Claims
- 1. The carbonylation process which comprises reacting allyl alcohol and carbon monoxide under carbonylation conditions substantially in the absence of water and in the presence of a catalytically effective amount of a catalyst composition containing zero valent palladium promoted with a catalyst promoting amount of a hydrogen halide selected from the group consisting of hydrogen fluoride, hydrogen chloride, hydrogen bromide and hydrogeniodide to provide one product or a mixture of products predominately made up of C.sub.4 and C.sub.5 carboxylic acids selected from the group consisting of vinylacetic acid, crotonic acid, butyric acid, isobutyric acid, glutaric acid and methyl succinic acid.
- 2. The process of claim 1 wherein the carbon monoxide is present in substantial molar excess compared to allyl alcohol.
- 3. The process of claim 2 wherein the carbon monoxide is present at about 1.5 to about 10 moles per mole of allyl alcohol.
- 4. The process of claim 1 wherein the zero valent palladium is supported on an inert carrier.
- 5. The process of claim 4 wherein the inert carrier is carbon.
- 6. The process of claim 1 wherein the promoter is present at a molar ratio of HX:Pd of from about 10:1 to about 200:1.
- 7. The process of claim 1 wherein from about 0.00001 to about 0.5 molar equivalents of zero valent palladium per mole of allyl alcohol are used.
- 8. The process of claim 7 wherein from about 0.01 to about 0.1 molar equivalents of zero valent palladium per mole of allyl alcohol are used.
- 9. The process of claim 7 wherein the reaction of allyl alcohol and carbon monoxide is carried out from about 80.degree. C. to about 300.degree. C.
- 10. The process of claim 1 wherein the reaction of allyl alcohol and carbon monoxide is carried out at about 80.degree. C. to about 135.degree. C. and the reaction produces one or more oxygenated products other than a C.sub.4 carboxylic acid, said oxygenated products being selected from the group consisting of allyl ether, allyl vinyl acetate and.
- 11. The process of claim 9 wherein the reaction of allyl alcohol and carbon monoxide is carried out at about 150.degree. C. to about 300.degree. C.
- 12. The process of claim 1 wherein the reaction of allyl alcohol and carbon monoxide is carried out at from about 2,000 psig to about 5,000 psig.
- 13. The process of claim 12 wherein the reaction of allyl alcohol and carbon monoxide is carried out from about 2,500 psig to about 3,500 psig.
- 14. The process of claim 1 carried out substantially in the absence of oxidizing agent.
- 15. A process for making vinylacetic acid which comprises reacting allyl alcohol and carbon monoxide under carbonylation conditions substantially in the absence of water and in the presence of a catalytically effective amount of a catalyst composition containing zero valent palladium promoted with a catalyst promoting amount of a hydrogen halide selected from the group consisting of hydrogen fluoride, hydrogen chloride, hydrogen bromide and hydrogen iodide to provide said vinylacetic acid.
- 16. The process of claim 15 wherein the reaction of allyl alcohol and carbon monoxide is carried out at a temperature of from about 80.degree. C. to about 135.degree. C. and a pressure of from about 2,000 to about 5,000 psig.
- 17. The process of claim 15 carried out substantially in the absence of oxidizing agent.
- 18. A process for making a C.sub.4 carboxylic acid selected from the group consisting of crotonic acid, butyric acid and isobutyric acid which comprises reacting allyl alcohol and carbon monoxide under carbonylation conditions substantially in the absence of water and in the presence of a catalytically effective amount of a catalyst composition containing zero valent palladium promoted with a catalyst promoting amount of a hydrogen halide selected from the group consisting hydrogen fluoride, hydrogen chloride, hydrogen bromide, and hydrogen iodide to provide said C.sub.4 carboxylic acid.
- 19. The process of claim 18 wherein the reaction of allyl alcohol and carbon monoxide is carried out at a temperature of from about 150.degree. C. to about 300.degree. C. and a pressure of from about 2,000 to about 5,000 psig.
Parent Case Info
This is a continuation of application Ser. No. 276,105, filed on June 22, 1981, now abandoned.
US Referenced Citations (1)
Number |
Name |
Date |
Kind |
3501518 |
Kutepow II et al. |
Mar 1970 |
|
Foreign Referenced Citations (1)
Number |
Date |
Country |
1137163 |
Dec 1968 |
GBX |
Continuations (1)
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Number |
Date |
Country |
Parent |
276105 |
Jun 1981 |
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