Claims
- 1. In a process for recovering an aliphatic carboxylic acid and/or an ester thereof by distilling a liquid mixture containing the aliphatic carboxylic acid and/or the ester thereof and a catalyst of a metal of Group VIII of the periodic table of elements, the improvement wherein carbon monoxide is introduced into the distillation system to carry out the distillation in the presence of carbon monoxide at a partial pressure of at least 0.05 kg/cm.sup.2 (absolute) in the distillation system to prevent the decomposition of said catalyst, there being no catalyst removed from said liquid mixture to be distilled, the amount of said catalyst in said liquid mixture to be distilled being 10.sup.-4 to 10.sup.-1 mole per liter of the total of the starting material and solvent used to obtain said liquid mixture.
- 2. The process of claim 1 wherein said liquid mixture is a liquid reaction mixture obtained by reacting a phenol, an aliphatic carboxylic acid ester or an aliphatic ether, and carbon monoxide in the presence of a catalyst of a metal of Group VIII of the periodic table of elements and an iodine-type promotor.
- 3. The process of claim 1 wherein said liquid mixture is a liquid reaction mixture obtained by reacting an alcohol or an ether with carbon monoxide in the presence of a catalyst consisting of a compound of a metal of Group VIII of the periodic table of elements and an iodine-type promotor.
- 4. The process of claim 1 wherein said liquid mixture is a liquid reaction mixture obtained directly from a reaction for producing said aliphatic carboxylic acid and/or the ester thereof.
Priority Claims (1)
Number |
Date |
Country |
Kind |
54-39920 |
Apr 1979 |
JPX |
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Parent Case Info
This application is a continuation of Ser. No. 136,484, filed Apr. 2, 1980 now abandoned.
US Referenced Citations (2)
Continuations (1)
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Number |
Date |
Country |
Parent |
136484 |
Apr 1980 |
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