Claims
- 1. A process for the preparation of p-dichlorobenzene, a p-chlorinated monohalogenated benzene or a p-chlorinated monoalkyl benzene having 1 to 10 carbon atoms in the alkyl group, from benzene, a monohalogenated benzene or a monoalkyl benzene having 1 to 10 carbon atoms in the alkyl group, respectively, which comprises chlorinating benzene, a monohalogenated benzene or a monoalkyl benzene having 1 to 10 carbon atoms in the alkyl group in the liquid phase at a temperature of 0.degree. to 400.degree. C. by using chlorine as a chlorinating agent, wherein a zeolite placed in intimate contact with a metal salt selected from the group consisting of halide, nitrate, carbonate or sulfate of an alkali metal, an alkaline earth metal or lanthanum is used as a catalyst for the chlorination.
- 2. A process according to claim 1, wherein the zeolite is selected from the group consisting of zeolite Y, zeolite L, zeolite X, gmelinite, zeolite ZSM-5, offretite/erionite type zeolite and mordenite.
- 3. A process according to claim 1, wherein the zeolite is selected from the group consisting of zeolite Y and zeolite L.
- 4. A process according to claim 1, wherein the metal salt is a chloride, nitrate, carbonate or sulfate of sodium, potassium, rubidium, cesium, magnesium, calcium, strontium, barium or lanthanum.
- 5. A process according to claim 1, wherein the amount of the metal salt is in the range of 0.1 to 90% by weight based on the weight of the catalyst.
- 6. A process according to claim 1, wherein the amount of the metal salt is in the range of 10 to 80% by weight based on the weight of the catalyst.
- 7. A process according to claim 6, wherein the zeolite placed in intimate contact with the metal salt is prepared by conducting at least once the steps of impregnating the zeolite with a solution of the metal salt in a solvent and then drying the metal salt solution-impregnated zeolite at a temperature of 80.degree. to 150.degree. C.
- 8. A process according to claim 7, wherein the dried zeolite is calcined at a temperature of 200.degree. to 900.degree. C. in an air or inert gas atmosphere.
- 9. A process according to claim 1, wherein the zeolite placed in intimate contact with the metal salt is prepared by mixing the zeolite with the metal salt in the state where the zeolite contains at least 0.1% by weight of water, and then drying the metal salt-mixed zeolite.
- 10. A process according to claim 9, wherein the dried zeolite is calcined at a temperature of 200.degree. to 900.degree. C. in an air or inert gas atmosphere.
- 11. A process according to claim 1, wherein the chlorination is carried out in the liquid phase at a temperature of 20.degree. to 150.degree. C.
- 12. A process according to claim 1, wherein the chlorination is carried out in a continuous manner is which 0.01 to 5 moles of gaseous chlorine as a chlorinating agent per mole of the aromatic hydrocarbon is introduced into a reaction liquid.
Priority Claims (1)
Number |
Date |
Country |
Kind |
60-28466 |
Feb 1985 |
JPX |
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Parent Case Info
This application is a continuation of application of Ser. No. 06/629,905 filed Feb. 18, 1986, now abandoned which is a continuation of application number 07/083,006, filed Aug. 6, 1987, now abandoned.
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Continuations (2)
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Number |
Date |
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Parent |
83006 |
Aug 1987 |
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Parent |
829905 |
Feb 1986 |
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