Claims
- 1. A process for the preparation of fluoroalkyl alkoxylates comprising reacting a fluorinated alcohol with an alkylene epoxide having 2 to 10 carbon atoms, or mixture of said alkylene epoxides, at a temperature from 90.degree. C. to 200.degree. C. and a pressure from ambient atmospheric pressure to 100 psig in the presence of an alkali metal borohydride present at a molar ratio of alkali metal borohydride to fluorinated alcohol of at least 0.005, and at least one iodine source selected from the group consisting of an alkali metal iodide, an alkaline earth metal iodide, elemental iodine, and mixtures of the same, at a molar ratio of iodine source to alkali metal borohydride of from 0.1:1.0 to 300:1; said fluorinated alcohol having the general formula:
- R.sub.f --Q--OH
- wherein
- R.sub.f is a linear or branched perfluoroalkyl group having from 4 to 20 carbon atoms, or a mixture of these groups;
- Q is --(CH.sub.2).sub.n --, ##STR4## each of R.sup.1 and R.sup.4 is independently hydrogen or an alkyl group containing from 1-6 carbon atoms;
- each of R.sup.2 and R.sup.3 is independently a divalent linear or branched alkylene group containing from 1-6 carbon atoms; and
- n is an integer of from 1 to 6.
- 2. The process of claim 1 wherein the fluorinated alcohol has the structure R.sub.f CH.sub.2 CH.sub.2 OH in which R.sub.f is a linear perfluoroalkyl group having from 4 to 20 carbon atoms, or a mixture of these groups.
- 3. The process of claim 1 wherein said alkylene epoxide is ethylene oxide or propylene oxide or a mixture thereof.
- 4. The process of claim 1 wherein said alkylene epoxide is ethylene oxide.
- 5. The process of claim 1 wherein said alkali metal borohydride is sodium borohydride.
- 6. The process of claim 1 wherein the molar ratio of alkali metal borohydride to fluorinated alcohol is from 0.25:1 to 0.1:1.
- 7. The process of claim 1 wherein said iodine source is elemental iodine, sodium iodide or a mixture thereof.
- 8. The process of claim 1 wherein the molar ratio of iodine source to alkali metal borohydride is from 0.1:1 to 0.5:1.
- 9. The process of claim 1 wherein the molar ratio of iodine source to alkali metal borohydride is from 0.1:1 to 0.3:1.
- 10. A process for preparing a mixture of fluoroalkylethoxylates which comprises reacting ethylene oxide with a perfluoroalkylalkanol in accordance with the following equation: ##STR5## wherein F(CF2)m- is a linear perfluoroalkyl group;
- m is an integer from about 4 to about 20, provided that the mixture contains at least 5 weight percent of molecules in which m is 8 or higher or mixtures of the same, but in no more than 5 weight percent of the molecules is m equal to 14 or higher, or mixtures of the same;
- n is an integer from 1 to 3;
- p is an integer from about 2 to about 40, provided that the distribution of molecules in said mixture has an average p from 8 to 17; and the catalyst consists essentially of a mixture of an alkali metal borohydride and at least one source of iodine selected from the group consisting of elemental iodine, alkali metal iodides and alkaline earth metal iodides.
- 11. The process of claim 10 where n is 2.
- 12. The process of claim 10 wherein the average of p in the molecular distribution of the mixture is from about 12 to about 17.
- 13. The process of claim 12 wherein n is 2.
- 14. The process of either claim 10, 11, 12 or 13 wherein said source of iodine is elemental iodine.
- 15. The process of either claim 10, 11, 12 or 13 wherein said source of iodine is sodium iodide.
- 16. The process of either claim 10, 11, 12 or 13 wherein said source of iodine is a mixture of elemental iodine and sodium iodide.
CROSS-REFERENCE TO RELATED APPLICATIONS
This is a continuation-in-part of application Ser. No. 08/263,091 filed 21 Jun. 1994 now allowed.
US Referenced Citations (8)
Foreign Referenced Citations (1)
Number |
Date |
Country |
0161459 |
Apr 1985 |
EPX |
Continuation in Parts (1)
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Number |
Date |
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Parent |
263091 |
Jun 1994 |
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