Claims
- 1. Process for preparing an oxyalkylated product which comprises
- 1. providing a mixture containing
- a. a phenol, at least in an amount sufficient to form a complex with an aluminum or iron substance in the mixture,
- b. a non-phenolic active hydrogen compound having 2 to 8 active hydrogens per molecule and having an average molecular weight below about 10,000,
- c. a substance containing aluminum or iron which will form a complex with phenol, and
- d. an organic acid anhydride, at least one of which components (a), (b), and (d) is halogenated,
- 2. heating the mixture to a temperature in the range of from about 80.degree. C. to about 250.degree. C., and
- 3. oxyalkylating the heated mixture by adding thereto sufficient alkylene oxide having from 2 to 12 carbon atoms to form an oxyalkylated polyol product.
- 2. Process of claim 1 wherein each of the phenol (a), the active hydrogen compound (b), and the organic acid anhydride (d) is halogenated.
- 3. Process of claim 1 which further includes the step of terminating the oxyalkyation of the mixture by adding to the mixture a tri (lower alkyl) amine having from 1 to 4 carbon atoms in each alkyl group in an amount which is at most approximately equivalent to the original phenol content of the mixture but which is sufficient in amount to promote oxyalkylation of any un-oxyalkylated phenol in the mixture, and additional alkylene oxide until no more alkylene oxide will react in the mixture.
- 4. An oxyalkylated polyol prepared by the process of claim 1.
- 5. An oxyalkylated polyol prepared by the process of claim 2.
- 6. An oxyalkylated polyol prepared by the process of claim 3.
Parent Case Info
This is a division of application Ser. No. 425,524, filed Dec. 17, 1973 now U.S. Pat. No. 3,957,922.
US Referenced Citations (5)
Divisions (1)
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Number |
Date |
Country |
Parent |
425524 |
Dec 1973 |
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