Claims
- 1. Process for separating mixtures of m- and p-dichlorobenzene having at least 50% by weight of m-dichlorobenzene, by treating such mixtures in the liquid phase with a pentasil zeolite, the amount of dichlorobenezene treated being 0.05 to 2 times the amount of pentasil zeolite used, wherein the mixture is treated in from 50 to 25% by weight of a dichlorobenzene mixture of a solvent from the group of cyclic saturated hydrocarbons having 5 to 15 carbon atoms, alkyl-substituted aromatic hydrocarbons having 8 to 12 carbon atoms, and halogen-substituted aromatic hydrocarbons having 6to 10 carbon atoms and 1 to 3 halogen atoms or a mixture of a plurality thereof, with the exception of the solvents ethylbenzene, chlorobenzene, p-xylene, p-chlorotoluene and dichlorobenzene, at from 20.degree. to 200.degree. C. and wherein said pentasil zeolite contains, as exchangeable cations, protons, cations of the first or second main group of the Mendeleev Periodic System of the Elements, cations of the rare earth metals or a mixture of a plurality thereof, the enriched m-dichlorobenzene is removed as filtrate, and p-dichlorobenzene is obtained by desorption of the pentasil zeolite.
- 2. The process of claim 1, wherein the following structure types are used as pentasil zeolites: ZSM 5, ZSM 11, ZSM 8, ZSM 5/ZSM 11-intermediates, Zeta 1, Zeta 3, ZBM 10, Ultrasil, Ultrazet, TZ-01, NU-4, NU-5, AZ-1.
- 3. The process of claim 2, wherein the following structure types are used as pentasil zeolites: ZSM 5, ZSM 8, ZSM 11 and ZSM 5ZSM 11-intermediates.
- 4. The process of claim 3, wherein the following structure types are used as pentasil zeolites: ZSM 5 and ZSM 11.
- 5. The process of claim 1, wherein mixtures containing more than 70% by weight of m-dichlorobenzene are used.
- 6. The process of claim 1, wherein one or more solvents from the group of cyclic saturated hydrocarbons having 5 to 12 carbon atoms, alkyl-substituted benzenes having 8 to 10 carbon atoms and 1 to 3 alkyl radicals which in each case contain up to 3 carbon atoms but together not more than 4 carbon atoms, and also the chlorinated benzene derivatives having 6 to 8 carbon atoms and 1 to 3 chlorine atoms is/are used, with the exception of ethylbenzene, chlorobenzene and dichlorobenzene.
- 7. The process of claim 6, wherein cyclohexane, o-xylene, m-xylene, mesitylene; 1,2,4-trichlorobenzene, 3,4-dichlorotoluene or a mixture of a plurality thereof is used.
- 8. The process of claim 1, wherein from 0.1 to i amount units of dichlorobenzene mixture is used per amount unit of pentasil zeolite.
- 9. The process of claim 7, wherein from 0.2 to 0.8 amount units of dichlorobenzene mixture is used per amount unit of pentasil zeolite.
Priority Claims (1)
Number |
Date |
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4218841 |
Jun 1992 |
DEX |
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Parent Case Info
This application is a continuation of, application Ser. No. 08/071,739, filed Jun. 3, 1993 now abandoned.
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Continuations (1)
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Number |
Date |
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Parent |
71739 |
Jun 1993 |
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