Claims
- 1. A process for manufacturing a polymer comprised of an alkyl substituted poly(2,2'-bipyridine-5,5'-diyl) having a chemical formula which is at least one of: ##STR17## where R and R' are H or an alkyl group having not less than 1 carbon atom, except that at least one of R and R' is an alkyl group having not less than 3 carbons, `n` is a degree of polymerization and is not less than 10, the process comprising:
- a. providing at least one alkyl substituted 5,5'-dihalogenated-2,2'-bipyridine having alkyl substituents in the 3-, 4- or 6-position of two pyridinediyl groups; and
- b. polymerizing the at least one alkyl substituted 5,5'-dihalogeanted-2,2'-bipyridine by adding an effective amount thereto of at least one substance which is effective to remove halogens therefrom, which at least one substance is selected from the group consisting of (a) at least one metal which is capable of dehalogenating the alkyl substituted 5,5'-dihalogenated-2,2'-bipyridine and (b) at least one compound containing at least one metal which is capable of dehalogenating alkyl substituted 5,5'-dihalogenated-2,2'-bipyridine.
- 2. The process as claimed in claim 1, wherein the at least one compound containing at least one metal is at least one zero-valent nickel compound.
- 3. A process for manufacturing a polymer comprised of an alkyl substituted poly(2,2'-bipyridine-5,5'-diyl) having a chemical formula which is at least one of: ##STR18## where R and R' are H or an alkyl group having not less than 1 carbon atom, except that at least one of R and R' is an alkyl group having not less than 3 carbons, `n` is a degree of polymerization and is not less than 10, the process comprising:
- a. providing at least one alkyl substituted 5,5'-dihalogenated-2,2'-bipyridine having alkyl substituents in the 3-, 4- or 6-position of two pyridinediyl groups; and
- b. polymerizing the at least one alkyl substituted 5,5'-dihalogenated-2,2'-bipyridine by subjecting the at least one alkyl substituted 5,5'-dihalogeanted-2,2'-bipyridine to an electrochemical reduction in the presence of at least one compound containing at least one metal which is capable of dehalogenating the at least one alkyl substituted 5,5'-dihalogeanted-2,2'-bipyridine and which is at least one transition metal whereby halogens are removed from the at least one alkyl substituted 5,5'-dihalogenated-2,2'-bipyridine.
- 4. A process for manufacturing a polymer comprised of an alkyl substituted poly(2,2'-bipyridine-5,5'-diyl) having a chemical formula which is at least one of: ##STR19## where R and R' are H or an alkyl group having not less than 1 carbon atom, except that at least one of R and R' is an alkyl group having not less than 3 carbons, `n` is a degree of polymerization and is not less than 10, the process comprising:
- a. providing at least one alkyl substituted 5,5'-dihalogenated-2,2'-bipyridine having alkyl substituents in the 3-, 4- or 6-position of two pyridinediyl groups; and
- b. polymerizing the at least one alkyl substituted 5,5'-dihalogenated-2,2'-bipyridine by subjecting the at least one alkyl substituted 5,5'-dihalogeanted-2,2'-bipyridine to a dehalogenation polycondensation reaction by adding an effective amount of, in combination, at least one metal selected from the group consisting of magnesium (Mg) and zinc (Zn), and at least one compound containing at least one metal which is a transition metal, which at least one metal and at least one compound are capable, in combination, of dehalogenating the alkyl substituted 5,5'-dihalogeanted-2,2'-bipyridine.
- 5. The process as claimed in claim 3, wherein the at least one compound is a divalent nickel compound and the process further comprises conducting the electrochemical reduction at the reduction potential of the divalent nickel compound.
- 6. The process as claimed in claim 4, wherein the at least one compound is a divalent nickel compound and the process further comprises employing the at least one metal to reduce the divalent nickel compound to provide a zero-valent nickel compound.
Priority Claims (1)
Number |
Date |
Country |
Kind |
5-70405 |
Mar 1993 |
JPX |
|
Parent Case Info
This is a division of application Ser. No. 08/128,038 filed Sep. 29, 1993, now U.S. Pat. No. 5,424,381.
Non-Patent Literature Citations (3)
Entry |
Yamamoto et al., Chemistry Letters, pp. 223-224, 1990. |
"Preparation and Properties of Poly(2,2'-bipyridine-5,5'-diyl)". |
Yamamoto, et al., "Preparation and Properties of Poly(2,2'-bipyridine-5,5'-diyl)", Chemistry Letters, The Chemical Society of Japan, (1990), pp. 223-224. |
Divisions (1)
|
Number |
Date |
Country |
Parent |
128038 |
Sep 1993 |
|