Patent Application
20150323248
The present invention relates to a process for recovering hydrogen and capturing carbon dioxide utilizing a carbon dioxide separation unit and two membrane separation units. The present invention further provides for a process within a hydrogen generation plant to increase recovery of hydrogen and capture equal to or greater than 80% of the carbon dioxide in a synthesis gas stream.
Hydrogen is an important feedstock for many chemical and petrochemical processes. However, hydrogen production is associated with large amounts of carbon dioxide (CO2) emissions. Accordingly, it is desirable to not only provide a means to produce hydrogen but also a means to recover the carbon dioxide associated with the hydrogen production. With increased emission regulations and a possible future CO2 tax there is a need to develop carbon dioxide capture solutions. The cost of capture can impact the cost of hydrogen production. Therefore, it is important to develop a solution with lower cost of capture and improved efficiency of hydrogen production plant.
Physical or chemical solvents such as rectisol, selexol, amines, potassium carbonate etc. have been used traditionally for many decades to absorb carbon dioxide from synthesis gas in hydrogen plants, HYCO (hydrogen and carbon monoxide co-production) plants. However, the process of solvent absorption requires absorber and stripper columns with very high capital costs. The scrubbing solvent needs to be regenerated by temperature swing or pressure swing in order to release the absorbed carbon dioxide. The regeneration process can involve large amounts of steam or compression energy resulting in high operating costs. Another disadvantage of using the solvent absorber is that the purity of the recovered carbon dioxide may not be very high and further processing using liquefaction and partial condensation may be needed. Example U.S. Pat. No. 6,500,241 describes the use of acid gas removal unit and auto refrigeration unit for removing carbon dioxide from synthesis gas and PSA off-gas. U.S. Pat. No. 4,553,981 and U.S. Pat. No. 7,682,597 describe the use of a carbon dioxide scrubber downstream of the shift reactor to remove carbon dioxide from synthesis gas.
Carbon dioxide can be captured from a hydrogen plant by using cryogenic processing, namely partial liquefaction or distillation at low temperatures. Such a process is favorable at higher carbon dioxide concentrations. In hydrogen plants, carbon dioxide can be captured from several different locations in the process train including process synthesis gas or flue gas. Flue gas processing can pose several challenges because of many impurities coming from the combustion that therefore make the capture process very expensive. Carbon dioxide from process gas can be captured from high pressure synthesis gas before pressure swing adsorption unit or from pressure swing adsorption off-gas. The concentration of carbon dioxide in the gas before pressure swing adsorption is much lower than in the pressure swing adsorption off-gas and hence the pressure swing adsorption off-gas is more suitable for cryogenic separation. U.S. Pat. No. 6,301,927 provides an example of an auto refrigeration process that employs the use of a compression and expansion turbine to liquefy carbon dioxide and further separate it from other gases. Another patent, FR Patent No. 2877939 provides a way to remove carbon dioxide from pressure swing adsorption off-gas by using successive steps of compression and cooling to remove carbon dioxide by partial liquefaction and/or distillation. This patent describes the use of a membrane on the non-condensable gas to permeate hydrogen and recycle hydrogen back to the pressure swing adsorption unit in order to increase hydrogen recovery. However, carbon dioxide recovery for the unit is not very high. In U.S. Pat. No. 4,639,257, provides the use of carbon dioxide selective membrane in combination with distillation column for a carbon dioxide containing gas mixture in order to increase the recovery of carbon dioxide. A carbon dioxide selective membrane is used on the overhead of the distillation column with carbon dioxide rich permeate recycled back to feed or to the distillation column itself. Another carbon dioxide selective membrane is proposed for the feed gas before the distillation column in case the concentration of carbon dioxide is below equilibrium concentration at the freezing temperature of the mixture. However, this patent is suitable for a gas mixture containing carbon dioxide, nitrogen, methane and hydrocarbon. U.S. Patent Publication No. 2010/0129284, describes the use of a hydrogen selective membrane, a carbon dioxide selective membrane in combination with carbon dioxide liquefier in order to increase the recovery of hydrogen and carbon dioxide. However, carbon dioxide selective membrane is always located upstream of the liquefier requiring additional compression of the carbon dioxide permeate from the membrane feeding to the liquefier.
Hydrogen plants can emit large quantities of carbon dioxide into the atmosphere. Carbon dioxide capture solutions have been proposed in the past using several different separation techniques like absorption, cryogenic, adsorption or membrane. There is always some hydrogen loss from pressure swing adsorption processes. In addition, there is some carbon dioxide loss from the capture process which can be recovered by improving the carbon dioxide capture process. If additional hydrogen and carbon dioxide can be recovered from the capture process there can be significant savings with regards to the size of reformer, natural gas consumption, carbon dioxide tax etc. for the same size hydrogen plant.
Accordingly, there still exists a need for a process to recover both hydrogen and carbon dioxide with a carbon dioxide recovery rate of at least 50% from synthesis gas, as well as a process for producing hydrogen in a hydrogen generation plant that allows for the overall capture of at least 80% of the carbon dioxide, in the hydrogen production process.
A solution of the invention is a process for producing hydrogen and capturing carbon dioxide in a hydrogen generation plant, the process comprising the steps of:
a) subjecting a synthesis gas 15 coming from a synthesis gas producing unit 31 to a process unit 0 to obtain a hydrogen product stream 23 and a hydrogen depleted process stream 1;
b) compressing, cooling to a temperature equal to or less than −10° C., and purifying/separating—each operation in one or more steps and in any order—at least a portion of the process stream 1 in a carbon dioxide separation unit 4 to produce a carbon dioxide rich liquid stream 6 and a carbon dioxide lean non-condensable stream 5;
c) withdrawing the carbon dioxide lean non-condensable stream 5 from the carbon dioxide separation unit 4 and passing the carbon dioxide lean non-condensable stream 5 through a hydrogen selective membrane separation unit 7 to form a hydrogen rich permeate stream 8 with the remaining components in the carbon dioxide lean non-condensable stream 5 forming a hydrogen lean residue stream 9;
d) passing the hydrogen lean residue stream 9 through a carbon dioxide selective membrane separation unit 10 to form a carbon dioxide enriched permeate stream 11 with the remaining components in the hydrogen lean residue stream 9 forming a carbon dioxide depleted residue stream 12;
e) optionally compressing the hydrogen rich permeate stream 8 or a part of it, in a compressor 13 and recycling at least a part of the hydrogen rich permeate stream 8 for use as a supplemental feed stream in the synthesis gas producing unit 31, the process unit 0 or in both, and/or as a fuel for the synthesis gas producing unit;
f) recycling at least a part of the carbon dioxide enriched permeate stream 11 to the carbon dioxide separation unit 4 in the process stream 1 prior to the compression or within the compression between stages of compression, or compressing the carbon dioxide enriched permeate stream 11 in another compressor and recycling the carbon dioxide enriched permeate stream 11 in the carbon dioxide separation unit 4 and recycling the carbon dioxide depleted residue stream 12 to be used as a supplemental feed stream for the synthesis gas producing unit 31 and/or as a fuel for the synthesis gas producing unit 31 or for steam regeneration or in another process.
According to particular embodiments of the present invention, the process is characterized by the following characteristics:
This present invention provides a method to more efficiently recover hydrogen and carbon dioxide, preferably at least 50%, even more preferably at least 80% and most preferably at least 90% of the carbon dioxide. The proposed use combines hydrogen selective membranes and carbon dioxide selective membranes together with carbon dioxide separation units such that hydrogen and carbon dioxide are produced with increased recoveries and improved process efficiency. Increased hydrogen recovery by using hydrogen selective membranes can reduce the size of the synthesis gas producing unit, natural gas consumption for feed and fuel for the same size hydrogen plant. Increased carbon dioxide recovery will reduce the emissions of carbon dioxide into the atmosphere and will result in cost savings in case of a carbon tax.
It is possible to efficiently recover hydrogen and carbon dioxide from process streams obtained from process units which have a purification step that provides a hydrogen rich fraction which can be utilized downstream (for instance, in the production of electricity) as in the present process. While overcoming many of the disadvantages of the prior art systems that deal with the recovery of hydrogen and carbon dioxide from such streams, this can be accomplished by integrating a carbon dioxide separation unit, a hydrogen selective membrane separation unit and a carbon dioxide selective membrane separation unit into the process for treating streams taken from such process units in the manner noted herein. In addition, increased production of hydrogen and carbon dioxide capture of equal to or greater than 80% from synthesis gas in hydrogen generation plants may also be accomplished by integrating a carbon dioxide separation unit, a hydrogen selective membrane separation unit and a carbon dioxide selective membrane separation unit into the schematic of a hydrogen generation plant by choosing the best locations to recycle some of the streams issued from the different units.
The proposed schematic includes a synthesis gas producing unit, a process unit which is preferentially a pressure swing adsorption unit, a carbon dioxide separation unit-including compression, optional drying, heat exchange, purification/separation, a hydrogen selective membrane separation unit and a carbon dioxide selective membrane separation unit.
The processes of the present invention will be further described with regard to the figures contained herein. These figures are included merely for illustration purposes and are not intended in any way to limit the processes of the present invention. The process of the present invention as depicted in
The synthesis gas 15 that is supplied to the process unit 0 can be coming from any synthesis gas producing unit 31. For example, the synthesis gas 15 may be produced from a reformer unit with a water gas shift unit and with or without a pre-reformer unit, a partial oxidation unit (POx), an autothermal reformer unit (ATR). It could be synthesis gas from a coal gasification unit, a refinery off gas or any other gas mixture that contains hydrogen, carbon monoxide and carbon dioxide as components in the gas mixture In the more preferred situation, the synthesis gas 15 will be the product of a hydrocarbon containing feed stream 16 that has been subjected to steam hydrocarbon reforming and water gas shift (not shown in
A more detailed view of a Steam Reformer is depicted in
The advantage of such pre-reformers 17 is that the overall need for fuel to provide direct heat to the reforming reaction is reduced, hence naturally decreasing carbon dioxide production in the plant (leading to the high overall carbon dioxide recovery). In addition, the pre-reformer 17 may be operated in the same manner that is known in the art utilizing general conditions, including temperatures and pressures.
The next step of the preferred process involves reforming the pre-reformed gas stream 18 (or in the case where there is no pre-reforming, the hydrocarbon containing gas stream 16) in a steam methane reformer unit 19 in order to obtain a reformed stream 20. As with the pre-reformer 17, the present invention is not meant to be limited by the steam methane reformer unit 19 or the process for carrying out the reaction in the steam methane reformer unit 19. Accordingly, any steam methane reformer unit 19 known in the art may be used in the process of the present invention. By way of general description, with regard to the steam methane reformer unit 19 of
Once the reforming is carried out, the resulting stream 20 is subjected to a shift reaction in a water gas shift reactor 21 in order to obtain a synthesis gas 15. The stream 20 is subjected to a shift reaction due to the high amount of carbon monoxide that is often present due to the steam methane reforming (the amount of carbon monoxide actually depends upon the composition of the initial stream injected into the steam methane reformer unit 19). The water gas shift reactor 21 functions to form additional hydrogen and carbon dioxide by further reacting or treating the stream 20 in order to obtain a synthesis gas 15 for the process unit 0. The stream 20 is introduced into the water gas shift reactor 21 (which can contain a variety of stages or one stage; various stages not shown) along with steam (not shown) to form additional hydrogen and carbon dioxide. The water gas shift reactor 21 converts the carbon monoxide to carbon dioxide with the liberation of additional hydrogen by reaction at high temperature in the presence of the additional steam. Such reactors 21 typically operate at a temperature from about 200° C. to about 500° C. In some cases the stream from the steam methane reformer 19 will be at a higher temperature so optionally the stream may first be cooled with a heat exchanger (typically a steam generator—not shown) before being passed through the water gas shift reactor 21. In a preferred alternative, the water gas shift reactor 21 is a multiple stage water gas shift reactor which includes high temperature shift (typically about 371° C. or above), medium temperature shift (typically around 288° C.), low temperature shift (typically about 177° C. to 204° C.) or any combination thereof. Such multiple stage water gas shift reactors are known and are used to concentrate the amount of carbon dioxide in the resulting gas stream by the manner in which the shifts are arranged (with the high temperature shift resulting in less carbon monoxide reaction and the low temperature shift resulting in more carbon monoxide reaction). The various recycled streams that could be introduced in the Steam Reforming unit will be described hereunder.
In addition, those of ordinary skill in the art will recognize that the present invention is not meant to be limited by the hydrocarbon feed stream 16 which will ultimately form the feed gas 15 utilized in the present invention. Depending upon the source of the hydrocarbon feed streams 16, those of ordinary skill in the art will recognize that there will likely be small amounts of other components present in the ultimate feed gas 15, e.g. inerts such as nitrogen. Other impurities could be also present such as water, alcohol and heavy hydrocarbons traces (particularly methanol, C2- mainly ethane and ethylene-, aromatics) and others components as ppm level such as NH3, H2S. These impurities have been formed in the synthesis gas generation process or have passed through the purification steps (desulfurization for instance).
Preferably, the process unit 0 utilized will be a pressure swing adsorption unit that is used to recovery and purify hydrogen, although those of ordinary skill in the art will recognize that any other unit that functions to carry out hydrogen purification may is also contemplated to be within the scope of the present invention. The pressure swing adsorption unit utilized can be any pressure swing adsorption unit known in the art and can comprise anywhere from two to sixteen adsorption beds (not shown) although more adsorption beds may be utilized. During the process of hydrogen purification, each of the adsorption beds (not shown) will individually under go a cycle that typically comprises: a) pressurization with pure hydrogen product and/or synthesis gas, b) constant feed and hydrogen product release; c) pressure equalizations to transfer high pressure hydrogen-rich void gas to another bed at lower pressure; d) depressurization to slightly above atmospheric pressure; e) purge using hydrogen from co-current depressurization; and f) pressure equalizations with another bed at higher pressure to accept hydrogen-rich void gas. Preferably the adsorbents used in the pressure swing adsorption unit 0 include, but are not limited to, activated alumina, activated carbon, zeolite and their combinations. As a result of hydrogen purification, two separate gas streams are obtained-one that is a gaseous medium to very high purity hydrogen stream that is withdrawn and used as a hydrogen product 23 and the other which is often referred to as a pressure swing adsorption tail gas (referred to hereinafter as the “process stream. The process stream 1 is withdrawn from the adsorption beds of the pressure swing adsorption unit during the depressurization and purge steps. As used herein, the phrase “medium to very high purity hydrogen stream” refers to greater than 99% hydrogen. Furthermore, as used herein, the phrase “high purity hydrogen stream” refers to greater than 99.9% Hydrogen.
Depressurisation and purge are usually made at the lowest pressure which allows for the circulation of the gas towards the burners, i.e. just above atmospheric pressure. In the present process, due to the compression of the off-gas downwards the PSA, it could be interesting to maintain a higher pressure for the depressurization and purge steps in order to decrease both the size and the energy consumption of the compression. The corresponding decrease in hydrogen recovery could be compensated by the H2 recycles provided in the present process.
The removal of hydrogen product 23 from the feed gas 15 in the process unit 0 results in a process stream 1 that is purged from the process unit 0. This process stream 1 contains at least carbon dioxide, hydrogen and methane. Typically, the process stream contains at least methane, carbon monoxide, carbon dioxide, water, any unrecovered hydrogen and possibly nitrogen and traces of impurities (such as methanol, C2, aromatics, NH3, H2S . . . ) at ppm level.
In the process of the present invention as depicted in
Prior to being introduced into the cold purification/separation device 4.1 of the carbon dioxide separation unit 4, the process stream 1 obtained is compressed in a compressor 2. As used throughout, the term “compressor” is meant to include not only a compressor that has a single stage for compression but also a compressor that includes multiple stages for compression (typically from two to eight stages) with means for cooling between the various stages of the compressor. Note that the number of stages necessary to achieve the desired level of compression (pressure) depends on the inlet/outlet pressure ratio. Such determinations are readily determinable to those skilled in the art. The degree of compression prior to the cooling of the stream will depend in part upon the configuration of the carbon dioxide separation unit 4. More specifically, the process stream 1 will be compressed to a pressure equal to or greater than 35 bar prior to the cooling in the heat exchanger 3 of the present process as depicted in
If only part of the PSA off-gas is treated to recover CO2 and hydrogen, the other part of this off-gas could be produced at a second lower pressure thus increasing the performances of the PSA.
Prior to being compressed, the process stream 1 may optionally be passed through one or more filters, including a series of filters (not shown) in order to remove any adsorbent that may have passed through from the process unit 0. Those skilled in the art will recognize that a variety of different types of filters may be utilized to filter the process stream, including, but not limited to, ceramic filters, baghouses, metallic filters etc.
The compressed process stream 1 (or portion thereof) is then subjected to cooling to a temperature that is equal to or less than −10° C. by subjecting the process stream 1 to heat exchange in a heat exchanger 3. In a preferred embodiment, the process stream 1 is cooled to a temperature that is equal to or less than −30° C. Any type of heat exchanger 3 that is known in the art may be utilized to cool the process stream 1 to the desired temperature.
The next step of the process involves the separation and purification of the cooled process stream 1 to produce a carbon dioxide rich liquid stream 6 and a carbon dioxide lean non-condensable stream 5. This unit 4.1 may be any unit which is capable of separating/purifying carbon dioxide from a stream that contains carbon dioxide at a temperature that is equal to or less than −10° C., preferably equal to or less than −40° C. In other words, the carbon dioxide separation occurs at sub-ambient temperatures and conditions. Those of ordinary skill in the art recognize that such sub-ambient separation/purification is known in the art. Accordingly, the present process is not meant to be limited by the carbon dioxide separation unit 4 or the process for carrying out the separation/purification in the carbon dioxide separation/purification unit 4.1. As used throughout with regard to the present invention, the phrase “carbon dioxide separation unit” refers not only to the liquefaction units and/or distillation columns included therein, but also to all of the additional components that typically are considered to make up a carbon dioxide separation unit 4, including, but not limited to, one or more components selected from additional heat exchangers, additional compressors, dryers 4.2, etc. The term “dryers”4.2 is a general wording for removal of impurities which could be incompatible with the downstream equipments (plugging of exchanger for instance . . . ), or with the final use of the CO2 (according to composition requirement).
Those of ordinary skill in the art recognize that such purification could be made through several kinds of processes and preferentially through an adsorption process. Well known adsorbents could be used (activated alumina, Silica Gel, activated carbon . . . ). Preferentially, the process will be of the regenerative type, preferentially of the TSA (Temperature Swing Adsorption) type. The regeneration gas could be various one, internal stream such as part of the purified stream, permeate or residue stream from the downstream membranes—particularly the residue from the carbon dioxide membrane—or external stream such as available dry nitrogen.
With regard to the present carbon dioxide separation unit 4, the separation/purification 4.1 is typically carried out utilizing single or multi-step partial liquefaction as depicted in FIG. 2.a which includes one liquefaction unit 14; single or multi-step partial liquefaction in combination with at least one distillation column as depicted in FIG. 2.b which includes two liquefaction units (a first liquefaction unit 14.1 and a second liquefaction unit 14.2 and one distillation column 24; and single or multi-step partial liquefaction in combination with at least one distillation column and at least one compressor and/or heat exchanger as depicted in FIG. 2.c which includes two liquefaction units (a first liquefaction unit 14.1 and a second liquefaction unit 14.2, one distillation column 24, one compressor 25 and one heat exchanger 26. When two or more liquefaction units 14 are included in the carbon dioxide separation/purification unit 4.1, those skilled in the art will recognize that liquefaction within each of these units may take place at the same temperature (with different pressures) or at different temperatures (with the same pressure). In any event, the temperature for such liquefaction will generally be between about −10° C. and −57° C., preferably between about −30° C. and −57° C.
The optional driers could be installed prior to compression, during compression between stages of compression, after compression, after partial cooling.
Going back to
An additional purification unit—not shown—could be used on part or totality of the CO2 produced stream to reach the final required purity (catalysis, adsorption . . . ).
The carbon dioxide non-condensable stream 5 that is withdrawn from the carbon dioxide separation unit is typically at a high or medium pressure since the process stream 1 treated in the carbon dioxide separation unit 4 will be at a pressure that is equal to or greater than 35 bar. As used herein with regard to the carbon dioxide non-condensable stream 5, the phrase “high pressure” refers to a pressure that ranges from about 50 bar to about 100 bar, preferably from about 50 bar to about 80 bar. As used herein with regard to the carbon dioxide non-condensable stream 5, the phrase “medium pressure” refers to a pressure that ranges from about 10 bar to about 49 bar, preferably from about 25 bar to about 49 bar.
As depicted on
Transmembrane rate of transport of migrating components through the polymeric continuous phase is commonly referred to as flux and is driven primarily by molecular solution/diffusion mechanisms. Preferably, the polymer is selectively gas permeable to the components, meaning that the gases to be separated from each other permeate the membrane at different rates. That is, a highly permeable gas will travel a distance through the continuous phase faster than will a less permeable gas. The selectivity of a gas permeable polymer is the ratio of the permeabilities of the individual component gases, e.g. Permeability of component A to permeability of component B. Hence, the greater the difference between transmembrane fluxes of individual components, the larger will be the component pair selectivity of a particular polymeric membrane.
With regard to the present process, the permeate stream that is obtained will generally contain from about 40% to about 90% hydrogen with the remaining part of the permeate stream comprising the other components contained in the carbon dioxide non-condensable stream 5. Accordingly, a “hydrogen rich” permeate stream will generally contain greater than or equal to 40% hydrogen, preferably up to or greater than 90% hydrogen. In an alternative embodiment of the present process, the carbon dioxide non-condensable stream 5 can be treated in the hydrogen selective membrane separation unit 7 at low pressure in order to increase the recovery of hydrogen. As used herein with regard to the carbon dioxide non-condensable stream 5, the phrase “low pressure” refers to a pressure that is equal to or less than 10 bar, preferably from about equal to or less than 1 bar absolute to less than 10 bar. Note that when the carbon dioxide non-condensable stream 5 is permeated at low pressure, the carbon dioxide non-condensable stream 5 pressure is reduced (as it will be at high to medium pressure) by any method known in the art such as one or more valves, a turbine, etc. (not shown) with or without energy recovery. In a still further embodiment, the hydrogen rich permeate stream 8 is permeated at the same pressure as the feed gas 15 of the process unit 0.
Note that the hydrogen rich permeate stream 8 could be issued as two or more streams at different pressures when using membranes installed in series on the residue. This is generally made to decrease compression energy, more particularly if it could avoid a compression machine on one of streams.
The remaining components in the carbon dioxide lean non-condensable stream 5 form a hydrogen lean residue stream 9. As used herein with regard to the hydrogen lean residue stream 9, the phrase “hydrogen lean” refers to the residue stream having a percentage of hydrogen that is less than that in the carbon dioxide non-condensable stream 5.
The hydrogen selective membrane separation unit 7 utilized in the process of the present invention contains at least one membrane that is selective for hydrogen over the other components in the carbon dioxide lean non-condensable stream 5. Note that the target molecule, in this case hydrogen, determines how the permeate stream is used. With regard to each of the membranes utilized in the present process, each membrane has a permeate side 7.1 and a residue side 7.2. Since the membrane is selective for hydrogen, it allows for the passing of hydrogen through the membrane to the permeate side 7.1 of the membrane. While a variety of different types of membranes may be utilized in the hydrogen selective membrane separation unit 7 of the process of the present invention, the preferred membrane is a polymeric membrane that is selective for hydrogen that is selected from one or more polyamides, polyaramides, polybenzimidazoles, polybenzimidazole blends with polyimides, polyamides/imides. Hydrogen selective membranes will have a H2/CO2 selectivity given by the ratio of H2 permeance to the CO2 permeance at the operating conditions that is greater than 1.25, preferably greater than 5, more preferably greater than 8.
The hydrogen selective membranes of the present invention can be fabricated into any membrane form by any appropriate conventional method. For example, the hydrogen selective membranes may be cast as a sheet at the desired thickness onto a flat support layer (for flat sheet membranes), or extruded through a conventional hollow fiber spinneret (for hollow fiber membranes). Processes for preparing uniformly dense membranes or asymmetric membranes are also available and known to those skilled in the art. In addition, it is possible to prepare composite membranes by casting or extruding the membrane over a porous support of another material in either flat film or hollow fiber form. The separating layer of the composite membrane can be a dense ultra-thin or asymmetric film. In the preferred embodiment of the present process, the hydrogen selective membranes are in the form of modules comprising membranes formed as either hollow fibers or spiral wound asymmetric flat sheets.
The hydrogen selective membrane separation unit 7 includes at least one of the above noted membranes. With regard to the actual configuration of the hydrogen selective membrane separation unit 7, the hydrogen selective membrane separation unit 7 can take on any number of configurations. In one embodiment, there is only one membrane element in the hydrogen selective membrane separation unit 7. In an alternative embodiment, the hydrogen selective membrane separation unit 7 comprises a series of hydrogen selective membrane elements within a single membrane housing (not shown). With regard to this embodiment, the series of hydrogen selective membranes can be made up of hydrogen selective membranes of the same type selected from the hydrogen selective membranes detailed above or of two or more different hydrogen selective membranes selected from the hydrogen selective membranes detailed above. In the embodiment where there are two or more hydrogen selective membranes, the hydrogen selective membranes will preferably be of the same type and the same fabrication (for example, sheets or fibers). In a still further embodiment concerning the configuration of the hydrogen selective membrane separation unit 7, the hydrogen selective membrane separation unit 7 comprises two or more membrane housings with each of the housings having one or more hydrogen selective membranes as described hereinbefore. More specifically, in this embodiment, there can be two or more membrane housings, with each of the housings having either one hydrogen selective membrane or two or more hydrogen selective membranes of the same type or two or more hydrogen selective membranes of two of more different types. The resulting hydrogen selective membranes may be mounted in any convenient type of housing or vessel adapted to provide a supply of the carbon dioxide non-condensable stream 5, and removal of the permeate stream 7.1 and residue stream 7.2. The housing also provides a high-pressure side (for the carbon dioxide non-condensable stream 5 and the residue stream and a low-pressure side of the hydrogen selective membrane (for the permeate stream). As an example of configurations contemplated to be within the present invention, flat-sheet membranes can be stacked in plate-and-frame modules or wound in spiral-wound modules. Hollow-fiber membranes can be potted with a thermoset resin in cylindrical housings. The final hydrogen selective membrane separation unit 7 comprises one or more membrane modules or housings, which may be housed individually in pressure vessels or multiple elements may be mounted together in a sealed housing of appropriate diameter and length.
As noted above, as a result of passing the carbon dioxide non-condensable stream 5 through the hydrogen selective membrane separation unit 7, two separate streams are formed: a hydrogen rich permeate stream 8 and a hydrogen lean residue stream 9.
In a first option, as depicted in
More specifically, in the preferred embodiment, the hydrogen rich permeate stream 8 is utilized as two separate fractions—as a first hydrogen rich permeate fraction 8.1 to be used as a supplemental feed stream for processes that are upstream of the process unit 0, mainly for the synthesis gas generation unit 31 and as a second hydrogen rich permeate fraction 8.2 to be used as a supplemental feed stream in the process unit 0 with the objective being to optimize the use of the recycle stream 8 in order to maximize the conversion of carbon monoxide to carbon dioxide and hydrogen. With regard to this particular embodiment, the proportion of each fraction recycled to the corresponding devices (0, and what ever device is upstream) depends upon the percentage of production (the load) from the feed gas producing unit. Those of ordinary skill in the art will recognize that a number of different factors can contribute to the determination of the load including, but not limited to, the design of the plant and the size of the various components of the feed gas producing unit, the process unit 0, heat exchangers, carbon dioxide removal unit, etc. Preferably the conversion of carbon monoxide to carbon dioxide and hydrogen is maximized utilizing a portion of the recycle stream 8.1 and/or 8.3 while the remaining portion of the recycle stream 8.2 is sent to the process unit 0. This is accomplished by first directing the flow of the hydrogen rich permeate stream 8 to be added to the stream that is to be fed into the synthesis gas producing unit in the feed itself 8.1 or inside the synthesis gas generating processes 8.3. The optimum solution is to split the hydrogen rich permeate stream 8 with one part or fraction going to the synthesis gas producing unit and the other part or fraction going to the stream to be introduced into the process unit.
In a still further embodiment of the present invention as depicted in
As used herein, the phrase “low temperature water gas shift reactor” refers to a water gas shift reaction that generally occurs in the 180 to 240° C. range to further reduce carbon monoxide levels compared to the higher temperature water gas shift reactor which generally operates in a higher temperature range and is utilized to convert bulk (higher percentages) of carbon monoxide. Low temperature water gas shift reactors of the type contemplated in the present invention are known in the art and accordingly will not be described in great detail herein other than to not that such reactors require proper heating means (not shown) and steam injection (not shown). Furthermore, the size of the low temperature water gas shift reactor 32 will depend upon the quantity of hydrogen rich permeate 8 processed. Typically, this stream 8 will be smaller in size than the quantity of the feed stream 15 processed.
In a still further modification to this embodiment as shown in
In a second option, the hydrogen rich permeate stream is used as fuel in the synthesis gas generation plant 8.3, a steam generation plant or in another process 8.4.
Stream 8.3 used in the synthesis gas generation unit 31 could thus be a supplemental feed and/or used as fuel gas.
Note that, as already mentioned, the hydrogen rich permeate stream 8 could be issued as two or more streams at different pressures when using membranes installed in series on the residue. This is generally made to decrease compression energy, more particularly if it could avoid a compression machine on one of streams. It is well known by those ordinary skilled in the art of permeation.
With regard to the additional streams, as depicted on
In the next step of the present process, as shown in
The remaining components in the hydrogen lean residue stream 9 form a carbon dioxide depleted residue stream 12. As used herein with regard to the carbon dioxide depleted residue stream 12, the phrase “carbon dioxide depleted” refers to the residue stream having a percentage of carbon dioxide that is less than that in the stream introduced into the carbon dioxide membrane separation unit 10 (the hydrogen lean residue stream 9).
The carbon dioxide selective membrane separation unit 10 utilized in the process of the present invention contains at least one membrane that is selective for carbon dioxide over the other components in the hydrogen lean residue stream 9. Note that the target molecule, in this case carbon dioxide, determines how the permeate stream is used. With regard to each of the membranes utilized in the present process, each carbon dioxide selective membrane has a permeate side 10.1 and a residue side 10.2. Since the membrane is selective for carbon dioxide, it allows for the passing of carbon dioxide through the membrane to the permeate side 10.1 of the membrane.
While a variety of different types of membranes may be utilized in the carbon dioxide selective membrane separation unit 10 of the process of the present invention, the preferred membrane is a polymeric membrane that is selective for carbon dioxide that is selected from one or more polyimides, polyetherimides polysulfone, polyethersulfones, polyarylsulfone, polycarbonate, tetrabromo-bisphenol A polycarbonate, tetrachloro-bisphenol A polycarbonate, polydimethylsiloxane, natural rubber, cellulose actetate, cellulose triacetate, ethyl cellulose, PDD-TFE and polytriazole.
With regard to each of the carbon dioxide selective membranes utilized in the carbon dioxide selective membrane separation unit 10 of the present process, each carbon dioxide selective membrane has a permeate side 10.1 and a residue side 10.2. Since the membrane is selective for carbon dioxide, it allows for the passing of carbon dioxide through the membrane to the permeate side 10.1 of the membrane. While the membrane is selective for carbon dioxide, those skilled in the art will recognize that a minor portion of the other components in the hydrogen lean residue stream 9 will also pass through the carbon dioxide selective membrane to become a part of the permeate. Accordingly, with regard to the present process, the permeate stream that is obtained will generally contain from about 40% to about 90% carbon dioxide with the remaining part of the permeate stream comprising the other components contained in the hydrogen lean residue stream 9. As a result of passing the hydrogen lean residue stream 9 into the carbon dioxide selective membrane separation unit 10 and through the membrane, this stream is separated into two streams-one which is considered to be carbon dioxide enriched and one which is considered to be carbon dioxide depleted.
While a variety of different types of membranes may be utilized in the carbon dioxide selective membrane separation unit 10 of the process of the present invention, the preferred membrane is made of any number of polymers that are suitable as membrane materials. With regard to the membranes of the present invention, these polymers include, but are not limited to, substituted or unsubstituted polymers selected from polysiloxane, polycarbonates, silicone-containing polycarbonates, brominated polycarbonates, polysulfones, polyether sulfones, sulfonated polysulfones, sulfonated polyether sulfones, polyimides and aryl polyimides, polyether imides, polyketones, polyether ketones, polyamides including aryl polyamides, poly(esteramide-diisocyanate), polyamide/imides, polyolefins such as polyethylene, polypropylene, polybutylene, poly-4-methyl pentene, polyacetylenes, polytrimethysilylpropyne, fluorinated polymers such as those formed from tetrafluoroethylene and perfluorodioxoles, poly(styrenes), including styrene-containing copolymers such as acrylonitrile-styrene copolymers, styrene-butadiene copolymers and styrene-vinylbenzylhalide copolymers, cellulosic polymers, such as cellulose acetate-butyrate, cellulose propionate, ethyl cellulose, methyl cellulose, cellulose triacetate, and nitrocellulose, polyethers, poly(arylene oxides) such as poly(phenylene oxide) and poly(xylene oxide), polyurethanes, polyesters (including polyarylates), such as poly(ethylene terephthalate), and poly(phenylene terephthalate), poly(alkyl methacrylates), poly(acrylates), polysulfides, polyvinyls, e.g., poly(vinyl chloride), poly(vinyl fluoride), poly(vinylidene chloride), poly(vinylidene fluoride), poly(vinyl alcohol), poly(vinyl esters) such as poly(vinyl acetate) and poly(vinyl propionate), poly(vinyl pyridines), poly(vinyl pyrrolidones), poly(vinyl ketones), poly(vinyl ethers), poly(vinyl aldehydes) such as poly(vinyl formal) and poly(vinyl butyral), poly(vinyl amides), poly(vinyl amines), poly(vinyl urethanes), poly(vinyl ureas), poly(vinyl phosphates), and poly(vinyl sulfates), polyallyls, poly(benzobenzimidazole), polyhydrazides, polyoxadiazoles, polytriazoles: poly(benzimidazole), polycarbodiimides, polyphosphazines, and interpolymers, including block interpolymers containing repeating units from the above such as terpolymers of acrylonitrile-vinyl bromide-sodium salt of para-sulfophenylmethallyl ethers, and grafts and blends containing any of the foregoing. The polymer suitable for use is intended to also encompass copolymers of two or more monomers utilized to obtain any of the homopolymers or copolymers named above. Typical substituents providing substituted polymers include halogens such as fluorine, chlorine and bromine, hydroxyl groups, lower alkyl groups, lower alkoxy groups, monocyclic aryl, lower acyl groups and the like.
With regard to one embodiment of the present invention, the preferred polymers include, but are not limited to, polysiloxane, polycarbonates, silicone-containing polycarbonates, brominated polycarbonates, polysulfones, polyether sulfones, sulfonated polysulfones, sulfonated polyether sulfones, polyimides, polyetherimides, polyketones, polyether ketones, polyamides, polyamide/imides, polyolefins such as poly-4-methyl pentene, polyacetylenes such as polytrimethysilylpropyne, and fluoropolymers including fluorinated polymers and copolymers of fluorinated monomers such as fluorinated olefins and fluorodioxoles, and cellulosic polymers, such as cellulose diacetate and cellulose triacetate. Examples of preferred polyimides are Ultem 1000, P84 and P84-HT polymers, and Matrimid 5218.
Of the above noted polymeric membranes, the most preferred membranes are those made of polyimides. More specifically, polyimides of the type disclosed in U.S. Pat. No. 7,018,445 and U.S. Pat. No. 7,025,804, each incorporated herein in their entirety by reference.
With regard to these types of membranes, the process of the present invention preferably utilizes a membrane comprising a blend of at least one polymer of a Type 1 copolyimide and at least one polymer of a Type 2 copolyimide in which the Type 1 copolyimide comprises repeating units of formula I
in which R2 is a moiety having a composition selected from the group consisting of formula A, formula B, formula C and a mixture thereof,
Z is a moiety having a composition selected from the group consisting of formula L, formula M, formula N and a mixture thereof; and
R1 is a moiety having a composition selected from the group consisting of formula Q, formula S, formula T, and a mixture thereof,
in which the Type 2 copolyimide comprises the repeating units of formulas IIa and IIb
in which Ar is a moiety having a composition selected from the group consisting of formula U, formula V, and a mixture thereof,
in which
X, X1, X2, X3 independently are hydrogen or an alkyl group having 1 to 6 carbon atoms, provided that at least two of X, X1, X2, or X3 on each of U and V are an alkyl group,
Ar′ is any aromatic moiety,
Ra and Rb each independently have composition of formulas A, B, C, D or a mixture thereof, and
Z is a moiety having composition selected from the group consisting of formula L, formula M, formula N and a mixture thereof
The material of the membrane consists essentially of the blend of these copolyimides. Provided that they do not significantly adversely affect the separation performance of the membrane, other components can be present in the blend such as, processing aids, chemical and thermal stabilizers and the like.
In a preferred embodiment, the repeating units of the Type 1 copolyimide have the composition of formula Ia.
Wherein R1 is as defined hereinbefore. A preferred polymer of this composition in which it is understood that R1 is formula Q in about 16% of the repeating units, formula S in about 64% of the repeating units and formula T in about 20% of the repeating units is available from HP Polymer GmbH under the tradename P84
In another preferred embodiment, the Type 1 copolyimide comprises repeating units of formula Ib.
Wherein R1 is as defined hereinbefore. Preference is given to using the Type 1 copolyimide of formula Ib in which R1 is a composition of formula Q in about 1-99% of the repeating units, and of formulas in a complementary amount totaling 100% of the repeating units.
In yet another preferred embodiment, the Type 1 copolyimide is a copolymer comprising repeating units of both formula Ia and Ib in which units of formula Ib constitute about 1-99% of the total repeating units of formulas Ia and Ib. A polymer of this structure is available from HP Polymer GmbH under the tradename P84-HT325.
In the Type 2 polyimide, the repeating unit of formula IIa should be at least about 25%, and preferably at least about 50% of the total repeating units of formula IIa and formula IIb. Ar′ can be the same as or different from Ar.
The polyimides utilized to form the membranes of the present process will typically have a weight average molecular weight within the range of about 23,000 to about 400,000 and preferably about 50,000 to about 280,000.
The carbon dioxide selective membranes of the present process can be fabricated into any membrane form by any appropriate conventional method as noted hereinbefore with regard to the hydrogen selective membranes (i.e., flat sheet membranes or hollow fiber membranes). While the carbon dioxide selective membranes do not have to be in the same form as the hydrogen selective membranes, in one preferred embodiment, the form of the carbon dioxide selective membranes is in the hollow fiber form and the hydrogen selective membranes are in the same form.
As with the hydrogen selective membrane separation unit 7, the carbon dioxide membrane separation unit 10 includes at least one of the above noted membranes. With regard to the actual configuration of the carbon dioxide selective membrane separation unit 10, the carbon dioxide selective membrane separation unit 10 can take on any number of different configurations as discussed hereinbefore with regard to the hydrogen selective membrane separation unit 7.
As noted and shown on
More specifically, the carbon dioxide enriched permeate stream 11 may be recycled to the process stream 1 from the process unit 0 where is it added to the process stream 1 prior to the carbon dioxide separation/purification unit 4.1, recycled prior to compressor 2 or within the compressor 2 between two of the stages of compression (not shown in
The carbon dioxide depleted residue stream 12 that is obtained from the carbon dioxide selective membrane separation unit 10 can be withdrawn for further use. For example, the carbon dioxide depleted residue stream 12 can be used as a fuel 12.2 (for example as a steam methane reformer fuel), as a feed stream 12.1 (for example as a steam methane reformer feed stream) or as both a fuel and a feed stream in this process or used in other processes 12.3 such as in another hydrogen generation plant. In addition, the carbon dioxide depleted residue stream 12 can be used to regenerate any dryers that may be positioned within the process schematic of the present invention to remove moisture and other impurities if any. Its pressure could be reduced by any method known in the art such valves, turbines with or without energy recovery. This stream could be heated before pressure reduction to increase the energy recovery if any. It could be noted that using part or the totality of this stream as a fuel (or in another process) helps to remove gases like nitrogen from the global system avoiding an accumulation of inerts due to the several possible recycles.
In
In that case, it could be a low pressure hydrogen permeate, i.e; at the minimum pressure which allows for injecting this stream in the burners (generally less than 2 bar abs, approximately at 1.5 bar abs). As mentioned before, another part of the hydrogen rich permeate could be produced at a higher pressure for another use.
The operating temperatures for the hydrogen selective membranes and the carbon dioxide selective membranes are each independently selected based on the physical properties of each membrane such that it is mechanically stable and a sufficient gas flux can be maintained across the membrane. Typically, the stream being fed to each of the membrane separation units (7, 10) will be heated or cooled, if necessary, to a temperature which ranges from about −55° C. to about 150° C. In other words, the process of membrane separation in each of these units (7, 10) typically operates at the noted temperature. In one alternative, the hydrogen lean reside stream 9 is fed into the carbon dioxide selective membrane unit 10 at low to sub-ambient temperatures, preferably from −55° C. to about 30° C., preferably from −55° C. to about 10° C.
In such cases, the carbon dioxide selective membranes are cold membranes. With regard to this particular alternative, the cold brought to the carbon dioxide lean non-condensable stream 5 is taken for instance from the liquid carbon dioxide stream 1, (preferably after the step of pumping if any).
In still another alternative, the carbon dioxide lean non-condensable stream 5 from the carbon dioxide separation unit 4 is fed to the hydrogen selective membrane separation unit 7 after being heated to a temperature from about 50° C. to about 150° C. in an optional heat exchanger 28. With regard to this particular alternative, the heat brought to the carbon dioxide lean non-condensable stream 5 is taken for instance from the process stream 1 after the step of compression.
In an even further still embodiment of the present invention, as shown in
The size of the low temperature water gas shift reactor 33 would depend upon the amount of the carbon dioxide lean non-condensable stream 5 being processed. Note that when this option is utilized, the membranes utilized in the hydrogen and carbon dioxide membrane units (7, 10) will be designed to address wet synthesis gas.
| Number | Date | Country | Kind |
|---|---|---|---|
| 12174867.7 | Apr 2012 | EP | regional |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/EP2013/059281 | 5/3/2013 | WO | 00 |
