The present invention generally refers to a process for manufacturing combined solar panels of photovoltaic and thermal type capable of converting the solar energy into both electric and thermal energy with high efficiency. The present invention further generally refers to a solar panel manufactured through such a process.
More particularly, the present invention refers to a process for manufacturing solar panels comprising, in combination, at least one photovoltaic panel and one heat-exchanging thermal panel (heat exchanger).
There are known solar panels of photovoltaic and thermal type (combined solar panels) adapted to convert solar energy into electric and thermal energy.
For example, from the publication US 2004/0025931 in the name of the Applicant, it is known a combined solar panel adapted to simultaneously generate both electric and thermal energy.
A known solar panel includes a panel or heat exchanger containing a fluid, and a photovoltaic panel comprising a plurality of photovoltaic cells and a glass sheet.
More particularly a known thermal exchanger includes a plate made of a heat-conducting material (plate) glued to a first face of the photovoltaic cells (cells), with a second face of the cells—to be exposed to the solar energy—which is protected by the glass sheet (sheet) which too is glued to the cells.
The process for manufacturing the known combined solar panels provides that, in order to glue the sheet and the plate to the opposite faces of the cells, a thin transparent layer of ethyl vinyl acetate (Ethyl Vinyl Acetate or EVA) is interposed between the sheet and the cells and between the cells and the plate. The EVA used in the known process contains additives for delaying its yellowing (which is caused by the exposure to the ultraviolet rays during the operating life of the solar panel) and have the purpose to prevent a direct contact between the cells and the glass or plate, to eliminate the interstices that would otherwise be formed because of a not perfectly smooth surface of the cells, and to electrically insulate the active part of the photovoltaic panel.
The cells of the photovoltaic panel are generally glued to the sheet and to the plate through a vacuum curing (polymerisation) process carried out in an apparatus known as “laminator”, comprising an upper chamber and a lower chamber horizontally divided by an elastic membrane. The lower chamber of the laminator contains an electric plate capable to maintain an inner temperature rather uniform and constant, with oscillations within +20° C.
A typical laminating cycle begins by placing the sandwich or module formed by glass, EVA, photovoltaic cells, EVA and plate, inside the lower chamber, making vacuum in both chambers and bringing the laminator to a temperature of about 100° C. so as to remove air stagnation (bubbles) from the sandwich.
The vacuum is then removed from the upper chamber, so that the membrane separating the two chambers uniformly compresses the module thus favouring the adhesion of the EVA to the cells, to the front glass and the plate, and the laminator is brought to a temperature of about 150° C. that allows the polymerisation of the EVA. This step can last from 10 to 20 minutes.
Finally the temperature is lowered to 100° C. and air is slowly admitted.
It is stressed that the parameters of the lamination cycle are always selected as a result of a trade-off among the specifications supplied by the EVA manufacturers, the specific experimentation of the module producers, and an optimisation of the process times with the aim to increase the production per hour. In fact, on the one hand, in order to evaluate the lamination quality it is often used the degree of EVA polymerisation, chemically determined through its insolubility (by weighing the starting amount of the polymer and the final dry residue after the thermal treatment), but on the other hand the finished product has to be obtained in the shortest time as possible and with a cost of the electric energy which is optimised in respect of its quality.
Although the lamination process for manufacturing the modules is not complex and the lamination discard rate is pretty low (<2%), the combined solar panels and particularly the photovoltaic panels are not faultless, even because of the additional operations that are often manually accomplished (such as cell alignment, welding of the contacts between the cells, welding of the termination strings, etc.).
The CEI EN 61215 (CEI 82-8) regulation lists the defects that can be recognized in a photovoltaic panel through a visual inspection (test 10.1) and through other inspections, but does not establish a merit classification which on the other hand would be useful for an acceptance test of a supply.
A typical defect listed in the above regulation as a defect that can be recognized through visual inspection (visually), it is the breakage of parts of one or more cells, generally caused by an excessive pressure during the lamination or by an improper handling of the cells in the assembly step.
Besides the defects that can be visually recognized, there are defects that cannot be visually detected and are surely more insidious.
Of course there are methods adapted to verify existence of defects before installing the solar panel, but since as a general rule they are time-consuming tests and some times invasive and requiring expensive equipments, the detection of these defects is generally committed to the guarantee supplied by the factory quality control on samples (by using anyway the reference regulations for the number of the samples in order that the tests are statistically meaningful).
Among the most common defects that cannot be visually detected there are the so-called “hot spot.”
The hot spots are locations of the solar panel (panel) at which, in the operating panels, a temperature is detected that is higher by some degrees than that of the remainder of the panel, which temperature excess is caused by an high electric resistance, usually caused by defective welding. The hot spots can be detected, for example, through IR imaging (infrared analysis) of the panel under working conditions.
Defective welding also causes electric disconnection of panel portions, possibly after years of regular exposition and working.
Among the defects that cannot be visually detected, one of the most common is the EVA yellowing after several years of operating life. Early optical degradation of the EVA by altering the colour towards a characteristic yellow-brown colour decreases the transmittance value. The main cause of the yellowing is a low polymerisation degree (<70%) and an improper stocking of the EVA before the lamination.
Generally this defect doesn't determine appreciable reductions of the solar panel performance per se.
Rather a more serious drawback arises from the associated production of acetic acid released by the EVA decomposition in contact with the cells, that can induce the corrosion of electrically conductive parts, such as electric contacts, etc.
Still more serious are the panel delaminations in use because of the ungluing among the different layers of the panel. Delamination is generally due to a poor cleaning in the assembly step of the panel or to a low degree of EVA polymerisation (<70%). During type tests (i.e. tests on a panel sample taken from the production line), delamination is checked through normalised cycles, for example according to CEI EN 61215, in a thermal chamber.
Resuming, the Applicant discovered that the known process for manufacturing composite solar panels brings about a number of problems the solution of which would allow a reduction of the defectiveness of the panels, both those visible and those that are not visible.
More particularly, the Applicant discovered that, in the known manufacturing process, the cell welding process and the lamination cycle are particularly critical and subjected to introduce defects in the composite solar panels.
It is an object of the present invention to provide a process for manufacturing a combined solar panel that is devoid of the above cited defectiveness problems, both visible and not visible ones.
An additional objects of the present invention is to provide a solar panel of the photovoltaic and thermal type having a high overall efficiency.
In accordance with the present invention, these objects are accomplished through a process for manufacturing solar panels of the photovoltaic and thermal type and through a high efficiency solar panel as claimed in the attached claims.
The claims constitute integral part of the technical teaching hereby disclosed in respect of the invention.
In accordance with a preferred embodiment, the process according to the present invention for manufacturing combined solar panels in which there is provided the presence of a thermal panel and a photovoltaic panel equipped with photovoltaic cells and a sheet that is transparent to the solar energy, provides that the cells of the photovoltaic panel are fixed to the thermal panel and to the transparent sheet thanks to a discrete number of glue spots and a resin.
In accordance with a further characteristic of the present invention, the manufacturing process provides that the resin is introduced into the panel during its construction by applying a progressive vacuum to the vertically positioned panel being manufactured.
In accordance with another characteristic of the present invention, the cells of the photovoltaic panel have contacts that are associated to rheophores having an increased cross-section in comparison to that of the contacts so as to optimise the electric efficiency of the photovoltaic panel by reducing the voltage drops.
The above and other characteristics of the present invention will result clear from the following description of preferred embodiments, given only with exemplary and not limiting purposes, with the aid of the attached figures, in which components indicated by a same or similar numerical reference relate to components having the same or similar functionality and construction, and in which:
a and
a,
With reference to
More particularly, the thermal exchanger 12 is realized as follows:
In a second step there is foreseen to make strings 40 (
More particularly, the strings 40 (
a plurality of cells 41, in a number predetermined as a function of the size of the panel 10, are aligned and welded together, e.g. in series. The cells 41, of a known type, are for example cells of crystalline silicon of circular or octagonal shape, each having on opposite faces, contacts of opposite polarity, respectively first contacts 42a and second contacts 42b. In the preferred embodiment, the contacts of each face, 42a and 42b respectively, are associated to respective rheophores, first 43a and second rheophores 43b, so that the first rheophores 43a of a first cell 41 are connected, for example by welding, to the second rheophores 43b of a second cell 41, and the first rheophores 43a of the second cell 41 are connected to the second rheophores of a third cell 41, and so on. As can be easily understood by the skilled of the art, such arrangement amounts to a series connection of the cells 41.
Preferably, the welding is carried out, for example, through a front/rear welder of a known type.
Still more preferably the cell connecting rheophores, 43a and 43b respectively, are made with a larger thickness than usual. For example the first rheophores 43a are made by welding to the contacts 42a, generally having a rectangular cross-section of about 2×0.1-0.2 mm, rectangular cross-section leads of 2.5-3.0×0.3 mm, whereas the second rheophores 43b are made by welding to the contacts 42b a suitably-sized thin metal sheet preferably comprising one or more notches or folds 43c, transversally extending with respect to the welding direction, adapted to prevent the cell from being subjected to mechanical stress during the welding.
The so formed rheophores allow to reduce the voltage drop caused by the connections between a cell and another thus optimising the photovoltaic panel efficiency.
As a matter of fact, the electric resistance of an electric connection is given by the known relationship
R=ρL/S
where
ρ=material resistivity
L=conductor length
S=conductor cross-section
Obviously, an increase of the current (power) generated by the cells brings about an increase of the voltage drop on the connections (ribbons) between the cells. A way to reduce these voltage drops is to increase the quantity S i.e. to increase the thickness of the connections between the cells. The above described arrangement increases the rheophores's thickness, thus reducing the voltage drop caused by the electric connections and optimises after all the efficiency of the photovoltaic panel.
In a third step of the process it is provided that the photovoltaic panel 11 is directly made and combined with the heat exchanger 12 (
The photovoltaic panel 11 are built as follows:
According to a preferred embodiment, starting from the surface to be exposed to the solar energy, a solar panel 10 manufactured through the disclosed process comprises:
Preferably the plate 15 has a high mechanical resistance, high transparency, high thermal transmittance U (W/m2*K), high planarity, high hardness, is capable to protect the lower elements from water infiltrations and from chemically reacting pollutants, it is selected so as to not pollute the substrate through migration processes, it is resistant to atmospheric abrasion and erosion, it is chemically and geometrically stable at high temperatures. The plate can be for example a toughened glass plate of known type.
Preferably the spacers 54 and 55 have high resistance to ageing and light, high resistance to the large temperature changes, good adhesion to the substrata, elasticity, a wide range of operating temperatures, good impermeability to gases, good electric resistance, elevated chemical inertia towards the photovoltaic cells and with the cell embedding material, high optical transparency. For example the spacers are made of silicone.
The photosensitive layer 14 is preferably formed by elementary photovoltaic cells of crystalline silicon, for example cells with a power of 2.1 W and size of 125×125 mm from SHARP or from ENI-EUROSOLARE companies. Of course the manufacturing process and the panel can be used for different kinds of cells, such as for example thin film cells, gallium arsenide cells, etc.
The resin or the embedding/blocking material of the cells 58 has preferably a high transparency, high binding power, short curing times and it is not thermosetting, has a high thermal dispersion, low viscosity, high resistance to ageing and to light, including the ultraviolet radiation, high resistance to the large temperature changes, an extended range of operating temperatures (−30° C.≦T≦150° C.) uniformity and continuity in the distribution of the mechanical stresses/tensions, high elasticity, it is chemically inert and is a good dielectric.
The resin can be for example a commercial resin of the CE9500 type cured with CE9500 cat. or of the CE100-7 A.E. type cured with CE100-7 A.E. sold by CAFARELLI RESINS company, or a resin of the NT620 type cured with NT620 cat. of the NEW TECH company.
Of course, as will be evident to the skilled of the art, the resin can also be of other types without departing from the scopes of the invention as described and claimed.
Preferably the heat exchanger 12 is a thermal machine in which power is transferred to a fluid through a solid surface. The laws governing such power transfer are irradiation, convection, forced convection and conduction. The heat exchanger includes sheets, preferably metal sheets, having a large thermal conductivity k, a low “fouling factor” F=(m2*K/W) both on the side where the cooling fluid flows, and on the outer side of the exchanger (panel/external environment border), large resistance to chemical oxidation/reduction processes, and is adapted not to contaminate the cells through ion migration processes, good weldability, high deformability and resistance to mechanical stresses.
Preferably the heat carrying fluid 19 has a large cooling capability, a low kinematic viscosity (m2/s), and is not polluting.
Preferably the layer of insulating material 24a is adapted to provide a large thermal insulation, very good protection against water infiltrations and against polluting agents that are chemically reactive, is resistant to atmospheric abrasion and erosion, has a stable insulating power and is geometrically stable in the time. The insulating material is, for example, polyurethane foam or plastic material.
In accordance with a preferred embodiment of the above disclosed manufacturing process, the glue spots, 54 and 55, are applied onto the insulating layer 24b and the plate 15, respectively. According to other embodiments the glue spots can of course be applied, for example by a numerical control machine, onto opposite faces of the strings 40 of cells 41 without departing from the scope of the invention as disclosed and claimed.
According to a preferred embodiment, the manufacturing process and the panel provide for the presence of the insulating layer 24b, but of course, as can be easily understood by the skilled of the art, the presence of this layer is not compulsory since both the bed of the spacers 54 and the resin 58 are adapted to electrically insulate the upper face 26b of the heat exchanger 12 from the photosensitive layer 14.
Since the solar panel manufactured as disclosed does not require lamination steps, it is not affected by the drawbacks deriving from such steps. More particularly, the lack of lamination steps and the provision of steps for introducing properly selected resins into the module, ensures a high quality and a lack of defects in the short and medium term.
Moreover, the use of connections between the cells using conductors of increased thickness optimises the efficiency of the cells.
Several obvious changes are possible to the above description in respect of size, shapes, materials, components, circuit elements and connections, as well as in respect of the circuitry details, of the illustrated construction and of the manufacturing process without departing from the invention as defined in the attached claims.
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/IT06/00712 | 10/9/2006 | WO | 00 | 5/18/2009 |