Claims
- 1. A process for the manufacture of acetic acid, ethanol, acetaldehyde and any secondary products thereof which comprises catalytically reacting carbon monoxide and hydrogen using a catalyst, applied onto a carrier, containing salts or complex compounds of rhodium either with a valence of less than 3 or prepared by reduction of correspondingly supported compounds of trivalent rhodium at a temperature below 300.degree. C., halide ions and a co-catalyst of magnesium in the form of a salt or complex compound.
- 2. The process according to claim 1 wherein the catalyst contains 0.1 to 20 weight percent rhodium, 0.1 to 25 weight percent magnesium and 0.01 to 20 weight percent halide ions.
- 3. The process according to claim 1 wherein the carrier is either silicic acid or magnesium silicate.
- 4. The process according to claim 1, 2 or 3 wherein the catalyst is in the form of a complex compound of either Mg.sub.3 [RhCl.sub.6 ].sub.2 or Mg[Rh(CO).sub.2 Cl.sub.2 ].sub.2.
- 5. The process according to claim 1 or 3 wherein the halide ions are chlorides.
- 6. The process according to claim 5 wherein the catalyst is in the form of a complex compound of either Mg.sub.3 [RhCl.sub.6 ].sub.2 or Mg[Rh(CO).sub.2 Cl.sub.2 ].sub.2.
- 7. The process according to claim 1 or 3 further comprising the continuous or discontinuous addition of volatile magnesium salts or magnesium compounds together with the carbon monoxide and hydrogen as gaseous starting materials to the reaction zone during the reaction.
- 8. The process according to claim 4 further comprising the continuous or discontinuous addition of volatile magnesium salts or magnesium compounds together with the carbon monoxide and hydrogen as gaseous starting materials to the reaction zone during the reaction.
- 9. The process according to claim 7 wherein the magnesium salt or magnesium compound used is either magnesium acetate or magnesium chloride.
- 10. The process according to claim 1, 2 or 3 further comprising the continuous or discontinuous addition to the reaction zone of a hydrogen halide or a volatile organic halogen compound not containing any sulfur or nitrogen in the molecule and splitting off hydrogen halide under reaction conditions together with the gaseous starting materials during the reaction.
- 11. The process according to claim 7 further comprising the continuous or discontinuous addition to the reaction zone of a hydrogen halide or a volatile organic halogen compound not containing any sulfur or nitrogen in the molecule and splitting off hydrogen halide under reaction conditions together with the gaseous starting materials during the reaction.
- 12. The process according to claim 10 wherein the hydrogen halide is hydrogen chloride.
- 13. The process according to claim 10 wherein the organic halogen compound is acetyl chloride.
Priority Claims (3)
Number |
Date |
Country |
Kind |
2814365 |
Apr 1978 |
DEX |
|
2825495 |
Jun 1978 |
DEX |
|
2850110 |
Nov 1978 |
DEX |
|
Parent Case Info
This is a continuation of application Ser. No. 025,033 filed Mar. 29, 1979, now abandoned.
US Referenced Citations (4)
Continuations (1)
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Number |
Date |
Country |
Parent |
25033 |
Mar 1979 |
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