Patent Application
20070262484
The present invention relates to a process for producing a multilayered unstretched film of thermoplastic resins, a process for producing a multilayered-resin-coated metal sheet coated and laminated with multiple layers of thermoplastic resin, and an apparatus for producing a multilayered unstretched film of a thermoplastic resin.
For producing a multilayered film of plural thermoplastic resins, much used is a feed-block method comprising combining plural heated and melted resins before they flow into a T-die, then widening them through one manifold and thereafter ejecting them out through a die lip of a T-die; or a multi-manifold method comprising providing plural manifolds inside a T-die, leading plural heated and melted resins separately to the respective manifolds and widening them therein, and thereafter combining them and ejecting them out through a die lip of the T-die. The multilayered thermoplastic resin film produced according to any of these methods, which is ejected out through a T-die and extruded out onto a casting roll, is trimmed by cutting off both its edges so as to have a constant thickness in the cross direction thereof, since both its edges are solidified thicker on the casting roll than the center part of the film owing to the characteristics of the highly-viscous resin melts. The multilayered resins of the cut and removed thick parts could not be recycled as materials for films by heating and melting them in extruders, and are therefore discarded; and this is a bar to the cost reduction in producing multilayered films.
For reducing the economical loss of non-recyclable trimmed film wastes, a method is proposed in Patent Reference 1. The method relates to a film having an indispensable requirement of high quality, such as an electrically-insulating film of a biaxially-stretched polypropylene film for production of capacitors; and this comprises heating and melting a propylene polymer B in a first extruder, heating and melting a propylene polymer A in a second extruder, and co-extruding them through a flat sheet die, wherein the propylene polymer A is extruded by feeing it to both sides of the propylene polymer B, the resulting resin film is biaxially stretched, and then the propylene polymer A on both sides of the propylene polymer B are trimmed off. In the method, the propylene polymer B satisfying the indispensable requirement of high quality is used as possible effectively so as not to give trimmed film wastes. In the method, however, the propylene polymer B to be used must be so designed that it is compatible with the propylene polymer A in point of the molecular weight, the residual ash, the melt flow index and the melting point thereof, and therefore, the use of the method is limited and the method is not applicable to production of films of general-purpose thermoplastic resins.
Information of a prior-art reference relating to the present application includes the following:
Problems that the Invention is to Solve
The present invention is to provide a process for producing a multilayered unstretched film, a process for producing a multilayered-resin-coated metal sheet, and an apparatus for producing a multilayered unstretched film, in which the thick film parts to be discarded after the film formation is minimized for cost reduction in film production.
Means for Solving the Problems
The process for producing a multilayered unstretched film according to a multi-manifold method of the invention to solve the above-mentioned problems comprises separately heating and melting plural thermoplastic resins, widening the heated and melted thermoplastic resins through the respective manifolds, and then combining and extruding them, wherein plural thermoplastic resins that are to be formed into a multilayered unstretched film and another thermoplastic resin than the plural thermoplastic resins are separately heated and melted, the other thermoplastic resin is led to both sides of the plural thermoplastic resins just before the resins are widened in their respective manifolds, then they are fed to the respective manifolds so that the other thermoplastic resin can coexist on both sides of the plural thermoplastic resins, and widened and then combined, and thereafter they are ejected out through the die lip of a T-die onto a casting roll to thereby form a multilayered unstretched film where a multilayered film of the other thermoplastic resin coexists on both sides of the multilayered film of the plural thermoplastic resins, and then the multilayered film of the other thermoplastic resin portion is cut off (claim 1);
in the process for producing a multilayered unstretched film of the above (claim 1), the plural thermoplastic resins and the other thermoplastic resin are heated and melted separately in different extruders, and fed to the resin melt supply ducts connected to the respective extruders for heating the plural thermoplastic resins, the heated and melted plural thermoplastic resins and the heated and melted other thermoplastic resin are fed separately to plural feed blocks where holes are formed on both sides of the lower part of the respective ducts for the plural thermoplastic resins and the end of the duct for the other thermoplastic resin is connected with each hole formed on both sides of each duct, and thereafter these are widened through plural manifolds separately connected to the respective feed blocks and extruded out through the die lip of the extrusion T-dye onto a casting roll in such a condition that the other thermoplastic resin coexists on both sides of the multilayered thermoplastic resins (claim 2);
in the process for producing a multilayered unstretched film of the above (claim 1 or 2), in each feed block, the cross section of the lower part of each duct for the plural thermoplastic resins is rectangular, and the cross section of the holes to be formed on both sides of the lower part of each duct is rectangular (claim 3);
in the process for producing a multilayered unstretched film of the above (claims 1 to 3), the multilayered thermoplastic resins and the other thermoplastic resin are ejected out through the die lip of the T-die to form the multilayered unstretched film in such a manner that the other thermoplastic resin may form only a part inevitably thicker than the part of the multilayered plural thermoplastic resins (claim 4);
in the process for producing a multilayered unstretched film of the above (claims 1 to 4), the difference in the melt viscosity between the plural thermoplastic resins and the other thermoplastic resin is at most 3000 poises at a shear rate of from 20 to 500 sec−1 (claim 5);
in the process for producing a multilayered unstretched film of the above (claims 1 to 5), the other thermoplastic resin is a colored thermoplastic resin (claim 6).
The process for producing a multilayered-resin-coated metal sheet of the invention comprises forming films according to a multi-manifold method that comprises heating and melting plural thermoplastic resins, separately widening the heated and melted thermoplastic resins through the respective manifolds, then combining and extruding them, and thereafter ejecting and extruding them through the die lip of a T-die onto a metal sheet to coat it by lamination to produce a multilayered-resin-coated metal sheet, wherein plural thermoplastic resins constituting a multilayered resin that is to coat a metal sheet by lamination thereon and another thermoplastic resin than the plural thermoplastic resins are separately heated and melted, the other thermoplastic resin is led to both sides of the plural thermoplastic resins just before the resins are widened in their respective manifolds, then they are ejected out onto the metal sheet so that the other thermoplastic resin can coexist on both sides of the plural thermoplastic resins and that the width of the part of the multilayered thermoplastic resins is larger than the width of the metal sheet to give a resin-coated metal sheet where only the part of the multi-layered thermoplastic resins is laminated on the metal sheet to coat it, and thereafter the resin parts protruding from both sides of the metal sheet are cut off (claim 7);
in the process for producing a multilayered-resin-coated metal sheet of the above (claim 7), the multilayered thermoplastic resins and the other thermoplastic resin are ejected out through the die lip of the T-die onto the metal sheet in such a manner that the other thermoplastic resin may form only a part inevitably thicker than the part of the multilayered thermoplastic resins (claim 8);
in the process for producing a multilayered-resin-coated metal sheet of the above (claims 7 or 8), the difference in the melt viscosity between the plural thermoplastic resins and the other thermoplastic resin is at most 3000 poises at a shear rate of from 20 to 500 sec−1 (claim 9);
in the process for producing a multilayered-resin-coated metal sheet of the above (claims 7 to 9), the other thermoplastic resin is a colored thermoplastic resin (claim 10).
The apparatus for producing a multilayered (n-layered) unstretched film of the invention is to produce such a multilayered unstretched film according to a multi-manifold method comprising separately heating and melting a plural number (n: n is a natural number, and the same shall apply hereinunder) of thermoplastic resins, then widening the heated and melted, plural thermoplastic resins through the respective manifolds and thereafter combining and extruding them to produce a multilayered (n-layered) unstretched film, and the apparatus comprises a plural number (n.) of extruders (A1 to An) for separately heating and melting the plural thermoplastic resins to constitute the respective layers of the multilayered (n-layered) unstretched film, at least one extruder (B) for heating and melting another thermoplastic resin than the plural thermoplastic resins, a plural number (n) of ducts (C1 to Cn) for resin melt supply each connected to the respective extruders (A1 to An), a plural number (n) of ducts (D1 to Dn) for resin melt supply each connected to the extruder (B), a plural number (n) of feed blocks where two holes are formed on both sides of the lower part of the ducts (C1 to Cn) for resin melt supply and are connected to the ducts (D1 to Dn) for resin melt supply, a plural number (n) of manifolds, one die lip connected to each manifold, and one T-die connected to each feed block (claim 11);
in the apparatus for producing a multilayered unstretched film of the above (claim 11), in each of the plural feed blocks, the cross section of the lower part of each duct to which the plural thermoplastic resins are fed is rectangular, and the cross section of the holes to be formed on both sides of the lower part of the duct is rectangular (claim 12).
In the drawings, 1 is a feed block; 2 is a T-die; 4 is a die lip; 5 is a casting (chill) roll; 6 is a lapping part; 7 is a meeting place; 10 is an apparatus for producing an unstretched film; 15 is a cutting tool; 20 is an unstretched film; 20A is an intended thermoplastic resin; 20 B is another thermoplastic resin; 30 is a metal sheet; 40 is a resin-coated metal sheet; A1, A2, A3 and B are extruders; C1, C2 and C3 are ducts for resin melt supply; C1R, C2R and C3R are connection parts of the lowermost part of the duct for resin melt supply, to a T-die; D1, D2 and D3 are ducts for resin melt supply; l, H2 and H3 are holes; HlR, H2R and H3R are the parts just before the hole of the duct for resin melt supply; M1 and M2 and M3 are manifolds.
The invention is described in detail hereinunder. In the process for producing a multilayered unstretched film of the invention, the resins to form the intended multilayered unstretched film include a polyolefin resin of one or more polymers or copolymers of 1-alkene having from 2 to 8 carbon atoms, such as low-density polyethylene, middle-density polyethylene, high-density polyethylene, polypropylene, polybutene-1, polypentene-1, polyhexene-1, polyheptene-1, polyoctene-1, ethylene-propylenecopolymer, ethylene-butene-1 copolymer, ethylene-hexane copolymer; a polyamide resin such as 6-nylon, 6,6-nylon, 6,10-nylon; and a polyester resin comprising, as the acid component thereof, one or more acids of a dibasic aromatic dicarboxylic acid such as terephthalic acid, isophthalic acid, orthophthalic acid, p-β-oxyethoxybenzoic acid, naphthalene-2,6-dicarboxylic acid, diphenoxyethane-4,4-dicarboxylic acid, 5-sodium-sulfoisophthalic acid; an alicyclicdicarboxylic acid such as hexahydroterephthalic acid, cyclohexanedicarboxylic acid; an aliphatic dicarboxylic acid such as adipic acid, sebacic acid, dimer acid; a polybasic acid such as trimellitic acid, pyromellitic acid, hemimellitic acid, 1,1,2,2-ethane-tetracarboxylic acid, 1,1,2-ethane-tricarboxylic acid, 1,3,5-pentane-tricarboxylic acid, 1,2,3,4-cyclopentane-tetracarboxylic acid, biphenyl-3,4,3,4-cyclopentane-tetracarboxylic acid; and, as the alcohol component thereof, one or more diols such as ethylene glycol, propylene glycol, 1,4-butanediol, neopentyl glycol, 1,6-hexylene glycol, diethylene glycol, triethylene glycol, cyclohexanedimethanol, and other polyalcohols such as pentaerythritol, glycerol, trimethylolpropane, 1,2,6-hexanetriol, sorbitol, 1,1,4,4-tetrakis(hydroxymethyl)cyclohexane. In the invention, the plural thermoplastic resins for the intended multilayered thermoplastic resin and the other thermoplastic resin that differs from the intended thermoplastic resins are formed into films by controlling their melt viscosity in the manner to be mentioned hereinunder. Accordingly, they are not specifically defined in point of the resin composition thereof, and any of the above-mentioned resins maybe used for the intended thermoplastic resins and for the other thermoplastic resin that differs from the intended thermoplastic resins and is to coexist on both sides of the intended thermoplastic resins, as combined.
Next described is a process for producing a film where a different thermoplastic resin coexists on both sides of the intended multilayered thermoplastic resins, using the process and the apparatus for producing a multilayered unstretched film of the invention.
The intended plural thermoplastic resins 20A heated and melted in the extruders Al, A2 and A3 are fed to the feed block via the ducts C1, C2 andC3 for resin melt supply, and is extruded toward the T-die 2 connected to the lowermost part of the feed block. The other thermoplastic resin 20B heated and melted in the extruder B is fed to the feed block 1 via the ducts D1, D2 and D3 for resin melt supply, and extruded out into the ducts C1, C2 and C3 for resin melt supply for the intended plural thermoplastic resins, through the holes l, H2 and H3 formed on both sides of the lower part of the ducts C1, C2 and C3 for resin melt supply, and the thermoplastic resin B is thus made to coexist on both sides of the intended three thermoplastic resins 20A. Next, the resin melts that comprise the thermoplastic resin B coexisting on both sides of the intended three thermoplastic resins 20A are widened in the manifolds M1, M2 andM3 provided inside the T-die2, then combined at the meeting place 7 provided just above the die lip 4 of the T-die 2, and laminated in three layers, and thereafter ejected through the die lip 4 onto the casting roll 5 disposed below the T-die 2. In this stage, both edges in the cross direction of the thus-ejected, still molten unstretched resin film 20 are inevitably thicker than any other part. Accordingly, the multilayered unstretched film 20 is formed in which the thermoplastic resin 20B thicker than the intended thermoplastic resin 20A coexists on both sides of the thermoplastic resin 20A.
For facilitating the working step in film formation in the film-forming apparatus, when the ducts C1, C2 and C3 and the ducts D1, D2 and D3 for resin melt supply all have a circular cross section, then the other thermoplastic resin 20B coexists on both sides of the intended three thermoplastic resins 20A, having a cross-sectional profile as in
In case where the melt viscosity of any of the intended three thermoplastic resins 20A is extremely larger than the melt viscosity of the other thermoplastic resin 20B, then the thermoplastic resin 20B is to coexist on both sides of any of the intended thermoplastic resins 20A, having the cross-sectional profile as in the upper view of
In case where the melt viscosity of any of the intended thermoplastic resins 20A is extremely smaller than the melt viscosity of the other thermoplastic resin 20B, then the thermoplastic resin 20B is to coexist on both sides of any of the intended thermoplastic resins 20A, having the cross-sectional profile as in the upper view of
These lapping parts 6 where any of the intended thermoplastic resins 20A and the other thermoplastic resin 20B overlap with each other must be removed as they are unacceptable in products. In case where the lapping part 6 is great, then the area to be removed is large and the yield of the intended thermoplastic resins is low. For facilitating the detection of the lapping part 6, it is desirable that a color pigment is added to the other thermoplastic resin 20B to color it. In case where the intended thermoplastic resins are color resins, then a color pigment of which the color differs from the color of the intended thermoplastic resins may be preferably added to the other thermoplastic resin 20B or no pigment may be preferably added thereto so that the resin 20B could be a transparent resin.
For minimizing the lapping part 6 of any of the intended thermoplastic resins 20A and the other thermoplastic resin 20B, in the invention, the difference in the melt viscosity between any of the intended thermoplastic resins 20A and the other thermoplastic resin 20B that pass through the feed block and the T-die may be at most 3000 poises at a shear rate of from 20 to 500 sec−1, whereby the thermoplastic resin 20B may coexist on both sides of any of the intended thermoplastic resins 20A, having a cross-sectional profile as in the upper view of
In case where the melt viscosity difference between any of the intended thermoplastic resins 20A and the other thermoplastic resin 20B is controlled to be at most 3000 poises at a shear rate of from 20 to 500 sec−1, and in case where the melt viscosity of any of the intended thermoplastic resins 20A is larger than the melt viscosity of the other thermoplastic resin 20B and where any of the intended thermoplastic resins 20A alone ejected out through the die lip 4 of the T-die 2 may pulsate whereby the formed film width may periodically greatly fluctuate, then the other thermoplastic resin 20B having a larger melt viscosity than any of the intended thermoplastic resins 20A may be made to coexist on both sides of the thermoplastic resin 20A whereby the pulsation of any of the intended thermoplastic resins 20A may be inhibited and the fluctuation of the film width may be reduced. Accordingly, the intended unstretched film may be formed at a higher speed than other resin films of any of the intended thermoplastic resins 20A alone or of a plurality of the intended thermoplastic resins.
As in
Next described is the process for producing a resin-coated metal sheet of the invention.
The invention is described in more detail with reference to the following Examples.
As one of thermoplastic resins to be formed into a three-layered unstretched film, a polyester resin I (ethylene terephthalate/ethylene isophthalate copolymer (ethylene isophthalate, 5 mol %) ; melting point, 243° C.; melt viscosity at a temperature of 260° C. and at a shear rate of 100 sec−1, 7500 poises) was heated and melted at 260° C., using an extruder A1; as another of the thermoplastic resins, a polyester resin II (ethylene terephthalate/ethylene isophthalate copolymer (ethylene isophthalate, 10 mol %); melting point, 233° C.; melt viscosity at a temperature of 260° C. and at a shear rate of 100 sec−1, 7000 poises) was heated and melted at 260° C., using an extruder A2; and as still another of the thermoplastic resins, a polyester resin III (ethylene terephthalate/ethylene isophthalate copolymer (ethylene isophthalate, 15 mol %); melting point, 220° C.; melt viscosity at a temperature of 260° C. and at a shear rate of 100 sec−1, 6500 poises) was heated and melted at 260° C., using an extruder A3. As a thermoplastic resin to coexist on both sides of each of these intended thermoplastic resins, the polyester resin I, the polyester resin II and the polyester resin III, a resin (melt viscosity at a temperature of 200° C. and at a shear rate of 100 sec−1, 3500 poises) prepared by adding 15% by weight of a color component TiO2 to polyethylene (melting point, 145° C.) was heated and melted at 200° C., using an extruder B. Next, the heated and melted polyester resins I, II and III were fed from the respective extruders A1, A2 and A3 to a feed block 1, via resin melt supply ducts C1, C2 and C3 heated at 260° C. by neighboring heaters; and the heated and melted polyethylene was fed from the extruder B thereto, via resin melt supply ducts D1, D2 and D3 each heated at 200° C. by neighboring heaters. The resin melt supply ducts C1, C2 and C3 run through the feed block 1. Via the holes H1, H2 and H3 formed on both sides of the lower part of the ducts to communicate with the resin melt supply ducts D1, D2 and D3, the polyethylene was extruded out into the resin melt supply ducts C1, C2 and C3 whereby the polyethylene was made to coexist on both sides of each of the polyester resin I, the polyester resin II and the polyester resin III. Next, the resin melts were widened through the manifolds M1, M2 and M3 provided inside the T-die 2 in such a manner that the width of the part of each of the polyester resin I, the polyester resin II and the polyester resin III after film formation could be about 85 cm and the width of the part of the polyethylene on both sides of these resins could be about 7.5 cm, and thereafter combined at the meeting place 7 and laminated, dropped via the die lip 4 onto a continuously-rotating casting roll (chill roll) 5 and cooled and solidified thereon to give a three-layered resin film having a width of about 1 m. Just before the feed block 2, the resin temperature and the resin melt viscosity at a shear rate of 100 sec−1 were as follows: Polyester resin I: 260° C., about 6500 poises. Polyester resin II: 260° C., about 6000 poises. Polyester resin III: 260° C., about 5500 poises. Polyethylene (with TiO2 added): 200° C., about 4500 poises. Thus formed, the three layered film had substantially no lapping part 6 of any of the polyester resin I, the polyester resin II or the polyester resin III and the polyethylene. Accordingly, at the position of 40 cm on both sides from the center of the three-layered resin film, the film was trimmed on both sides thereof with a cutter to give a three-layered unstretched resin film of the polyester resin I, the polyester resin II and the polyester resin III having a width of 80 cm, and this was wound up around a coiler.
As one of thermoplastic resins to be formed into a three-layered unstretched film, a polyester resin (ethylene terephthalate/ethylene isophthalate copolymer (ethylene isophthalate, 5 mol %); melting point, 243° C.; melt viscosity at a temperature of 260° C. and at a shear rate of 100 sec−1, 7500 poises) was heated and melted at 260° C., using an extruder A1; as another of the thermoplastic resins, a polybutylene terephthalate I (melting point, 230° C.; melt viscosity at a temperature of 260° C. and at a shear rate of 100 sec−1, 6500 poises) was heated and melted at 260° C., using an extruder A2; and as still another of the thermoplastic resins, a polybutylene terephthalate I (melting point, 231° C.; melt viscosity at a temperature of 260° C. and at a shear rate of 100 sec−1, 7000 poises) was heated and melted at 260° C., using an extruder A3. As a thermoplastic resin to coexist on both sides of each of these intended thermoplastic resins, the polyester resin, the polybutylene terephthalate I and the polybutylene terephthalate II, a resin (melt viscosity at a temperature of 200° C. and at a shear rate of 100 sec−1, 4500 poises) prepared by adding 20% by weight of a color component TiO2 to polyethylene (melting point, 160° C.) was heated and melted at 200° C., using an extruder B. Next, in the same manner as in Example 1 except that the width of the part of each of the polyester resin, the polybutylene terephthalate I and the polybutylene terephthalate II after film formation could be about 90 cm and the width of the part of the polyethylene on both sides of each of these resins could be about 5 cm; the polyester resin, the polybutylene terephthalate I, the polybutylene terephthalate II and the polyethylene were ejected out and dropped onto a chill roll 5 and cooled and solidified thereon to form a resin film having a width of about 1 m. Just before the feed block 2, the resin temperature and the resin melt viscosity at a shear rate of 100 sec−1 were as follows: Polyester resin: 260° C., about 6000 poises. Polybutylene terephthalate I: 260° C., about 5000 poises. Polybutylene terephthalate II: 260° C., about 5500 poises. Polyethylene (with TiO2 added): 200° C., about 4500 poises. Thus formed, the three-layered film had substantially no lapping part 6 of any of the polyester resin, the polybutylene terephthalate I or the polybutylene terephthalate II and the polyethylene. Accordingly, at the position of 44 cm on both sides from the center of the three-layered resin film, the film was trimmed on both sides thereof with a cutter to give a three-layered unstretched resin film of the polyester resin, the polybutylene terephthalate I and the polybutylene terephthalate II having a width of 88 cm, and this was wound up around a coiler.
As one of thermoplastic resins to be formed into a three-layered unstretched film, a polyester resin I (ethylene terephthalate/ethylene isophthalate copolymer (ethylene isophthalate, 3 mol %) ; melting point, 250° C.; melt viscosity at a temperature of 260° C. and at a shear rate of 100 sec−1, 8000 poises) was heated and melted at 260° C., using an extruder A1; as another of the thermoplastic resins, a polyester resin II (ethylene terephthalate/ethylene isophthalate copolymer (ethylene isophthalate, 10 mol %); melting point, 233° C.; melt viscosity at a temperature of 260° C. and at a shear rate of 100 sec−1, 7000 poises) was heated and melted at 260° C., using an extruder A2; and as still another of the thermoplastic resins, a polyester resin III (ethylene terephthalate/ethylene isophthalate copolymer (ethylene isophthalate, 15 mol %); melting point, 220° C.; melt viscosity at a temperature of 260° C. and at a shear rate of 100 sec−1, 6500 poises) was heated and melted at 260° C., using an extruder A3. As a thermoplastic resin to coexist on both sides of each of these intended thermoplastic resins, the polyester resin I, the polyester resin II and the polyester resin III, a resin (melt viscosity at a temperature of 200° C. and at a shear rate of 100 sec−1, 4000 poises) prepared by adding 20% by weight of a color component TiO2 to polyethylene (melting point, 140° C.) was heated and melted at 200° C., using an extruder B. Next, in the same manner as in Example 1 except that the width of the part of each of the polyester resin I, the polyester resin II and the polyester resin III after film formation could be about 80 cm and the width of the part of the polyethylene on both sides of each of these resins could be about 10 cm; the polyester resin I, the polyester resin II, the polyester resin III and the polyethylene were ejected out and dropped onto a chill roll 5 and cooled and solidified thereon to form a resin film having a width of about 1 m. Just before the feed block 2, the resin temperature and the resin melt viscosity at a shear rate of 100 sec−1 were as follows: Polyester resin I: 260° C., about 7500 poises. Polyester resin II: 260° C., about 6000 poises. Polyester resin III: 260° C., about 5500 poises. Polyethylene (with TiO2 added): 200° C., about 3500 poises. Thus formed, the layer composed of the polyester resin I and the polyethylene on both sides thereof in the three-layered film had a lapping part 6 where the polyethylene had stepped in the upper and lower edges of the polyester resin I, as in
As three thermoplastic resins to form a three-layered unstretched film, the same polyester resin, polybutylene terephthalate I and polybutylene terephthalate II as those used in Example 2 were separately heated and melted in the same manner as in Example 2. As a thermoplastic resin to coexist on both sides of each of these intended thermoplastic resins, the polyester resin, the polybutylene terephthalate I and the polybutylene terephthalate II; a resin (melt viscosity at a temperature of 265° C. and at a shear rate of 100 sec−1, 9700 poises) prepared by adding 20% by weight of a color component TiO2 to polyethylene terephthalate (melting point, 255° C.) was heated and melted at 265° C., using an extruder B. Next, in the same manner as in Example 1 except that the polyester resin, the polybutylene terephthalate I and the polybutylene terephthalate II were extruded out from the extruders A1, A2 and A3 via the resin melt supply ducts C1, C2 and c3 heated at 260° C. with neighboring heaters and the polyethylene terephthalate was from the extruder B via the resin melt supply ducts D1, D2 and D3 heated at 260° C., all through the feed block 1 in such a manner that a resin film having the polyethylene terephthalate (with TiO2 added) coexisting on both sides of each of the polyester resin, the polybutylene terephthalate I and the polybutylene terephthalate II after their extrusion through the T-die could be obtained, and that the width of the part of each of the polyester resin, the polybutylene terephthalate I and the polybutylene terephthalate II after the film formation could be about 80 cm and the width of the part of the polyethylene terephthalate (with TiO2 added) on both sides of each of these resins could be about 10 cm; the polyester resin, the polybutylene terephthalate I, the polybutylene terephthalate II and the polyethylene terephthalate were ejected out and dropped onto a chill roll 5 and cooled and solidified thereon to form a three-layered resin film having a width of about 1 m. Just before the feed block 1, the resin temperature and the resin melt viscosity at a shear rate of 100 sec−1 were as follows: Polyester resin: 260° C., about 6000 poises. Polybutylene terephthalate I: 260° C., about 5000 poises. Polybutylene terephthalate II: 260° C., about 5500 poises. polyethylene terephthalate (with TiO2 added): 260° C., about 9500 poises. Thus formed, the film had a lapping part 6 where any of the polyester resin, the polybutylene terephthalate I and the polybutylene terephthalate II had stepped in the upper and lower edges of the polyethylene terephthalate, as in
In the same film-forming apparatus as that used for production of the unstretched film in Examples 1 and 2 and Comparative Examples 1 and 2, a metal sheet, or that is, a zinc-plated steel sheet having a thickness of 0.3 mm and a width of 75 cm was continuously introduced, as uncoiled from an uncoiler, in place of the chill roll 5 therein. In the same manner as in Example 1, the same polyester resin I, the polyester resin II, polyester resin and polyethylene as those in Example 1 were melted and heated, and ejected out onto the zinc-plated metal sheet to coat it by lamination, through the die lip 4 disposed below the T-die 2 in such a manner that the polyethylene could coexist on both sides of the polyester resin I, the polyester resin II and the polyester resin III. The three-layered resin film thus formed by ejection, in which the polyethylene coexisted on both sides of the three-layered resins of the polyester resin I, the polyester resin II and the polyester resin III, had an overall with of about 1 m in such a manner that the width of the part of the three-layered resins of the polyester resin I, the polyester resin II and the polyester resin III was about 80 cm and the width of the part of the polyethylene on both sides of the three-layered resins was about 10 cm. On both sides in the cross direction of the zinc-plated steel sheet, a part of the three-layered resins of the polyester resin I, the polyester resin II and the polyester resin III and all the polyethylene protruded out, and the protruding resin parts were cut off with a cutter. Thus produced, the three-layered-resin-coated, zinc-plated steel sheet in which the entire surface of the zinc-plated steel sheet was coated with the three-layered resins of the polyester resin I, the polyester resin II and the polyester resin III by lamination thereon was coiled around a coiler.
The process for producing a multilayered unstretched film according to a multi-manifold method of the invention comprises separately heating and melting plural thermoplastic resins, widening the heated and melted thermoplastic resins through the respective manifolds, and then combining and extruding them, wherein plural thermoplastic resins that are to be formed into a multilayered unstretched film and another thermoplastic resin than the plural thermoplastic resins are separately heated and melted, the other thermoplastic resin is led to both sides of the plural thermoplastic resins just before the resins are widened in their respective manifolds, then they are fed to the respective manifolds so that the other thermoplastic resin can coexist on both sides of the plural thermoplastic resins, and widened and then combined, and thereafter they are ejected out through the die lip of a T-die onto a casting roll to thereby form a multilayered unstretched film where a multilayered film of the other thermoplastic resin coexists on both sides of the multilayered film of the plural thermoplastic resins, and then the multilayered film of the other thermoplastic resin is cut off. Accordingly, in the process, the intended thermoplastic resin part is not almost cut off; and the other thermoplastic resin part that has been cut off in the process can be recycled as the other thermoplastic resin in the next step of producing multilayered unstretched films. Accordingly, the thick film part to be discarded after film formation is minimized, and the production cost of the multilayered unstretched film of the intended plural thermoplastic resins can be reduced.
The process for producing a multilayered-resin-coated metal sheet of the invention comprises forming films according to a multi-manifold method that comprises heating and melting plural thermoplastic resins, separately widening the heated and melted thermoplastic resins through the respective manifolds, then combining and extruding them, and thereafter ejecting and extruding them through the die lip of a T-die onto a metal sheet to coat it by lamination to produce a multilayered-resin-coated metal sheet, wherein plural thermoplastic resins that are to coat a metal sheet by lamination thereon and another thermoplastic resin than the plural thermoplastic resins are separately heated and melted, the other thermoplastic resin is led to both sides of the plural thermoplastic resins just before the resins are widened in their respective manifolds, then they are ejected out onto a metal sheet so that the other thermoplastic resin can coexist on both sides of the plural thermoplastic resins and that the width of the part of the multilayered thermoplastic resins is larger than the width of the metal sheet to give a resin-coated metal sheet where only the part of the multi-layered thermoplastic resins is laminated on the metal sheet to coat it, and thereafter the resin parts protruding from both sides of the metal sheet are cut off. Accordingly, in the process, the intended thermoplastic resin part is not almost cut off, and the entire surface of the metal sheet is coated with it; and the process gives a resin-coated metal sheet substantially with no loss of the intended thermoplastic resin. In addition, the other thermoplastic resin part that has been cut off in the process can be recycled as the other thermoplastic resin in the next step of producing multilayered unstretched films. Accordingly, the production cost of the multilayered-resin-coated metal sheet in which a metal sheet is coated and laminated with a multilayered resin film of the intended plural thermoplastic resins can be reduced.
The apparatus for producing a multilayered unstretched film of the invention is to produce such a multilayered (n-layered) unstretched film according to a multi-manifold method comprising separately heating and melting a plural number (n) of thermoplastic resins, then widening the heated and melted, plural thermoplastic resins through the respective manifolds and thereafter combining and extruding them to produce a multilayered (n-layered) unstretched film. The apparatus comprises a plural number (n) of extruders (A1 to A1) for separately heating and melting the plural thermoplastic resins to constitute the respective layers of the multilayered (n-layered) unstretched film, at least one extruder (B) for heating and melting another thermoplastic resin than the plural thermoplastic resins, a plural number (n) of ducts (C1 to Cn) for resin melt supply each connected to the respective extruders (A1 to An), a plural number (n) of ducts (D1 to Dn) for resin melt supply each connected to the extruder (B), a plural number (n) of feed blocks where two holes are formed on both sides of the lower part of the ducts (C1 to Cn) for resin melt supply and are connected to the ducts (D1 to Dn) for resin melt supply, a plural number (n) of manifolds, one die lip connected to each manifold, and one T-die connected to each feed block. In case where intended multilayered unstretched films are formed by the use of the apparatus for multilayered unstretched film production of the invention, then an unstretched film having another thermoplastic resin coexisting on both sides of intended multilayered thermoplastic resins may be formed, and thereafter the other multilayered thermoplastic resin part that is formed to be inevitably thicker than the intended multilayered thermoplastic resin part may be cut off. Accordingly, in the apparatus, the intended thermoplastic resin part is not almost cut off; and the other thermoplastic resin part that has been cut off can be recycled as the other thermoplastic resin in the next step of producing multilayered unstretched films. Accordingly, the thick film part to be discarded after film formation is minimized, and the production cost of the multilayered unstretched film of the intended plural thermoplastic resins can be reduced.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2004-055685 | Mar 2004 | JP | national |
| Filing Document | Filing Date | Country | Kind | 371c Date |
|---|---|---|---|---|
| PCT/JP05/03124 | 2/25/2005 | WO | 4/5/2007 |
