Claims
- 1. In a process for the production of dental compositions by the photopolymerization of at least one vinyl monomer in the presence of a photoinitiator, the improvement comprising polymerizing said at least one vinyl monomer in the presence of a photoinitiator comprising:
- (a) at least one photosensitizer of the formula ##STR12## wherein X is selected from the group consisting of CO, C(R.sup.1)(R.sup.2) and C(R.sup.3)(OR.sup.4), wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4 are each selected from the group consisting of hydrogen and a hydrocarbon radical;
- n is 0 or 1; and
- A is selected from hydrocarbon radicals which may be substituted and which may be bonded together with the proviso that when n is 1 and X is C(R.sup.1)(R.sup.2), and when n is 0, A is an aromatic radical; and
- (b) at least one reducing agent having the formula ##STR13## wherein R.sup.5 is selected from the group consisting of alkyl, substituted alkyl, aryl, substituted aryl, aralkyl and substituted aralkyl.
- 2. The process of claim 1 wherein R.sup.5 is an alkyl group having 1-5 carbon atoms or a substituted alkyl group wherein the alkyl radical has 1-5 carbon atoms.
- 3. The process of claim 1 wherein R.sup.5 is phenyl.
- 4. The process of claim 1 wherein R.sup.5 is benzyl.
- 5. The process of claim 1 wherein R.sup.5 is substituted alkyl and the substituents are selected from the group consisting of acyl, acyloxy, alkoxysulfonyl and aryloxysulfonyl.
- 6. The process of claim 1 wherein R.sup.5 is substituted aryl and the substituents are selected from the group consisting of alkyl, acyl, acyloxy, alkoxysulfonyl and aryloxysulfonyl.
- 7. The process of claim 1 wherein R.sup.5 is substituted aralkyl and the substituents are selected from the group consisting of alkyl, acyl, acyloxy, alkoxysulfonyl and aryloxysulfonyl.
- 8. The process of claim 1 wherein the amount of each of the photosensitizer and the reducing agent is 10.sup.-2 to 10% by weight.
- 9. The process of claim 8 wherein the photosensitizer is camphorquinone.
- 10. The process of claim 1 wherein the photosensitizer is camphorquinone.
- 11. The process of claim 1 wherein the reducing agent is selected from the group consisting of benzylmeldrum acid and phenylmeldrum acid.
- 12. A photopolymerizable dental material comprising at least one vinyl monomer and a photoinitiator comprising:
- (a) at least one photosensitizer of the formula ##STR14## wherein X is selected from the group consisting of CO, C(R.sup.1)(R.sup.2) and C(R.sup.3)(OR.sup.4), wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4 are each selected from the group consisting of hydrogen and a hydrocarbon radical;
- n is 0 or 1; and
- A is selected from hydrocarbon radicals which may be substituted and which may be bonded together with the proviso that when n is 1 and X is C(R.sup.1)(R.sup.2), and when n is 0, A is an aromatic radical; and
- (b) at least one reducing agent having the formula ##STR15## wherein R.sup.5 is selected from the group consisting of alkyl, substituted alkyl, aryl, substituted aryl, aralkyl and substituted aralkyl.
- 13. In a process for the production of dental compositions by the photopolymerization of at least one vinyl monomer in the presence of a photoinitiator, the improvement comprising polymerizing said at least one vinyl monomer in the presence of a photoinitiator comprising:
- (a) at least one photosensitizer of the formula ##STR16## wherein X is selected from the group consisting of CO, C(R.sup.1)(R.sup.2) and C(R.sup.3)(OR.sup.4), wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4 are each selected from the group consisting of hydrogen and a hydrocarbon radical;
- n is 0 or 1; and
- A is selected from hydrocarbon radicals which may be substituted and which may be bonded together with the proviso that when n is 1 and X is C(R.sup.1 (R.sup.2), and when n is 0, A is an aromatic radical; and
- (b) a reducing agent having the formula ##STR17##
- 14. The process of claim 13 wherein said photosenitizer is camphorquinone.
- 15. The process of claim 13 wherein the amount of the photosensitizer is 10.sup.-2 to 10% by weight.
- 16. The process of claim 13 wherein the amount of the reducing agent is 10.sup.-2 to 10% by weight.
- 17. The process of claim 13 wherein said photosensitizer is camphorquinone, the amount of each of said photosensitizer and said reducing agent being 10.sup.-2 to 10% by weight.
- 18. A photopolymerizable dental material comprising at least one vinyl monomer and a photoinitiator comprising
- (a) at least one photosensitizer of the formula ##STR18## wherein X is selected from the group consisting of CO, C(R.sup.1)(R.sup.2) and C(R.sup.3)(OR.sup.4); wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4 are each selected from the group consisting of hydrogen and a hydrocarbon radical;
- n is 0 or 1; and
- A is selected from hydrocarbon radicals which may be substituted and which may be bonded together with the proviso that when n is 1 and X is C(R.sup.1)(R.sup.2), and when n is 0, A is an aromatic radical; and
- (b) a reducing agent having the formula ##STR19##
- 19. The process of claim 9 wherein R.sup.5 is ethyl.
Priority Claims (1)
Number |
Date |
Country |
Kind |
3136484 |
Sep 1981 |
DEX |
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Parent Case Info
This application is a continuation-in-part of Ser. No. 413,804, filed Sept. 1, 1982, now U.S. Pat. No. 4,534,839.
US Referenced Citations (7)
Foreign Referenced Citations (3)
Number |
Date |
Country |
2403211 |
Jan 1974 |
DEX |
3136484 |
Apr 1983 |
DEX |
124594 |
Oct 1978 |
JPX |
Non-Patent Literature Citations (2)
Entry |
Brederick et al., "About CH-Active Polymerization Initiators" Macromolecular Chemie 92, 70-90, 1966. |
Roffey, "Photopolymerization . . . " Wiley & Sons, 1982, pp. 70-72, 85-88. |
Continuation in Parts (1)
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Number |
Date |
Country |
Parent |
413804 |
Sep 1982 |
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