Claims
- 1. A process for producing a disperse dye or their mixtures thereof of the formula (I) ##STR5## wherein one Y is hydroxyl and the other Y is methylamine, n is 0.5 to 2.0, which comprises the steps of:
- subjecting 1,5-dinitro-anthraquinone or 1,8-dinitroanthraquinone or their mixtures thereof or mixtures of nitration residues of 1-nitro-anthraquinone, 1,5-dinitro-anthraquinone, 1,6-dinitro-anthraquinone, 1,7-dinitro-anthraquinone and 1,8-dinitro-anthraquinone to aminolysis with methylamine to give 1,5-dimethylaminoanthraquinone or 1,8-dimethylaminoanthraquinone or their mixtures or corresponding mixtures of dimethylamino residues;
- brominating said 1,5-dimethylamino anthraquinone or
- 1. 8-dimethylamino anthraquinone or their mixtures or mixtures of dimethylamino residue, to give the corresponding bromo compound of the formula III or their mixtures thereof ##STR6## wherein one X is bromine and the other X is methylamine; and hydrolysing said bromo compound or their mixtures thereof with sulfuric acid, optionally containing SO.sub.3, in the presence of boric acid, at a temperature between 100.degree. and 150.degree. C., to give said disperse dye or their mixtures thereof.
- 2. A process according to claim 1, wherein 4 parts of H.sub.2 SO.sub.4 and at least 0.1 part of boric acid are used to 1 part of the compound of the formula III.
- 3. A process according to claim 1, wherein said sulfuric acid contains up to 40% of SO.sub.3.
- 4. A process according to claim 1, wherein 1,5-dinitroanthraquinone is used as starting material.
- 5. A process according to claim 1, wherein 1,8-dinitroanthraquinone is used as starting material.
- 6. A process according to claim 1, wherein a mixture of 1,5-dinitro-anthraquinone and 1,8-dinitro-anthraquinone is used as starting material.
- 7. A process according to claim 1, wherein a mixture of nitration residues is used as starting material.
Priority Claims (1)
Number |
Date |
Country |
Kind |
1347/78 |
Feb 1978 |
CHX |
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Parent Case Info
This is a continuation of application Ser. No. 008,218 filed on Jan. 31, 1979, now abandoned.
US Referenced Citations (1)
Number |
Name |
Date |
Kind |
4045457 |
Gehrke et al. |
Aug 1977 |
|
Foreign Referenced Citations (2)
Number |
Date |
Country |
462430 |
Jan 1971 |
JPX |
977608 |
Dec 1964 |
GBX |
Continuations (1)
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Number |
Date |
Country |
Parent |
8218 |
Jan 1979 |
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