Claims
- 1. A process for separating ar,ar-dihalo-ar-alkylbenzenes wherein two of the ring substituents are meta oriented with respect to each other and wherein alkyl includes substituted alkyl, said process comprising (1) contacting an isomeric mixture containing an ar,ar-dihalo-ar-alkylbenzene having the substituents in the 1,2,4- ring positions (1,2,4- isomer) and an isomer thereof having the substituents in the 1,3,5-ring positions (1,3,5- isomer) with an alkylating agent in the presence of a catalytic amount of a Friedel-Crafts catalyst at a reaction temperature less than about 90.degree. C such that the 1,2,4- isomer is preferentially alkylated and (2) separating the alkylated 1,2,4- isomer from the unreacted 1,3,5- isomer.
- 2. The process of claim 1 wherein (1) the isomeric mixture contains ar,ar-dihalo-ar-alkylbenzenes represented by the formulas: ##STR3## wherein each X is individually halogen and R is alkyl or substituted alkyl and (2) the isomeric mixture is contacted with an alkylating agent in the presence of a catalytic amount of an aluminum trihalide at a reaction temperature of between about -20.degree. C and about 60.degree. C.
- 3. The process of claim 2 wherein X is Cl or Br and R is alkyl having from 3 to 5 carbon atoms.
- 4. The process of claim 3 wherein R contains three carbon atoms.
- 5. The process of claim 2 wherein the alkylating agent is an alkyl halide or an olefin.
- 6. The process of claim 2 wherein the alkylating agent is isopropyl chloride or propene.
- 7. The process of claim 2 wherein an isomeric mixture of 3,5-dichlorocumene and 2,4-dichlorocumene is contacted with propene or isopropyl chloride in the presence of from about 0.5 to about 1.5 weight percent of aluminum trichloride at a temperature between about -20.degree. C and about 20.degree. C.
CROSS REFERENCE TO RELATED APPLICATIONS
This application is a continuation-in-part of application Ser. No. 707,924 filed July 22, 1976 now U.S. Pat. No. 4,059,642.
Non-Patent Literature Citations (1)
Entry |
ohah et al., Aromatic Substitution XVIII, Friedel Crafts t-Butylation of Benzene and Methylbenzenes wt-Butyl Bromide & Isotulylene, JACS; 86, 3-20-64; p. 1060. |
Continuation in Parts (1)
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Number |
Date |
Country |
Parent |
707924 |
Jul 1976 |
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