropanediol; and mixtures thereof.
According to a particular embodiment, the organic base is a primary (poly)hydroxyalkylamine.
The term “primary (poly)hydroxyalkylamine” in particular means a primary dihydroxyalkylamine, it being understood that the term “primary” means a primary amine function, i.e. —NH2, and the alkyl group being a linear or branched C1-C8 and preferably a branched C4 hydrocarbon-based chain, such as 1,3-dihydroxy-2-methylpropyl. The primary (poly)hydroxyalkylamine is preferentially 1,3-dihydroxy-2-methyl-2-propylamine (also known as aminomethylpropanediol or AMPD).
According to a particular embodiment of the invention, the organic base is aminomethylpropanediol. Such an aminomethylpropanediol that is suitable for use in the invention is, for example, AMPD Ultra PC® sold by the company Angus (Dow Corning).
The hydrogen bonding-inhibiting agent may be chosen from organic solvents that are capable of breaking hydrogen bonding.
Among these organic solvents, mention may be made of monoalcohols including from 2 to 8 carbon atoms, notably from 2 to 6 carbon atoms and in particular from 2 to 4 carbon atoms such as ethanol, isopropanol, propanol or butanol, and mixtures thereof, and more particularly ethanol.
The organic solvent(s) that are capable of breaking hydrogen bonding are preferably present in contents of greater than 10% by weight, or even greater than 30% by weight, more preferentially ranging from 30% to 75% by weight, relative to the total weight of composition (D).
According to a particular embodiment, the coating process of the invention is a process for making up keratin materials wherein the polyphenol(s) X and/or the monoglycerolated and/or polyglycerolated polyoxyalkylenated nonionic compound(s) Y or the coating agent formed beforehand by hydrogen bonding interaction between them is (are) in a composition with at least one dyestuff, preferably at least one pigment.
According to a particular embodiment of the invention, composition (A), (B), (C) and/or (D) comprises at least one dyestuff, which is synthetic, natural or of natural origin.
The dyestuff may be chosen from coated or uncoated pigments, water-soluble dyes, liposoluble dyes, and mixtures thereof.
The term “pigments” means white or coloured, mineral or organic particles, which are insoluble in an aqueous medium, and which are intended to colour and/or opacify the resulting composition and/or deposit.
According to a particular embodiment, the pigments used according to the invention are chosen from mineral pigments.
The term “mineral pigment” means any pigment that satisfies the definition in Ullmann's encyclopaedia in the chapter on inorganic pigments. Among the mineral pigments that are useful in the present invention, mention may be made of zirconium oxide or cerium oxide, and also zinc oxide, iron oxide (black, yellow or red) or chromium oxide, manganese violet, ultramarine blue, chromium hydrate and ferric blue, titanium dioxide, and metal powders, for instance aluminium powder and copper powder. The following mineral pigments may also be used: Ta2O5, Ti3O5, Ti2O3, TiO, ZrO2 as a mixture with TiO2, ZrO2, Nb2O5, CeO2, ZnS.
The size of the pigment that is useful in the context of the present invention is generally greater than 100 nm and may range up to 10 μm, preferably from 200 nm to 5 μm and more preferentially from 300 nm to 1 μm.
According to a particular form of the invention, the pigments have a size characterized by a D[50] greater than 100 nm and possibly ranging up to 10 μm, preferably from 200 nm to 5 μm and more preferentially from 300 nm to 1 μm.
The sizes are measured by static light scattering using a commercial MasterSizer 3000® particle size analyser from Malvern, which makes it possible to determine the particle size distribution of all of the particles over a wide range which may extend from 0.01 μm to 1000 μm. The data are processed on the basis of the standard Mie scattering theory. This theory is the most suitable for size distributions ranging from submicron to multimicron; it allows an “effective” particle diameter to be determined. This theory is notably described in the publication by Van de Hulst, H. C., Light Scattering by Small Particles, Chapters 9 and 10, Wiley, New York, 1957.
D[50] represents the maximum size that 50% by volume of the particles have.
In the context of the present invention, the mineral pigments are more particularly iron oxide and/or titanium dioxide. Examples that may be mentioned more particularly include and titanium dioxides and iron oxide coated with aluminium stearoyl glutamate, sold, for example, under the reference NAI® by the company Miyoshi Kasei.
As mineral pigments that may be used in the invention, mention may also be made of nacres.
The term “nacres” should be understood as meaning coloured particles of any form, which may or may not be iridescent, notably produced by certain molluscs in their shell, or alternatively synthesized, and which have a colour effect via optical interference.
The nacres may be chosen from nacreous pigments such as titanium mica coated with an iron oxide, titanium mica coated with bismuth oxychloride, titanium mica coated with chromium oxide, titanium mica coated with an organic dye and also nacreous pigments based on bismuth oxychloride. They may also be mica particles, at the surface of which are superposed at least two successive layers of metal oxides and/or of organic dyestuffs.
According to a particular embodiment, the pigments used according to the invention are chosen from mineral pigments.
Examples of nacres that may also be mentioned include natural mica covered with titanium oxide, with iron oxide, with natural pigment or with bismuth oxychloride.
The nacres may more particularly have a yellow, pink, red, bronze, orange, brown, gold and/or coppery colour or tint.
Among the pigments that may be used according to the invention, mention may also be made of those having an optical effect different from a simple conventional colouring effect, i.e. a unified and stabilized effect such as produced by conventional dyestuffs, for instance monochromatic pigments. For the purposes of the invention, the term “stabilized” means lacking the effect of variability of the colour with the angle of observation or in response to a temperature change.
For example, this material may be chosen from particles with a metallic tint, goniochromatic colouring agents, diffractive pigments, thermochromic agents, optical brighteners, and also fibres, notably interference fibres. Needless to say, these various materials may be combined in order simultaneously to afford two effects, or even a novel effect in accordance with the invention.
According to a particular embodiment, composition (A), (B), (C) and/or (D) according to the invention comprises at least one uncoated pigment.
According to another particular embodiment, composition (A), (B), (C) and/or (D) according to the invention comprises at least one pigment coated with at least one lipophilic or hydrophobic compound.
This type of pigment is particularly advantageous. Insofar as they are treated with a hydrophobic compound, they show predominant affinity for an oily phase, which can then convey them.
The coating may also comprise at least one additional non-lipophilic compound.
For the purposes of the invention, the “coating” of a pigment according to the invention generally denotes the total or partial surface treatment of the pigment with a surface agent, absorbed, adsorbed or grafted onto said pigment.
The surface-treated pigments may be prepared according to surface treatment techniques of chemical, electronic, mechanochemical or mechanical nature that are well known to a person skilled in the art. Commercial products may also be used.
The surface agent may be absorbed, adsorbed or grafted onto the pigments by evaporation of solvent, chemical reaction and creation of a covalent bond.
According to one variant, the surface treatment consists of coating the pigments.
The coating may represent from 0.1% to 20% by weight and in particular from 0.5% to 5% by weight relative to the total weight of the coated pigment.
The coating may be produced, for example, by adsorption of a liquid surface agent onto the surface of the solid particles by simple mixing with stirring of the particles and of said surface agent, optionally with heating, prior to the incorporation of the particles into the other ingredients of the makeup or care composition.
The coating may be produced, for example, by chemical reaction of a surface agent with the surface of the solid pigment particles and creation of a covalent bond between the surface agent and the particles. This method is notably described in patent U.S. Pat. No. 4,578,266.
The chemical surface treatment may consist in diluting the surface agent in a volatile solvent, dispersing the pigments in this mixture and then slowly evaporating off the volatile solvent, so that the surface agent is deposited on the surface of the pigments.
When the pigment comprises a lipophilic or hydrophobic coating, it is preferably present in the fatty phase of the composition according to the invention.
According to a particular embodiment of the invention, the pigments may be coated according to the invention with at least one compound chosen from silicone surface agents; fluoro surface agents; fluorosilicone surface agents; metal soaps; N-acylamino acids or salts thereof; lecithin and derivatives thereof; isopropyl triisostearyl titanate; isostearyl sebacate; natural plant or animal waxes; polar synthetic waxes; fatty esters; phospholipids; and mixtures thereof.
According to a particular embodiment of the invention, the pigments may be coated with a hydrophilic compound.
According to a particular embodiment, the dyestuff is an organic pigment, which is synthetic, natural or of natural origin.
The term “organic pigment” refers to any pigment that satisfies the definition in Ullmann's encyclopaedia in the chapter on organic pigments. The organic pigment may notably be chosen from nitroso, nitro, azo, xanthene, quinoline, anthraquinone, phthalocyanine, metal complex type, isoindolinone, isoindoline, quinacridone, perinone, perylene, diketopyrrolopyrrole, thioindigo, dioxazine, triphenylmethane and quinophthalone compounds.
The organic pigment(s) may be chosen, for example, from carmine, carbon black, aniline black, melanin, azo yellow, quinacridone, phthalocyanine blue, sorghum red, the blue pigments codified in the Color Index under the references CI 42090, 69800, 69825, 73000, 74100 and 74160, the yellow pigments codified in the Color Index under the references CI 11680, 11710, 15985, 19140, 20040, 21100, 21108, 47000 and 47005, the green pigments codified in the Color Index under the references CI 61565, 61570 and 74260, the orange pigments codified in the Color Index under the references CI 11725, 15510, 45370 and 71105, the red pigments codified in the Color Index under the references CI 12085, 12120, 12370, 12420, 12490, 14700, 15525, 15580, 15620, 15630, 15800, 15850, 15865, 15880, 17200, 26100, 45380, 45410, 58000, 73360, 73915 and 75470, and the pigments obtained by oxidative polymerization of indolic or phenolic derivatives as described in patent FR 2 679 771.
The pigments may also be in the form of composite pigments as described in patent EP 1184 426. These composite pigments may notably be composed of particles including a mineral core at least partially covered with an organic pigment and at least one binder for fixing the organic pigments to the core.
The pigment may also be a lake. The term “lake” means insolubilized dyes adsorbed onto insoluble particles, the assembly thus obtained remaining insoluble during use.
The inorganic substrates onto which the dyes are adsorbed are, for example, alumina, silica, calcium sodium borosilicate or calcium aluminium borosilicate and aluminium.
Among the organic dyes, mention may be made of cochineal carmine. Mention may also be made of the products known under the following names: D&C Red 21 (CI 45 380), D&C Orange 5 (CI 45 370), D&C Red 27 (CI 45 410), D&C Orange 10 (CI 45 425), D&C Red 3 (CI 45 430), D&C Red 4 (CI 15 510), D&C Red 33 (CI 17 200), D&C Yellow 5 (CI 19 140), D&C Yellow 6 (CI 15 985), D&C Green 5 (CI 61 570), D&C Yellow 10 (CI 77 002), D&C Green 3 (CI 42 053), D&C Blue 1 (CI 42 090).
An example of a lake that may be mentioned is the product known under the name D&C Red 7 (CI 15 850:1).
The pigment(s) are preferably present in composition (A), (B), (C) and/or (D) in contents of less than 60% by weight, or even less than 50% by weight, more particularly ranging from 2% to 50% by weight and even better still from 3% to 45% by weight, relative to the total weight of composition (A), (B), (C) and/or (D).
According to a particular embodiment of the invention, the dyestuff is a water-soluble dye or a liposoluble dye.
For the purposes of the invention, the term “water-soluble dyestuff” means any natural or synthetic, generally organic compound, which is soluble in an aqueous phase or water-miscible solvents and which is capable of imparting colour.
For the purposes of the invention, the term “liposoluble dyestuff” means any natural or synthetic, generally organic compound, which is soluble in an oily phase or in solvents that are miscible with the oily phase, and which is capable of imparting colour.
As water-soluble dyes that are suitable for use in the invention, mention may notably be made of synthetic or natural water-soluble dyes, for instance FDC Red 4, DC Red 6, DC Red 22, DC Red 28, DC Red 30, DC Red 33, DC Orange 4, DC Yellow 5, DC Yellow 6, DC Yellow 8, FDC Green 3, DC Green 5 and FDC Blue 1.
Among the natural water-soluble dyes, mention may be made of anthocyanins.
As liposoluble dyes that are suitable for use in the invention, mention may notably be made of liposoluble dyes, for instance DC Red 17, DC Red 21, DC Red 27, DC Green 6, DC Yellow 11, DC Violet 2, DC Orange 5, Sudan red and Sudan brown.
As illustrations of natural liposoluble dyes, mention may be made particularly of carotenes, for instance β-carotene, α-carotene and lycopene; quinoline yellow; xanthophylls such as astaxanthin, antheraxanthin, citranaxanthin, cryptoxanthin, canthaxanthin, diatomoxanthin, flavoxanthin, fucoxanthin, lutein, rhodoxanthin, rubixanthin, siphonaxanthin, violaxanthin, zeaxanthin; annatto; curcumin; quinizarin (ceres green BB, D&C green No. 6, CI 61565, 1,4-di-p-toluidinoanthraquinone, green No. 202, quinazine green SS) and chlorophylls.
The water-soluble or liposoluble dye(s) are preferably present in composition (A), (B), (C) and/or (D) in contents of less than 4% by weight, or even less than 2% by weight, more preferentially ranging from 0.01% to 2% by weight and even better still from 0.02% to 1.5% by weight, relative to the total weight of composition (A), (B), (C) and/or (D).
According to a particular embodiment, the invention relates to a cosmetic process for making up keratin materials, which consists in successively applying, irrespective of the order of application to said keratin materials:
According to a first variant, the following are successively applied onto the keratin materials:
According to a particular embodiment, said makeup composition (A) is aqueous and the post-treatment composition (B) is aqueous.
According to another particular embodiment, said makeup composition (A) is aqueous and the post-treatment composition (B) is anhydrous.
According to another particular embodiment, said makeup composition (A) is anhydrous and the post-treatment composition (B) is aqueous. According to another particular embodiment, said makeup composition (A) is anhydrous and the post-treatment composition (B) is anhydrous.
According to a second variant, the following are successively applied onto the keratin materials:
According to a particular embodiment, said makeup composition (B) is aqueous and the post-treatment composition (A) is aqueous.
According to another particular embodiment, said makeup composition (B) is aqueous and the post-treatment composition (A) is anhydrous.
According to another particular embodiment, said makeup composition (B) is anhydrous and the post-treatment composition (A) is aqueous.
According to another particular embodiment, said makeup composition (B) is anhydrous and the post-treatment composition (A) is anhydrous.
According to a third variant, the following are successively applied onto the keratin materials:
According to a particular embodiment, said pretreatment composition (A) is aqueous and the makeup composition (B) is aqueous.
According to another particular embodiment, said pretreatment composition (A) is aqueous and the makeup composition (B) is anhydrous.
According to another particular embodiment, said pretreatment composition (A) is anhydrous and the makeup composition (B) is aqueous.
According to another particular embodiment, said pretreatment composition (A) is anhydrous and the makeup composition (B) is anhydrous.
According to a fourth variant, the following are successively applied onto the keratin materials:
According to a particular embodiment, said pretreatment composition (B) is aqueous and the makeup composition (A) is aqueous.
According to another particular embodiment, said pretreatment composition (B) is aqueous and the makeup composition (A) is anhydrous.
According to another particular embodiment, said pretreatment composition (B) is anhydrous and the makeup composition (A) is aqueous.
According to another particular embodiment, said pretreatment composition (B) is anhydrous and the makeup composition (A) is anhydrous.
Among variants 1 to 4 defined previously, use will preferably be made of variants 1 and 2, in which a first coat of makeup is applied with composition (A) or composition (B) containing said dyestuff(s).
Use will preferably be made as dyestuff of one or more pigments, when composition (A) and/or the makeup composition (B) comprises an anhydrous support comprising an oily phase.
Among the variants 1 to 4 defined previously, use will more particularly be made of variants 1 and 4 in which the dyestuffs are in composition (A) as defined previously.
According to a particularly preferred embodiment, the following are successively applied onto the keratin materials:
Another cosmetic process for making up keratin materials according to the invention consists in applying to said keratin materials at least one composition (C) as defined previously comprising at least one dyestuff.
Another cosmetic process for making up keratin materials according to the invention consists in applying to said keratin materials at least one composition (D) comprising at least one dyestuff.
According to another subject, the present invention relates to a process for making up keratin materials, which consists in successively applying to said materials, independently of the order:
According to a particular form, said process for making up keratin materials consists in successively applying to said materials:
According to another particular form, said process for making up keratin materials consists in successively applying to said materials:
Another subject of the present invention is a cosmetic kit for making up keratin materials, notably for care and/or makeup, more particularly for makeup, comprising at least:
Another process for making up keratin materials according to the invention consists in successively applying, irrespective of the order of application, to said keratin materials:
Another process for making up keratin materials according to the invention consists in successively applying, irrespective of the order of application, to said keratin materials:
The makeup composition (M) comprises at least one dyestuff chosen from those defined previously.
The makeup composition (M) in accordance with the invention may be a makeup product for the skin, the face, the cheeks or the area around the eyes, notably chosen from foundations, eyeshadows and face powders, lipsticks, mascaras, eyebrow makeup products and eyeliners.
The foundations (M) according to the invention are preferably gels, creams, milks or lotions. They may be aqueous dispersions, oily anhydrous compositions or multi-phase compositions such as oil-in-water emulsions, water-in-oil emulsions, or two-phase or three-phase compositions.
The foundations (M) in accordance with the invention may contain one or more ingredients commonly used in products of this type such as organic solvents, volatile oils, non-volatile oils, waxes, resins, thickeners, gelling agents, surfactants, film-forming polymers, fillers, cosmetic active agents such as vitamins, UV sunscreens or moisturizers. The dyestuffs used are preferentially pigments, and notably hydrophobic coated pigments.
For high-viscosity compositions such as thickened creams, the viscosity measured at 25° C. and at atmospheric pressure is greater than or equal to 4.5 Pa·s at a shear rate of 200 s−1 and less than or equal to 50 Pa·s using a Brookfield Rheomat RM 180 viscometer equipped with a No. 4 spindle, the measurement being taken after 10 minutes of rotation of the spindle in order to stabilize the rotational speed and the viscosity.
For fluid compositions, the viscosity measured at 25° C. and at atmospheric pressure is less than or equal to 4.5 Pa·s, notably between 1 mPa·s and 4.5 Pa·s at a shear rate of 200 s−1 and less than or equal to 50 Pa·s using a Brookfield Rheomat RM 180 viscometer equipped with a No. 4 spindle, the measurement being taken after 10 minutes of rotation of the spindle in order to stabilize the rotational speed and the viscosity.
The foundation compositions may also be in hot-cast solid form.
The makeup compositions (M) in accordance with the invention in the form of eyeshadows or face powders are preferably in loose or compact powder form. The dyestuffs used are preferentially pigments, and notably hydrophobic coated pigments.
The term “compact powder” means a mass of product whose cohesion is at least partly provided by compacting during the manufacture. In particular, it should more specifically be understood that these powders have a Shore A hardness, measured using a Zwick durometer, which ranges, depending on the strength of the tints under consideration, from 12 to 50° Shore A, preferably from 15 to 25° Shore A.
The term “loose powder” means a mass of product that is capable of collapsing under its own weight; such a mass being formed by particles that are predominantly isolated and mobile relative to each other.
The makeup compositions (M) according to the invention in loose or compact powder form generally comprise at least one pulverulent phase comprising at least one filler. The composition may comprise the pulverulent phase in an amount of greater than or equal to 50% by weight relative to the total weight of the composition. The fillers are generally colourless or white particles of any shape, which are insoluble or dispersed in the medium of the composition, irrespective of the temperature at which the composition is manufactured. These fillers, of mineral or organic, natural or synthetic nature, give the composition softness and give the skin a matt effect and uniformity. The fillers may be in lamellar (or platelet), spherical (or globular) or fibrous form or in a form intermediate between these defined forms. The amount of filler(s) may be greater than or equal to 40% by weight relative to the total weight of the composition. The compositions are generally anhydrous. The powders of the invention may also contain an oily phase. They may also contain common cosmetic additives notably chosen from film-forming polymers, active agents, sunscreens, preserving agents, antioxidants, solvents, fragrances, surfactants, thickeners, bactericides, odour absorbers, active substances (i.e. moisturizers, vitamins, etc.), and mixtures thereof.
The makeup composition (M) in accordance with the invention may be a lip makeup product, notably a lipstick, a lip gloss or a lip balm.
The lipstick compositions (M) may be in solid form such as a wand, or products in a dish or in liquid form. They may be anhydrous or aqueous, notably water-in-oil or oil-in-water emulsions. Depending on the support and the presentation form, they may contain one or more ingredients commonly used in products of this type such as organic solvents, volatile oils, non-volatile oils, waxes, film-forming polymers, fillers, cosmetic active agents such as vitamins, UV sunscreens or moisturizers. The dyestuffs used are pigments, water-soluble dyes, liposoluble dyes, and mixtures thereof.
The makeup composition (M) in accordance with the invention may also be a makeup product for the eyelashes and/or the eyebrows, notably chosen from mascaras and eyeliners.
The mascaras (M) in accordance with the invention are preferably oil-in-water emulsions with waxes, anionic emulsifying surfactants such as alkyl phosphate salts, fatty acid salts, nonionic surfactants such as polyoxyethylenated fatty alcohols, or film-forming polymers, notably in the form of a particle dispersion (latex). They may also contain common additives such as fillers, thickeners, gelling agents, cosmetic active agents such as vitamins, amino acids or moisturizers. The dyestuffs used are chosen from pigments, water-soluble dyes, liposoluble dyes, and mixtures thereof.
The eyeliners are preferably aqueous compositions with film-forming polymers, notably in the form of a particle dispersion (latex). They may contain common ingredients chosen from waxes, surfactants, fillers, thickeners, gelling agents, cosmetic active agents such as vitamins, amino acids or moisturizers, and mixtures thereof.
Compositions (A), (B), (C) and/or (D) of the invention may contain additives that are common in cosmetics. Mention may notably be made of antioxidants, preserving agents, neutralizers, gelling agents or thickeners, surfactants, cosmetic active agents, for instance emollients, moisturizers or vitamins, and mixtures thereof.
In particular, the antioxidants are used to prevent the oxidation of the polyphenol X. They may be chosen from ascorbic acid and derivatives thereof, erythorbic acid, sulfites and metabisulfite, and reducing agents of thiol type, in particular cysteine. Mention may also be made of carotenes and lycopenes, which also act as liposoluble dyes.
These additives may be present in compositions (A), (B), (C) and/or (D) in a content ranging from 0.01% to 15.0% relative to the total weight of the composition.
Needless to say, a person skilled in the art will take care to select the optional additional additives and/or the amount thereof such that the advantageous properties of compositions (A), (B), (C) and/or (D) according to the invention are not, or are not substantially, adversely affected by the envisaged addition.
Compositions (A), (B), (C) and/or (D) may be manufactured via the known processes, generally used in the cosmetic field.
Compositions (A), (B), (C) and/or (D) used according to the invention may be care products for keratin materials such as the skin, the area around the eyes, the lips, the hair, the eyelashes, the eyebrows and the nails.
Compositions (A), (B), (C) and/or (D) used according to the invention may be makeup products for keratin materials such as the skin, the area around the eyes, the lips, the eyelashes, the eyebrows and the nails, such as foundations, eyeshadows, lipsticks, mascaras, eyeliners, nail varnishes, primers or finishers.
Compositions (A), (B), (C) and/or (D) used according to the invention may be hybrid products, i.e. products for caring for and making up keratin materials such as the skin, the area around the eyes, the lips, the eyelashes, the eyebrows and the nails, such as foundations, eyeshadows, lipsticks, mascaras, eyeliners and nail varnishes.
Compositions (A), (B), (C), (D) and/or (M) according to the invention may each be packaged in a container delimiting at least one compartment that comprises said composition, said container being closed by a closing member.
The container may be in any suitable form. It may notably be in the form of a bottle, a tube, a jar or a case.
The closing member may be in the form of a removable stopper, a lid or a cover, notably of the type including a body fixed to the container and a cap articulated on the body. It may also be in the form of a member for selectively closing the container, notably a pump, a valve or a flap valve.
The container may be combined with an applicator, notably in the form of a brush including an arrangement of bristles maintained by a twisted wire. Such a twisted brush is described notably in patent U.S. Pat. No. 4,887,622. It may also be in the form of a comb including a plurality of application members, obtained notably by moulding. Such combs are described, for example, in patent FR 2 796 529. The applicator may be in the form of a fine brush, as described, for example, in patent FR 2 722 380. The applicator may be in the form of a block of foam or of elastomer. The applicator may be free (sponge) or securely fastened to a rod borne by the closing member, as described, for example, in patent U.S. Pat. No. 5,492,426. The applicator may be securely fastened to the container, as described, for example, in patent FR 2 761959.
The product may be contained directly in the container, or indirectly.
The closing member may be coupled to the container by screwing. Alternatively, the coupling between the closing member and the container occurs other than by screwing, in particular via a bayonet mechanism, by click-fastening or by gripping. The term “click-fastening” in particular means any system involving the crossing of a bead or cord of material by elastic deformation of a portion, notably of the closing member, followed by return to the elastically unconstrained position of said portion after the bead or cord has been crossed.
The container may be at least partially made of thermoplastic material. Examples of thermoplastic materials that may be mentioned include polypropylene and polyethylene.
The container may have rigid or deformable walls, notably in the form of a tube or a tube bottle.
The container may comprise means intended to bring about or facilitate the dispensing of the composition. By way of example, the container may have deformable walls so as to cause the composition to exit in response to excess pressure inside the container, which excess pressure is brought about by the elastic (or nonelastic) squeezing of the walls of the container
The container may be equipped with a drainer positioned in the vicinity of the opening of the container. Such a drainer makes it possible to wipe the applicator and possibly the rod to which it may be securely fastened. Such a drainer is described, for example, in patent FR 2 792 618.
Throughout the description, including the claims, the term “including a” should be understood as being synonymous with “including at least one”, unless otherwise specified.
The expressions “between . . . and . . . ”, and “ranging from . . . to . . . ” should be understood as meaning limits included, unless otherwise specified.
The invention is illustrated in greater detail by the examples and figures presented below. Unless otherwise indicated, the amounts shown are expressed as mass percentages.
a) Processes in which a Composition (D) Comprising the Polyphenol X, the Compound Y that is Capable of Interacting by Hydrogen Bonding and a Hydrogen-Bonding Inhibitor (Ethanol) are Applied
The following compositions were prepared.
Phases A and B were prepared by mixing the ingredients of each of these phases at room temperature with stirring until homogeneous solutions were obtained. Next, phases A, B and C were mixed in a beaker until homogeneous compositions were obtained.
Square transparent PET plates with a side length of 6 cm were cut.
An adhesive disc (Monaderm® ref. PA22/36 double-sided disc, diameter 22/36), the inner circle of which was 22 mm in diameter, was applied, in order to control and to delimit the application area. The same amount of product per unit area was thus applied.
0.15 g of sample product was placed in this circle.
The sample was left to dry for 12 hours at room temperature.
Next, the plate was soaked with 600 ml of water with stirring for 2 minutes.
The amount of product remaining on the plate was then characterized by measuring the optical transmittance measured using a Haze® Guard i machine (Byk).
This test characterized the water resistance of the compositions tested.
Examples 1 to 4 according to the invention comprising tannic acid (polyphenol X) and a hydrogen bonding compound Y led to low transmittance values, reflecting the fact that a substantial amount of deposit remained on the support: the water resistance and the persistence of these deposits were improved.
On the other hand, Examples 1a to 4a outside the invention not containing any tannic acid and Example 4b outside the invention not containing any hydrogen bonding compound Y led to high transmittance values. This demonstrated that there was no longer anything remaining on the PET plate: the water resistance was too low.
The following compositions were prepared.
Pinus
pinaster
Camellia
sinensis
Examples 5 to 9 and 5a to 10a were prepared under the same conditions as previously.
The same water resistance test was performed under the same conditions as previously.
Examples 5 to 9 according to the invention comprising green tea extract or extract of maritime pine bark rich in procyanidins (polyphenol X) and a hydrogen bonding compound Y led to low transmittance values, reflecting the fact that a substantial amount of deposit remained on the support: the water resistance and the persistence of these deposits were improved.
On the other hand, Examples 5a to 8a outside the invention not containing any polyphenol and Examples 9a and 10a outside the invention not containing any hydrogen bonding compound Y led to much higher transmittance values. This demonstrated that the amount of deposit on the PET plate had decreased: the water resistance was too low.
The following compositions were prepared.
Phases A and B were prepared by mixing the ingredients of each of these phases at room temperature with stirring until homogeneous solutions were obtained. Next, phases A, B and C were mixed in a beaker. Homogeneous red compositions were obtained.
Sealing discs of screw lids with a totally flat surface made of white polypropylene suitable for 15 ml jars with a diameter of 43 mm were recovered.
0.15 g of product was placed in one of the sealing discs.
The sample was left to dry for 12 hours.
Next, the plate was soaked with 40 ml of water with stirring for 2 minutes.
The colour remaining on the white plate was then characterized.
Examples 10 to 14 according to the invention comprising tannic acid (polyphenol X) and a hydrogen bonding compound Y led to the persistence of a red-coloured deposit on the surface of the sealing disc. The water resistance and the persistence of these deposits were improved.
In contrast, Examples 1b to 4b outside the invention not containing any tannic acid (polyphenol X) and Example 5b outside the invention not containing any hydrogen bonding compound Y led to total diffusion of the water-soluble dye and to a white colour on the surface of the sealing disc. The water resistance and the persistence of these deposits were poor.
The anhydrous liquid lipsticks having the following composition were prepared.
The liquid lipstick R1 having the following composition was prepared.
Phase A was prepared by mixing the ingredients of this phase at room temperature until a transparent homogeneous phase was obtained.
The ingredients of phase E were placed in a melting pan and mixed at a temperature of 95° C. until a homogeneous mixture was obtained. Phase A was then added, followed by phase B and finally phase C. Once the mixture was homogeneous, it was cooled with stirring down to room temperature.
Phase B was prepared by mixing the ingredients of this phase until a transparent homogeneous phase was obtained. Next, phases A and B were mixed until a homogeneous phase was obtained.
Square transparent PET plates with a side length of 6 cm were cut.
An adhesive disc (Monaderm® ref. PA22/36 double-sided disc, diameter 22/36), the inner circle of which was 22 mm in diameter, was applied, making it possible to control and to delimit the application area. The same amount of product per unit area was thus applied. 0.15 g of each example of composition was placed in this circle. Each sample was left to dry for 12 hours at room temperature. The adhesive disc was then removed. The plate covered with this red deposit was then dipped in 100 ml of isododecane with stirring for 30 seconds. The plate was then removed and placed with the coloured face down on a paper towel (Wypall L40® from Kimberly-Clark). A mass of 2 kg was applied, distributed over a rectangular area of 37 mm×50 mm. This operation was repeated eight times successively on the same sample. The red marks left on the absorbent paper and the amount of product remaining on the PET plate were then evaluated. This test characterized the transfer resistance of the composition in the presence of oil.
The deposit obtained using composition R1 outside the invention was completely transferred after seven cycles. In other words, no more coloured deposit remained on the PET plate after seven cycles. Composition 15 according to the invention transferred onto the towel after eight cycles, but the amount of deposit on the PET plate remained very substantial in comparison with R1. Composition 16 transferred slightly more than composition 15 and the amount of deposit remaining on the PET plate after eight cycles was markedly larger than that for composition R1. Composition 17 transferred colour sparingly up to eight cycles and the amount of deposit remaining was markedly larger than for composition R1.
Composition 1c outside the invention was heterogeneous: it underwent phase separation.
b) Process in which a Composition (C) Comprising a Preformed Coating Agent Obtained by Interaction of a Polyphenol X and of a Compound Y Capable of Interacting by Hydrogen Bonding is Applied
The coating agent P1 was prepared from the following composition.
Phases A and B were prepared separately, so as to obtain transparent homogeneous compositions. Phases A and B were then mixed, and reacted together to form a precipitate. The precipitate was then isolated by filtration followed by washing with water.
The coating agent P2 was prepared from the following composition under the same preparation conditions as previously.
The anhydrous liquid lipsticks having the following composition were prepared.
The lipstick R1 as described previously was used.
The preformed treating agent P1 or P2 was introduced into the liquid lipstick composition R1, which was stirred until a homogeneous mixture was obtained.
The same transfer resistance test as described previously for Examples 15 to 17 was performed.
The deposit obtained using composition R1 was completely transferred after seven cycles. In other words, no more coloured deposit remained on the PET plate after seven cycles.
Compositions 18 and 19 of the invention comprising tannic acid (polyphenol X) and a hydrogen bonding compound Y transferred slightly onto the towel up to eight cycles and the amount of deposit on the PET plate remained very substantial in comparison with composition R1.
The following formulations were prepared:
Square transparent PET plates with a side length of 6 cm were cut.
An adhesive disc (Monaderm® ref. PA22/36 double-sided disc, diameter 22/36), the inner circle of which was 22 mm in diameter, was applied, making it possible to control and to delimit the application area. The same amount of product per unit area was thus applied. 0.1 g of the above formulations was then applied to the PET support as a superposition of 1) base coat and 2) top coat without mixing, allowing the base coat to dry before applying the top coat.
The optical transmittance of the deposits thus obtained was measured using a Haze Guard® i machine (Byk).
The deposits were then immersed in 50 ml of demineralized water with stirring for 1 minute, followed by immersion in isododecane with stirring for 1 minute.
After drying, the optical transmittance of the resistant deposits was measured under the same conditions.
The deposits were then immersed in 50 ml of isododecane with stirring for 1 minute.
The change in transmittance was expressed as a percentage increase relative to the transmittance measured before immersion. The higher this increase, the lower the resistance of the deposit to water and the greater the degradation of the film obtained.
The results are collated in the table below:
The values show that
a) Two-Stage Makeup Process with 1) Application of a First Coat (Base Coat) of Composition (A) Comprising a Polyphenol X (Tannic Acid) and 2) Application of a Second Coat (Top Coat) of a Composition (B) Comprising a Monoglycerolated and/or Polyglcerolated Polyoxyalkylenated Compound Y
The following formulations were prepared:
0.1 g of the above formulations was then applied to the PET support as a superposition of 1) base coat and 2) top coat without mixing, allowing the base coat to dry before applying the top coat.
The optical transmittance of the deposits thus obtained was measured using a Haze Guard i machine (Byk). The deposits were then immersed in 50 ml of demineralized water with stirring for 1 minute. After drying, the optical transmittance of the resistant deposits was measured under the same conditions. The variation in transmittance was expressed as a percentage increase relative to the transmittance measured before immersion. The higher this increase, the lower the resistance of the deposit to water. The results are collated in the table below:
In contrast with the two-stage makeup processes outside the invention using the polyphenol tannic acid alone or the hydrogen bonding acceptor compound Y alone, the two-stage makeup processes according to the invention using the superposition of a first coat with tannic acid and of a second coat with the hydrogen bonding acceptor compound Y led to a very marked improvement in the water resistance.
b) Two-Stage Makeup Process with 1) Application of a First Coat (Base Coat) of Makeup Composition R1 and 2) Application of a Second Coat (Top Coat) of a Composition (D) Comprising a Polyphenol X, a Compound Y which is Capable of Interacting with the Polyphenol by Hydrogen Bonding and a Hydrogen Bonding Inhibitor (Ethanol)
The lipstick R1 as defined previously is used as first coat.
The following second-coat (Top Coat) compositions were prepared.
The ingredients of phase A were mixed until a transparent homogeneous mixture was obtained.
A first coat of lipstick R1 was applied to an adhesive disc defined below, followed by application to said first makeup coat, as second coat, of one of the compositions 22 to 24 according to the invention.
As a reference process, only one coat of lipstick R1 as defined previously was applied.
Square transparent PET plates with a side length of 6 cm were cut.
An adhesive disc (Monaderm@ ref. PA22/36 double-sided disc, diameter 22/36), the inner circle of which was 22 mm in diameter, was applied, making it possible to control and to delimit the application area. The same amount of product per unit area was thus applied.
0.15 g of a first coat of makeup composition R1 was placed in this circle.
The first coat was left to dry for 6 hours at room temperature.
0.15 g of each top coat composition 22, 23 or 24 according to the invention was then deposited on the first coat.
The second coat was left to dry for 12 hours at room temperature.
The adhesive disc was then removed. The plate covered with this red deposit was then dipped in 100 ml of isododecane with stirring for 30 seconds. The plate was then removed and placed with the coloured face down on a paper towel (Wypall L40@ from Kimberly-Clark). A mass of 2 kg was applied, distributed over a rectangular area of 37 mm×50 mm. This operation was repeated eight times successively on the same sample.
The red marks left on the absorbent paper and the amount of product remaining on the PET plate were then evaluated.
This test characterized the transfer resistance of the composition in the presence of oil.
The deposit obtained with only one coat of composition R1 was completely transferred after seven cycles: no more coloured deposit remained on the PET plate.
No transfer was observed with the superposition of composition R1 with one of the top coat compositions 22, 23 and 24 according to the invention.
The top coat compositions 22, 23 and 24 according to the invention comprising tannic acid (polyphenol X) and a hydrogen bonding compound Y afforded a significant improvement in the transfer resistance in the presence of oil.
A mascara composition M1 as defined below is used as first coat.
All the above ingredients, with the exception of the acrylic film-forming polymer (Daitosol 5000 AD), were introduced into a volume of water corresponding to 20% of the total water, in a tank, at room temperature.
The mixture obtained was heated at 95° C. with stirring for 20 minutes. The remaining water was then added and the mixture was homogenized and emulsified for 15 minutes with mechanical stirring (impeller+turbomixer) at this temperature. The mixture was then cooled with stirring to 40° C. The acrylic film-forming polymer (Daitosol 5000 AD®) was then added. The final mixture was homogenized with the impeller and left to cool to 20° C.
The following second-coat composition according to the invention (Top Coat) was prepared.
The ingredients of phase A were mixed until a transparent homogeneous mixture was obtained.
Formulations M1 and 25 were packaged in the Hypnose® pack from Lancôme. The products were applied to false eyelash specimens. The mascara M1 is applied to the false eyelash specimens by applying two times 15 brush strokes. The mascara is left to dry on the specimens for 6 hours.
Next, on one specimen, the mascara M1 of two times 15 brush strokes is superposed with two times 15 brush strokes of the top coat composition 25, allowing composition M1 to dry before applying composition 25. The whole is left to dry for 6 hours. These specimens are then dipped in a beaker containing 600 ml of water with stirring. After 10 minutes, the specimens are removed and the amount of mascara remaining on the specimens is noted. The water resistance of the mascara is thus evaluated.
The amount of black remaining on the specimens was evaluated by evaluating the number of black pixels by means of photographs of the specimens. Using a Nikon D800 camera set at a resolution of 20 megapixels, photos are taken of the specimen without makeup, of the made-up specimen and of the specimen after having been subjected to immersion in water for 10 minutes. The number of black pixels due to the specimen without makeup was then subtracted to determine the number of black pixels for the mascara deposit after makeup and the number of black pixels for the deposit remaining on the eyelash after immersion. This measurement is repeated twice to subsequently obtain a mean of the percentage of black pixels remaining on the specimen after immersion.
The above table shows that with the mascara composition M1, only 23.9% of its initial deposit remained, whereas with the sample obtained by superposition of the mascara M1 with the top coat composition 25, 100% of the initial deposit remained. The superposition of a mascara composition with Example 25 according to the invention comprising an agent resulting from the combination of a polyphenol X and of a compound Y thus significantly increases the amount of deposit remaining on the eyelash and thus the water resistance of the deposit.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2013292 | Dec 2020 | FR | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/EP2021/084230 | 12/3/2021 | WO |
