Claims
- 1. Process for the catalytic isomerization of endo tetrahydrodimethyldicyclopentadiene comprising:
- (a) contacting endo tetrahydrodimethyldicyclopentadiene with a catalytic amount of acidic alumina having isomeric activity;
- (b) having the contacting occur at an isomerization temperature in the range of from about 100.degree. C. to about 400.degree. C. and in the presence of sufficient hydrogen to maintain the isomeric activity of the alumina; and
- (c) continuing the contacting until the endo diene is isomerized to its exo isomer.
- 2. Process according to claim 1 wherein in addition to the acidic alumina a hydrogenation metal is present.
- 3. Process according to claim 1 or 2 wherein the acidic alumina is silica-alumina.
- 4. Process according to claim 2 wherein the hydrogenation metal is palladium or nickel.
- 5. Process according to claim 2 wherein the catalyst is (1) a mixture of palladium on carbon and an acid clay; (2) a mixture of palladium on carbon and nickel on silica alumina; or (3) palladium on alumina, and the hydrogen has a pressure of at least about 30 psig.
- 6. Process according to claim 2 wherein the catalyst is a mixture of palladium on carbon and nickel on silica alumina and the hydrogen has a pressure of at least about 105 psig.
- 7. Process according to claim 2 wherein the catalyst is nickel on silica-alumina and the hydrogen has a pressure of at least about 200 psig.
- 8. Process according to claim 1 wherein the catalyst to the diene ratio ranges between from about one-half part by weight of catalyst per hundred parts by weight of the diene to about one to one.
- 9. Process according to claim 5, 6 or 7 wherein the resulting isomer mixture has a density (20.degree. C.)/4 in the range between from about 0.911 to about 0.918.
- 10. Process according to claim 5, 6 or 8 wherein the resulting isomer mixture has a kinematic viscosity @ 100.degree. F. in the range between from about 2 cst to about 3 cst.
CROSS-REFERENCE TO RELATED APPLICATION
This application is a continuation-in-part of U.S. Application Ser. No. 961,911, filed Nov. 20, 1978 now abandoned, which was a continuation-in-part of U.S. application Ser. No. 838,182, filed Sept. 30, 1977, now abandoned.
BACKGROUND OF THE INVENTION
The invention herein described was made in the course of or under a contract thereunder with U.S. Air Force Systems Command.
US Referenced Citations (3)
Number |
Name |
Date |
Kind |
3381046 |
Cohen et al. |
Apr 1968 |
|
4059644 |
Cannell |
Nov 1977 |
|
4177217 |
Janoski et al. |
Dec 1979 |
|
Continuation in Parts (2)
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Number |
Date |
Country |
Parent |
961911 |
Nov 1978 |
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Parent |
838182 |
Sep 1977 |
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