Process for the oxidation of olefins using catalysts containing various promoter elements

Abstract

The present invention is a process for the oxidation of olefins to unsaturated aldehydes and acids using a catalyst containing iron, bismuth, molybdenum plus at least one of nickel, cobalt, magnesium, zinc, cadmium or calcium and according to the invention, an element selected from germanium, cerium, thorium, manganese, niobium, chromium, praseodymium, yttrium, zirconium, ruthenium, gallium, tin, indium, copper, lanthanum, tantalum or tungsten. These catalysts may also contain certain elements that further enhance the desirability of the oxidation process.

Description

BACKGROUND OF THE INVENTION

The process for oxidizing olefins with various multi-component catalysts is known. Grasselli and Hardman, in U.S. Pat. No. 3,642,930 disclose that certain complex catalysts can be employed in the oxidation of olefins to obtain unsaturated aldehydes and acids. These catalysts indeed are very desirable for this oxidation reaction, but a continuous search has been made for other catalysts that would improve the results obtained with these catalysts of Grasselli and Hardman. The present invention is a result of such a search.

SUMMARY OF THE INVENTION

The invention is in the process for the preparation of unsaturated aldehydes and acids from propylene or isobutylene by the vapor phase oxidation of propylene or isobutylene with molecular oxygen at a temperature of about 200.degree. to 600.degree. C. in the presence of a catalyst, the improvement comprising using as the catalyst a catalyst of the formula

X.sub.a A.sub.b D.sub.c E.sub.d Fe.sub.f Bi.sub.g Mo.sub.12 O.sub.x wherein X is Ce, Th, Mn, Pr, Nb, Ge, Cr, Y, Zr, Ru, Ga, Sn, In, Cu, La, Ta, W or mixture thereof; A is an alkali metal, Tl or mixture thereof; D is Ni, Co, Mg, Zn, Cd, Ca, Sr, or mixture thereof; E is P, As, B, S, Al or mixture thereof; and wherein a is greater than 0 but less than 5; b and d are 0-4; c, f and g are 0.1-12; and x is the number of oxygens required to satisfy the valence requirements of the other elements present. This oxidation reaction give especially desirable results at atmospheric or superatmospheric pressure.

The central aspect of the present invention is the particular catalyst employed. The catalysts may be any of the catalysts delineated by the formula described above. In the preferred practice of the invention each of the elements described by X is separately incorporated into the catalyst. This is conveniently accomplished by setting X independently equal to the various elements. Also preferred as far as the broad compositional structure of the catalyst is concerned are those catalysts that contain potassium, rubidium, cesium or mixture thereof and those catalysts that contain nickel, cobalt or mixture thereof.

The catalysts of the invention are prepared by techniques that are broadly known in the art. These techniques include the coprecipitation of soluble salts. More specific information on the preparation of the catalysts is given in the Specific Embodiments.

The catalysts of the invention may be used in the supported or unsupported form. Suitable support materials include silica, alumina, Alundum, titania, zirconia, silicon carbide and the like. The catalysts may also be used in various physical forms. The catalysts can be employed in a fixed-bed reactor or a fluid-bed reactor.

The process for oxidation of propylene or isobutylene is well known in the art. Broadly, a mixture of the olefin and molecular oxygen, optionally in the presence of steam or other diluent is contacted with a catalyst at an elevated temperature of about 200.degree.-600.degree. C. for a contact time sufficient to convert the olefin to the corresponding unsaturated aldehyde and acid. Normally, the product from these reactions contains a very large portion of the aldehyde and a smaller byproduct amount of the unsaturated acid. The contact time may vary widely from a few seconds to a number of seconds or more. The reaction can be conducted under atmospheric, superatmospheric or subatmospheric pressure with the use of a superatmospheric pressure normally being used on a commercial scale.

One special advantage of the catalysts of the invention is their ability to withstand the feed of large amounts of olefin over the catalyst in a given time. This is normally measured in terms of WWH which is the weight of olefin per weight of catalyst per hour. In other words, these catalysts can efficiently work on large amounts of olefin. Catalysts found in this art tend to be less efficient when large amounts of olefin are fed in a given period of time.

SPECIFIC EMBODIMENTS

EXAMPLES 1-8--Oxidation of isobutylene at atmospheric pressure

Various catalysts of the invention containing 20% SiO.sub.2 were prepared by the procedures described below.

EXAMPLE 1

Pr.sub.0.5 K.sub.0.1 Ni.sub.2.5 Co.sub.4.5 Fe.sub.3 BiMo.sub.12 O.sub.x

A slurry of 63.56 g. of (NH.sub.4).sub.6 Mo.sub.7 O.sub.24.4H.sub.2 O, 52.33 g. Nalco 40% silica sol and 2.60 g. PrO.sub.2 was prepared. Separately, a solution of 36.36 g. Fe(NO.sub.3).sub.3.9H.sub.2 O, 14.55 g. Bi(NO.sub.3).sub.3.5H.sub.2 O, 39.29 g. Co(NO.sub.3).sub.2.6H.sub.2 O, 21.80 g. NI(NO.sub.3).sub.2.6H.sub.2 O and 3.03 g. of a 10% solution of KNO.sub.3 was prepared. The slurry and solution were combined, the liquid evaporated to a paste and the paste was dried at 120.degree. C. overnight. The catalyst was heat treated at 290.degree. C. for three hours, at 425.degree. C. for three hours and at 550.degree. C. for 16 hours.

EXAMPLES 2-5

The catalysts were prepared in the same manner as described above except that the appropriate amount of the nitrates of manganese and thorium, the chloride of germanium and the oxide of niobium were added in place of the praseodymium.

EXAMPLE 6

Mn.sub.0.5 Cs.sub.0.5 K.sub.0. 5 Ni.sub.2.5 Co.sub.4.5 Fe.sub.3 BiMo.sub.12 O.sub.x

A solution of 2.72 g. CsNO.sub.3, 1.19 g. KNO.sub.3, 20.33 g. Ni(NO.sub.3).sub.2.6H.sub.2 O, 36.61 g. Co(NO.sub.3).sub.2.6H.sub.2 O, 33.9 g. Fe(NO.sub.3).sub.3.9H.sub.2 O 13.6 g. Bi(NO.sub.3).sub.3.5H.sub.2 O was added to a slurry of 2.5 g. Mn(NO.sub.3).sub.2, 59.2 g. (NH.sub.4).sub.6 Mo.sub.7 O.sub.24.4H.sub.2 O and 50 g. Nalco 40% silica sol. The mixture was evaporated, dried and heat treated as shown in Example 1.

EXAMPLES 7-8

The catalysts were prepared in the same manner except that the 1.46 g. GeO.sub.2 or 1.84 g. Nb.sub.2 O.sub.5 was added instead of the manganese nitrate.

In a fixed-bed reactor, constructed of a 0.75 cm. inside diameter stainless steel tube, was placed 5 cc. of each of the catalysts prepared above. These catalysts were tested at a reaction temperature of 371.degree. C. using a feed of isobutylene/air/steam of 1/10/4 and an apparent contact time of 3.3 seconds. The results of these experiments are given in Table 1. The results are stated as follows: ##EQU1## In the Tables MA is methacrolein, and MAA is methacrylic acid.

Table 1______________________________________Oxidation of Isobutylene toMethacrolein and Methacrylic Acidat Atmospheric Pressure Using a Catalyst ofYNi.sub.2.5 Co.sub.4.5 Fe.sub.3 BiMo.sub.12 O.sub.x Results, % Yield Per Pass Conver- Select-Ex. Catalyst, Y= MA MAA Total sion ivity______________________________________1 Pr.sub.0.5 K.sub.0.1 61.6 2.2 63.8 91.3 69.92 Mn.sub.0.5 K.sub.0.1 68.5 2.9 71.4 100.0 71.43 Ge.sub.0.5 K.sub.0.1 67.0 4.5 71.5 100.0 71.54 Nb.sub.0.5 K.sub.0.1 52.2 2.5 54.7 82.9 66.15 Th.sub.0.5 K.sub.0.1 74.3 2.6 76.9 100.0 76.96 Mn.sub.0.5 Cs.sub.0.5 68.3 3.4 71.7 100.0 71.7 K.sub.0.57 Ge.sub.0.5 Cs.sub.0.5 77.1 1.0 78.1 94.3 82.9 K.sub.0.58 Nb.sub.0.5 Cs.sub.0.5 75.3 1.2 76.5 94.7 80.8 K.sub.0.5______________________________________

EXAMPLES 9-13--Oxidation of isobutylene at superatmospheric pressure.

In the same manner as described above, various catalysts prepared above were used in reactions at superatmospheric pressure. The catalysts were prepared as follows:

EXAMPLE 9

Cr.sub.0.5 Cs.sub.0.5 Ni.sub.2.5 Co.sub.4.5 Fe.sub.3 BiMo.sub.12 O.sub.x

A solution of 1.1 g. CsNO.sub.3, 8.2 g. Ni(NO.sub.3).sub.2.6H.sub.2 O, 14.8 g. Co(NO.sub.3).sub.2.6H.sub.2 O, 13.7 g. Fe(NO.sub.3).sub.3.5H.sub.2 O, 5.5 g. Bi(NO.sub.3) .sub.3.5H.sub.2 O, 2.3 g. Cr(NO.sub.3).sub.3.9H.sub.2 O was prepared and a slurry of 23.9 g. (NH.sub.4).sub.6 Mo.sub.7 O.sub.24.4H.sub.2 O and 20 g. Nalco 40% silica was added. The catalyst was dried and heated at 430.degree. C. for four hours and 600.degree. C. for three hours.

EXAMPLES 10-13

These catalysts were prepared in the same manner as Example 9 using the appropriate ingredients as starting materials.

The pressure, unless otherwise noted, at 12 p.s.i.g. The temperature of the reaction and the results are shown in Table 2. The feed was of the same composition as described above and the apparent contact time was 3.5-4.1 seconds and the WWH was 0.098-0.159.

Table 2__________________________________________________________________________Oxidation of Isobutylene to Methacroleinand Methacrylic Acid at SuperatmosphericPressure in the Presence of a Catalyst ofYNi.sub.2.5 Co.sub.4.5 Fe.sub.3 BiMo.sub.12 O.sub.x Results, % Temp., Conver- Select-Example Catalyst, Y= .degree.C. MA MAA Total sion ivity__________________________________________________________________________ 9 Cr.sub.0.5 Cs.sub.0.5 371 58.9 2.9 61.8 81.7 75.610 Ge.sub.0.5 Cs.sub.0.5 371 68.4 5.6 74.0 96.5 76.711 Mn.sub.0.5 Cs.sub.0.1 343 64.5 4.8 69.3 99.6 69.512 Th.sub.0.5 Cs.sub.0.5 343 61.5 3.5 65.0 89.0 73.013 Ce.sub.0.5 Cs.sub.0.2 363 70.3 6.4 76.7 98.9 77.6__________________________________________________________________________

EXAMPLE 14--Preparation of acrolein

In the same manner as shown in the examples above, acrolein and acrolein and acrylic acid were prepared from propylene. The catalyst was 80% Ge.sub.0.5 K.sub.0.1 Ni.sub.2.5 Co.sub.4.5 Fe.sub.3 BiMo.sub.12 O.sub.x +20% SiO.sub.2. The catalyst was heat treated at 550.degree. C. for 16 hours. Five cc. of the catayst was employed, the reaction temperature was 350.degree. C. and the apparent contact time was 2.5 seconds. The feed of propylene/air/steam was 1/11/4. The single pass yield of acrolein was 84.8%, the single pass yield to acrylic acid was 5.2%, the conversion of the propylene was 93.0% and the selectivity to acrolein and acrylic acid was 96.8%.

EXAMPLES 15 TO 20--Oxidation of propylene at atmospheric pressure

These catalysts were prepared in the same manner as described in Example 1, except praseodymium dioxide was replaced by the following compounds in the amounts below:

______________________________________X= Compound Amount, g.______________________________________La.sub.0.5 lanthanum nitrate 6.22Y.sub.0.5 yttrium nitrate 5.48Ru.sub.0.5 ruthenium chloride 3.11Ga.sub.0.5 gallium nitrate 6.27In.sub.0.5 indium nitrate 5.86Zr.sub.0.5 zirconium chlorate 4.84______________________________________

In a fixed-bed reactor, constructed of a 0.75 cm. inside diameter stainless steel tube, was placed 5 cc. of each of the catalysts prepared above. These catalysts were reacted at a reaction temperature of 330.degree. C. using a feed of propylene/air/steam of 1/10/4 and an apparent contact time of 3.3 seconds. The results of these experiments are given in Table 3.

Table 3__________________________________________________________________________Oxidation of Propylene to AcroleinAnd Acrylic Acid at Atmospheric PressureIn the Presence of a Catalyst ofX K.sub.0.1 Ni.sub.2.5 Co.sub.4.5 Fe.sub.3 BiMo.sub.12 O.sub.x Results, %Example Catalyst, X= Acrolein Acrylic Acid ACR + AA Conversion__________________________________________________________________________15 La.sub.0.5 79.9 10.8 90.7 99.016 Y.sub.0.5 83.6 6.2 89.8 96.917 Ru.sub.0.5 82.5 4.1 86.6 94.918 Ga.sub.0.5 81.5 10.5 92.0 98.819 In.sub.0.5 81.7 7.2 88.9 94.620 Zr.sub.0.5 70.1 4.1 74.2 81.6__________________________________________________________________________

In the same manner described above, these catalysts may be effectively utilized in the oxidation of isobutylene to methacrolein and methacrylic acid.

Claims

1. In the process for the preparation of unsaturated aldehydes and acids from propylene or isobutylene by the vapor phase oxidation of propylene or isobutylene with molecular oxygen at a temperature of about 200.degree. to 600.degree. C. in the presence of a catalyst, the improvement comprising using as the catalyst a catalyst of the formula

X.sub.a A.sub.b D.sub.c E.sub.d Fe.sub.f Bi.sub.g Mo.sub.12 O.sub.x

wherein

X is at least one element selected from the group consisting of Y, Ru, Ga, and Zr;

A is at least one element selected from the group consisting of an alkali metal and Tl;

D is at least one element selected from the group consisting of Ni, Co, Mg, Zn, Cd, Ca, and Sr;

E is at least one element selected from the group consisting of P, As, B, S, and Al;

and wherein

a is less than 5.0 excluding 0;

b is a positive number less than or equal to 4; d is a number from 0 to 4; 0-4;

c, f and g are numbers from 0.1-12; and

x is the number of oxygens required to satisfy the valence requirements of the other elements present.

2. The process of claim 1 wherein X is yttrium.

3. The process of claim 1 wherein X is ruthenium.

4. The process of claim 1 wherein X is gallium.

5. The process of claim 1 wherein X is zirconium.

6. The process of claim 1 wherein A is potassium.

7. The process of claim 1 wherein methacrolein and methacrylic acid are prepared from isobutylene.

8. The process of claim 1 wherein acrolein and acrylic acid are prepared from propylene.

9. The process of claim 1 wherein D is at least one element selected from nickel and cobalt.

10. The process of claim 1 wherein A is at least one element selected from the group consisting of potassium, rubidium and cesium.