Claims
- 1. A process for the preparation of waxy esterification products comprising reacting acidic, hard paraffin oxidation products of synthetic origin with an alcohol in the molten state in the presence of an effective amount of a catalytic zinc compound.
- 2. A process of claim 1, wherein the hard paraffin oxidation product has been partially saponified prior to reaction with the alcohol.
- 3. A process of claim 1, wherein at least 70% of the acid function of the paraffin oxidation products as determined by acid number is esterified, and wherein the acid number of the waxy ester product is lowered to a value below 10 mg KOH/g.
- 4. A process of claim 1, wherein the zinc compound is an oxide, a hydroxide or a mineral acid salt.
- 5. A process of claim 1, wherein the zinc compound is the zinc salt of a carboxylic acid.
- 6. A process of claim 1, wherein the hard paraffin oxidation product is an air oxidized product of a Fischer-Tropsch synthesis or an oxidized product of an ethylene polymerization by the Ziegler process.
- 7. A process of claim 6, wherein the hard paraffin oxidation product has an acid number of 5 to 80 and was prepared in molten condition in the presence of a zinc salt by air oxidation of a product of ethylene polymerization by the Ziegler process having a molecular weight (determined by the vapor pressure technique osmometrically) of 1000 to 4000.
- 8. A process of claim 1, wherein the amount of zinc compound is 0.01 to 3.0 weight %.
- 9. A process of claim 1, wherein the zinc compound is zinc stearate.
- 10. A process of claim 1, wherein the alcohol is a monovalent alcohol of 4-20 carbon atoms having a terminal hydroxy group.
- 11. A process of claim 1, wherein the alcohol is multivalent.
- 12. A process of claim 11, wherein the alcohol is of 2-5 C-atoms and has at least one terminal OH group.
- 13. A process of claim 1, wherein the alcohol is 1,2-ethanediol, 1,2-propanediol, 1,3-propanediol, 1,3-butanediol, 1,4-butanediol, glycerine or pentaerythritol.
- 14. A process of claim 1, wherein the amount of alcohol is from 1 to 1.5 times the stoichiometric amount.
- 15. A process of claim 4, carried out at a temperature of 140.degree.-220.degree. C.
- 16. A process of claim 1, wherein the hard paraffin oxidation product was prepared using a zinc catalyst and the same zinc catalyst is used as said catalytic zinc compound.
- 17. A waxy esterification product prepared by the process of claim 1.
- 18. A waxy esterification product prepared by the process of claim 3.
- 19. A waxy esterification product prepared by the process of claim 9.
- 20. A process of claim 1 wherein the paraffin oxidation product has a dropping point of 90.degree.-110.degree. C. and is prepared by Fischer-Tropsch oxidation or has a dropping point of 95.degree. to 140.degree. C. and is a polyethylene wax oxidation product.
- 21. A process of claim 1 wherein the paraffin oxidation prooduct has a dropping point of 90.degree.-140.degree. C.
Priority Claims (1)
Number |
Date |
Country |
Kind |
3427884 |
Jul 1984 |
DEX |
|
Parent Case Info
This application is a continuation of application Ser. No. 07/283,029, filed Nov. 30, 1988, which is a cont. of Ser. No. 07/204,961, of June 9, 1988, which is a cont. of Ser. No. 07/090,415 of Aug. 26, 1987, which is a cont. of Ser. No. 06/759,571 of July 26, 1985, all now abandoned.
US Referenced Citations (2)
Foreign Referenced Citations (2)
Number |
Date |
Country |
1007398 |
Mar 1977 |
CAX |
1274105 |
Aug 1968 |
DEX |
Non-Patent Literature Citations (3)
Entry |
Kohn, Encyclopedia of Science and Technology, vol. 14, pp. 508-510, McGraw-Hill. |
Szabo et al., Chemical Abstracts, vol. 89, No. 91420p, 1978. |
Translation of first page of German 1,274,105. |
Continuations (4)
|
Number |
Date |
Country |
Parent |
283029 |
Nov 1988 |
|
Parent |
204961 |
Jun 1988 |
|
Parent |
90415 |
Aug 1987 |
|
Parent |
759571 |
Jul 1985 |
|