Claims
- 1. A process for the preparation of .alpha.-acetoxy-.alpha.-methyl-N,N'-diacetylmalonamide in which hydrocyanic acid or cyanide is reacted with acetic anhydride in a first step and then the mixture so obtained is treated with acetic acid in the presence of an acid catalyst in the second step, wherein the first step is carried out with the acetic anhydride in the presence of an anion exchange resin catalyst, wherein the functional groups are the acetate form of quaternary ammonium or tertiary amine groups and the molar ratio of anhydride to hydrocyanic acid or cyanide is at least one.
- 2. A process according to claim 1 wherein the temperature of the first step of the reaction is from 20.degree. to about 100.degree. C.
- 3. A process according to claim 1 wherein the reaction temperature is from about 60.degree. to about 90.degree. C.
- 4. A process according to claim 1 wherein the groups are the acetate form of benzyldimethylamine or benzyltrimethylammonium.
- 5. A process according to claim 1 wherein the first step is carried out continuously in a tubular reaction zone, the zone being packed with the anion exchange resin.
Priority Claims (1)
Number |
Date |
Country |
Kind |
82 01624 |
Feb 1982 |
FRX |
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Parent Case Info
This application is a continuation, of application Ser. No. 728,446, filed May 1, 1985 abandoned which is a continuation, of application Ser. No. 459,100, filed Jan. 19, 1983 abandoned.
Foreign Referenced Citations (1)
Number |
Date |
Country |
2738975 |
Mar 1978 |
DEX |
Non-Patent Literature Citations (3)
Entry |
Calmon et al., Ion Exchangers in Organic and Biochemistry, Interscience Publishers, Inc., N.Y., 1957, pp. 662-663. |
Dow Chemical Company, Dowex:: Ion Exchanger, Dow Chemical Company, Midland, Michigan, 1964, pp. 7-8 and 34. |
Kressman, I. R. E., Manufacturing Chemist, Nov., 1956, pp. 454-458. |
Continuations (2)
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Number |
Date |
Country |
Parent |
728446 |
May 1985 |
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Parent |
459100 |
Jan 1983 |
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