Claims
- 1. A process for producing N-substituted maleimides which comprises heating maleic anhydride and an aromatic or aliphatic primary amine in the presence of an ion exchange resin in an organic solvent in the temperature range of 50.degree. C. to 160.degree. C. to effect cyclodehydration.
- 2. A process according to claim 1, wherein the aromatic primary amine is aniline, naphthylamine, toluidine, dimethylaniline, chloroaniline, dichloroaniline, hydroxyaniline, nitroaniline or phenylenediamine.
- 3. A process according to claim 1, wherein the aliphatic primary amine is methylamine, ethylamine, propylamine, butylamine, benzylamine, cyclohexylamine or ethylenediamine.
- 4. A process according to claim 1, wherein the ion exchange resin is a strongly acidic ion exchange resin, a weakly acidic ion exchange resin, or a weakly basic ion exchange resin.
- 5. A process according to claim 1, wherein the organic solvent is an aromatic hydrocarbon solvent.
- 6. A process according to claim 1, wherein the organic solvent is a mixture of an aromatic hydrocarbon solvent and an aprotic polar solvent.
- 7. A process for producing N-substituted maleimides which comprises heating aromatic or aliphatic monoamides of maleic acid in the presence of an ion exchange resin in an organic solvent in the temperature range of 50.degree. C. to 160.degree. C. to effect cyclodehydration.
- 8. A process according to claim 7, wherein the aromatic or aliphatic monoamides of maleic acid is a product formed by the reaction of maleic anhydride with a corresponding amine, said monoamides being used without being separated from the reaction mixture.
- 9. A process according to claim 7, wherein the aromatic primary amine is aniline, naphthylamine, toluidine, dimethylaniline, chloroaniline, dichloroaniline, hydroxyaniline, nitroaniline, or phenylenediamine.
- 10. A process according to claim 7, wherein the aliphatic primary amine is methylamine, ethylamine, propylamine, butylamine, benzylamine, cyclohexylamine, or ethylenediamine.
- 11. A process according to claim 7, wherein the ion exchange resin is a strongly acidic ion exchange resin, a weakly acidic ion exchange resin, or a weakly basic ion exchange resin.
- 12. A process according to claim 7, wherein the organic solvent is an aromatic hydrocarbon solvent.
- 13. A process according to claim 7, wherein the organic solvent is a mixture of an aromatic hydrocarbon solvent and an aprotic polar solvent.
- 14. A process according to claim 1 wherein said ion exchange resin is present in an amount from 1 to 40% by weight based on the amount of the reaction liquid.
Priority Claims (1)
Number |
Date |
Country |
Kind |
59-206199 |
Oct 1984 |
JPX |
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Parent Case Info
This is a continuation of application Ser. No. 778,709, filed Sept. 23, 1985.
US Referenced Citations (1)
Number |
Name |
Date |
Kind |
3338919 |
Nield |
Aug 1967 |
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Foreign Referenced Citations (2)
Number |
Date |
Country |
906494 |
Aug 1972 |
CAX |
1041027 |
Sep 1966 |
GBX |
Non-Patent Literature Citations (3)
Entry |
J. Org. Chem., 24, 135-136 (1959) (Coleman et al.). |
Org. Syth., vol. 5, 944-946 (1973). |
Calmon et al. (Ed), Ion Exchangers in Organic and Biochemistry, Interscience, NY, NY (1957), pp. 658, 659 and 663-667. |
Continuations (1)
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Number |
Date |
Country |
Parent |
778709 |
Sep 1985 |
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