Claims
- 1. A process for the hydrocarbon solution polymerization of a monomer composition containing 10-90 percent by weight of a conjugated diene and 10-90 percent by weight of an alpha-olefin having 2-10 carbon atoms to produce a copolymer having 5-90 percent of the alpha-olefin in the resultant copolymer comprising the steps of maintaining said monomer composition at a temperature in the range of -30.degree. to 50.degree. C in intimate contact with a catalyst composition consisting essentially of:
- a. an aluminum hydride of the formula R.sub.2 AlH where R is hydrogen or a hydrocarbon radical of 1-20 carbon atoms, there being at least one hydrocarbon radical per molecule;
- b. a metal halide compound having the formula TiBr.sub.n Cl.sub.4-n or VBr.sub.m Cl.sub.5-m wherein n has a value of 0-4 and m has a value of 0-5; and
- c. a carbonyl-containing compound having no more than 20 carbon atoms selected from the class consisting of aldehydes, ketones and carboxylic acids, esters, amides and carbamates; said carbonyl-containing compound having no halogen atoms therein except that there may be a chlorine attached directly to a carbon of an aromatic ring in said compound; the concentration of said titanium or vanadium halide being 0.1-4 millimoles per 100 grams of said monomer composition, said aluminum hydride being present in a proportion of 1-4 moles per mole of titanium or vanadium halide, and said carbonyl compound being present in a proportion of 0.7-4 moles per mole of titanium or vanadium halide, said polymerization being conducted for a period of at least one hour.
- 2. The process of claim 1 in which said diene is butadiene.
- 3. The process of claim 2 in which said alpha-olefin is propylene.
- 4. The process of claim 3 in which the ratio of said aluminum hydrocarbon hydride is about 2-3 moles per mole of said halide.
- 5. The process of claim 4 in which said halide is a titanium halide.
- 6. The process of claim 4 in which said halide is titanium tetrachloride.
- 7. The process of claim 6 in which said aluminum hydrocarbon hydride is a dialkyl aluminum hydride.
- 8. The process of claim 6 in which said hydride is diisobutyl aluminum hydride.
- 9. The process of claim 6 in which said carbonyl compound is a ketone.
- 10. The process of claim 6 in which said carbonyl compound is acetophenone.
- 11. The process of claim 9 in which said temperature is 0.degree.-50.degree. C.
- 12. The process of claim 11 in which said monomer composition is 10-50 percent by weight propylene.
- 13. The process of claim 12 in which said carbonyl compound is used in a proportion of 1-2 moles per mole of said halide.
Parent Case Info
This application is a continuation-in-part of application Ser. No. 627,983 filed Nov. 3, 1975, now abandoned, which in turn is a continuation-in-part of application Ser. No. 509,525 filed Sep. 26, 1974, now abandoned.
US Referenced Citations (6)
Continuation in Parts (2)
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Number |
Date |
Country |
Parent |
627983 |
Nov 1975 |
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Parent |
509525 |
Sep 1974 |
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